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In this paper, a method of ultrasound-assisted low-pressure closed acid digestion followed by inductively coupled plasma mass spectrometry (ICP-MS) analysis was proposed for trace element quantification in rock samples. By using 1.5 mL of a binary acid mixture of HNO3–HF with a ratio of 2:1, rock powder samples of 50 mg were completely decomposed in 12 h at 140 °C after 4 h of ultrasonic treatment with or without pressure relief procedure. The element extraction efficiency of this method was evaluated via the yielded relative errors (REs) of the trace elements in a series of geological standard reference materials (SRMs) with compositions from basic to acidic. It was found that the contents of trace elements (i.e., 36 metal elements from Li to U) in basalt BCR-2, diabase W-2a, andesite AGV-2, granodiorite GSP-2, and granite GSR-1 were comparable with the reported reference values, giving REs with absolute values less than 10%. It was also found that clear solutions without sample powder residues by naked-eye observation can be obtained when using the low-pressure closed decomposition method without ultrasonic pretreatment. The quantification results, however, were found to be negatively biased for most of the studied trace elements, and, in particular, the content bias of Zr in SRM GSP-2 was down to −86.28% due to the low extraction efficiency of refractory minerals of the low-pressure closed digestion method. By applying this proposed digestion strategy, the decomposition property of the ternary combination of HNO3–HF–mannitol in terms of trace element quantification accuracy was also investigated. Results showed that the concentrations of trace elements in the studied SRMs were consistent with the reference values, giving REs within ±6.94%, which revealed that there was no deterioration of extraction efficiencies of trace elements and neglected mass interferences from mannitol. This study demonstrated the essential role of ultrasound irradiation in rock sample decomposition to achieve the high extraction efficiency of trace elements under a low-pressure environment, and the developed approach with promising future applications in geoscience exhibited considerable merits, including a high extraction efficiency, feasible digestion process, less time consumption, and lower safety associated risks. [ABSTRACT FROM AUTHOR]

The correct choice of a stone aggregate for railway ballast is directly related to the stability, safety, efficiency, and maintenance costs of the track. The aggregate must meet several criteria to ensure it is the most appropriate material. Thus, the present study aimed to evaluate four distinct stones: two granites, a diabase, and a basalt, all mined in the eastern region of the state of São Paulo, Brazil, regarding their applicability as ballast. Using Brazilian and ASTM procedures for stone samples, the tests were conducted on 55 and 75-mm specimens, in dry and wet conditions. As a result, all stones met the physical properties established by the standards. Among the mechanical properties, uniaxial compressive strength stood out, with all stones where the tested materials advantageously exceeding the 100 MPa required by the Brazilian standard. Regarding the accelerated weathering test with ethylene glycol, only basalt showed more significant changes, although its resistance to weathering was still lower than 10%. Our findings indicate that these stones perform adequately as ballast for railway applications. The study is expected to contribute to revisions of technical standards and the improvement of a database on Brazilian stone materials for use as railway ballast. [ABSTRACT FROM AUTHOR]

Nova Colinas, centered at 07°09′33″ S/46°06′30″ W, is the ninth confirmed complex impact structure in Brazil and the fifth in the Parnaíba Basin, with a diameter of ~6.5–7 km and a nearly circular shape. Impactites include shocked siltstones from the Pedra de Fogo Fm. found at the central peak, brecciated sandstone from the Sambaíba Fm. bearing microscopic shock features, and brecciated basalt from the Mosquito Fm. bearing shatter cones. The impact event's age has been constrained to the interval from ~130 to ~199 Ma based on the local stratigraphy. Due to its moderate to advanced stage of erosion, geophysical modeling combined with geological field data were employed for its characterization. A new geological map was produced through field observations and remote sensing image interpretation, as well as a 3‐D model based on ground gravity data and numerical modeling. iSALE2D shock physics code was employed to simulate the formation of Nova Colinas crater. The results revealed its main structural zones: the central uplift, annular basin, and outer rim, each associated with specific lithostratigraphic units from the Parnaíba Basin. Bouguer residual anomalies ranged from −3.6 to 1.2 mGal, with a nearly circular positive anomaly at the center of the structure, surrounded by a negative anomaly. 3‐D gravity data inversion indicated a buried high‐density body, likely due to the uplift of a diabase sill. Results of the numerical modeling point out that the final crater reached gravitational stability with a diameter of ~7 km and a depth of ~240 m, suggesting that a narrow outcrop strip of the Motuca Fm. was uplifted to a higher level compared to the Sambaíba Fm. strata, forming an antiform‐like “arch” that creates an inner ring that exposes rocks of the Motuca Formation. [ABSTRACT FROM AUTHOR]

Fragments of Proto‐Tethyan oceanic lithosphere are well‐preserved along the southern belt of the North Qilian suture, and the origin and emplacement of these ophiolites have become subjects of intense debate. In this study, we integrate field observations, mineralogical and geochemical analyses, zircon U‐Pb dating, and isotopic data to investigate the Yanglong ophiolite. The Yanglong ophiolitic rocks are found as tectonic slices resting on the Neoproterozoic sedimentary and volcanic rocks. These rocks are composed of Cambrian serpentinized peridotite, gabbro, dolerite, and rodingite. The spinels in the serpentinized peridotites have variable Cr# values (21, 38–46, and 59–61) and display affinity to those in abyssal and forearc peridotites. The dolerites show slight enrichment in Th and have elevated (La/Sm)N ratios (1.19–2.01), indicating a subduction‐related geochemical affinity. The Yanglong ophiolitic rocks have positive zircon ɛHf(t) values (+10.3–+18.4) and whole‐rock ɛND(t) values (+5.3–+6.7) indicating derivation from partial melting of a depleted mantle source. These results, together with the regional geology, collectively suggest that the Yanglong ophiolite was generated in a forearc setting during the Early Cambrian northward intra‐oceanic subduction. It was emplaced onto the Central Qilian Block during the subsequent arc‐continent collision, no later than the Early Ordovician. [ABSTRACT FROM AUTHOR]

The Huozhou complex in the Trans-North China Orogen exhibits two events of mafic magmatism (separated by ca. 700 Ma): Neoproterozoic (920 ± 15 Ma) Shimenyu diabase and Late Triassic (217 ± 2.5 Ma) Xingtangsi diabase. Investigations have focused on systematic petrology, zircon U-Pb dating, Lu-Hf isotopes, and lithogeochemistry. The research findings indicate that the Late Triassic Xingtangsi diabase of the Huozhou complex can be classified as a transitional type between intermediate and mafic rocks based on their SiO2 content. This classification is supported by an average SiO2 content of 53.94%, ranging from 53.33% to 54.28%. In the Zr/TiO2 vs. Ce diagram, all samples lie within the range of basalt. The zircons from the Late Triassic Xingtangsi diabase have low εHf(t) values ranging from –12.7 to –8.7, with an average of –11.1. Additionally, the single-stage model age TDM1 is estimated to be between 1207 and 1701 Ma. These findings suggest that the magma responsible for the dyke originated from either partial melting or an enriched mantle source inside the Meso-Proterozoic lithospheric mantle. The elevated concentrations of Th (thorium) and LREEs (light rare earth elements), as well as the Th/Yb and Th/Nb ratios, suggest the potential incorporation of subducted sediments within the magma source region. The rock displays negative Nb, Ta, Zr, Hf, and Ti anomalies. These geochemical attributes align with the distinctive traits observed in volcanic rocks found within island arcs. The formation of the Late Triassic Xingtangsi diabase is likely associated with the geological context of an arc setting, which arises from the collision between the Yangtze plate and the North China Craton. [ABSTRACT FROM AUTHOR]

