1. Microwave-induced high surface functionalization of multi-walled carbon nanotubes for long-term dispersion in water.
- Author
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Davarpanah, M., Maghrebi, M., and Hosseinipour, E.
- Subjects
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MULTIWALLED carbon nanotube synthesis , *FUNCTIONAL groups , *MOLECULAR structure , *DISPERSION (Chemistry) , *POLAR solvents - Abstract
Multi-walled carbon nanotubes (MWCNTs) were functionalized by monoethanolamine (MEA), diethanolamine (DEA) and triethanolamine (TEA) by a rapid microwave-assisted method. Surface functional groups and morphology of MWCNTs were analyzed by ultraviolet-visible spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis, Raman spectroscopy and transmission electron microscopy. The water dispersibility of samples was also measured over time and compared with that of MWCNT functionalized by ethylenediamine (EDA). Accordingly, the dispersibility was in the sequence MEA-MWCNTs > DEA-MWCNTs > TEA-MWCNTs > EDA-MWCNTs > pristine MWCNTs. The significant long-term dispersibility of MEA-MWCNTs was related to its exceptionally high surface functionalization (89.3 %) and lack of chemical bridging between adjacent MWCNTs. This strategy, along with the low-cost functionalizing agents, could pave the way for large-scale dispersion of CNTs in the polar solvents. [ABSTRACT FROM AUTHOR]
- Published
- 2014
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