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2. Stabilities of the C-H...O bonded complexes of the haloforms HCCl(sub n)F(sub 3-n)(n=0-3) with dimethyl ether, oxirane, and acetone: An experimental and theoretical study

Author

Delanoye, Sofie N., Herrebout, Wouter A,., and Veken, Benjamin J. van der

Subjects
Acetone -- Structure, Acetone -- Atomic properties, Infrared spectroscopy -- Usage, Ethylene oxide -- Structure, Ethylene oxide -- Atomic properties, Argon -- Structure, Argon -- Atomic properties, Chemicals, plastics and rubber industries
Abstract

Complexation enthalpies of the complexes of the haloforms HCCl(sub n)F(sub 3-n) (n=0-3) with dimethyl ether, oxirane, and acetone are determined in liquid krypton and liquid argon using infrared spectroscopy. For each of the Lewis bases the ab initio complexation energies increase slightly from the fluoroform to the chloroform complex.

Published
2005

3. A cryosolution infrared study of the complexes of fluoroform with ammonia and pyridine: Evidence for a C-H...N Pseudo blue-shifting hydrogen bond

Author

Herrebout, Wouter A., Melikova, Sonia M., Delanoye, Sofie N., Rutkowski, Konstantin S., Veken, Benjamin J. van der, and Shchepkin, Dimitri N.

Subjects
Fluorine compounds -- Chemical properties, Fluorine compounds -- Spectra, Infrared spectroscopy -- Usage, Pyridine -- Chemical properties, Pyridine -- Spectra, Ammonia -- Chemical properties, Ammonia -- Spectra, Chemicals, plastics and rubber industries
Abstract

An investigation of the mid-infrared spectra of mixed solutions in liquid xenon containing fluoroform and either ammonia or pyridine is conducted at temperatures between 173 and 213 K. For both Lewis bases, a new band is found in the CH stretching region at a frequency 5 cm(super -1) higher than that of monomer fluoroform, which is assigned to a complex between fluoroform and the Lewis base.

Published
2005

4. Improper or classical hydrogen bonding? a comparative cryosolutions infrared study of the complexes of HCCIF(sub)2, HCCI(sub)2F, and HCCl(sub)3 with dimethyl ether

Author

Delanoye, Sofie N., Herrebout, Wouter A., and vander Verken, Benjamin J.

Subjects
Hydrogen bonding -- Analysis, Chemical bonds -- Analysis, Cryobiochemistry -- Research, Photoelectricity -- Analysis, Chemistry
Abstract

Mixtures of haloforms of the HCCIF type compounds with dimethyl ether in liquid nitrogen or krypton form a 1:1 complex with the ether. In the case of HCCIF(sub)2, HCCI(sub)2F, the complexation causes a blue shift for the haloform C--H stretching, whereas for HCCl(sub)3 a red shif is observed.

Published
2002

7. Optical and radiometric models of the NOMAD instrument part II: The infrared channels - SO and LNO

Author

Thomas, I. R., Vandaele, A. C., Robert, S., Neefs, E., Drummond, R., Daerden, F., Delanoye, S., Ristic, B., Berkenbosch, S., Clairquin, R., Maes, J., Bonnewijn, S., Depiesse, C., Mahieux, A., Trompet, L., Neary, L., Willame, Y., Wilquet, V., Nevejans, D., Aballea, L., Moelans, W., De Vos, L., Lesschaeve, S., Van Vooren, N., Lopez Moreno, J. J., Patel, M. R., Bellucci, G., Vandaele, Ann Carine, Moreno, Lopez, Juan, Jose, Bellucci, Giancarlo, Patel, Manish, Allen, Mark, Altieri, Francesca, Aoki, Shohei, Bolsée, David, Clancy, Todd, Cloutis, Edward, Daerden, Frank, Depiesse, Cédric, Fedorova, Anna, Formisano, Vittorio, Funke, Bernd, Fussen, Didier, Garcia Comas, Maya, Geminale, Anna, Gérard, Jean Claude, Gillotay, Didier, Giuranna, Marco, Gonzalez Galindo, Francisco, Ignatiev, Nicolai, Kaminski, Jacek, Karatekin, Ozgur, Kasaba, Yasumasa, Lefèvre, Franck, Lewis, Stephen, López Puertas, Manuel, López Valverde, Miguel, Mahieux, Arnaud, Mason, Jon, Mcconnell, Jack, Mumma, Mike, Neary, Lori, Neefs, Eddy, Novak, Robert, Renotte, Etienne, Robert, Séverine, Sindoni, Giuseppe, Smith, Mike, Thomas, Ian R., Trokhimovsky, Sacha, Vander Auwera, Jean, Villanueva, Geronimo, Whiteway, Jim, Willame, Yannick, Wilquet, Valerie, Wolff, Mike, Alonso Rodrigo, Gustavo, Aparicio Del Moral, Beatriz, Barzin, Pascal, Benmoussa, Ali, Berkenbosch, Sophie, Biondi, David, Bonnewijn, Sabrina, Candini, Gian Paolo, Clairquin, Roland, Cubas, Javier, Delanoye, Sofie, Giordanengo, Boris, Gissot, Samuel, Gomez, Alejandro, Zafra, Jose Jeronimo, Leese, Mark, Maes, Jeroen, Mazy, Emmanuel, Mazzoli, Alexandra, Meseguer, Jose, Morales, Rafael, Orban, Anne, Del Carmen Pastor Morales, Maria, Perez Grande, Isabel, Ristic, Bojan, Rodriguez Gomez, Julio, Saggin, Bortolino, Samain, Valérie, Sanz Andres, Angel, Sanz, Rosario, Simar, Juan Felipe, Thibert, Tanguy, Belgian Science Policy Office, European Space Agency, and UK Space Agency

