1. Effect of Grain Coalescence on Dislocation and Stress Evolution of GaN Films Grown on Nanoscale Patterned Sapphire Substrates
- Author
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Pan, Zuojian, Chen, Zhizhong, Chen, Yiyong, Zhang, Haodong, Yang, Han, Nie, Jingxin, Deng, Chuhan, Dong, Boyan, Wang, Daqi, Li, Yuchen, Chen, Weihua, Jiao, Fei, Kang, Xiangning, Jia, Chuanyu, Liang, Zhiwen, Wang, Qi, Zhang, Guoyi, and Shen, Bo
- Subjects
Condensed Matter - Materials Science - Abstract
Two types of nucleation layers (NLs), including in-situ low-temperature grown GaN (LT-GaN) and ex-situ sputtered physical vapor deposition AlN (PVD-AlN), are applied on cone-shaped nanoscale patterned sapphire substrate (NPSS). The initial growth process of GaN on these two NLs is comparably investigated by a series of growth interruptions. The coalescence process of GaN grains is modulated by adjusting the three-dimensional (3D) temperatures. The results indicate that higher 3D temperatures reduce the edge dislocation density while increasing the residual compressive stress in GaN films. Compared to the LT-GaN NLs, the PVD-AlN NLs effectively resist Ostwald ripening and facilitate the uniform growth of GaN grains on NPSS. Furthermore, GaN films grown on NPSS with PVD-AlN NLs exhibit a reduction of over 50% in both screw and edge dislocation densities compared to those grown on LT-GaN NLs. Additionally, PVD-AlN NLs result in an increase of about 0.5 GPa in the residual compressive stress observed in GaN films.
- Published
- 2023
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