Accurate subsurface imaging is crucial for understanding complex geological structures. Traditional approaches often involve separate inversion of different geophysical datasets, which may not fully capture the structural similarities between the models. Joint inversion, integrating multiple datasets, offers a more comprehensive view by enhancing the resolution and the accuracy of subsurface models. In this study, we propose a joint inversion technique for DC resistivity and vertical gravity gradient data, leveraging the cross-gradient constraint to enforce structural similarities between the resulting models. This method is applied to both synthetic and real datasets, including case studies involving qanats in Iran and a dolerite dyke in South Africa. The results demonstrate that joint inversion significantly improves the accuracy of resistivity and density models compared to independent inversion, particularly in resolving intricate geological features. This approach has proven effective in enhancing subsurface mapping for multi-disciplinary purposes, including resource exploration, heritage conservation, and risk mitigation for the built environment. [ABSTRACT FROM AUTHOR]

Diabase intrusion is a common geological phenomenon in lacustrine shale formations in continental basins in China, which has important effects on the physical and chemical properties of shale oil reservoirs. In this paper, we systematically analyzed the pore structure of diabase-intruded lacustrine shale in the Gaoyou sag of the Subei Basin using geochemical tests, thin-section observation, argon ion polishing scanning electron microscopy (SEM), low-temperature nitrogen adsorption experiments (LTNA), and other methods combined with monofractal and multifractal theories. The results show that the intrusion metamorphic segments are a diabase zone, hornfels zone, slate zone, and normal shale zone from the intrusion center. The pores of hornfels and slate are mostly oriented and dissolution is obvious. Many microfractures and secondary minerals such as quartz and chlorite are observed. The pore volumes of diabase and hornfels are small, while those of slate and normal shale are larger. The monofractal dimensions D1 and D2 of the intrusion segment show a general trend of decreasing first and then increasing from the intrusion center to the shale zone. The multifractal parameters' H index decreases gradually from the lower normal shale to the upper metamorphic zone hornfels, while Δα and Rd increase gradually. The total organic carbon (TOC) content of the intrusion zone has little effect on the pore structure, and the fractal characteristics fluctuate weakly, while the vitrinite reflectivity (Ro) value change has a significant impact on the monofractal characteristics of the shale pore. Pore volume also affects the pore heterogeneity; the larger the specific surface area (SSA) and total pore volume (TPV), the lower the pore heterogeneity and the higher the surface roughness and pore connectivity. The diabase intrusion caused three modification mechanisms of mechanical squeezing, the thermal effect, and chemical action on the shale surrounding rocks, resulting in different degrees of pore formation or change. The pore evolution model of the metamorphic belt with the combined action of "mechanical-thermal-chemical" is established, and the influence of diabase intrusion on the pore types and pore size distribution (PSD) of shale reservoirs is quantitatively described, providing a new perspective and method for understanding the impact of diabase intrusion on the characteristics and exploration potential of shale oil reservoirs. [ABSTRACT FROM AUTHOR]

The 369 m deep M4 drill hole, located ~18 km NNW of the center of the 146 Ma Morokweng impact structure (MIS), intersects shocked Archean granitoid gneisses and subsidiary dolerite intrusions that are cut by faults, cataclasites and mm‐ to m‐wide suevitic and pseudotachylitic breccia dikes. The shock features in quartz in the gneisses and breccia dikes include decorated planar deformation features (PDFs), planar fractures, feather features, and toasting. Other minerals show features that may be shock‐related, such as multiple sets of planar features and alternate twin ladder structures in feldspars, kink bands in biotite, and planar features in titanite, apatite, and zircon; however, these are variably annealed and/or overprinted by hydrothermal alteration effects, and confirmation of their origin awaits further study. Universal Stage measurements of PDF sets in quartz from 12 gneissic target rocks and from lithic and mineral clasts in three suevitic and three pseudotachylitic breccia dikes reveal four dominant sets: (0001), {101¯3}, {101¯4} and {101¯2}. Based on these observations, the average peak shock pressure in these rocks is estimated at ≤16 GPa, which supports the original proximity (within one transient cavity radius) of these rocks to the point of impact. No discernible depth‐dependent shock attenuation was noted in the core. These shock levels and the elevated structural position of the rocks in the M4 core relative to the impact melt sheet intersected in drill holes closer to the center of the MIS suggest that the M4 lithologies represent part of the parautochthonous peak ring volume that subsequently experienced 1.5–2 km of post‐impact erosion before it was buried beneath younger sediments. Numerical modeling using the iSALE‐2D code suggests that the original Morokweng crater had a rim‐to‐rim diameter of between 70 and 80 km, and that the rocks in the M4 core were originally located at a depth of 7–8 km and a radial distance of 8–9 km from the point of impact. [ABSTRACT FROM AUTHOR]

The paper presents new geological, geochronological, geochemical and Nd-Sr isotopic data on the Meso- Neoproterozoic dolerites of the Siberian Craton. New U-Pb baddeleyite and apatite ages of a E-W-trending dyke and two sills from southeastern Siberia are 982 ± 11, 977 ± 7, 970 ± 31 and 972 ± 60 Ma, respectively, extending the area of distribution of the event by more than 100 km to the north. The Sette-Daban intrusions are subalkalic mostly low-Ti dolerites, although high-Ti dolerites have been locally documented as well. Trace element abundances in dolerites vary from typical to E-MORB to OIB with arc-like signatures represented by high Th/Yb and low TiO2/Yb ratios. All dolerite samples display moderately positive εNd(t) values varying from +3.3 to +7.7 and indicating the magmas were derived from a depleted mantle source. E-MORB and OIB intrusions are attributed to the different degree of interaction of magma between the depleted asthenospheric mantle and regions within the sub-continental lithospheric mantle (SCLM) that were metasomatically enriched during earlier subduction events. Available data on Sette-Daban event distribution, composition and duration satisfy the characteristics of a typical Large Igneous Province (LIP). Similar age 1000–950 Ma mafic magmatism is also recognized in the Baltic and Amazonian cratons and can be potentially correlated with the Sette-Daban event. [ABSTRACT FROM AUTHOR]

The Luk-Ulo Melange Complex (LMC) is characterized by a chaotic assemblage of mixed rocks with a block-in-matrix fabric. The exposed blocks consist of various scattered rock types, trending in an ENE-WSW direction. In the case of Mt. Parang, the origin of the diabase remains uncertain, with ongoing debate as to whether it is associated with in situ volcanic activity or represents an exotic block within the melange deposit. Subsurface data obtained through geophysical investigation can aid in modeling the geometry of intrusive bodies using inverse modeling techniques. In this study, we conducted a gravity survey and performed 3D inverse modeling to investigate the subsurface beneath Karangsambung. A total of 818 gravity data points and 28 rock density measurements were integrated with existing geological data to construct an a priori 3D geological model. To ensure the results align with geological concepts, the 3D inversion utilized a stochastic approach, allowing for the incorporation of multiple geological constraints over fifty million iterative procedures. Ultimately, the inversion successfully reduced the misfit between observed and calculated data from 2.71 to 0.55 mGal. Based on the inverted 3D model, the diabase rock in Mt. Parang is identified as having an intrusive origin. The intrusion model exhibited minimal changes in density, volume, and shape during the inversion process. Additionally, the model suggests the presence of a solidified magma reservoir at a depth of approximately 3 km, potentially related to Dakah volcanism. The inverted model also reveals the block-in-matrix structure of the Luk-Ulo Melange Complex in the northern area. [ABSTRACT FROM AUTHOR]

