Search

Quantum coherence as an asymmetry relative to a translation group generated by a Hermitian operator, is a necessary resource for the quantum parameter estimation. On the other hand, the sensitivity of the parameter estimation is known to be related to the imaginary part of the weak value of the Hermitian operator generating the unitary imprinting of the parameter being estimated. This naturally suggests a question if one can use the imaginary part of the weak value to characterize the coherence as asymmetry. In this work, we show that the average absolute imaginary part of the weak value of the generator of the translation group, maximized over all possible projective measurement bases, can be used to quantify the coherence as asymmetry relative to the translation group, satisfying certain desirable requirements. We argue that the quantifier of coherence so defined, called TC (translationally-covariant) w-coherence, can be obtained experimentally using a hybrid quantum-classical circuit via the estimation of weak value combined with a classical optimization procedure. We obtain upper bounds of the TC w-coherence in terms of the quantum standard deviation, quantum Fisher information, and the imaginary part of the Kirkwood-Dirac quasiprobability. We further obtain a lower bound and derive a relation between the TC w-coherences relative to two generators of translation group taking a form analogous to the Kennard-Weyl-Robertson uncertainty relation., Comment: 31 pages, no figures

Kirkwood-Dirac (KD) quasiprobability is a quantum analog of phase space probability of classical statistical mechanics, allowing negative or/and nonreal values. It gives an informationally complete representation of a quantum state. Recent works have revealed the important roles played by the KD quasiprobability in the broad fields of quantum science and quantum technology. In the present work, we use the KD quasiprobability to access the quantum coherence in a quantum state. We show that the $l_1$-norm of the imaginary part of the KD quasiprobability over an incoherent reference basis and a second basis, maximized over all possible choices of the latter, can be used to quantify quantum coherence, satisfying certain desirable properties. It is upper bounded by the quantum uncertainty, i.e., the quantum standard deviation, of the incoherent basis in the state. It gives a lower bound to the $l_1$-norm quantum coherence, and for a single qubit, they are identical. We discuss the measurement of the KD coherence based on the measurement of the KD quasiprobability and an optimization procedure in hybrid quantum-classical schemes, and suggest statistical interpretations. We also discuss its relevance in the physics of linear response regime., Comment: 23 pages, no figures

We propose a characterization and a quantification of general quantum correlation which is exhibited even by a separable (unentangled) mixed bipartite state in terms of the nonclassical values of the associated Kirkwood-Dirac (KD) quasiprobability. Such a general quantum correlation, wherein entanglement is a subset, is not only intriguing from a fundamental point of view, but it has also been recognized as a resource in a variety of schemes of quantum information processing and quantum technology. Given a bipartite state, we construct a quantity based on the imaginary part the associated KD quasiprobability defined over a pair of orthonormal product bases and an optimization procedure over all pairs of such bases. We show that it satisfies certain requirements expected for a quantifier of general quantum correlations. It gives a lower bound to the total sum of the quantum standard deviation of all the elements of the product (local) basis, minimized over all such bases. It suggests an interpretation as the minimum genuine quantum share of uncertainty in all possible local von-Neumann projective measurement. Moreover, it is a faithful witness for entanglement and measurement-induced nonlocality of pure bipartite states. We then discuss a variational scheme for its estimation, and based on this, we offer information theoretical meanings of the general quantum correlation. Our results suggest a deep connection between the general quantum correlation and the nonclassical values of the KD quasiprobability and the associated strange weak values., Comment: 30 pages, major revision from previous version, published version in JPA

We study the Li interstitial diffusion in pristine and defective ZnO bulk by means of first-principles density functional theory (DFT) coupled with Nudged Elastic Band (NEB) calculations. We consider three types of point defects, i.e., oxygen vacancy (Ovac), Zn vacancy (Znvac) and ZnO vacancy pair (ZnOvac-pair) and investigate their individual effect on the energy barrier of Li interstitial diffusion. Our results predict that Ovac and Znvac lower the Li diffusion energy barrier as compared to the pristine ZnO case. However, we further find that Li interstitial on the other hand may possibly be trapped inside the Znvac subsequently forming the LiZn substitutional type of defect. The similar behavior also observed for Li interstitial in the vicinity of Zn-Ovac_pair though with less change of Li diffusion barriers as compared to the other two cases. Our results indicate that among the three considered defects only Ovac shows possible enhancement of the kinetics of Li diffusion inside ZnO bulk.

