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Quantum correlations, like entanglement, represent the characteristic trait of quantum mechanics, and pose essential issues and challenges to the interpretation of this pillar of modern physics. Although quantum correlations are largely acknowledged as a major resource to achieve quantum advantage in many tasks of quantum technologies, their full quantitative description and the axiomatic basis underlying them are still under investigation. Previous works suggested that the origin of nonlocal correlations is grounded in principles capturing (from outside the quantum formalism) the essence of quantum uncertainty. In particular, the recently-introduced principle of Relativistic Independence gave rise to a new bound intertwining local and nonlocal correlations. Here we test such a bound by realizing together sequential and joint weak measurements on entangled photon pairs, allowing to simultaneously quantify both local and nonlocal correlations by measuring incompatible observables on the same quantum system without collapsing its state, a task typically forbidden in the traditional (projective) quantum measurement framework. Our results demonstrate the existence of a fundamental limit on the extent of quantum correlations, shedding light on the profound role of uncertainty in both enabling and balancing them., Comment: 23 pages, 3 figures

Recently, it has been proposed a new method [arXiv:2405.21029] to detect quantum gravity effects, based on generating gravitational entanglement between two nano-diamonds with Nitrogen-Vacancy defects, in a magnetically trapped configuration. Here we analyse in detail the proposed experimental setup, with a particular focus on implementing the detection of the gravitationally-induced entanglement using an optical readout based on measuring the position of the nano-diamonds and its complementary basis. We also summarise some of the key theoretical and experimental ideas on which this proposed scheme is based., Comment: 8 pages, 2 figures

Quantum theory is notoriously counterintuitive, and yet remains entirely self-consistent when applied universally. Here we uncover a new manifestation of its unusual consequences. We demonstrate, theoretically and experimentally (by means of polarization-encoded single-photon qubits), that Heisenberg's uncertainty principle leads to the impossibility of stringing together logical deductions about outcomes of consecutive non-compatible measurements. This phenomenon resembles the geometry of a Penrose triangle, where each corner is locally consistent while the global structure is impossible. Besides this, we show how overlooking this non-trivial logical structure leads to the erroneous possibility of distinguishing non-orthogonal states with a single measurement.

We present an advanced quantum super-resolution imaging technique based on photon statistics measurement and its accurate modeling. Our reconstruction algorithm adapts to any kind of non-Poissonian emitters, outperforming the corresponding classical SOFI method. It offers sub-diffraction resolution improvement that scales with the $\sqrt{j}$, where $j$ is the highest order central moments of the photocounts. More remarkably, in combination with structured illumination a linear improvement with j can be reached. Through simulations and experiments, we prove our method's clear superiority over traditional SOFI, especially in low excitation light conditions, providing a promising avenue for non-invasive super-resolution microscopy of delicate samples.

In this paper, we present a new experimental apparatus for the measurement of the detection efficiency of free-space single-photon detectors based on the substitution method. For the first time, we extend the analysis to account for the wavelength dependence introduced by the transmissivity of the optical window in front of the detector's active area. Our method involves measuring the detector's response at different wavelengths and comparing it to a calibrated reference detector. This allows us to accurately quantify the efficiency variations due to the optical window's transmissivity. The results provide a comprehensive understanding of the wavelength-dependent efficiency, which is crucial for optimizing the performance of single-photon detectors in various applications, including quantum communication and photonics research. This characterization technique offers a significant advancement in the precision and reliability of single-photon detection efficiency measurements.