Copyright of Journal of Chongqing University of Technology (Natural Science) is the property of Chongqing University of Technology and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The Main Karoo Basin in South Africa is a typical example of an expanding arid region dependent on groundwater resources. Dolerite dikes in the region, analogous to dolerite dikes worldwide, are known to influence subsurface groundwater flow and spatially relate to high-yielding boreholes. Here, the effect of dolerite dikes on groundwater flow is remotely assessed using the Modified Soil Adjusted Vegetation Index derived from high-resolution multi-spectral satellite imagery. From imagery collected during the wet and dry seasons of 2018 and 2021, two aquifer models relating to 505 dikes were identified; (1) barrier-controlled aquifers are induced by ~ 56% of dikes, (2) fractured aquifers are induced by ~ 35% of dikes. Surficial areas overlying aquifers are also shown to sustain vegetation growth through dry seasons. This research demonstrates the efficacy of vegetation indices to rapidly characterise dike-related aquifer models and their seasonal sustainability, critical for effective groundwater exploration and management. [ABSTRACT FROM AUTHOR]

Dolerite dikes were studied in the western part of the Aldan terrane, in the middle reaches of the Tokko River. These dolerite dikes form a swarm of submeridional trend about 1 km wide. The dolerites of the thickest dike preserve their primary textural and structural features and mineral composition: plagioclase + pigeonite + augite + titanomagnetite. Dolerite in the chilled margins and central parts of the dike are homogeneous in composition, corresponds to low-Mg tholeiites, has low contents of Ti and other HFSE, with weak enrichment in light REE and small negative Nb anomalies. Sm–Nd isotope data on magmatic minerals of dolerite from the central part of the dike yield a good linear regression in an isochron diagram that gives to an age of 2510 ± 64 Ma, which probably corresponds to the crystallization age of the basalt. Metadolerites in a thin dike retain plagioclase porphyritic structures, but the pyroxenes are completely replaced by amphibole and chlorite. The metadolerites are contrastingly different in low contents of MgO, Cr, and Ni and in higher contents of TiO2, Fe2O3, P2O5, Nb, and all REE. The differences in the composition of the dikes may be explained by the longterm (about 65%) crystallization differentiation of the initial melt and the emplacement of the residual melt from a shallow intermediate magma chamber via opening cracks. Such conditions probably may have existed in tectonically stable intraplate settings. The age of the dolerites of the dike swarm is comparable to that of the anorogenic granites of the Nelyuki complex (~2.4–2.5 Ga), which are widespread in the western part of Aldan granulite–gneiss terrane. Our data bridge some gaps in characteristics of intraplate anorogenic magmatism that occurred in the western Aldan Shield in the Late Archean and marked the final consolidation of a large block of Archean crust in the Chara–Olekma granite–greenstone area. [ABSTRACT FROM AUTHOR]

The Tarim Craton is an ancient Precambrian continental block, and detailed knowledge of its thermo‐tectonic history is crucial for understanding the early history of continental evolution. Abundant layered mafic rocks, which have commonly been regarded as basalts, occur within the Ediacaran Sugetbrak Formation (Fm.) in the Aksu region of the northwestern Tarim Craton. Clear intrusive features have now been discovered, including mafic rocks truncating Ediacaran sedimentary layers, exhibiting an intrusion‐baked margin where they interact with both the overlying and bottom wall rocks, and displaying a fine‐grained transition zone from their interior to their margins. The new findings demonstrate that these mafic rocks within the Aksu Ediacaran strata were not erupted basalts but instead are intrusive diabase dykes. Therefore, these mafic rocks cannot be used to constrain the timing of the Sugetbrak Fm. in the Aksu area, nor as marker layers for regional stratigraphic correlation. Furthermore, the Ediacaran thermo‐tectonic evolution in this region, deduced from the assumption that the mafic rocks are lavas, needs to be revised. [ABSTRACT FROM AUTHOR]

Petrographic studies have been carried out on the Early Miocene Darnó Conglomerate Formation, which consists only of debris of ophiolitic mélange and is found today on Darnó Hill in SW Bükk, NE Hungary. The studied sediments are bounded by the Darnó line from Darnó Hill. The aim of this work was to show if it is possible to reconstruct the petrographic composition of the source area only from its debris. The rock types were determined in thin sections using a polarizing microscope, and a quantitative analysis of the different rock types was carried out using the grain counting method, the results of which were interpreted as volume ratios. The main rock types observed in the studied samples (textural varieties of basalt, dolerite/microgabbro, claystone, siltstone, and radiolarite) are similar to the rock types of the mélange assemblage of Darnó Hill. Based on the volume calculations of basaltic detrital grains with different textures characteristic for pillow basalts, it could be established that pillow basalts dominated the igneous rocks in the source area of the Darnó Conglomerate on Darnó Hill already in the Miocene. Thus, this work shows that the lithological composition of a source area can be precisely outlined by a detailed petrographic analysis of the debris eroded from the immediate vicinity. [ABSTRACT FROM AUTHOR]

Identifying volcanic reservoir types and their distribution patterns in volcanic edifices is important for accurate prediction and exploration of hydrocarbon reservoirs. Herein, we analyzed the distribution patterns of different reservoir levels in volcanic edifices, discussed controlling factors, and reclassified reservoir types. This was done using core observations, whole-rock geochemistry, and reservoir physical property analysis, combined with logging, drilling, seismic, and oil-gas test data. Reservoirs can be divided into three classes based on their physical properties. The Mesozoic intermediate and basic rocks formed Class I reservoirs, most lithologies formed Class II reservoirs, and diabase intrusions and tight volcanic rocks formed Class III reservoirs. Reservoirs form in different lithologies in the Huanghua depression due to weathering. Tectonic faults deepen the influence of weathering leading to the formation of reservoirs in tight. Additionally, volcanic rhythms and fractures control the vertical distribution of Cenozoic basaltic reservoirs. Volcanic reservoirs are classified into five types based on the main controlling factors and distribution patterns in volcanic edifices: tectonic-alteration, vesicle-fracture, weathered-effusive, weathered-eruptive, and weathered-tectonic types. Among these, the weathered-eruptive type can easily form Class I reservoirs, making it the best target for exploration. Whereas the weathered-tectonic and vesicle-fracture types tend to develop Class II reservoirs and can be potential targets. The new classification takes into account the relationship between reservoir levels and their distribution in volcanic edifices, it is more conducive to igneous reservoir prediction in the Huanghua depression. This study provides a novel idea for the classification and comparative study of igneous reservoirs in petroliferous basins. [ABSTRACT FROM AUTHOR]

Copyright of Roads & Bridges / Drogi i Mosty is the property of Road & Bridge Research Institute and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Dolerite structures, such as dykes and sills are the main target for groundwater exploration in the Karoo Supergroup area which is the main stratigraphic unit in South Africa. Morgenzon Farm is one of the sites in the Karoo Supergroup, including a dolerite dyke, which is of interest here. The magnetization/susceptibility and resistivity of the dolerite dyke are significantly larger than those of the encompassing sedimentary materials. Therefore, the low induction number electromagnetic (EM-LIN) and magnetometry approaches may be useful for its detection. The EM-LIN is composed of three techniques: EM38, EM31, and EM34, with the latter being manipulated. Since both EM34 and magnetometry inverse problems are linear, a regularized weighted minimum length solution algorithm is utilized for their inverse modelling, but with one main discrepancy: the model weighting function for the magnetometry method is attained from the multiplication of depth weighting and compactness constraints, while the model weighting function is only equal to depth weighting for the EM34 approach. Recovered susceptibility and conductivity sections derived respectively from magnetic and EM34 data sets show high consistency. Inverted models represent a dolerite dyke in the middle of the profile with a depth range of 4 to 15m. [ABSTRACT FROM AUTHOR]

