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The Ozone Monitoring Instrument (OMI) was launched on July 15, 2004 on the National Aeronautics and Space Administration's Earth Observing System Aura satellite. The OMI instrument is an ultraviolet-visible imaging spectrograph that uses two-dimensional charge-coupled device detectors to register both the spectrum and the swath perpendicular to the flight direction with a 115[degrees] wide swath, which enables global daily ground coverage with high spatial resolution. This paper presents the OMI design and discusses the main performance and calibration features and results. Index Terms--Calibration, charge coupled device (CCD), remote sensing, ultraviolet spectroscopy.

The paper presents the Simulator for Investigation of Solar Temperature Error of Radiosondes (SISTER), a setup that was developed to quantify the solar heating of the temperature sensor of radiosondes under laboratory conditions by recreating as closely as possible the atmospheric and illumination conditions that are encountered during a daytime radiosounding ascent. SISTER controls the pressure (3 hPa to 1020 hPa) and ventilation speed of the air inside the windtunnel-like setup to simulate the conditions between the surface and 35 km altitude, to determine the dependence of the radiation temperature error on the irradiance and the convective cooling. The radiosonde is mounted inside a quartz tube, while the complete sensor boom is illuminated by an external light source to include the conductive heat transfer between sensor and boom. A special feature of SISTER is that the radiosonde is rotated around its axis to imitate the spinning of the radiosonde in flight. The characterisation of the radiation temperature error is performed for various pressures, ventilation speeds and illumination angles, yielding a 2D-parameterisation of the radiation error for each illumination angle, with an uncertainty smaller than 0.2 K (?? = 2) for typical ascend speeds. This parameterisation is applied in the GRUAN processing for radiosonde data, which relies on the extensive characterisation of the sensor properties to produce a traceable reference data product which is free of manufacturer dependent effects. The GRUAN radiation correction model combines the laboratory characterisation with model calculations of the actual radiation field during the sounding to estimate the correction profile. In the second part of this paper it is described how this procedure was applied in the development of the GRUAN data product for the Vaisala RS41 radiosonde (version 1, RS41-GDP.1). The magnitude of the averaged correction profile increases gradually from 0.1 K at the surface to approximately 0.8 K at 35 km altitude. Comparison between sounding data (?? = 154) that were GRUAN-processed and Vaisala-processed reveal that the daytime differences are smaller than +0.1 K (GRUAN - Vaisala) in the troposphere and increase above the tropopause steadily with altitude to +0.35 K (GRUAN - Vaisala) at 35 km. These differences are just within the limits of the combined uncertainties (with coverage factor ?? = 2) of both data products, meaning that the GRUAN processing and the Vaisala processing are in agreement. [ABSTRACT FROM AUTHOR]

This paper describes the GRUAN-wide approach to manage the transition from the Vaisala RS92 to the Vaisala RS41 as the operational radiosonde. The goal of the GCOS Reference Upper-Air Network (GRUAN) is to provide long-term high-quality reference observations of upper air Essential Climate Variables (ECVs) such as temperature and water vapor. With GRUAN data being used for climate monitoring, it is vital that the change of measurement system does not introduce inhomogeneities in to the data record. The majority of the 27 GRUAN sites were launching the RS92 as their operational radiosonde, and following the end of production of the RS92 in the last quarter of 2017, most of these sites have now switched to the RS41. Such a large-scale change in instrumentation is unprecedented in the history of GRUAN and poses a challenge for the network. Several measurement programmes have been initiated to characterize differences in biases, uncertainties and noise between the two radiosonde types. These include laboratory characterization of measurement errors, extensive twin sounding studies with RS92 and RS41 on the same balloon, and comparison with ancillary data. This integrated approach is commensurate with the GRUAN principles of traceability and deliberate redundancy. A two-year period of regular twin soundings is recommended, and for sites that are not able to implement this burden sharing is employed, such that measurements at a certain site are considered representative of other sites with similar climatological characteristics. All data relevant to the RS92-RS41 transition are archived in a database that will be accessible to the scientific community for external scrutiny. Furthermore, the knowledge and experience gained about GRUAN's RS92-RS41 transition will be extensively documented to ensure traceability of the process. This documentation will benefit other networks in managing changes in their operational radiosonde systems. Preliminary analysis of the laboratory experiments indicates that the manufacturer's calibration of the RS41's temperature and humidity sensors is more accurate than for the RS92; with uncertainties of < 0.1 K for the temperature and < 1 % RH for the humidity sensor. A first analysis of 224 RS92-RS41 twin soundings at Lindenberg Observatory show nighttime temperature differences < 0.1 K. However, daytime temperature differences in the stratosphere increase steadily with altitude, with TRS92-GDP.2 up to 0.6 K higher than TRS41 at 35 km. RHRS41 values are up to 8 % higher, which is consistent with the analysis of satellite-radiosonde collocations. [ABSTRACT FROM AUTHOR]

We have performed molecular beam scattering experiments of O2, N2, and Ar from the Ag(111) surface in the translational energy regime from 0.2 to 2.6 eV and at surface temperatures of 600 and 150 K. The experiments were carried out to probe the repulsive part in the particle–surface interaction potential. It is shown that the scattering dynamics of the systems N2–Ag(111) and Ar–Ag(111) is characteristic of physisorption systems. The scattering data for the system O2–Ag(111) shows that both the physisorption and chemisorption part of the interaction potential are probed in the experiment. For ‘‘normal incidence energies’’ exceeding a threshold energy, the barrier to the chemisorption part of the interaction potential can be crossed. An upper limit for this threshold is Ei cos2 θi=0.3 eV. Although the chemisorption region is probed, the (dissociative and nondissociative) chemisorption probability remains negligible. © 1995 American Institute of Physics. [ABSTRACT FROM AUTHOR]