Unifying quantum theory and general relativity is the holy grail of contemporary physics. Nonetheless, the lack of experimental evidence driving this process led to a plethora of mathematical models with a substantial impossibility of discriminating among them or even establishing if gravity really needs to be quantized or if, vice versa, quantum mechanics must be "gravitized" at some scale. Recently, it has been proposed that the observation of the generation of entanglement by gravitational interaction, could represent a breakthrough demonstrating the quantum nature of gravity. A few experimental proposals have been advanced in this sense, but the extreme technological requirements (e.g., the need for free-falling gravitationally-interacting masses in a quantum superposition state) make their implementation still far ahead. Here we present a feasibility study for a table-top nanodiamond-based interferometer eventually enabling easier and less resource-demanding quantum gravity tests. With respect to the aforementioned proposals, by relying on quantum superpositions of steady massive (mesoscopic) objects our interferometer may allow exploiting just small-range electromagnetic fields (much easier to implement and control) and, at the same time, the re-utilization of the massive quantum probes exploited, inevitably lost in free-falling interferometric schemes., Comment: 8 pages, 5 figures

The impact of noise sources in real-world implementations of Twin-Field Quantum Key Distribution (TF-QKD) protocols is investigated, focusing on phase noise from photon sources and connecting fibers. This work emphasizes the role of laser quality, network topology, fiber length, arm balance, and detector performance in determining key rates. Remarkably, it reveals that the leading TF-QKD protocols are similarly affected by phase noise despite different mechanisms. This study demonstrates duty cycle improvements of over a factor of two through narrow-linewidth lasers and phase-control techniques, highlighting the potential synergy with high-precision time/frequency distribution services. Ultrastable lasers, evolving toward integration and miniaturization, offer promise for agile TF-QKD implementations on existing networks. Properly addressing phase noise and practical constraints allows for consistent key rate predictions, protocol selection, and layout design, crucial for establishing secure long-haul links for the Quantum Communication Infrastructures under development in several countries., Comment: 20 pages, 8 figures, 3 tables. Post-print version

Bell inequalities are one of the cornerstones of quantum foundations, and fundamental tools for quantum technologies. Recently, the scientific community worldwide has put a lot of effort towards them, which culminated with loophole-free experiments. Nonetheless, none of the experimental tests so far was able to extract information on the full inequality from each entangled pair, since the wave function collapse forbids performing, on the same quantum state, all the measurements needed for evaluating the entire Bell parameter. We present here the first single-pair Bell inequality test, able to obtain a Bell parameter value for every entangled pair detected. This is made possible by exploiting sequential weak measurements, allowing to measure non-commuting observables in sequence on the same state, on each entangled particle. Such an approach not only grants unprecedented measurement capability, but also removes the need to choose between different measurement bases, intrinsically eliminating the freedom-of-choice loophole and stretching the concept of counterfactual-definiteness (since it allows measuring in the otherwise not-chosen bases). We also demonstrate how, after the Bell parameter measurement, the pair under test still presents a noteworthy amount of entanglement, providing evidence of the absence of (complete) wave function collapse and allowing to exploit this quantum resource for further protocols., Comment: 14 pages, 3 figures

We introduce a novel technique for the reconstruction of multimode optical fields, based on simultaneously exploiting both the generalized Glauber's $K^{th}$-order correlation function $g^{(K)}$ and a recently proposed anti-correlation function (dubbed $\theta^{(K)}$) which is resilient to Poissonian noise. We experimentally demonstrate that this method yields mode reconstructions with higher fidelity with respect to those obtained with reconstruction methods based only on $g^{(K)}$'s, even requiring less "a priori" information. The reliability and versatility of our technique make it suitable for a widespread use in real applications of optical quantum measurement, from quantum information to quantum metrology, especially when one needs to characterize ensembles of single-photon emitters in the presence of background noise (due, for example, to residual excitation laser, stray light, or unwanted fluorescence)., Comment: 11 pages, 3 figures

We propose and experimentally demonstrate a general method allowing us to unravel microscopic noise events that affect a continuous quantum variable. Such unraveling is achieved by frequent measurements of a discrete variable coupled to the continuous one. The experimental realization involves photons traversing a noisy channel. There, their polarization, whose coupling to the photons spatial wavepacket is subjected to stochastic noise, is frequently measured in the quantum Zeno regime. The measurements not only preserve the polarization state, but also enable the recording of the full noise statistics from the spatially-resolved detection of the photons emerging from the channel. This method proves the possibility of employing photons as quantum noise sensors and robust carriers of information., Comment: 6 pages, 3 figures