Knowledge of the closure of the archipelago-type southern Paleo-Asian Ocean has been limited by uncertainty regarding whether the Alxa tectonic belt was isolated from the North China craton by an ocean around the Helanshan tectonic belt. Newly released seismic reflection profiles across the Alxa-Ordos border showed that the Alxa tectonic belt and Ordos Basin were located in a paleogeographically linked basin throughout the Paleozoic, indicating that the Tianshan and Solonker sutures were contiguous. The ca. 320–285 Ma successions in the Helanshan tectonic belt and surroundings, fed by a northeasterly Inner Mongolia continental arc source, display a retrogradational stacking pattern along with diabase sill emplacement. This inferred retroarc extensional setting was coeval with asthenospheric upwelling and thinning of the continental arc driven by retreating subduction of the Paleo-Asian Ocean. The subsequent ca. 280–260 Ma sedimentary hiatus coincided with magmatic flare-up, crustal thickening, and retroarc foreland formation in the Inner Mongolia continental arc, indicating a geodynamic transition from retroarc extension to compression in the mid-Permian. Then craton-scale drainage reorganization occurred during the Early Triassic (ca. 250– 230 Ma), manifested by the discharge of the Middle Triassic fluvial system southeastward to the central Ordos Basin; this was steered by southeastward expansion of the Alxa tectonic belt during the final termination of the Paleo-Asian Ocean. Postcollision lithospheric adjustment since ca. 230 Ma resulted in vigorous alkaline magmatism and supracrustal stretching in the Inner Mongolia continental arc as well as mafic magmatism and rifting in the study area. Hence, Carboniferous to Triassic polyphase tectonic transitions in the western North China craton were retroarc basin expressions related to complicated subduction-closure processes in the southern Paleo-Asian Ocean. [ABSTRACT FROM AUTHOR]

Purpose: To investigate diabetic retinopathy (DR) as a potential marker of cardiovascular disease (CVD) in adults with type 1 diabetes attending the Danish DR‐screening programme and non‐diabetes adults. Methods: In this registry‐based matched case–cohort study, we identified 16 547 adults with type 1 diabetes, who were registered in the Danish Registry of Diabetic Retinopathy (DiaBase). Each case was age‐ and sex‐matched by five non‐diabetes individuals (n = 82 399), and odds ratios (ORs) and hazard ratios (HRs) were estimated for incident and upcoming CVD in multivariable models. Results: Adults with type 1 diabetes (median age 44.5 years, 57.6% male) were more likely to have prevalent CVD (OR 1.29; 95% CI, 1.20–1.38) and to develop CVD within 5 years (HR 1.19; 95% CI, 1.08–1.30) as compared to non‐diabetes control. However, adults without DR were less likely to develop CVD (HR 0.84; 95% CI, 0.72–0.97) compared to the reference population. For adults with type 1 diabetes, there was an increasing risk for incident CVD for increasing levels of DR (HR 1.33, 1.95, 1.71 and 2.39 for DR‐levels 1–4, respectively). Patients with CVD at the time of the first screening had a higher risk to develop DR during follow‐up (HR 1.23; 95% CI, 1.02–1.49). Conclusion: In a nationwide matched case–cohort study adjusted for potential confounders, DR was identified as an independent marker of prevalent and incident CVD in type 1 diabetes with increasing risk demonstrated for higher levels of DR. Likewise, CVD also independently predicted the risk of incident DR. [ABSTRACT FROM AUTHOR]

Heat flow data obtained in connection with geothermal resource exploration suggests anomalous upper crustal structure and processes in parts of central east Tasmania. The regional scale crustal geology of the Midlands of Tasmania is, however, mostly obscured at the surface by the Permo-Triassic sedimentary sequences of the Tasmania Basin together with extensive exposures of Jurassic dolerite. We investigate controls on undercover crustal processes in this region by combining long period and broadband magnetotelluric (MT) datasets in 3D inversions for the geoelectric structure; followed by an interpretation that is informed by aspects of the pre-existing 3D regional geological and geophysical model. The new 3D model allows improved resolution of low resistivity anomalies together with a qualitative appraisal of spatially variable model sensitivity. The most robust features ( $ \lt 1\,\Omega {\rm m} $ < 1 Ω m ) in the 2–3 km depth interval occur where N–S and E–W faults intersect with a high point in the topography of the upper surface of a deep seated granite body. Enhancement of conductivity in this zone by clay, graphite or mineralisation, or a combination thereof, is likely. Other low resistivity features suggest that conductive pathways exist where major or multiple faults are present. These interpretations provide support for continued exploration in the Midlands of Tasmania for a variety of resources related to crustal fluids and fracturing. [ABSTRACT FROM AUTHOR]

Copyright of World Nuclear Geoscience is the property of World Nuclear Geoscience Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Measurements of multiple cosmogenic nuclides in a single sample are valuable for various applications of cosmogenic nuclide exposure dating and allow for correcting exposure ages for surface weathering and erosion and establishing exposure–burial history. Here we provide advances in the measurement of cosmogenic 10 Be in pyroxene and constraints on the production rate that provide new opportunities for measurements of multi-nuclide systems, such as 10Be/3He , in pyroxene-bearing samples. We extracted and measured cosmogenic 10 Be in pyroxene from two sets of Ferrar Dolerite samples collected from the Transantarctic Mountains in Antarctica. One set of samples has 10 Be concentrations close to saturation, which allows for the production rate calibration of 10 Be in pyroxene by assuming production–decay equilibrium. The other set of samples, which has a more recent exposure history, is used to determine if a rapid fusion method can be successfully applied to samples with Holocene to Last Glacial Maximum exposure ages. From measured 10 Be concentrations in the near-saturation sample set we find the production rate of 10 Be in pyroxene to be 3.74 ± 0.10 atoms g -1 yr -1 , which is consistent with 10Be/3He paired nuclide ratios from samples assumed to have simple exposure. Given the high 10 Be concentration measured in this sample set, a sample mass of ∼ 0.5 g of pyroxene is sufficient for the extraction of cosmogenic 10 Be from pyroxene using a rapid fusion method. However, for the set of samples that have low 10 Be concentrations, measured concentrations were higher than expected. We attribute spuriously high 10 Be concentrations to failure in removing all meteoric 10 Be and/or a highly variable and poorly quantified procedural blank background correction. [ABSTRACT FROM AUTHOR]

The Nellie Tonalite forms a discontinuous 20 km elongate northwest-trending felsic intrusion at the far-western end of the Western Zone of the Lamboo Province, in the Wunaamin Miliwundi Orogen, Western Australia. This intrusion is poorly understood with previous interpretations assigning it to the ca 1860 Ma Paperbark Supersuite. We present the first geochronological results for the Nellie Tonalite, which have a weighted mean laser ablation, inductively coupled plasma, mass spectrometry (LA-ICP-MS) U–Pb zircon age of 1794 ± 4 Ma. This date is coincident with the age for felsic granophyres of the Hart Dolerite, which have previously been described from the Kimberley Basin overlying the Halls Creek Orogen and central parts of the Wunaamin Miliwundi Orogen. Other similarities of the Nellie Tonalite with the felsic Hart Dolerite are micrographic and granophyric intergrowths of quartz and K-feldspar, and a distinct geochemical depletion of V. This V depletion is interpreted to be the result of closed-system, in situ fractional crystallisation of titanomagnetite from a basaltic composition. The fractional residue from this process can be found at several locations across the Halls Creek Orogen and Wunaamin Miliwundi Orogen and at Speewah Dome in the east Kimberley where magnetite gabbros within the Hart Dolerite also host a large Ti–V mineral resource. It is proposed that the Nellie Tonalite is a western correlate of the felsic Hart Dolerite. This demonstrates that the magmatic processes required for Speewah-style Ti–V mineralisation are extensive across the entire Lamboo Province. Additionally, the scale, constancy of the composition, texture and age of the felsic Hart Dolerite encompassing the entire inland margin of the Kimberley Region, and the rapid emplacement time of <3 m.y., support the interpretation of a mantle plume model for the emplacement of the Hart Dolerite. KEY POINTS: The Nellie Tonalite is redefined as a granophyric granite, has been dated to 1794 ± 4 Ma and is coeval with the ca 1800 Ma Hart Dolerite. Petrographic, geochemical and geochronological evidence suggests that the Nellie Tonalite is a product of in situ fractional crystallisation of the Hart Dolerite (felsic Hart Dolerite). Plots of Ti/Nb vs V/Sc are ideal in identifying the distinctive V-depletion associated with the felsic Hart Dolerite, which marks a valuable stratigraphic horizon for identifying potential Speewah-style Ti–V mineralisation. [ABSTRACT FROM AUTHOR]