Subjects
Physics, Martian, 010504 meteorology & atmospheric sciences, Spectrometer, Atmospheric composition, Spectrometers and spectroscopic instrumentation, 01 natural sciences, Occultation, Atomic and Molecular Physics, and Optics, Trace gas, law.invention, Remote sensing and sensors, Orbiter, Space instrumentation, Atmosphere of Earth, law, Atomic and Molecular Physics, Martian surface, 0103 physical sciences, Nadir, Radiative transfer, and Optics, 010303 astronomy & astrophysics, 0105 earth and related environmental sciences, Remote sensing
Abstract

NOMAD is a suite of three spectrometers that will be launched in 2016 as part of the joint ESA-Roscosmos ExoMars Trace Gas Orbiter mission. The instrument contains three channels that cover the IR and UV spectral ranges and can perform solar occultation, nadir and limb observations, to detect and map a wide variety of Martian atmospheric gases and trace species. Part I of this work described the models of the UVIS channel; in this second part, we present the optical models representing the two IR channels, SO (Solar Occultation) and LNO (Limb, Nadir and Occultation), and use them to determine signal to noise ratios (SNRs) for many expected observational cases. In solar occultation mode, both the SO and LNO channel exhibit very high SNRs >5000. SNRs of around 100 were found for the LNO channel in nadir mode, depending on the atmospheric conditions, Martian surface properties, and observation geometry., NOMAD has been made possible thanks to funding by the Belgian Science Policy Office (BELSPO) and financial and contractual coordination by the ESA Prodex Office. The research was performed as part of the “Interuniversity Attraction Poles” programme financed by the Belgian government (Planet TOPERS). UK funding is acknowledged under the UK Space Agency grant ST/I003061/1.

Published
2016

8. Infrared spectra of the complexes of trifluoroethane with dimethyl ether, acetone and oxirane: A crysolution study

Author

Herrebout, Wouter A., Delanoye, Sofie N., Maes, Bert U.W., and vna der Veken, Benjamin

Subjects
Methyl groups -- Chemical properties, Lewis structures -- Research, Hydrogen bonding -- Research, Chemicals, plastics and rubber industries
Abstract

Infrared spectra of solutions of trifluororethane and dimethyl ether, acetone, or oxirane in liquid krypton and liquid argon were studied. Analysis of the infrared spectra of the solutions suggested that for all Lewis bases, a complex with the Lewis acid is formed and the interaction between Lewis base and Lewis acid occurs through a hydrogen bond between the TFE C-H bond and the oxygen atom of the Lewis base.

Published
2006

9. Blue-shifting or red-shifting hydrogen bonding? Predictions for haloform complexes with dimethyl ether on the basis of perturbation theory

Author

Herrebout, Wouter A., Delanoye, Sofie N., and Van Der Veken, Benjamin J.

Subjects
Methyl ether -- Analysis, Perturbation (Mathematics) -- Analysis, Hydrogen bonding -- Analysis, Chemicals, plastics and rubber industries
Abstract

Calculations of the frequency shifts of the C-H stretching mode, v1, of the halo forms CHF3, CHCIF3, CHCl2F, and CHCl3 were carried out because of the complexation with dimethyl ether using an ab initio interaction potential between the two molecules, using a perturbative approach. The calculated results are compared with experimental literature data on these complexes.

Published
2004

10. Optical and radiometric models of the NOMAD instrument part I: the UVIS channel

Author

Vandaele, Ann C., Willame, Yannick, Depiesse, Cédric, Thomas, Ian R., Robert, Séverine, Bolsée, David, Patel, Manish R., Mason, Jon P., Leese, Mark, Lesschaeve, Stefan, Antoine, Philippe, Daerden, Frank, Delanoye, Sofie, Drummond, Rachel, Neefs, Eddy, Ristic, Bojan, Lopez Moreno, José Juan, Bellucci, Giancarlo, Allen, M., Altieri, F., Aoki, S., Clancy, T., Cloutis, E., Fedorova, A., Formisano, V., Funke, B., Fussen, D., Garcia Comas, M., Geminale, A., Gérard, J. C., Gillotay, D., Giuranna, M., Gonzalez Galindo, F., Ignatiev, N., Kaminski, J., Karatekin, O., Kasaba, Y., Lefèvre, F., Lewis, S., López Puertas, M., López Valverde, M., Mahieux, A., Mumma, M., Neary, L., Novak, R., Renotte, E., Sindoni, G., Smith, M., Trokhimovskiy, A., Vander Auwera, J., Villanueva, G., Viscardy, S., Whiteway, J., Wilquet, V., Wolff, M., Alonso Rodrigo, G., Aparicio Del Moral, B., Barzin, P., Benmoussa, A., Berkenbosch, S., Biondi, D., Bonnewijn, S., Candini, G., Clairquin, R., Cubas, J., Giordanengo, B., Gissot, S., Gomez, A., Zafra, J. J., Maes, J., Mazy, E., Mazzoli, A., Meseguer, J., Morales, R., Orban, A., Pastor Morales, M., Perez Grande, I., Rodriguez Gomez, J., Saggin, Bortolino, Samain, V., Sanz Andres, A., Sanz, R., Simar, J. F., Thibert, T., European Space Agency, UK Space Agency, and Belgian Science Policy Office

Subjects
Solar occultation, Radiometric model, Occultation, Signal, law.invention, Orbiter, Optics, law, Atomic and Molecular Physics, Nadir, Optical constants, Science objectives, Remote sensing, Physics, Martian, business.industry, Signal to noise, Atmosphere of Mars, IR spectral range, Atomic and Molecular Physics, and Optics, Trace gas, Wavelength, Optical models, Atmospheric absorption, and Optics, business, Martian atmospheres
Abstract

The NOMAD instrument has been designed to best fulfil the science objectives of the ExoMars Trace Gas Orbiter mission that will be launched in 2016. The instrument is a combination of three channels that cover the UV, visible and IR spectral ranges and can perform solar occultation, nadir and limb observations. In this series of two papers, we present the optical models representing the three channels of the instrument and use them to determine signal to noise levels for different observation modes and Martian conditions. In this first part, we focus on the UVIS channel, which will sound the Martian atmosphere using nadir and solar occultation viewing modes, covering the 200-650nm spectral range. High SNR levels (, NOMAD has been made possible thanks to funding by the Belgian Science Policy Office (BELSPO) and financial and contractual coordination by the ESA Prodex Office (contracts no 4000107727 and 4000103401). The research was performed as part of the >Interuniversity Attraction Poles> programme financed by the Belgian government (Planet TOPERS, contract PAI no P7/15). UK funding is acknowledged under the UK Space Agency grant ST/I003061/1.

Published
2015

11. Science objectives and performances of NOMAD, a spectrometer suite for the ExoMars TGO mission

Author

Vandaele, A. C, Neefs, E., Drummond, R., Thomas, I. R., Daerden, F., Lopez Moreno, J. J., Rodriguez, J., Patel, M. R., Bellucci, G., Allen, M., Altieri, F., Bolsée, D., Clancy, T., Delanoye, S., Depiesse, C., Cloutis, E., Fedorova, A., Formisano, V., Funke, B., Fussen, D., Geminale, A., Gérard, J. C., Giuranna, M., Ignatiev, N., Kaminski, J., Karatekin, O., Lefèvre, F., López Puertas, M., López Valverde, M., Mahieux, A., Mcconnell, J., Mumma, M., Neary, L., Renotte, E., Ristic, B., Robert, S., Smith, M., Trokhimovsky, S., Vanderauwera, J., Villanueva, G., Whiteway, J., Wilquet, V., Wolff, M., Vandaele, Ann Carine, Lopez Moreno, Jose Juan, Bellucci, Giancarlo, Patel, Manish, Allen, Mark, Altieri, Francesca, Aoki, Shohei, Bolsée, David, Clancy, Todd, Cloutis, Edward, Daerden, Frank, Depiesse, Cédric, Fedorova, Anna, Formisano, Vittorio, Funke, Bernd, Fussen, Didier, Garcia Comas, Maya, Geminale, Anna, Gérard, Jean Claude, Gillotay, Didier, Giuranna, Marco, Gonzalez Galindo, Francisco, Ignatiev, Nicolai, Kaminski, Jacek, Karatekin, Ozgur, Kasabe, Yasumasa, Lefèvre, Franck, Lewis, Stephen, López Puertas, Manuel, López Valverde, Miguel, Mahieux, Arnaud, Mason, Jon, Mumma, Mike, Neary, Lori, Neefs, Eddy, Renotte, Etienne, Robert, Séverine, Sindoni, Giuseppe, Smith, Mike, Thomas, Ian R., Trokhimovsky, Sacha, Vander Auwera, Jean, Villanueva, Geronimo, Whiteway, Jim, Willame, Yannick, Wilquet, Valerie, Wolff, Mike, Alonso Rodrigo, Gustavo, Aparicio Del Moral, Beatriz, Barzin, Pascal, Ben Moussa, Ali, Berkenbosch, Sophie, Biondi, David, Bonnewijn, Sabrina, Candini, Gian Paolo, Clairquin, Roland, Cubas, Javier, Delanoye, Sofie, Giordanengo, Boris, Gissot, Samuel, Gomez, Alejandro, Zafra, Jose Jeronimo, Leese, Mark, Maes, Jeroen, Mazy, Emmanuel, Mazzoli, Alexandra, Meseguer, Jose, Morales, Rafael, Orban, Anne, Pastor Morales, Maria Del Carmen, Perez Grande, Isabel, Ristic, Bojan, Rodriguez Gomez, Julio, Saggin, Bortolino, Samain, Valérie, Sanz Andres, Angel, Sanz, Rosario, Simar, Juan Felipe, Thibert, Tanguy, Belgian Institute for Space Aeronomy / Institut d'Aéronomie Spatiale de Belgique (BIRA-IASB), Instituto de Astrofísica de Andalucía (IAA), Consejo Superior de Investigaciones Científicas [Madrid] (CSIC), The Open University [Milton Keynes] (OU), Istituto di Astrofisica e Planetologia Spaziali - INAF (IAPS), Istituto Nazionale di Astrofisica (INAF), Jet Propulsion Laboratory (JPL), NASA-California Institute of Technology (CALTECH), Space Science Institute [Boulder] (SSI), Department of Geography [Winnipeg], University of Winnipeg, Space Research Institute of the Russian Academy of Sciences (IKI), Russian Academy of Sciences [Moscow] (RAS), Laboratoire de Physique Atmosphérique et Planétaire (LPAP), Université de Liège, York University [Toronto], Royal Observatory of Belgium [Brussels] (ROB), PLANETO - LATMOS, Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), NASA Goddard Space Flight Center (GSFC), Centre Spatial de Liège (CSL), Spectroscopie de l'atmosphère, Service de Chimie Quantique et Photophysique, Université libre de Bruxelles (ULB), and Catholic University of America