We provide the first systematic characterization of the structural and photoluminescence properties of optically active defect centers fabricated upon implantation of 30-100 keV Mg+ ions in artificial diamond. The structural configurations of Mg-related defects were studied by the emission channeling technique for 27Mg implantations performed both at room-temperature and 800 {\deg}C, which allowed the identification of a major fraction of Mg atoms (~30-42%) in sites which are compatible with the split-vacancy structure of the MgV complex. A smaller fraction of Mg atoms (~13-17%) was found on substitutional sites. The photoluminescence emission was investigated both at the ensemble and individual defect level in a temperature range comprised between 5 K and 300 K, offering a detailed picture of the MgV-related emission properties and revealing the occurrence of previously unreported spectral features. The optical excitability of the MgV center was also studied as a function of the optical excitation wavelength enabling to identify the optimal conditions for photostable and intense emission. The results are discussed in the context of the preliminary experimental data and the theoretical models available in the literature, with appealing perspectives for the utilization of the tunable properties of the MgV center for quantum information processing applications., Comment: 7 figures

Single-photon detectors are a pivotal component in photonic quantum technologies. A precise and comprehensive calibration of the intrinsic detection efficiency is of utmost importance to ensure the proper evaluation of the performance in view of the specific technological application of interest, such as the protection against security breaches in quantum cryptographic solutions. Here we report on a systematic study on and comprehensive analysis of the estimation of the intrinsic detection efficiency of two commercial single-photon detectors based on single-photon avalanche diodes (SPADs) for various mean photon numbers and at high laser pulse repetition rates using different techniques. We observed an unexpected and signifucant drop in intrinsic detection efficiency at detection rates of 10 % and higher relative to the maximum detection rate. It is demonstrated that for data analysis a statistical model for the detection rate conveniently can be used if no timestamped data are available. We conclude that the full characterization of single-photon detectors used in critical applications should include the sensitivity of their intrinsic detection efficiency to high event rates., Comment: 23 pages, 9 figures

We report a systematic photoluminescence (PL) investigation of the spectral emission properties of individual optical defects fabricated in diamond upon ion implantation and annealing. Three spectral lines at 620 nm, 631 nm, and 647 nm are identified and attributed to the SnV center due to their occurrence in the PL spectra of the very same single-photon emitting defects. We show that the relative occurrence of the three spectral features can be modified by oxidizing the sample surface following thermal annealing. We finally report the relevant emission properties of each class of individual emitters, including the excited state emission lifetime and the emission intensity saturation parameters., Comment: 12 pages, 6 figures, 1 table

We report on the systematic characterization of the optical properties of diamond color centers based on Pb impurities. An ensemble photoluminescence analysis of their spectral emission was performed at different excitation wavelengths in the 405-520 nm range and at different temperatures in the 4-300 K range. The series of observed spectral features consist of different emission lines associated with Pb-related defects. Finally, a room-temperature investigation of single-photon emitters under 490.5 nm laser excitation is reported, revealing different spectral signatures with respect to those already reported under 514 nm excitation. This work represents a substantial progress with respect to previous studies on Pb-related color centers, both in the attribution of an articulated series of spectral features and in the understanding of the formation process of this type of defect, thus clarifying the potential of this system for high-impact applications in quantum technologies.

In quantum communication systems, the precise estimation of the detector's response to the incoming light is necessary to avoid security breaches. The typical working regime uses a free-running single-photon avalanche diode in combination with attenuated laser pulses at telecom wavelength for encoding information. We demonstrate the validity of an analytical model for this regime which considers the effects of dark counts and dead time on the measured count rate. For the purpose of gaining a better understanding of these effects, the photon detections were separated from the dark counts via a software-induced gating mechanism. The model was verified by experimental data for mean photon numbers covering three orders of magnitude as well as for laser repetition frequencies below and above the inverse dead time. Consequently, our model would be of interest for predicting the detector response not only in the field of quantum communications, but also in any other quantum physics experiment where high detection rates are needed.

