1. Separation of left- and right-handed semiconducting single-walled carbon nanotube enantiomers using achiral amino acid surfactant.
- Author
-
Zhang, Yan, Li, Ying, Qiu, Xuyun, Gao, Qi, Tang, Zhenjuan, and Zhou, Shuai
- Subjects
- *
SINGLE walled carbon nanotubes , *HANDEDNESS , *MOLECULAR structure , *RACEMIC mixtures , *MOLECULAR dynamics - Abstract
Synthesized single-walled carbon nanotubes (SWNTs) are racemic mixtures of various (n, m) species with different electronic types, which greatly impeded their practical applications and fundamental research. In this paper, achiral amino acid surfactant sodium N-cocoyl sarcosinate (N-CS) not only displayed selectivity toward s-SWNTs but also could further separate the sorted s-SWNTs by the chirality indices (n, m) and left- and right-handedness with the aid of density gradient ultracentrifugation (DGU). The specific molecular structure of N-CS offered the possibility of recognizing the left- and right-handedness of SWNTs. The enantiomer separation mechanism was illustrated by Molecular dynamics simulations. Achiral amino-acid surfactant N-CS was used to separate SWNTs by chiral indices and left- and right-handedness with the aid of density gradient ultracentrifugation [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF