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The reliability, lower computational complexity, and ease of implementation of control observers make them one of the most promising methods for the state estimation of Li-ion batteries (LIBs) in commercial applications. To pave their way, this study performs a comprehensive and systematic evaluation of four main categories of control observer-based methods in different practical scenarios considering estimation accuracy, computational time convergence speed, stability, and robustness against measurement uncertainties. Observers are designed using a second-order equivalent circuit model whose observability against different scenarios is rigorously investigated to verify the feasibility of the proposed analysis. Established techniques then are validated against driving datasets and their comparative usefulness is evaluated using an experimental setup. The analysis also evaluates the adaptability of different techniques to electric vehicle field data. The results indicate better accuracy, stability, robustness, and faster convergence for the PI and PID, while the estimations of the Luenberger observers find it hard to converge against highly dynamic loadfiles. Moreover, this study also discusses the sensitivity of observer-based techniques to battery ohmic polarization and voltage-related measurement uncertainties. The most remarkable contribution of the proposed study lies in providing guidance for researchers when choosing the control observers for online state estimation of LIBs.

Lithium-ion battery (LIB) sources have played an essential role in self-sustained transportation energy systems and have been widely deployed in the last few years. To realize reliable battery maintenance, identifying its electrochemical parameters is necessary. However, the battery model contains many parameters while the measurable states are only the current and voltage, inducing the identification inherently an ill-conditioned problem. A parameter identification approach is proposed, including the experiment, model, and algorithm. Electrochemical parameters are first grouped manually based on the physical properties and assigned to two sequenced tests for identification. The two tests named the quasi-static test and the dynamic test, are compressed on time for practical implementation. Proper optimization models and a sensitivity-oriented stepwise (SSO) optimization algorithm are developed to search for the optimal parameters efficiently. Typically, the Sobol method is applied to conduct the sensitivity analysis. Based on the sensitivity indexes, the SSO algorithm can decouple the mixed impacts of different parameters during the identification. For validation, numerical experiments on a typical NCM811 battery at different life stages are conducted. The proposed approach saves about half the time finding the proper parameter value. The identification accuracy of crucial parameters related to battery degradation can exceed 95\%. Case study results indicate that the identified parameters can not only improve the accuracy of the battery model but also be used as the indicator of the battery SOH.

The penetrations of lithium-ion batteries in transport, energy and communication systems are increasing rapidly. A meticulous model applicable for precise in-situ monitoring and convenient online controlling is in sought to bridge the gap between research and applications. This paper proposes a simplified electro-chemical model and its discrete-time state-space realization derived from the pseudo-two-dimensional model. The solution-phase migration and solid-phase diffusion dynamics with varying parameters are captured and rigorous mathematical expressions of reaction rate distribution and terminal voltage are derived. A simulation framework including initializing, stabilizing and closed-loop correcting schemes with low computation cost are designed. Numeric experiments on different types of batteries in various operating scenarios are conducted for validation.