We present a detailed description of the experiment realising for the first time a protective measurement, a novel measurement protocol which combines weak interactions with a ``protection mechanism'' preserving the measured state coherence during the whole measurement process. Furthermore, protective measurement allows finding the expectation value of an observable, i.e. an inherently statistical quantity, by measuring a single particle, without the need of any statistics. This peculiar property, in sharp contrast with the framework of traditional (projective) quantum measurement, might constitute a groundbreaking advance for several quantum technology related fields., Comment: 13 pages, 5 figures

We show that, by utilising temporal quantum correlations as expressed by pseudo-density operators (PDOs), it is possible to recover formally the standard quantum dynamical evolution as a sequence of teleportations in time. We demonstrate that any completely positive evolution can be formally reconstructed by teleportation with different temporally correlated states. This provides a different interpretation of maximally correlated PDOs, as resources to induce quantum time-evolution. Furthermore, we note that the possibility of this protocol stems from the strict formal correspondence between spatial and temporal entanglement in quantum theory. We proceed to demonstrate experimentally this correspondence, by showing a multipartite violation of generalised temporal and spatial Bell inequalities and verifying agreement with theoretical predictions to a high degree of accuracy, in high-quality photon qubits., Comment: preprint

We experimentally demonstrate, for the first time, noise diagnostics by repeated quantum measurements. Specifically, we establish the ability of a single photon, subjected to random polarisation noise, to diagnose non-Markovian temporal correlations of such a noise process. In the frequency domain, these noise correlations correspond to colored noise spectra, as opposed to the ones related to Markovian, white noise. Both the noise spectrum and its corresponding temporal correlations are diagnosed by probing the photon by means of frequent, (partially-)selective polarisation measurements. Our main result is the experimental demonstration that noise with positive temporal correlations corresponds to our single photon undergoing a dynamical regime enabled by the quantum Zeno effect (QZE), while noise characterized by negative (anti-) correlations corresponds to regimes associated with the anti-Zeno effect (AZE). This demonstration opens the way to a new kind of noise spectroscopy based on QZE and AZE in photon (or other single-particle) state probing.

We introduce a protocol addressing the conformance test problem, which consists in determining whether a process under test conforms to a reference one. We consider a process to be characterized by the set of end-product it produces, which is generated according to a given probability distribution. We formulate the problem in the context of hypothesis testing and consider the specific case in which the objects can be modeled as pure loss channels. We demonstrate theoretically that a simple quantum strategy, using readily available resources and measurement schemes in the form of two-mode squeezed vacuum and photon-counting, can outperform any classical strategy. We experimentally implement this protocol, exploiting optical twin beams, validating our theoretical results, and demonstrating that, in this task, there is a quantum advantage in a realistic setting.

Quantum mechanics allows the distribution of intrinsically secure encryption keys by optical means. Twin-field quantum key distribution is the most promising technique for its implementation on long-distance fibers, but requires stabilizing the optical length of the communication channels between parties. In proof-of-principle experiments based on spooled fibers, this was achieved by interleaving the quantum communication with periodical adjustment frames. In this approach, longer duty cycles for the key streaming come at the cost of a looser control of channel length, and a successful key-transfer using this technique in a real world remains a significant challenge. Using interferometry techniques derived from frequency metrology, we developed a solution for the simultaneous key streaming and channel length control, and demonstrate it on a 206 km field-deployed fiber with 65 dB loss. Our technique reduces the quantum-bit-error-rate contributed by channel length variations to <1%, representing an effective solution for real-world quantum communications.