The energy budget and the interplay between stable friction evolution and dynamic stick‐slips are tested here under continuous slip along rough faults. We conducted 34 direct‐shear experiments coupled with precise roughness measurements on diabase and limestone fault samples. The faults broad roughness ranges from highly rough and interlocked fractured interfaces to smooth polished surfaces. The analysis focuses on two slip phases: (a) the evolution of the shear strength of rough sample under stable, cumulative displacement; and (b) the dynamic of unstable stick‐slip sliding. We found that the breakdown work during frictional strength evolution increases with roughness increase across multiple scales. The diabase samples are more sensitive to roughness increase than limestone samples in terms of the breakdown work implied by frictional evolution. We attribute this increased diabase sensitivity with fault roughness to its higher bulk elasticity and not to the fault shear stiffness. The diabase faults displayed multiple periodic system‐size stick‐slips, and the measured stored energy during the preparatory stage were surprisingly independent of the fault roughness. This finding suggests that during the preparatory stage a balance between the intracycle fault stiffness and stress drop govern the stored energy magnitude. Further, this energy balance suggests that some interface conditioning occurs before the spontaneous slip overcomes a sticking barrier. Plain Language Summary: The breakdown energy dissipated as work during friction evolution along laboratory faults can be determined by integration of the shear stress versus shear displacement. In this study, we quantitatively analyze the relationship between the roughness of laboratory faults and the dissipated energy during sliding. The experiments with rough diabase and limestone faults show an increase of breakdown work implied by the frictional strength with increasing fault roughness, and breakdown work increase with increasing host rock rigidity. We also find that the energy dissipated during frictional evolution of rough faults is four orders of magnitude larger than the energy dissipated during system size stick‐slip cycles in the same experimental setting. We attribute this observed discrepancy to the difference in contact area between interlocked, and sheared, surfaces. Surprisingly, our examination of breakdown work during stick‐slip cycles reveals a roughness‐independent behavior. We ultimately show that the energy components of both stick‐slip and friction evolution follow the same power law relationship when scaled to the sliding displacement. Key Points: The breakdown work implied by the evolution of frictional strength scales with roughness (RMS) height and elasticity of intact rockThe stored energy within stick‐slip cycles is four orders of magnitude lower than the energy accommodated during friction evolutionThe stored energy at the onset of breakdown during stick‐slip cycles is generally independent of fault roughness [ABSTRACT FROM AUTHOR]

Petrological, geochronological, and geochemical analyses of mafic rocks in northern Liaoning were conducted to constrain the formation age of the Proterozoic strata, and to further study the source characteristics, genesis, and tectonic setting. The mafic rocks in northern Liaoning primarily consist of basalt, diabase, gabbro, and amphibolite. Results of zircon U-Pb chronology reveal four stages of mafic magma activities in northern Liaoning: the first stage of basalt (2209 ± 12 Ma), the second stage of diabase (2154 ± 15 Ma), the third stage of gabbro (2063 ± 7 Ma), and the fourth stage of magmatic protolith of amphibolite (2018 ± 13 Ma). Combined with the unconformity overlying Neoproterozoic granite, the formation age of the Proterozoic strata in northern Liaoning was found to be Paleoproterozoic rather than Middle Neoproterozoic by the geochronology of these mafic rocks. A chronological framework of mafic magmatic activities in the eastern segment of the North China Craton (NCC) is proposed. The mafic rocks in northern Liaoning exhibit compositional ranges of 46.39–50.33 wt% for SiO2, 2.95–5.08 wt% for total alkalis (K2O + Na2O), 6.17–7.50 wt% for MgO, and 43.32–52.02 for the Mg number. TiO2 contents lie between 1.61 and 2.39 wt%, and those of MnO between 0.17 and 0.21 wt%. The first basalt and the fourth amphibolite show low total rare earth element contents. Normalized against primitive mantle, they are enriched in large ion lithophile elements (Rb, Ba, K), depleted in high field strength elements (Th, U, Nb, Ta, Zr, Ti), and exhibit negative anomalies in Sr and P, as well as slight positive anomalies in Zr and Hf. The second diabase and the third gabbro have similar average total rare earth element contents. The diabase shows slight negative Eu anomalies (Eu/Eu* = 0.72–0.88), enrichment in large ion lithophile elements (Ba), depletion in Rb, and slight positive anomalies in high field strength elements (Th, U, Nb, Ta, Zr, Hf, Ti), with negative anomalies in K, Sr, and P. The gabbro is enriched in large ion lithophile elements (Rb, Ba, K), depleted in high field strength elements (Th, U, Nb, Ta, Zr, Hf), and exhibits positive anomalies in Eu (Eu/Eu* = 1.31–1.37). The contents of Cr, Co, and Ni of these four stages of mafic rocks are higher than those of N-MORB. The characteristics of trace element ratios indicate that the mafic rocks belong to the calc-alkaline series and originate from the transitional mantle. During the process of magma ascent and emplacement, it is contaminated by continental crustal materials. There are residual hornblende and spinel in the magma source of the first basalt. The other three magma sources contain residual garnet and spinel. The third gabbro was formed in an island arc environment, and the other three stages of mafic rocks originated from the Dupal OIB and were formed in an oceanic island environment. The discovery of mafic rocks in northern Liaoning suggests that the Longgang Block underwent oceanic subduction and extinction in both the north and south in the Paleoproterozoic, indicating the possibility of being in two different tectonic domains. [ABSTRACT FROM AUTHOR]

The Jurassic igneous rocks on Sumatra Island are important for investigating the Mesotethyan evolution and regional correlation in Southeast Asia. This paper presents new laser ablation-multicollector-inductively coupled plasma-mass spectrometry zircon U-Pb-Hf geochronological and isotopic, whole-rock elemental, and Sr-Nd isotopic data for the newly identified Glebruk dolerite and andesite in North Sumatra. New zircon dating results suggest that these mafic-intermediate volcanic rocks, with ages of 150-146 Ma, were formed during the Late Jurassic. The Glebruk dolerite and andesite belong to the calc-alkaline series, are enriched in the light rare earth elements, and exhibit depletion in Nb, Ta, and Ti. Thus, they resemble arc-like volcanic rocks. They have low (87Sr/86Sr)i ratios of 0.7038-0.7048 and strong positive eNd(t) and eHf(t) values of +6.4 to +7.5 and +4.8 to +18.6, respectively. Their geochemical signatures suggest that these Late Jurassic volcanic rocks were derived from a depleted mantle wedge that was metasomatized by the slab-derived melts. The Glebruk volcanic rocks were formed in a continental arc setting in response to the Late Jurassic northward subduction of the Woyla Ocean beneath West Sumatra. Our results and regional geological observations suggest that the Mesotethyan subduction-related igneous rocks could extend from South Qiangtang through West Yunnan to North Sumatra. The Woyla Ocean could represent the southern extension of the Mesotethyan Ocean. [ABSTRACT FROM AUTHOR]