Subjects
[SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP], Solar, Occultation, law.invention, Orbiter, Mars atmosphere, law, Nadir, Aerosol, Observations, Spectroscopy, Ultraviolet, Remote sensing, Spectrometer, [SDU.ASTR.SR]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Solar and Stellar Astrophysics [astro-ph.SR], Suite, Astronomy and Astrophysics, Mars Exploration Program, Atmosphere of Mars, ExoMars, Trace gas, [SDU.ASTR.IM]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Instrumentation and Methods for Astrophysic [astro-ph.IM], Space and Planetary Science, Visible, Composition, Infrared, Methane, Occultation Nadir, Environmental science
Abstract

International audience; The NOMAD spectrometer suite on the ExoMars Trace Gas Orbiter will map the composition and distribution of Mars' atmospheric trace species in unprecedented detail, fulfilling many of the scientific objectives of the joint ESA-Roscosmos ExoMars Trace Gas Orbiter mission. The instrument is a combination of three channels, covering a spectral range from the UV to the IR, and can perform solar occultation, nadir and limb observations. In this paper, we present the science objectives of the instrument and how these objectives have influenced the design of the channels. We also discuss the expected performance of the instrument in terms of coverage and detection sensitivity.

Published
2015

12. Blue shifting hydrogen bonding in the complexes of chlorofluoro haloforms with acetone-d (sub 6) and oxirane-d (sub 4)

Author

Delanoye, Sofie N., Herrebout, Wouter A., and Veken, Benjamin J. van der

Subjects
Krypton -- Chemical properties, Chemical reactions -- Research, Chemistry
Abstract

The study deals with the infrared spectra of the complexes of the same haloforms with two further oxygen donors, acetone, and oxirane. The complexes are examined in liquid krypton as the medium.

Published
2002

13. SINBAD electronic models of the interface and control system for the NOMAD spectrometer on board of ESA ExoMars Trace Gas Orbiter mission

Author

Jerónimo Zafra, José M., additional, Sanz Mesa, Rosario, additional, Gómez López, Juan M., additional, Rodríguez Gómez, Julio F., additional, Aparicio del Moral, Beatriz, additional, Morales Muñoz, Rafael, additional, Candini, Gian Paolo, additional, Pastor Morales, M. Carmen, additional, Robles Muñoz, Nicolás, additional, López-Moreno, José Juan, additional, Vandaele, Ann Carine, additional, Neefs, Eddy, additional, Drummond, Rachel, additional, Delanoye, Sofie, additional, Berkenbosch, Sophie, additional, Clairquin, Roland, additional, Ristic, Bojan, additional, Maes, Jeroen, additional, Bonnewijn, Sabrina, additional, Patel, Manish R., additional, and Leese, Mark, additional

Published
2016
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14. SINBAD flight software, the on-board software of NOMAD in ExoMars 2016