The issue of irreversibility in a universe with time-reversal-symmetric laws is a central problem in physics. % , and, in particular, to statistical mechanics, information theory and quantum thermodynamics. In this letter, we discuss for the first time how irreversibility can emerge within the recently proposed constructor theory framework. Here irreversibility is expressed as the requirement that a task is possible, while its inverse is not. In particular, we demonstrate that this irreversibility is compatible with quantum theory's time reversal symmetric laws, by exploiting a specific model, based on the universal quantum homogeniser, realised experimentally with high-quality single-photon qubits., Comment: 6 pages, 4 figures

Understanding the human brain remains one of the most significant challenges of the 21st century. As theoretical studies continue to improve the description of the complex mechanisms that regulate biological processes, in parallel numerous experiments are conducted to enrich or verify these theoretical predictions and with the aim of extrapolating more accurate models. In the field of magnetometers for biological application, among the various sensors proposed for this purpose, NV centers have emerged as a promising solution due to their perfect biocompatibility and the possibility of being positioned in close proximity and even inside the cell, allowing a nanometric spatial resolution. There are still many difficulties that must be overcome in order to obtain both spatial resolution and sensitivity capable of revealing the very weak biological electromagnetic fields generated by neurons (or other cells). However, over the last few years, significant improvements have been achieved in this direction, thanks to the use of innovative techniques, which allow us to hope for an early application of these sensors for the measurement of fields such as the one generated by cardiac tissue, if not, in perspective, for the nerve fibers fields. In this review, we will analyze the new results regarding the application of NV centers and we will discuss the main challenges that currently prevent these quantum sensors from reaching their full potential., Comment: 21 pages, 13 figures

The possibility of using Nitrogen-vacancy centers in diamonds to measure nanoscale magnetic fields with unprecedented sensitivity is one of the most significant achievements of quantum sensing. Here we present an innovative experimental set-up, showing an achieved sensitivity comparable to the state of the art ODMR protocols if the sensing volume is taken into account. The apparatus allows magnetic sensing in biological samples such as individual cells, as it is characterized by a small sensing volume and full bio-compatibility. The sensitivity at different optical powers is studied to extend this technique to the intercellular scale., Comment: 6 pages, 5 figures

Non-classical correlations in optical beams offer the unprecedented opportunity of surpassing conventional limits of sensitivity and resolution in optical measurements and imaging, especially but not only, when a low photon flux down to the single photons are measured. We review the principles of quantum imaging and sensing techniques which exploit sub-Poissonian photon statistics and non-classical photon number correlation, presenting some state-of-the-art achievements in the field. These quantum photonics protocols have the potential to trigger major steps in many applications, such as microscopy and biophotonics and represent an important opportunity for a new deal in radiometry and photometry., Comment: 39 pages, 11 figures, 235 references

Recently, the fast development of quantum technologies led to the need for tools allowing the characterization of quantum resources. In particular, the ability to estimate non-classical aspects, e.g. entanglement and quantum discord, in two-qubit systems, is relevant to optimise the performance of quantum information processes. Here we present an experiment in which the amount of entanglement and discord are measured exploiting different estimators. Among them, some will prove to be optimal, i.e., able to reach the ultimate precision bound allowed by quantum mechanics. These estimation techniques have been tested with a specific family of states ranging from nearly pure Bell states to completely mixed states. This work represents a significant step in the development of reliable metrological tools for quantum technologies.

Measurements are crucial in quantum mechanics, in fundamental research as well as in applicative fields like quantum metrology, quantum-enhanced measurements and other quantum technologies. In the recent years, weak-interaction-based protocols like Weak Measurements and Protective Measurements have been experimentally realized, showing peculiar features leading to surprising advantages in several different applications. In this work we analyze the validity range for such measurement protocols, that is, how the interaction strength affects the weak value extraction, by measuring different polarization weak values measured on heralded single photons. We show that, even in the weak interaction regime, the coupling intensity limits the range of weak values achievable, putting a threshold on the signal amplification effect exploited in many weak measurement based experiments.

Quantum mechanics presents peculiar properties that, on the one hand, have been the subject of several theoretical and experimental studies about its very foundations and, on the other hand, provide tools for developing new technologies, the so-called quantum technologies. The nonclassicality pointed out by Leggett-Garg inequalities has represented, with Bell inequalities, one of the most investigated subject. In this letter we study the connection of Leggett-Garg inequalities with a new emerging field of quantum measurement, the weak values. In particular, we perform an experimental study of the four-time correlators Legget-Garg test, by exploiting single and sequential weak measurements performed on heralded single photons. We show violation of a four-parameters Leggett-Garg inequality in different experimental conditions, demonstrating an interesting connection between Leggett-Garg inequality violation and anomalous weak values.

