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Till to date, the application of sulfur-doped graphitic carbon nitride supported transition metal carbide interface for electrochemical sensor fabrication was less explored. In this work, we designed a simple synthesis of molybdenum carbide sphere embedded sulfur doped graphitic carbon nitride (Mo2C/SCN) catalyst for the nanomolar electrochemical sensor application. The synthesized Mo2C/SCN nanocatalyst was systematically characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM) with elemental mapping. The SEM images show that the porous SCN network adhered uniformly on Mo2C, causing a loss of crystallinity in the diffractogram. The corresponding elemental mapping of Mo2C/SCN shows distinct peaks for carbon (41.47%), nitrogen (32.54%), sulfur (1.37%), and molybdenum (24.62%) with no additional impurity peaks, reflecting the successful synthesis. Later, the glassy carbon electrode (GCE) was modified by Mo2C/SCN nanocatalyst for simultaneous sensing of uric acid (UA) and folic acid (FA). The fabricated Mo2C/SCN/GCE is capable of simultaneous and interference free electrochemical detection of UA and FA in a binary mixture. The limit of detection (LOD) calculated at Mo2C/SCN/GCE for UA and FA was 21.5 nM (0.09 – 47.0 μM) and 14.7 nM (0.09 – 167.25 μM) respectively by differential pulse voltammetric (DPV) technique. The presence of interferons has no significant effect on the sensor’s performance, making it suitable for real sample analysis. The present method can be extended to fabricate an electrochemical sensor for various molecules.

Abstract The modified electrode–analyte interaction is critical in establishing the sensing mechanism and in developing an electrochemical sensor. Here, the niacin-modified carbon paste electrode (NC/CPE) was fabricated for electrochemical sensing applications. The two stable structures of the niacin were optimized and confirmed by the absence of negative vibrational frequency, at B3LYP and B3LYP-GD3BJ level and 6–311 g** basis set. The physical and quantum chemical quantities were used to explain the molecular stability and electronic structure-related properties of the niacin. The natural bond orbital (NBO) analysis was performed to disclose the donor–acceptor interactions that were a critical role in explaining the modifier–analyte interaction. The fabricated NC/CPE was used for the determination of folic acid (FA) in physiological pH by cyclic voltammetry (CV) method. The limit of detection (LOD) for FA at NC/CPE was calculated to be 0.09 µM in the linear concentration range of 5.0 µM to 45.0 µM (0.2 M PBS, pH 7.4) by CV technique. The analytical applicability of the NC/CPE was evaluated in real samples, such as fruit juice and pharmaceutical sample, and the obtained results were acceptable. The HOMO and LUMO densities are used to identify the nucleophilic and electrophilic regions of niacin. The use of density functional theory-based quantum chemical simulations to understand the sensory performance of the modifier has laid a new foundation for fabricating electrochemical sensing platforms.

This study presents a transparent and soft haptic actuator based on an electroactive polymer designed to create abundant haptic sensations in flexible/deformable next-generation devices and to convey them to users. The haptic sensations are created in the form of vibrations and vary depending on the amplitude and frequency of the vibrations. The haptic actuator consists of a transparent and soft dielectric layer and two transparent and soft ionic conductive layers. The dielectric layer is sandwiched between the two ionic conductive layers, and is compressed in the thickness direction when an electric field is applied to the two ionic conductive layers. When the applied electric field is removed, the proposed haptic actuators are rapidly restored to their initial configuration. Owing to this effect, the actuator can easily create vibrations that are sufficiently strong for human perception. In this study, three different dielectric elastomers (silicone rubber, poly urethane, and acrylic polymer) are used for the dielectric layer. Experiments are conducted to investigate the haptic performance of the proposed soft vibrotactile actuators using an accelerometer. In the case of the silicone rubber-based actuator, the measured acceleration at the resonant frequency (80 Hz) is 1.408 g (g = 9.8m/s2) and the response time is approximately 2.8 ms. Furthermore, the perceived intensity of the stimuli generated by the proposed actuator is verified by perceptual experiments. The results indicate that the proposed actuator can selectively stimulate human mechanoreceptors with sufficient perceptual strength.

This paper presents an electroactive and soft vibrotactile actuator based on a dielectric elastomer. The vibrotactile actuator is composed of an upper layer, an adhesive tape layer, a dielectric layer with bumps, and a lower layer. When a voltage is applied to the actuator, an electrostatic force created between the upper and lower layers pulls the upper layer down, compressing the dielectric layer. As soon as the applied voltage is released, the upper layer is quickly restored to its initial state by the elastic force of the compressed dielectric elastomer. Because two forces contribute to the actuation at the same time, the created vibration is sufficiently strong to stimulate human mechanoreceptors. When the applied voltage is removed, the upper layer and dielectric elastomer return to their initial shapes. We conducted experiments to determine the best weight ratio of polydimethylsiloxane (PDMS) and Ecoflex, and to quantitatively investigate the haptic performance of the proposed vibrotactile actuator. The experiments clearly show that the plasticized vibrotactile actuator can create a variety of haptic sensations over a wide frequency range.

