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Photo‐rechargeable zinc‐ion batteries (PRZIBs) have attracted much attention in the field of energy storage due to their high safety and dexterity compared with currently integrated lithium‐ion batteries and solar cells. However, challenges remain toward their practical applications, originating from the unsatisfactory structural design of photocathodes, which results in low photoelectric conversion efficiency (PCE). Herein, a flexible MoS2/SnO2‐based photocathode is developed via constructing a sunflower‐shaped light‐trapping nanostructure with 3D hierarchical and self‐supporting properties, enabled by the hierarchical embellishment of MoS2 nanosheets and SnO2 quantum dots on carbon cloth (MoS2/SnO2 QDs@CC). This structural design provides a favorable pathway for the effective separation of photogenerated electron‐hole pairs and the efficient storage of Zn2+ on photocathodes. Consequently, the PRZIB assembled with MoS2/SnO2 QDs@CC delivers a desirable capacity of 366 mAh g−1 under a light intensity of 100 mW cm−2, and achieves an ultra‐high PCE of 2.7% at a current density of 0.125 mA cm−2. In practice, an integrated battery system consisting of four series‐connected quasi‐solid‐state PRZIBs is successfully applied as a wearable wristband of smartwatches, which opens a new door for the application of PRZIBs in next‐generation flexible energy storage devices. [ABSTRACT FROM AUTHOR]

As a visible-light response semiconductor materials, bismuth vanadate (BiVO4) is extensively applied in photodegradation organic dye field. In this study, we synthesized C3N5 nanosheets and coupled with decahedral BiVO4 to construct a Z-scheme C3N5/BiVO4 heterostructure with close interface contact. By introducing C3N5 into BiVO4, the built Z-scheme transfer pathway provides silky channel for charge carrier migration between different moieties and enables photoexcited electrons and holes accumulated on the surface of BiVO4 and C3N5. The accelerated separation of charge carriers ensures C3N5/BiVO4 heterostructures with a powerful oxidation capacity compared with pure BiVO4. Due to the synergistic effect in Z-scheme heterostructure, the C3N5/BiVO4 demonstrated an improved photodegradation ability of rhodamine B (RhB) and methylene blue (MB) that of bare BiVO4. [ABSTRACT FROM AUTHOR]

The effective utilization of the local surface plasmon resonance (LSPR) effect of metal nanoparticles to improve optical absorption capacity and inject hot electrons into photocatalysts opens up new directions and ideas to solve the problem of solar energy utilization efficiency of photocatalysts. In this study, we created an in situ technique for preparing plasmon Ag nanoparticles (NPs) decorated with a covalent organic framework (COF), named Ag/TpPa-1-COF. The LSPR effect of Ag NPs results in an outstanding rate of H2 production that is 801.4 μmol g−1 h−1 for the 3% Ag/TpPa-1 photocatalyst, which is almost 4 times as effective as that of the unmodified TpPa-1-COF. Moreover, finite-difference time-domain (FDTD) simulation results reveal that the strongest electric field intensity is presented when the catalyst is excited at λ = 465 nm. Furthermore, plasmonic "hot spots" induced by the interfacial electric field enhancement factor distribution of Ag/TpPa-1 were simulated in detail by adjusting the number, particle size, and gap distance of Ag NPs. Additionally, density functional theory (DFT) calculations show that electron transfer from Ag NPs to TpPa-1 occurs at the Ag/TpPa-1 interface, and N sites in Ag/TpPa-1 exhibit low Gibbs free energy (ΔGH*) for enhanced photocatalytic H2 evolution. Overall, this research provides new insights into the plasmonic "hot spot" region that performs effectively for hydrogen evolution. [ABSTRACT FROM AUTHOR]

A dispersion containing black TiO2 photocatalyst was prepared and sprayed onto the concrete's surface to achieve a black TiO2-based photocatalytic concrete paving eco-block, and its photocatalytic NO removal ratio is approximately 1.7 times as high as that of a white TiO2-based eco-block, resulting from the enhanced optical absorption intensity, abundant oxygen vacancies, and highly produced superoxide anion radicals (˙O2−) of black TiO2. Moreover, the black TiO2-based concrete paving eco-block exhibits significantly enhanced compressive strength and abrasion resistance when using water-glass as a binder, which could satisfy the demand for practical application. Furthermore, in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) was performed to dynamically track the reactive products and intermediates across the surface of the B-TiO2 photocatalyst in a time sequence to investigate the reaction mechanism. It has been demonstrated that almost no harmful by-products were produced when NO was removed via photocatalysis, and the applicability of the as-prepared eco-blocks was evaluated considering the effects of various reaction conditions. Additionally, a computational fluid dynamics (CFD) model for solar-driven photocatalytic abatement of atmospheric NO in a realistic urban street coating with black TiO2-based photocatalytic concrete paving eco-blocks was constructed and simulated to assess the real-world applicability of the developed approach. Overall, this research may offer fresh perspectives on how to create ecologically acceptable photocatalytic products for the removal of air pollutants using solar light. [ABSTRACT FROM AUTHOR]

Highly ordered TiO2 nanotube (TiO2 NT) arrays were prepared by anodic oxidizing method on the surface of the Ti substrate. Nitrogen-doped TiO2 nanotube (N-TiO2 NT) arrays were carried out by ammonia solution immersion, and Ag nanoparticles loaded N-doped TiO2 nanotube (Ag/N-TiO2 NT) arrays were obtained by successive ionic layer adsorption and reaction (SILAR) technique. The samples were characterized by the X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM), photoluminescence (PL) emission spectra, ultraviolet–visible (UV–vis) diffuse reflectance spectroscopy (DRS). The result indicated that the diameter and wall thickness of the TiO2 NT are 100–120 and 20–30 nm, respectively. Moreover, the morphology and structure of the highly ordered TiO2 NTs were not affected by N-doping. Furthermore, Ag nanoparticles were evenly deposited on the surface of TiO2 NTs in the form of elemental silver. Finally, the photocatalytic activity of Ag/N-TiO2 NTs was evaluated by degradation of methyl orange (MO) under visible-light irradiation. The Ag/N-TiO2 NTs exhibited enhanced photocatalytic properties, which could reach 95% after 90-min irradiation.