Author

Pastor-Morales, M. C., additional, Rodríguez-Gómez, Julio F., additional, Morales-Muñoz, Rafael, additional, Gómez-López, Juan M., additional, Aparicio-del-Moral, Beatriz, additional, Candini, Gian Paolo, additional, Jerónimo-Zafra, Jose M., additional, López-Moreno, Jose J., additional, Robles-Muñoz, Nicolás F., additional, Sanz-Mesa, Rosario, additional, Neefs, Eddy, additional, Vandaele, Ann C., additional, Drummond, Rachel, additional, Thomas, Ian R., additional, Berkenbosch, Sophie, additional, Clairquin, Roland, additional, Delanoye, Sofie, additional, Ristic, Bojan, additional, Maes, Jeroen, additional, Bonnewijn, Sabrina, additional, Patel, Manish R., additional, Leese, Mark, additional, and Mason, Jon P., additional

Published
2016
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15. NOMAD spectrometer on the ExoMars trace gas orbiter mission: part 1—design, manufacturing and testing of the infrared channels

Author

Neefs, Eddy, primary, Vandaele, Ann Carine, additional, Drummond, Rachel, additional, Thomas, Ian R., additional, Berkenbosch, Sophie, additional, Clairquin, Roland, additional, Delanoye, Sofie, additional, Ristic, Bojan, additional, Maes, Jeroen, additional, Bonnewijn, Sabrina, additional, Pieck, Gerry, additional, Equeter, Eddy, additional, Depiesse, Cédric, additional, Daerden, Frank, additional, Ransbeeck, Emiel Van, additional, Nevejans, Dennis, additional, Rodriguez-Gómez, Julio, additional, López-Moreno, José-Juan, additional, Sanz, Rosario, additional, Morales, Rafael, additional, Candini, Gian Paolo, additional, Pastor-Morales, M. Carmen, additional, Aparicio del Moral, Beatriz, additional, Jeronimo-Zafra, José-Maria, additional, Gómez-López, Juan Manuel, additional, Alonso-Rodrigo, Gustavo, additional, Pérez-Grande, Isabel, additional, Cubas, Javier, additional, Gomez-Sanjuan, Alejandro M., additional, Navarro-Medina, Fermín, additional, Thibert, Tanguy, additional, Patel, Manish R., additional, Bellucci, Giancarlo, additional, De Vos, Lieve, additional, Lesschaeve, Stefan, additional, Vooren, Nico Van, additional, Moelans, Wouter, additional, Aballea, Ludovic, additional, Glorieux, Stijn, additional, Baeke, Ann, additional, Kendall, Dave, additional, De Neef, Jurgen, additional, Soenen, Alexander, additional, Puech, Pierre-Yves, additional, Ward, Jon, additional, Jamoye, Jean-François, additional, Diez, David, additional, Vicario-Arroyo, Ana, additional, and Jankowski, Michel, additional

Published
2015
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20. SINBAD electronic models of the interface and control system for the NOMAD spectrometer on board of ESA ExoMars Trace Gas Orbiter mission

Author

MacEwen, Howard A., Fazio, Giovanni G., Lystrup, Makenzie, Batalha, Natalie, Siegler, Nicholas, Tong, Edward C., Jerónimo Zafra, José M., Sanz Mesa, Rosario, Gómez López, Juan M., Rodríguez Gómez, Julio F., Aparicio del Moral, Beatriz, Morales Muñoz, Rafael, Candini, Gian Paolo, Pastor Morales, M. Carmen, Robles Muñoz, Nicolás, López-Moreno, José Juan, Vandaele, Ann Carine, Neefs, Eddy, Drummond, Rachel, Delanoye, Sofie, Berkenbosch, Sophie, Clairquin, Roland, Ristic, Bojan, Maes, Jeroen, Bonnewijn, Sabrina, Patel, Manish R., and Leese, Mark

Published
2016
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21. SINBAD flight software, the on-board software of NOMAD in ExoMars 2016

Author

Chiozzi, Gianluca, Guzman, Juan C., Pastor-Morales, M. C., Rodríguez-Gómez, Julio F., Morales-Muñoz, Rafael, Gómez-López, Juan M., Aparicio-del-Moral, Beatriz, Candini, Gian Paolo, Jerónimo-Zafra, Jose M., López-Moreno, Jose J., Robles-Muñoz, Nicolás F., Sanz-Mesa, Rosario, Neefs, Eddy, Vandaele, Ann C., Drummond, Rachel, Thomas, Ian R., Berkenbosch, Sophie, Clairquin, Roland, Delanoye, Sofie, Ristic, Bojan, Maes, Jeroen, Bonnewijn, Sabrina, Patel, Manish R., Leese, Mark, and Mason, Jon P.

Published
2016
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22. Improper or Classical Hydrogen Bonding? A Comparative Cryosolutions Infrared Study of the Complexes of HCCIF[sub 2], HCCI[sub 2]F, and HCCI[sub 3] with Dimethyl Ether.

Author

Delanoye, Sofie N., Herrebout, Wouter A., and van der Veken, Benjamin J.

