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In modern economic and industrial realities, agricultural lands are often located next to industrial areas, which leads to soil contamination and, as a result, agricultural products with pollutants. Pollution of soils and plants by several pollutants of various nature has acquired huge proportions. There is a threat of migration of dangerous ecotoxicants, including heavy metals and benz[a]pyrene, one of the main persistent compounds, a marker of PAH soil contamination, along trophic chains that may be dangerous to public health. This study examines the use of various types of mineral sorbents (Tripoli, Brown coal, Diatomite) and mineral sorbents (Biochar, Granular activated coal) to reduce the toxic effects of pollutants on the sources of anthropogenic emissions of heavy metals and polycyclic aromatic hydrocarbons adjacent to the sources. Using scanning electron microscopy, it was found that the sorbents have a high specific surface area. With the help of phytotesting in combined contaminated soils, the optimal dose of sorbent administration was determined at the level of 1% and 2% for various pollution variants. In addition, the analyzed sorbents are ordered by the effect of reducing the phytotoxicity of combined soil pollution. It was found that the introduction of sorbents into contaminated soil contributed to an increase in the morphometric parameters of the test culture - barley (Hordeum sativum distichum), which confirms the effectiveness of the sorption remediation of jointly contaminated soils with heavy metals and benz(a)pyrene.

Heavy metals (HM) are among the most hazardous soil pollutants. The intensity of accumulation and distribution of HM in soils directly depends on the ecological conditions of pedogenesis and its buffering properties. At the same time, a significant accumulation of HM in the soil as a result of anthropogenic impacts reduces the buffering capacity of the soil and its resistance to pollution. The purpose of this work was to assess the buffering capacity of soils to HM pollution in the Don River delta and the coast of the Taganrog Bay of the Sea of Azov undergoing the great anthropogenic impact. The buffer capacity of experimental soils was carried out using the Il’in’s method (1995), based on the calculation of the inactivation ability of soils: organic matter, clay fraction (particle size < 0.01 mm), carbonates, sesquioxides, and pH. The content of HM was compared with soil Clarke and the maximum permissible concentration of HM in soils accepted in the Russian Federation. It was found that the experimental soils could be ordered by buffer capacity value as following (in decreasing order): haplic chernozem ≥ alluvial-meadow light loamy ≥ solonchak > alluvial-meadow sandy and sandy loamy > sandy primitive soil ≥ stratified alluvial soil. Keywords: trace elements, contamination, impact territories