The post-collisional evolution of the Tibetan lithosphere is of paramount significance to our understanding of collisional orogeny. It is generally postulated that the Lhasa lithospheric mantle was horizontally shortened and thickened coherently with the overlying crust to form a physical barrier, preventing Indian subduction beneath Tibet until the thickened mantle root was foundered during the Miocene. This study first identifies post-collisional oceanic-island basalt (OIB)-type magmatism in the Lhasa Block (LB), as attested by zircon U-Pb age (ca. 58 Ma) and geochemistry--positive Nb-Ta anomalies, high La/Yb, and depleted bulkrock Sr-Nd and zircon Hf isotopes, of diabase in the northern (inboard relative to Indus Suture) part of this block. Coupled with extensive early Paleogene arc-type magmatism in the southern-central LB and thermodynamic modeling, we suggest that these diabases were formed by partially molten upwelling asthenosphere near the base of continental crust, where much of the underlying lithospheric mantle had been removed due to Neo-Tethyan slab rollback and lithospheric delamination. Compared to OIB-type magmatism worldwide, the diabases investigated here were emplaced peculiarly in a region where the continental crust was under horizontal compression and shortening by coeval thrusting. Our study thus implies a decoupled deformation between the crust and mantle of the LB during the early Indian-Asian collision. [ABSTRACT FROM AUTHOR]

The Newark Basin comprises Late Triassic and Early Jurassic fluvio-lacustrine rocks (Stockton, Lockatong, Passaic, Feltville, Towaco, and Boonton Formations) and Early Jurassic diabase intrusions and basalt lava flows. Boron concentrations in private well water samples range up to 18,000 μg/L, exceeding the U.S. Environmental Protection Agency Health Advisory of 2000 μg/L for children and 5000 μg/L for adults. Boron was analyzed in minerals, rocks, and water samples using FUS-ICPMS, LA-ICP-MS, and MC ICP-MS, respectively. Boron concentrations reach up to 121 ppm in sandstone of the Passaic Formation, 42 ppm in black shale of the Lockatong Formation, 31.2 ppm in sandstone of the Stockton Formation, and 36 ppm in diabase. The δ11B isotopic values of groundwater range from 16.7 to 32.7‰, which fall within those of the diabase intrusion (25 to 31‰). Geostatistical analysis using Principal Component Analysis (PCA) reveals that boron is associated with clay minerals in black shales and with Na-bearing minerals (possibly feldspar and evaporite minerals) in sandstones. The PCA also shows that boron is not associated with any major phases in diabase intrusion, and is likely remobilized from the surrounding rocks by the intrusion-related late hydrothermal fluids and subsequently incorporated into diabase. Calcite veins found within the Triassic rock formations exhibit relatively elevated concentrations ranging from 6.3 to 97.3 ppm and may contain micro-inclusions rich in boron. Based on the available data, it is suggested that the primary sources of boron contaminating groundwater in the area are clay minerals in black shales, Na-bearing minerals in sandstone, diabase intrusion-related hydrothermal fluids, and a contribution from calcite veins. [ABSTRACT FROM AUTHOR]

It is well established that Cretaceous magmatism in the South China Block (SCB) is related to the Paleo‐Pacific subduction. However, the starting time and the associated deep crust‐mantle processes are still debatable. Mafic dike swarms carry important information on the deep earth (including mantle) geodynamics and geochemical evolution. In the Jiangnan Orogen (South China), there is no information on whether the Mesozoic magmatic activities in this region are also directly related to the Pacific subduction or not. In this study, we present detailed zircon U‐Pb geochronological, whole‐rock element and Sr‐Nd isotope data for Early Cretaceous Tuanshanbei dolerite dikes, and provide new constraints on the condition of the lithospheric mantle and mantle dynamics of the SCB during that time. LA‐ICP‐MS zircon U‐Pb dating suggests that this dolerite erupted in the Early Cretaceous (∼145 Ma). All samples have alkaline geochemical affinities with K2O + Na2O = 3.11–4.04 wt%, K2O/Na2O = 0.50–0.72, and Mg# = 62.24–65.13. They are enriched in LILE but depleted in HFSE with higher initial 87Sr/86Sr ratio (0.706896–0.714743) and lower εNd(t) (–2.61 to –1.67). They have high Nb/U, Nb/La, La/Sm and Rb/Sr, and low La/Nb, La/Ta, Ce/Pb, Ba/Rb, Tb/Yb and Gd/Yb ratios. Such geochemical signatures suggest that the fractional crystallization is obvious but crustal contamination play a negligible role during magmatic evolution. Tuanshanbei dolerite were most likely derived from low‐degree (2%–5%) partial melting of a phlogopite‐bearing mantle material consisted of ∼85% spinel peridotite and ∼15% garnet peridotite previously metasomatized by asthenosphere‐derived fluids/melts with minor subduction‐derived fluids/melts. Slab‐rollback generally lead to the upwelling of the hot asthenosphere. The upwelling of asthenosphere consuming the lithospheric mantle by thermo‐mechanical‐chemical erosion. The lithospheric mantle may have partially melted due to the heating by the upwelling asthenosphere and lithospheric extension. It is inferred that the Tuanshanbei dolerite might be associated with the initial slab rollback and corresponding lithospheric extension occurred potentially at ca. 145 Ma. [ABSTRACT FROM AUTHOR]

Mesoproterozoic (ca. 1.3 Ga) magmatism in the North China Craton (NCC) was dominated by mafic intrusions (dolerite sills) with lesser amounts of granitic magmatism, but our lack of knowledge of this magmatism hinders our understanding of the evolution of the NCC during this period. This study investigated porphyritic granites from the Huade–Kangbao area on the northern margin of the NCC. Zircon dating indicates the porphyritic granites were intruded during the Mesoproterozoic between 1285.4 ± 2.6 and 1278.6 ± 6.1 Ma. The granites have high silica contents (SiO2 = 63.10–73.73 wt.%), exhibit alkali enrichment (total alkalis = 7.71–8.79 wt.%), are peraluminous, and can be classified as weakly peraluminous A2-type granites. The granites have negative Eu anomalies (δEu = 0.14–0.44), enrichments in large-ion lithophile elements (LILEs; e.g., K, Rb, Th, and U), and depletions in high-field-strength elements (HFSEs; e.g., Nb, Ta, and Ti). εHf(t) values range from –6.43 to +2.41, with tDM2 ages of 1905–2462 Ma, suggesting the magmas were derived by partial melting of ancient crustal material. The geochronological and geochemical data, and regional geological features, indicate the Mesoproterozoic porphyritic granites from the northern margin of the NCC formed in an intraplate tectonic setting during continental extension and rifting, which represents the response of the NCC to the break-up of the Columbia supercontinent. [ABSTRACT FROM AUTHOR]

New evidence of the Early Silurian sublithospheric magmatic activity in the eastern part of the Altai–Sayan orogen has been obtained. This activity occurred between large-scale mantle-derived magmatic episodes of the Middle–Late Ordovician and Devonian. It involved high-Mg (15–22 wt % MgO) picritic dolerite dikes of the Naryn complex in the western part of the Tuva–Mongolian Superterrane. The dike complex consists of simple picrodolerite dikes and those combined with a central picrodolerite zone and granitoids at contacts with mingling relationships between contrasting rocks. The picrodolerite geochemical signature is similar to enriched basalts of the mid-ocean ridges or intraplate regions and is indicative of a sublithospheric mantle source. Initial picrodolerite melts were formed at a depth of about 120–140 km, a temperature of 1600–1640°C, and a melting degree of up to 20% at a dry peridotite source. These values are consistent with the conditions of the hot spot magmas origin. Granitoids from the combined dikes had a crustal geochemical signature and were formed due to the anatexis of the Tuva–Mongolian Superterrane host rocks initiated by the picrodolerite intrusion. The U–Pb zircon age (SHRIMP-II) of leucogranite from the combined dike is 439 ± 3 Ma interpreted as the age of the Naryn dike complex. The Early Silurian mantle-derived magmatic activity of the Southeastern Tuva most likely caused the migration of the Siberian paleocontinent over the African mantle hot field. [ABSTRACT FROM AUTHOR]