Subjects
*METHYL ether, *CARBON, *HYDROGEN, *ELECTRONS
Abstract

Investigates the use of cryosolutions infrared in determining the complexes of haloforms with dimethyl ether. Influence of the ether on the haloform carbon (C)-hydrogen (H) stretching; Reaction mechanism of C-H bonds with electrons of oxygen and nitrogen atoms; Complexation shift of the haloform C-H stretching.

Published
2002
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23. Development of a knowledge management system for the NOMAD instrument onboard the ExoMars TGO spacecraft

Author

Hetey, Laszlo, Neefs, Eddy, Thomas, Ian, Zender, Joe, Vandaele, Ann-Carine, Berkenbosch, Sophie, Ristic, Bojan, Bonnewijn, Sabrina, Delanoye, Sofie, Leese, Mark, Mason, Jon, Patel, Manish, Hetey, Laszlo, Neefs, Eddy, Thomas, Ian, Zender, Joe, Vandaele, Ann-Carine, Berkenbosch, Sophie, Ristic, Bojan, Bonnewijn, Sabrina, Delanoye, Sofie, Leese, Mark, Mason, Jon, and Patel, Manish

Abstract

Purpose This paper aims to describe the development of a knowledge management system (KMS) for the Nadir and Occultation for Mars Discovery (NOMAD) instrument on board the ESA/Roscosmos 2016 ExoMars Trace Gas Orbiter (TGO) spacecraft. The KMS collects knowledge acquired during the engineering process that involved over 30 project partners. In addition to the documentation and technical data (explicit knowledge), a dedicated effort was made to collect the gained experience (tacit knowledge) that is crucial for the operational phase of the TGO mission and also for future projects. The system is now in service and provides valuable information for the scientists and engineers working with NOMAD Design/methodology/approach The NOMAD KMS was built around six areas: official documentation, technical specifications and test results, lessons learned, management data (proposals, deliverables, progress reports and minutes of meetings), picture files and movie files. Today, the KMS contains 110 GB of data spread over 11,000 documents and more than 13,000 media files. A computer-aided design (CAD) library contains a model of the full instrument as well as exported sub-parts in different formats. A context search engine for both documents and media files was implemented. Findings The conceived KMS design is basic, flexible and very robust. It can be adapted to future projects of a similar size. Practical implications The paper provides practical guidelines on how to retain the knowledge from a larger aerospace project. The KMS tool presented here works offline, requires no maintenance and conforms to data protection standards. Originality/value This paper shows how knowledge management requirements for space missions can be fulfilled. The paper demonstrates how to transform the large collection of project data into a useful t

24. SINBAD flight software, the on board software of NOMAD in ExoMars 2016

Author

Pastor-Morales, M. C., Rodríguez-Gómez, Julio F., Morales-Muñoz, Rafael, Gómez-López, Juan M., Aparicio-del-Moral, Beatriz, Candini, Gian Paolo, Jerónimo-Zafra, Jose M., López-Moreno, Jose J., Robles-Muñoz, Nicolás F., Sanz-Mesa, Rosario, Neefs, Eddy, Vandaele, Ann C., Drummond, Rachel, Thomas, Ian R., Berkenbosch, Sophie, Clairquin, Roland, Delanoye, Sofie, Maes, Jeroen, Ristic, Bojan, Bonnewijn, Sabrina, Patel, M. R., Leese, Mark, Mason, J. P., Pastor-Morales, M. C., Rodríguez-Gómez, Julio F., Morales-Muñoz, Rafael, Gómez-López, Juan M., Aparicio-del-Moral, Beatriz, Candini, Gian Paolo, Jerónimo-Zafra, Jose M., López-Moreno, Jose J., Robles-Muñoz, Nicolás F., Sanz-Mesa, Rosario, Neefs, Eddy, Vandaele, Ann C., Drummond, Rachel, Thomas, Ian R., Berkenbosch, Sophie, Clairquin, Roland, Delanoye, Sofie, Maes, Jeroen, Ristic, Bojan, Bonnewijn, Sabrina, Patel, M. R., Leese, Mark, and Mason, J. P.

Abstract

The Spacecraft INterface and control Board for NomAD (SINBAD) is an electronic interface designed by the Instituto de Astroffisica de Andalucfia (IAA-CSIC). It is part of the Nadir and Occultation for MArs Discovery instrument (NOMAD) on board in the ESAs ExoMars Trace Gas Orbiter mission. This mission was launched in March 2016. The SINBAD Flight Software (SFS) is the software embedded in SINBAD. It is in charge of managing the interfaces, devices, data, observing sequences, patching and contingencies of NOMAD. It is presented in this paper the most remarkable aspects of the SFS design, likewise the main problems and lessons learned during the software development process.