We devise a classical algorithm which efficiently computes the quantum expectation values arising in a class of continuous variable quantum circuits wherein the final quantum observable | after the Heisenberg evolution associated with the circuits | is at most second order in momentum. The classical computational algorithm exploits a specific epistemic restriction in classical phase space which directly captures the quantum uncertainty relation, to transform the quantum circuits in the complex Hilbert space into classical albeit unconventional stochastic processes in the phase space. The resulting multidimensional integral is then evaluated using the Monte Carlo sampling method. The work shows that for the specific class of computational schemes, Wigner negativity is not a sufficient resource for quantum speedup. It highlights the potential role of the epistemic restriction as an intuitive conceptual tool which may be used to study the boundary between quantum and classical computations.

What does it take for real-deterministic c-valued (i.e., classical, commuting) variables to comply with the Heisenberg uncertainty principle? Here, we construct a class of real-deterministic c-valued variables out of the weak values obtained via a non-perturbing weak measurement of quantum operators with a post-selection over a complete set of state vectors basis, which always satisfies the Kennard-Robertson-Schr\"odinger uncertainty relation. First, we introduce an auxiliary global random variable and couple it to the imaginary part of the weak value to transform the incompatibility between the quantum operator and the basis into the fluctuation of an `error term', and then superimpose it onto the real-part of the weak value. We show that this class of ``c-valued physical quantities'' provides a real-deterministic contextual hidden variable model for the quantum expectation value of a certain class of operators. We then show that the Schr\"odinger and the Kennard-Robertson lower bounds can be obtained separately by imposing the classical uncertainty relation to the c-valued physical quantities associated with a pair of Hermitian operators. Within the representation, the complementarity between two incompatible quantum observables manifests the absence of a basis wherein the error terms of the associated two c-valued physical quantities simultaneously vanish. Furthermore, quantum uncertainty relation is captured by a specific irreducible epistemic restriction, foreign in classical mechanics, constraining the allowed form of the joint distribution of the two c-valued physical quantities. We then suggest an epistemic interpretation of the two terms decomposing the c-valued physical quantity as the optimal estimate under the epistemic restriction and the associated estimation error, and discuss the classical limit.

One of the advantages of a reconstruction of quantum mechanics based on transparent physical axioms is that it may offer insight to naturally generalize quantum mechanics by relaxing the axioms. Here, we discuss possible extensions of quantum mechanics within a general epistemic framework based on an operational scheme of estimation of momentum given positions under epistemic restriction. The epistemic restriction is parameterized by a global-nonseparable random variable on the order of Planck constant, an ontic extension to the separable classical phase space variables. Within the estimation scheme, the canonical quantum laws is reconstructed for a specific estimator and estimation error. In the present work, keeping the Born's quadratic law intact, we construct a class of nonlinear variants of Schr\"odinger equation and generalized Heisenberg uncertainty principle within the estimation scheme by assuming a more general class of estimation errors. The nonlinearity of the Schr\"odinger equation and the deviation from the Heisenberg uncertainty principle thus have a common transparent operational origin in terms of generalizations of estimation errors. We then argue that a broad class of nonlinearities and deviations from Heisenberg uncertainty principle arise from estimation errors violating a plausible inferential-causality principle of estimation independence which is respected by the standard quantum mechanics. This result therefore constrains possible extensions of quantum mechanics, and suggests directions to generalize quantum mechanics which comply with the principle of estimation independence.

The effect of UV light exposure on the properties of 6FDA-ODA polyimide and PI-TiNT composites has been studied using Raman spectroscopy, optical microscopy, nanoidentation and TEM.

The recent development of nanoscale fillers, such as carbon nanotube, graphene, and nanocellulose, allows the functionality of polymer nanocomposites to be controlled and enhanced. However, conventional synthesis methods of polymer nanocomposites cannot maximise the reinforcement of these nanofillers at high filler content. Approaches to the synthesis of high content filler polymer nanocomposites are suggested to facilitate future applications. The fabrication methods address design of the polymer nanocomposite architecture, which encompass one, two, and three dimensional morphology. Factors that hamper the reinforcement of nanostructures, such as alignment, dispersion of filler as well as interfacial bonding between filler and polymer are outlined. Using suitable approaches, maximum potential reinforcement of nanoscale filler can be anticipated without limitations in orientation, dispersion, and the integrity of the filler particle-matrix interface. High filler content polymer composites containing emerging materials such as 2D transition metal carbides, nitrides, and carbonitrides (MXenes) are expected in the future., Comment: 13 000 words, 4 tables and 11 figures