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This study aims to achieve in situ-formed pure Ti and Ti6Al4V coatings on 316L stainless steel through hot pressing and examine their wear and corrosion properties thoroughly in two simulated body fluids: physiological serum (0.9% NaCl) and Hanks' solution. The sintering and diffusion bonding process was conducted at 1050 °C under a uniaxial pressure of 40 MPa for 30 min in a vacuum environment of 10−4 mbar. Following sintering, in situ-formed pure Ti and Ti6Al4V coatings, approximately 1000 µm thick, were produced on 316L substrates approximately 3000 µm in thickness. The mean hardness of 316L substrates, pure Ti, and Ti6Al4V coatings are around 165 HV, 170 HV, and 420 HV, respectively. The interface of the stainless steel substrate and the pure Ti and Ti6Al4V coatings exhibited no microstructural defects, while the interface exhibited significantly higher hardness values (ranging from 600 to 700 HV). The coatings improved corrosion resistance in both electrolytes compared to the 316L substrate. Wet wear tests revealed reduced friction coefficients in 0.9% NaCl relative to Hanks' solution, highlighting the chemical interactions between the material surface and the electrolyte type and the significance of tribocorrosion in biocoatings. [ABSTRACT FROM AUTHOR]

Plasma electrolytic oxidation (PEO) is often used to improve the physical and mechanical properties of valve metals. This method allows for the formation of thicker and denser metal oxide coatings, which helps to improve physical and mechanical properties, especially the wear and corrosion resistance of the surface. The PEO process is widely used in areas such as mechanical engineering, aerospace, biomedical, and others. This review aims to summarize and explain the fundamental principles of the PEO process, with a focus on the influence of waveform types and their parameters on the properties of PEO coatings. This study found that a sinusoidal waveform promotes the generation of more stable discharges compared to a rectangular waveform, thereby enhancing the corrosion resistance of the coatings. Furthermore, it was demonstrated that using a rectangular waveform with adjustable parameters enables the production of thicker and more wear-resistant coatings. Meanwhile, the application of sawtooth and trapezoidal waveforms reduces sharp current spikes during the onset of discharges, minimizing defect formation and positively influencing the coating formation process. In addition, bipolar and unipolar modes are analyzed, and the promising future directions are discussed. [ABSTRACT FROM AUTHOR]

In this article, the process of creating calcium phosphate coatings through plasma electrolytic oxidation was investigated. Calcium phosphate coatings were deposited onto titanium substrates fabricated via the selective laser melting (SLM) method. The correlation between the characteristics of the coating and the applied voltage (200, 250, and 300 V) of PEO was studied. The surface morphology analysis indicates that an increase in applied voltage results in a larger pore size. It was discovered that, when a voltage of 300 V was applied, a layer of hydroxyapatite formed. However, at 300 V, the coating cracked, producing a significantly rough surface. Our analysis of the elemental composition of sample cross sections indicates the presence of TiO2 layers that are enriched with calcium (Ca) and phosphorus (P). The coefficient of friction and wear rate are primarily influenced by the morphology, pore size, and density of the titanium dioxide layer. Furthermore, a rise in the quantity of the beta phase of the titanium on the surface can be noticed as the applied voltage increases. As a result, it also affects the mechanical and tribological characteristics of the coating. The sample treated to a voltage of 250 V demonstrates a higher resistance to wear and a lower elastic modulus in comparison to the other two coatings. [ABSTRACT FROM AUTHOR]

Orthopaedic surgery is becoming increasingly common due to recent significant improvements in medical imaging, biomechanical modelling, and additive manufacturing. For the pelvis, surgical reconstruction using metal implants remains challenging due to the involvement of complex anatomical structures. In Kazakhstan, these operations are performed using typical implants. The purpose of the present work is to develop a spersonalised implant and its real application to work out the procedure and master the technology. This article describes all the relevant stages, from medical imaging to an accurate three-dimensional anatomical model of the implant. This described procedure can also be fundamental for virtual preoperative planning and the development of patient-specific incision guides. [ABSTRACT FROM AUTHOR]