25. SINBAD electronic models of the interface and control system for the NOMAD spectrometer on board of ESA ExoMars Trace Gas Orbiter mission

Author

Jerónimo Zafra, José M., Sanz Mesa, Rosario, Gómez López, Juan M., Rodríguez Gómez, Julio F., Aparicio del Moral, Beatriz, Morales Muñoz, Rafael, Candini, Gian Paolo, Pastor Morales, Maria del Carmen, Robles Muñoz, Nicolás, López-Moreno, José Juan, Vandaele, Ann Carine, Neefs, Eddy, Drummond, Rachel, Delanoye, Sofie, Berkenbosch, Sophie, Clairquin, Roland, Ristic, Bojan, Maes, Jeroen, Bonnewijn, Sabrina, Patel, Manish R., Leese, Mark, Jerónimo Zafra, José M., Sanz Mesa, Rosario, Gómez López, Juan M., Rodríguez Gómez, Julio F., Aparicio del Moral, Beatriz, Morales Muñoz, Rafael, Candini, Gian Paolo, Pastor Morales, Maria del Carmen, Robles Muñoz, Nicolás, López-Moreno, José Juan, Vandaele, Ann Carine, Neefs, Eddy, Drummond, Rachel, Delanoye, Sofie, Berkenbosch, Sophie, Clairquin, Roland, Ristic, Bojan, Maes, Jeroen, Bonnewijn, Sabrina, Patel, Manish R., and Leese, Mark

Abstract

NOMAD is a spectrometer suite: UV-visible-IR spectral ranges. NOMAD is part of the payload of ESA ExoMars Trace Gas Orbiter Mission. SINBAD boards are in charge of the communication and management of the power and control between the spacecraft and the instrument channels. SINBAD development took four years, while the entire development and test required five years, a very short time to develop an instrument devoted to a space mission. The hardware of SINBAD is shown in the attached poster: developed boards, prototype boards and final models. The models were delivered to the ESA in order to testing and integration with the spacecraft.

26. SINBAD flight software, the on board software of NOMAD in ExoMars 2016

Author

Pastor-Morales, M. C., Rodríguez-Gómez, Julio F., Morales-Muñoz, Rafael, Gómez-López, Juan M., Aparicio-del-Moral, Beatriz, Candini, Gian Paolo, Jerónimo-Zafra, Jose M., López-Moreno, Jose J., Robles-Muñoz, Nicolás F., Sanz-Mesa, Rosario, Neefs, Eddy, Vandaele, Ann C., Drummond, Rachel, Thomas, Ian R., Berkenbosch, Sophie, Clairquin, Roland, Delanoye, Sofie, Maes, Jeroen, Ristic, Bojan, Bonnewijn, Sabrina, Patel, M. R., Leese, Mark, Mason, J. P., Pastor-Morales, M. C., Rodríguez-Gómez, Julio F., Morales-Muñoz, Rafael, Gómez-López, Juan M., Aparicio-del-Moral, Beatriz, Candini, Gian Paolo, Jerónimo-Zafra, Jose M., López-Moreno, Jose J., Robles-Muñoz, Nicolás F., Sanz-Mesa, Rosario, Neefs, Eddy, Vandaele, Ann C., Drummond, Rachel, Thomas, Ian R., Berkenbosch, Sophie, Clairquin, Roland, Delanoye, Sofie, Maes, Jeroen, Ristic, Bojan, Bonnewijn, Sabrina, Patel, M. R., Leese, Mark, and Mason, J. P.

Abstract

The Spacecraft INterface and control Board for NomAD (SINBAD) is an electronic interface designed by the Instituto de Astroffisica de Andalucfia (IAA-CSIC). It is part of the Nadir and Occultation for MArs Discovery instrument (NOMAD) on board in the ESAs ExoMars Trace Gas Orbiter mission. This mission was launched in March 2016. The SINBAD Flight Software (SFS) is the software embedded in SINBAD. It is in charge of managing the interfaces, devices, data, observing sequences, patching and contingencies of NOMAD. It is presented in this paper the most remarkable aspects of the SFS design, likewise the main problems and lessons learned during the software development process.

27. SINBAD electronic models of the interface and control system for the NOMAD spectrometer on board of ESA ExoMars Trace Gas Orbiter mission

Author

Jerónimo Zafra, José M., Sanz Mesa, Rosario, Gómez López, Juan M., Rodríguez Gómez, Julio F., Aparicio del Moral, Beatriz, Morales Muñoz, Rafael, Candini, Gian Paolo, Pastor Morales, Maria del Carmen, Robles Muñoz, Nicolás, López-Moreno, José Juan, Vandaele, Ann Carine, Neefs, Eddy, Drummond, Rachel, Delanoye, Sofie, Berkenbosch, Sophie, Clairquin, Roland, Ristic, Bojan, Maes, Jeroen, Bonnewijn, Sabrina, Patel, Manish R., Leese, Mark, Jerónimo Zafra, José M., Sanz Mesa, Rosario, Gómez López, Juan M., Rodríguez Gómez, Julio F., Aparicio del Moral, Beatriz, Morales Muñoz, Rafael, Candini, Gian Paolo, Pastor Morales, Maria del Carmen, Robles Muñoz, Nicolás, López-Moreno, José Juan, Vandaele, Ann Carine, Neefs, Eddy, Drummond, Rachel, Delanoye, Sofie, Berkenbosch, Sophie, Clairquin, Roland, Ristic, Bojan, Maes, Jeroen, Bonnewijn, Sabrina, Patel, Manish R., and Leese, Mark

Abstract

NOMAD is a spectrometer suite: UV-visible-IR spectral ranges. NOMAD is part of the payload of ESA ExoMars Trace Gas Orbiter Mission. SINBAD boards are in charge of the communication and management of the power and control between the spacecraft and the instrument channels. SINBAD development took four years, while the entire development and test required five years, a very short time to develop an instrument devoted to a space mission. The hardware of SINBAD is shown in the attached poster: developed boards, prototype boards and final models. The models were delivered to the ESA in order to testing and integration with the spacecraft.