Abstract This paper presents a bio-inspired adaptive micro-lens with electrically tunable focus made of non-ionic high-molecular-weight polyvinyl chloride (PVC) gel. The optical device mimics the design of the crystalline lens and ciliary muscle of the human eye. It consists of a plano-convex PVC gel micro-lens on Indium Tin Oxide (ITO) glass, confined with an annular electrode operating as an artificial ciliary muscle. Upon electrical activation, the electroactive adhesive force of the PVC gel is exerted on the annular anode electrode, which reduces the sagittal height of the plano-convex PVC gel lens, resulting in focal length variation of the micro-lens. The focal length increases from 3.8 mm to 22.3 mm as the applied field is varied from 200 V/mm to 800 V/mm, comparable to that of the human lens. The device combines excellent optical characteristics with structural simplicity, fast response speed, silent operation, and low power consumption. The results show the PVC gel micro-lens is expected to open up new perspectives on practical tunable optics.

Metallic nanostructures (MNs) and metal-organic frameworks (MOFs) play a pivotal role by articulating their significance in high-performance supercapacitors along with conducting polymers (CPs). The interaction and synergistic pseudocapacitive effect of MNs with CPs have contributed to enhance the specific capacitance and cyclic stability. Among various conjugated heterocyclic CPs, polypyrrole (PPy) (prevalently knows as “synthetic metal”) is exclusively studied because of its excellent physicochemical properties, ease of preparation, flexibility in surface modifications, and unique molecular structure–property relationships. Numerous researchers attempted to improve the low electronic conductivity of MNs and MOFs, by incorporating conducting PPy and/or used decoration strategy. This was succeeded by fine-tuning this objective, which managed to get outstanding supercapacitive performances. This brief technical note epitomizes various PPy-based metallic hybrid materials with different nano-architectures, emphasizing its technical implications in fabricating high-performance electrode material for supercapacitor applications.

Bio-inspiration relentlessly sparks the novel ideas to develop innovative soft robotic structures from smart materials. The conceptual soft robotic designs inspired by biomimetic routes have resulted in pioneering research contributions based on the understanding of the material selection and actuation properties. In an attempt to overcome the hazardous injuries, soft robotic systems are used subsequently to ensure safe human–robot interaction. In contrast to dielectric elastomer actuators, prolific efforts were made by understanding the photo-actuating properties of liquid crystalline elastomers (LCEs) containing azo-derivatives to construct mechanical structures and tiny portable robots for specific technological applications. The structure and material properties of these stimuli-responsive polymers can skillfully be controlled by light. In this short technical note, we highlight the potential high-tech importance and the photo-actuation behavior of some remarkable LCEs with azobenzene chromophores.

In this paper, we propose a tiny haptic knob that creates torque feedback in consumer electronic devices. To develop the proposed haptic knob, we use a magnetorheological (MR) fluid. When an input current is applied to a solenoid coil, a magnetic field causes a change in the MR fluid’s viscosity. This change allows the proposed haptic knob to generate a resistive torque. We optimize the structure of the haptic knob, in which two operating modes of MR fluids contribute to the actuation simultaneously. We conduct magnetic path simulation and resistive torque simulation using the finite element method and perform experiments to measure the resistive torque and its torque rate according to the rotational speed and applied current. The results show that the proposed haptic knob generates sufficient torque feedback to stimulate users and creates a variety of haptic sensations.

In mobile devices, the screen size limits conveyance of immersive experiences; haptic feedback coupled with visual feedback is expected to have a better effect to maximize the level of immersion. Therefore, this paper presents a miniature tunable haptic stylus based on magnetorheological (MR) fluids to provide kinesthetic information to users. The designed stylus has a force generation, force transmission, and housing part; moreover, in the stylus, all three operating modes of MR fluids contribute to the haptic actuation to produce a wide range of resistive force generated by MR fluids in a limited size, thereby providing a variety of pressing sensations to users. A universal testing machine was constructed to evaluate haptic performance of the proposed haptic stylus, whose resistive force was measured with the constructed setup as a function of pressed depth and input current, and by varying the pressed depth and pressing speed. Under maximum input voltage, the stylus generates a wide range of resistive force from 2.33 N to 27.47 N, whereas under maximum pressed depth it varied from 1.08 N to 27.47 N with a corresponding change in voltage input from 0 V to 3.3 V. Therefore, the proposed haptic stylus can create varied haptic sensations.

The most important thing in a thin and soft haptic module with an electroactive polymer actuator array is to increase its vibrotactile amplitude and to create a variety of vibrotactile sensations. In this paper, we introduce a thin film-type electroactive polymer actuator array capable of stimulating two types of human mechanoreceptors simultaneously, and we present a haptic rendering method that maximizes the actuators’ vibrational force without improving the array’s haptic performance. The increase in vibrational amplitude of the soft electroactive polymer actuator array is achieved by creating a beat vibration, which is an interference pattern of two vibrations with slightly different frequencies. The textures of a target object are translated into haptic stimuli using the proposed method. We conducted qualitative and quantitative experiments to evaluate the performance of the proposed rendering method. The results showed that this method not only amplifies the vibration’s amplitude but also haptically simulates various objects’ surfaces.