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Fluids supplied by stored magma at depth are causal factors of volcanic unrest, as they can cause pressurization/heating of hydrothermal systems. However, evidence for links between hydrothermal pressurization, CO2 emission and volcano seismicity have remained elusive. Here, we use recent (2010−2020) observations at Campi Flegrei caldera (CFc) to show hydrothermal pressure, gas emission and seismicity at CFc share common source areas and well-matching temporal evolutions. We interpret the recent escalation in seismicity and surface gas emissions as caused by pressure-temperature increase at the top of a vertically elongated (0.3–2 km deep) gas front. Using mass (steam) balance considerations, we show hydrothermal pressurization is causing energy transfer from the fluids to the host rocks, ultimately triggering low magnitude earthquakes within a seismogenetic volume containing the hydrothermal system. This mechanism is probably common to other worldwide calderas in similar hydrothermal activity state., Journal of Volcanology and Geothermal Research, 414, ISSN:0377-0273

Studies concerning 222Rn emission from soils are growing interest in the Earth Sciences, due to the gas potential as a tracer of natural phenomena. This paper presents a study of radon monitoring in two sites of Campi Flegrei caldera (Neaples, Italy) during the period July 1, 2011–December 31, 2017. This area was characterized by several phases of volcanic unrest. A hybrid method based on Multiple Linear Regression + Remote Radon Estimation method + Singular Spectrum Analysis (MLR + RRE + SSA) is developed for the trend extraction and the identification of anomalies in the time series of 222Rn. The results are compared with several routinely used geo-indicators of the caldera unrest. The comparisons show strong correlation among the signals. The present study proves the 222Rn is a potential indicator of the evolution of a volcanic crisis.

The study concerns the analysis of 220Rn (thoron) recorded in the surface soil in two sites of the Campi Flegrei caldera (Naples, Southern Italy) characterized by phases of volcanic unrest in the seven-year period 1 July 2011–31 December 2017. Thoron comes only from the most surface layer, so the characteristics of its time series are strictly connected to the shallow phenomena, which can also act at a distance from the measuring point in these particular areas. Since we measured 220Rn in parallel with 222Rn (radon), we found that by using the same analysis applied to radon, we obtained interesting information. While knowing the limits of this radioisotope well, we highlight only the particular characteristics of the emissions of thoron in the surface soil. Here, we show that it also shows some clear features found in the radon signal, such as anomalies and signal trends. Consequently, we provide good evidence that, in spite of the very short life of 220Rn compared to 222Rn, both are related to the carrier effect of CO2, which has significantly increased in the last few years within the caldera. The hydrothermal alterations, induced by the increase in temperature and pressure of the caldera system, occur in the surface soils and significantly influence thoron’s power of exhalation from the surface layer. The effects on the surface thoron are reflected in both sites, but with less intensity, the same behavior of 222Rn following the increasing movements and fluctuations of the geophysical and geochemical parameters (CO2 flux, fumarolic tremor, background seismicity, soil deformation). An overall linear correlation was found between the 222−220Rn signals, indicating the effect of the CO2 vector. The overall results represent a significant step forward in the use and interpretation of the thoron signal.

This is a seven-year study (1/7/2011-31/12/2017) of radon monitoring at two sites of Campi Flegrei caldera (Neaples, Southern Italy) that in the last 70 years experienced repeated phases of volcanic unrest. The sites are equipped with devices for radon detection, based on the spectrometry analysis of the α-particles of radon daughters. A hybrid method, as combination of three known methods, is applied for the identification of residuals (anomalies) and trends of the time series of Radon. The results are compared with the following indicators of current caldera unrest: the tremor caused by the major fumarolic vent registered by a seismic station; the cumulative of background seismicity; the maximum vertical deformation acquired by GPS networks during the current phase of uplift; the temperature-pressure of the hydrothermal system estimated based on gas geo-indicators. The comparisons show strong correlation among independent signals and suggest that the extension of the area affected by current Campi Flegrei crisis is larger than the area of seismicity and of intense hydrothermal activity from which the radon stations are 1–4 km away. These results represent an absolute novelty in the study of a such calderic area and mark a significant step forward in the use and interpretation of the radon signal.

Radon is considered one of the short- and immediate-term earthquake precursors by International Association of Seismology and Physics of the Earth’s Interior. For this reason, the accurate and reliable measurement of its specific activity in soil gas is mandatory. Since its presence is influenced by many environmental factors, in order to eliminate this influence on the radon activity measurement a multi-parametric and multi-site analysis is necessary. Following this approach, a continuous radon monitoring was carried out in two sites of the Phlegrean Fields caldera (Campania, Italy) using the RaMonA system, which also allows for the measurement of temperature, relative humidity and pressure. In particular, the dependence of measured radon specific activity on the meteorological conditions was studied using the multiple linear regression method. The analysis was implemented also by testing data averages on different timescales. In this paper, the results of a preliminary analysis performed on data collected throughout 2012 are presented; the outcomes obtained allow to emphasize site-specific behavior and to discriminate apparent radon “anomalies” of climatic origin from those tied to the phenomena occurring in the earth’s crust. The method employed showed its usefulness by removing the effects of meteorological conditions and thus to better identify the possible radon anomalies caused by seismo-volcanic activity. The peculiarities of the different sites and some correlations with earthquakes are discussed.

Fumaroles are known to generate seismic and infrasonic tremor, but this fumarolic tremor has so far received little attention. Seismic records taken near the Pisciarelli fumarole, a vigorously degassing vent of the restless Campi Flegrei volcano in Italy, reveal a fumarolesourced tremor whose amplitude has recently intensified. We use independent geochemical evidence to interpret this fumarolic tremor for the first time quantitatively. We find that the temporal increase in fumarolic tremor RSAM (real-time seismic-amplitude measurement) quantitatively correlates with increases in independent proxies of fumarole activity, including the CO2concentrations in the fumarole's atmospheric plume, the fumarole composition (CO/CO2and H2/H2O ratios), and temperature (T) and pressure (P) conditions of the source hydrothermal system. This association between RSAM and geochemical data suggests that the current escalation in fumarolic tremor is driven by increased gas transport and venting from a hydrothermal system that evolves toward higher T-P conditions. More widely, our results suggest that monitoring the tremor generated by fumaroles can pave the way to real-time tracking and interpreting the evolution of an ongoing hydrothermal-magmatic unrest, thus complementing information from periodic gas surveys. Our novel method of fumarole monitoring, based on well-established seismic techniques, is potentially suitable for capturing signals of unrest at any active volcano, including those in remote regions.

A detailed analysis of a time-series of the Radon (222Rn) specific activity is carried out to identify anomalies that can be correlated with earthquakes occurrence in the monitored area. New hybrid methods are developed for this purpose and the advantages of each single component method are exploited. These methods are applied to two-years data series recorded continuously in the soils of a site within the seismo-volcanic area of Phlegrean Fields (Naples-Italy). Since the measurement system distinguishes and separately measures the 222Rn and 220Rn, an alternative estimation of the remote fraction of the gas and its anomalies has been also performed using the 220Rn trend. The results of different methods are compared to recognize and to highlight Radon anomalies. Clear relationships have been found between anomalies and earthquakes of local origin and selected according to a specific formula of the earthquake preparation zone. The effectiveness of the methods and the goodness of the results are established by the high values of the cross correlation factors between the anomalies and the occurrence of the earthquakes.