28. Development of a knowledge management system for the NOMAD instrument onboard the ExoMars TGO spacecraft

Author

Hetey, Laszlo, Neefs, Eddy, Thomas, Ian, Zender, Joe, Vandaele, Ann-Carine, Berkenbosch, Sophie, Ristic, Bojan, Bonnewijn, Sabrina, Delanoye, Sofie, Leese, Mark, Mason, Jon, Patel, Manish, Hetey, Laszlo, Neefs, Eddy, Thomas, Ian, Zender, Joe, Vandaele, Ann-Carine, Berkenbosch, Sophie, Ristic, Bojan, Bonnewijn, Sabrina, Delanoye, Sofie, Leese, Mark, Mason, Jon, and Patel, Manish

Abstract

Purpose This paper aims to describe the development of a knowledge management system (KMS) for the Nadir and Occultation for Mars Discovery (NOMAD) instrument on board the ESA/Roscosmos 2016 ExoMars Trace Gas Orbiter (TGO) spacecraft. The KMS collects knowledge acquired during the engineering process that involved over 30 project partners. In addition to the documentation and technical data (explicit knowledge), a dedicated effort was made to collect the gained experience (tacit knowledge) that is crucial for the operational phase of the TGO mission and also for future projects. The system is now in service and provides valuable information for the scientists and engineers working with NOMAD Design/methodology/approach The NOMAD KMS was built around six areas: official documentation, technical specifications and test results, lessons learned, management data (proposals, deliverables, progress reports and minutes of meetings), picture files and movie files. Today, the KMS contains 110 GB of data spread over 11,000 documents and more than 13,000 media files. A computer-aided design (CAD) library contains a model of the full instrument as well as exported sub-parts in different formats. A context search engine for both documents and media files was implemented. Findings The conceived KMS design is basic, flexible and very robust. It can be adapted to future projects of a similar size. Practical implications The paper provides practical guidelines on how to retain the knowledge from a larger aerospace project. The KMS tool presented here works offline, requires no maintenance and conforms to data protection standards. Originality/value This paper shows how knowledge management requirements for space missions can be fulfilled. The paper demonstrates how to transform the large collection of project data into a useful t

29. Optical and radiometric models of the NOMAD instrument part I: the UVIS channel.

Author

Vandaele AC, Willame Y, Depiesse C, Thomas IR, Robert S, Bolsée D, Patel MR, Mason JP, Leese M, Lesschaeve S, Antoine P, Daerden F, Delanoye S, Drummond R, Neefs E, Ristic B, Lopez-Moreno JJ, Bellucci G, and Team N

Abstract

The NOMAD instrument has been designed to best fulfil the science objectives of the ExoMars Trace Gas Orbiter mission that will be launched in 2016. The instrument is a combination of three channels that cover the UV, visible and IR spectral ranges and can perform solar occultation, nadir and limb observations. In this series of two papers, we present the optical models representing the three channels of the instrument and use them to determine signal to noise levels for different observation modes and Martian conditions. In this first part, we focus on the UVIS channel, which will sound the Martian atmosphere using nadir and solar occultation viewing modes, covering the 200-650nm spectral range. High SNR levels (>1000) can easily be reached for wavelengths higher than 300nm both in solar occultation and nadir modes when considering binning. Below 300nm SNR are lower primarily because of the lower signal and the impact of atmospheric absorption.

Published
2015
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30. Stabilities of the C-H...O bonded complexes of the haloforms HCClnF3-n (n = 0-3) with dimethyl ether, oxirane, and acetone: an experimental and theoretical study.

Author

Delanoye SN, Herrebout WA, and van der Veken BJ

Subjects
Models, Theoretical, Solvents, Thermodynamics, Acetone chemistry, Ethylene Oxide chemistry, Methyl Ethers chemistry
Abstract

Complexation enthalpies of the complexes of the haloforms HCCl(n)F(3-)(n) (n = 0-3) with dimethyl ether, oxirane, and acetone have been determined in liquid krypton and/or liquid argon using infrared spectroscopy. The same quantities were derived starting from ab initio complexation energies, calculated at the MP2=FULL/aug-cc-VTZ level, and by correcting these energies for thermodynamic and solvent contributions. The two sets of data are compared and discussed.

Published
2005
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