The "National Diamond Exploration Field Seminar" held by China Geological Survey in Suzhou, Anhui in 2013 kicked off a new round of primary diamond deposits exploration in China. In the past decade, a series of new progress in the exploration and research of primary diamond deposits have been made: the new batch of primary diamond resources identified in Langan, Anhui and Wafangdian, Liaoning further enhanced domestic supply ability of diamond resources. The VI diamond mineralization belt in Liaoning, the Pingyi-Feixian diamond mineralization belt in Shandong and new prospecting clues in Other regions will expand the exploration spaces of primary diamond deposits. The comprehensive exploration methods such as tectonic analysis-3D modeling-engineering verification, and high-resolution remote sensing information extraction are new exploring ideas for deep exploration and the discovery of hidden rock bodies. New insights in the genesis of diamond-bearing rock bodies, the emplacement model of kimberlite (potassium magnesium lamprophyre), and the study of diamond source area have been acquired. The chronological studies have shown that the mineralization of diamond-bearing parent rock in China extends from the Paleozoic to the late Mesozoic, which embodies the feature of multi-stage metallogenesis. Based on the progress and new problems in diamond exploration and research in the past decade, the suggestions for future exploration and research of primary diamond deposits is also proposed in the paper. [ABSTRACT FROM AUTHOR]

The dynamics and magma transport at the boundary between the upper and lower oceanic crusts (i.e., the dike–gabbro transition) are crucial for understanding the crustal accretion beneath mid-ocean ridges, which however have been studied at quite a few sites such as the East Pacific Rise and ophiolites like Troodos and Oman. Here we present detailed geological, petrological, and geochemical data for the dike–gabbro transition and associated basalts in the Yunzhug ophiolite, central Tibet, to constrain the complex magmatic processes in this specific horizon. The Yunzhug ophiolite contains a large (~ 20 km2) well-exposed sheeted dike complex, which is rooted in a dike–gabbro transition that consists of diverse lithologies, including diabase, gabbro, and minor porphyritic diabase. Petrographically, the Yunzhug gabbros could be grouped into the dominant Plg (plagioclase)-euhedral gabbros (euhedral–subhedral plagioclases enclosed in clinopyroxene oikocrysts) and a small amount of Cpx (clinopyroxene)-euhedral gabbros (with abundant euhedral clinopyroxenes). Plagioclases and their equilibrated melts of the two types of gabbros are similar, whereas clinopyroxenes and their equilibrated melts of the Cpx-euhedral gabbros are more primary and depleted than those of the Plg-euhedral gabbros. These petrographic and geochemical features suggest an earlier crystallization of clinopyroxene for the Cpx-euhedral gabbros, which is best explained by occasional water input in the magmatic system. Nevertheless, the modeled equilibrated melts of the two types of gabbros have compositions indistinguishable from the whole rock compositions of diabases and basalts, indicating a direct genetic linkage between these rocks. The unusual porphyritic diabases, on the other hand, provide evidence supporting for plagioclase accumulation and aggregation during magma upward migration, thus may have served as a unique way for magma to transport from the lower to upper crust. Studies of the Yunzhug ophiolite thus provide some key constraints on the complex magmatic processes in the oceanic dike–gabbro transition, regarding its dynamic accretion and magmatic plumbing mechanisms. [ABSTRACT FROM AUTHOR]

Background. Production of basalt fiber materials for thermal insulation materials, based on igneous rocks, meets the requirements of world standards. Purpose. Comparative analysis of chemical and mineralogical compositions and structures of igneous rocks for obtaining basalt fibers. Methodology. The studies were carried out using modern physicochemical methods adopted in the technology of mineral (basalt) fibers and thermal insulation materials. Originality. Chemical and mineralogical compositions and structures of various igneous rocks from different deposits were determined to establish their suitability for obtaining basalt fibers. Findings. The content of the main rock-forming components of igneous rocks was determined, their structure and properties were studied. [ABSTRACT FROM AUTHOR]

The stability of roadway sidewalls is crucial to ensuring people's safety and production efficiency in coal mining. This paper investigated the deformation and failure of deep roadway sidewalls, particularly the effects of height-width ratios and lateral pressure coefficients. Our research results indicate that brittle failure occurred in the diabase sidewall rock of the Datai coal mine, and a V-shaped pit was formed as a result of shear damage caused by high stress. When the height-width ratio of a roadway increases from 0.25 to 2.00, the tensile and shear plastic failure area of the sidewall increases, and vertical stress is transferred to a deep part of the roadway sidewall. There are two stress concentration zones and two stress peak points in the sidewall of a roadway. When the lateral pressure coefficient increases from 0.10 to 1.00, the tensile plastic zone of rock mass in the sidewall first decreases and gradually reaches stability. On the other hand, the shear failure area increases and then decreases. Similarly, the sidewall horizontal displacement decreases and then increases. Additionally, the vertical stress concentration position is located near the roadway sidewall. [ABSTRACT FROM AUTHOR]

For the Jiawula lead–zinc deposit, as easily accessible resources become depleted, mines are becoming deeper to replenish ore reserves. Identifying large, continuous, and high-grade ore bodies in deep areas has become a daunting problem. Moreover, separating lead–zinc-bearing complex ore bodies from waste material and extracting them from associated minerals are also difficult. Thus, pioneering exploratory strategies and technological methodologies are required to make breakthroughs in mineral discovery. Based on extensive-scale structural lithofacies mapping, this paper uses short-wave infrared (SWIR) spectroscopy technology to investigate hydrothermal alteration minerals in the mining area. It has identified a total of 16 hydroxyl-bearing alteration minerals, including chlorite, muscovite, illite, calcite, ankerite, kaolinite, and smectite. These minerals establish zoning characteristics around the ore bodies and on their flanks. They comprise a segmented assemblage that follows the pattern of comb-textured quartz–illite–chlorite–carbonate → muscovite–illite–chlorite–ankerite → illite–smectite–chlorite → chlorite–kaolinite–calcite. Deep-zone illitization with a lower Al–OH absorbance peak wavelength (<2206 nm) and higher crystallinity indices (>1.1) and chloritization with higher Fe–OH absorbance peak wavelengths (>2254) and higher crystallinity indices (>3.0) are indicators of potential hydrothermal centers in the deeper regions. By finding hydrothermal centers and connecting their spatial distribution with existing ore bodies, a pertinent relationship between diabase + andesite, Fe-chlorite + illite, and high-grade mineralization has been established. They correspond well with the lithology-alteration mineralization. This research provides a basis for predicting the positioning of concealed ore bodies deep inside a mine or at the periphery. [ABSTRACT FROM AUTHOR]

Early Paleozoic magmatism in the West Kunlun Orogenic Belt (WKOB) preserves important information about the tectonic evolution of the Proto-Tethys Ocean. This paper reports whole-rock compositions, zircon and apatite U-Pb dating, and zircon Hf isotopes for the Qiaerlong Pluton (QEL) at the northwestern margin of WKOB, with the aim of elucidating the petrogenesis of the pluton and shedding insights into the subduction-collision process of this oceanic slab. The QEL is mainly composed of Ordovician quartz monzodiorite (479 ± 3 Ma), quartz monzonite (467–472 Ma), and syenogranite (463 ± 4 Ma), and is intruded by Middle Silurian peraluminous granite (429 ± 20 Ma) and diabase (421 ± 4 Ma). Zircon εHf(t) values reveal that quartz monzodiorites (+2.1 to +9.9) and quartz monzonites (+0.6 to +6.8) were derived from a mixed source of juvenile crust and older lower crust, and syenogranites (−5.6 to +4.5) and peraluminous granites (−2.9 to +2.0) were generated from a mixed source of lower crust and upper crust; diabases had zircon εHf(t) values ranging from −0.3 to +4.1, and contained 463 ± 5 Ma captured zircon and 1 048 ± 39 Ma inherited zircon, indicating they originated from enriched lithospheric mantle and were contaminated by crustal materials. The Ordovician granitoids are enriched in LILEs and light rare-earth elements, and depleted in HFSEs with negative Nb, Ta, P, and Ti anomalies, suggesting that they formed in a subduction environment. Middle Silurian peraluminous granites have the characteristics of leucogranites with high SiO2 contents (74.92 wt.%–75.88 wt.%) and distinctly negative Eu anomalies (δEu = 0.03–0.14), indicating that they belong to highly fractionated granite and were formed in a post-collision extension setting. Comparative analysis of these results with other Early Paleozoic magmas reveals that the Proto-Tethys ocean closed before the Middle Silurian and its southward subduction resulted in the formation of QEL. [ABSTRACT FROM AUTHOR]