We show how the same set-up and procedure, exploiting spatially multi-mode quantum correlations, allows the absolute calibration of a EMCCD camera from the analog regime down to the single photon counting level, just by adjusting the brightness of the quantum source. At single photon level EMCCD can be operated as an on-off detector, where quantum efficiency depends on the discriminating threshold. We develop a simple model to explain the connection of the two different regime demonstrating that the efficiency estimated in the analog (bright) regime allows to accurately predict the detector behaviour in the photo-counting regime and vice-versa. This work establishes a bridge between two regions of the optical measurements that up to now have been based on completely different standards, detectors and measurement techniques.

We present the first experimental test that distinguishes between an event-based corpuscular model (EBCM) [H. De Raedt et al.: J. Comput. Theor. Nanosci. 8 (2011) 1052] of the interaction of photons with matter and quantum mechanics. The test looks at the interference that results as a single photon passes through a Mach-Zehnder interferometer [H. De Raedt et al.: J. Phys. Soc. Jpn. 74 (2005) 16]. The experimental results, obtained with a low-noise single-photon source [G. Brida et al.: Opt. Expr. 19 (2011) 1484], agree with the predictions of standard quantum mechanics with a reduced $\chi^2$ of 0.98 and falsify the EBCM with a reduced $\chi^2$ of greater than 20.

In counterfactual QKD information is transfered, in a secure way, between Alice and Bob even when no particle carrying the information is in fact transmitted between them. In this letter we fully implement the scheme for counterfactual QKD proposed in [T. Noh, \PRL \textbf{103}, 230501 (2009)], demonstrating for the first time that information can be transmitted between two parties without the transmission of a carrier.

Since, in general, non-orthogonal states cannot be cloned, any eavesdropping attempt in a Quantum Communication scheme using non-orthogonal states as carriers of information introduces some errors in the transmission, leading to the possibility of detecting the spy. Usually, orthogonal states are not used in Quantum Cryptography schemes since they can be faithfully cloned without altering the transmitted data. Nevertheless, L. Goldberg and L. Vaidman [\prl 75 (1995) 1239] proposed a protocol in which, even if the data exchange is realized using two orthogonal states, any attempt to eavesdrop is detectable by the legal users. In this scheme the orthogonal states are superpositions of two localized wave packets travelling along separate channels. Here we present an experiment realizing this scheme.

We propose and demonstrate experimentally a new method based on the spatial entanglement for the absolute calibration of analog detector. The idea consists on measuring the sub-shot-noise intensity correlation between two branches of parametric down conversion, containing many pairwise correlated spatial modes. We calibrate a scientific CCD camera and a preliminary evaluation of the statistical uncertainty indicates the metrological interest of the method.

Recently a test of nonclassicality for a single qubit was proposed [R. Alicki and N. Van Ryn, J. Phys. A: Math. Theor. 41, 062001 (2008)]. We present an optimized experimental realization of this test leading to a 46 standard deviation violation of classicality. This factor of 5 improvement over our previous result was achieved by moving from the infrared to the visible where we can take advantage of higher efficiency and lower noise photon detectors., Comment: 4 pages, 1 figure

We investigate the coupling efficiency of parametric downconversion light (PDC) into single and multi-mode optical fibers as a function of the pump beam diameter, crystal length and walk-off. We outline two different theoretical models for the preparation and collection of either single-mode or multi-mode PDC light (defined by, for instance, multi-mode fibers or apertures, corresponding to bucket detection). Moreover, we define the mode-matching collection efficiency, important for realizing a single-photon source based on PDC output into a well-defined single spatial mode. We also define a multimode collection efficiency that is useful for single-photon detector calibration applications., Comment: 13 pages, 12 figures