The study of the volcano–sedimentary sequence in the lower part of the Zaonega formation in the Paleoproterozoic Onega structure (Karelian craton, Fennoscandian Shield) has shown that tuffaceous and high-silica rocks predominate in its composition. High-silica rocks (SiO2 up to 94 wt %) are depleted in all elements and probably represent chemogenic siliceous silts. Tuffaceous rocks vary broadly in composition and were formed during mixing of tuffogenous basalt material and high-silica chemogenic sediments. In terms of levels of contents and the distribution character of trace elements, tuffogenous rocks are close to N-MORB volcanic rocks. This rock association is typical of the early stages of continental rifting in the Phanerozoic and may indicate the formation of volcano–sedimentary complexes of the Zaonega formation in the environment of continental rifting. The tuffaceous rocks in the lower part of the Zaonega formation are geochemically identical to dolerite dikes and MORB-type volcanic rocks 2.10–2.14 Ga in age. Their formation was probably related to this episode of large-scale extension and thinning of the continental lithosphere of the Karelian craton in the Middle Paleoproterozoic. In this case, the age limit of the Zaonega and underlying Tulomozero formations should be somewhat older than the 2.06–2.10 Ga interval accepted in the modern regional stratigraphic schemes of the Paleoproterozoic Fennoscandian shield. [ABSTRACT FROM AUTHOR]

Inner fracture zones play a decisive role in the formation of high-quality reservoirs in buried hill reservoirs in covered metamorphic rock. Based on core, sidewall core, thin section, seismic, logging and reservoir physical property data, the fracture development characteristics of the Bozhong 13-2 block buried hill reservoir are described in detail and the controlling factors and the influence on reservoir quality are discussed. The results showed: (1) three groups of tectonic fractures developed in the study area—near-EW-striking, ENE-striking and nearly N–S-striking fractures—were controlled by the early Indosinian thrusting, the late Indosinian to early Yanshanian sinistral strike-slipping and the late Yanshanian late dextral strike-slipping in the Bohai Bay Basin, respectively. The ENE- and nearly-E-W-striking fractures are the most common, and the dip angles of the fractures are mostly between 35° and 75° and thus oblique. (2) The Indosinian-early Yanshanian was the main fracture-forming period, and the dextral strike-slip action in the late Yanshanian was the key to maintaining effective fractures. Imaging logging shows that 97.87% of the fractures are effective fractures. Based on thin section observation, 14.47% of the fractures are unmodified open fractures and 80.37% of the fractures are effective fractures due to reactivation. (3) The late Yanshanian strike-slip fault transformed the deformation adjustment zone formed by the early Indosinian thrust faulting and the core of the fold structure was more conducive to fracture development. The fracture density of a single well located within the deformation adjustment zone and at the core of the fold is between 0.93–1.49 m−1, the fracture density of a single well located only at the core of the fold is between 0.67–0.75 m−1 and that of a single well located at the wing of the fold is between 0.35–0.59 m−1. Diabase dike intrusions promoted the development of local fractures. (4) Fractures promote the migration and accumulation of oil and gas, and the fracture density in the oil layer is between 0.81–2.19 m−1. That in the nonoil layer is between 0.25–1.12 m−1. In addition, fractures not only provide storage space but also effectively improve the reservoir capacity of the inner fracture zones of buried hill reservoirs by concentrating dissolution. [ABSTRACT FROM AUTHOR]

Measurements of multiple cosmogenic nuclides in a single sample are valuable for various applications of cosmogenic nuclide exposure dating and allow for correcting exposure ages for surface weathering and erosion and establishing exposure-burial history. Here we provide advances in the measurement of cosmogenic 10Be in pyroxene and constraints on the production rate which provide new opportunities for measurements of multi-nuclide systems, such as 10Be/³He, in pyroxene-bearing samples. We extracted and measured cosmogenic 10Be in pyroxene from two sets of Ferrar Dolerite samples collected from the Transantarctic Mountains in Antarctica. One set of samples has 10Be concentrations close to saturation which allows for the production rate calibration of 10Be in pyroxene by assuming production-erosion equilibrium. The other set of samples, which has a more recent exposure history, is used to determine if a rapid fusion method can be successfully applied to samples with Holocene to Last-Glacial-Maximum exposure ages. From measured 10Be concentrations in the near-saturation sample set we find the production rate of 10Be in pyroxene to be 3.74 +/- 0.10 atoms g-1 yr-1 and is consistent with 10Be/³He paired nuclide ratios from samples assumed to have simple exposure. Given the high 10Be concentration measured in this sample set, a sample mass of ~0.5 g of pyroxene is sufficient for the extraction of cosmogenic 10Be from pyroxene using a rapid fusion method. However, for the set of samples having low 10Be concentrations, measured concentrations were higher than expected. We attribute spuriously high 10Be concentration to potential failure in removing all meteoric 10Be and/or a highly variable and poorly quantified measurement background. [ABSTRACT FROM AUTHOR]

Several Jurassic, ophiolite-hosted Cu-Zn VMS deposits occur in Tuscany. They are hosted by tectonic units of oceanic affinity (Ligurian Units), such as the well-known deposits of nearby Liguria. Industrial production was small and definitively ceased in the 1960s. Locally, massive ore (chalcopyrite-bornite-chalcocite) with an exceptionally high grade was found. The Montecatini Val di Cecina mine exploited the largest "bonanza" and, for few decades in the 19th century, became one of the most profitable copper mines in Europe. This study provides an updated review of these deposits. Tuscan Cu-Zn VMSs mostly occur in proximity of the contact between the serpentinite-gabbro basement and the overlying basalts. Chalcopyrite-pyrite stockworks occur in serpentinite-gabbro cut by dolerite dykes, while the largest massive sulphide bodies are hosted by polymictic-monomictic breccias at the base of pillow basalts. Early chalcopyrite ores were mechanically–chemically reworked and upgraded to bornite-rich nodular ore embedded in a chlorite, calcic amphibole, Fe-rich serpentine, quartz, andradite, ilvaite, and xonotlite assemblage. This bornite-rich ore contains substantial amount of sphalerite and pyrite and ubiquitous grains of clausthalite, hessite, tellurium, and gold. They represent a prime example of the sub-seafloor portion of a hybrid mafic-ultramafic oceanic hydrothermal system formed in an OCC along the slow spreading ridge of the Jurassic Piedmont-Ligurian Ocean. The peculiar mineralogical–textural character of the bornite-rich ore was driven by an interface coupled dissolution–precipitation process mediated by fluids. [ABSTRACT FROM AUTHOR]

The tremolite nephrite deposit in Dahua county, Hechi City, Guangxi province, China is a new genetic type of nephrite deposit. It is hosed by Mg-poor limestone (~1.30 wt.% MgO) and intruded by diabase (~45 wt.% SiO2). The Mg and Si contents of these rocks are lower than those of the tremolite (58.18 wt.% SiO2, 13.18 wt.% CaO, 24.16 wt.% MgO), indicating an obviously insufficient source for the metallogenic material that generated the deposit. In particular, some tremolite nephrite ore bodies have no clear contact metamorphism between the host and intrusive rocks, which have the characteristics of stratified mineralization (stratified tremolite nephrite). The origin and mineralization of stratified tremolite nephrite remain poorly constrained. To address this shortcoming, the mineralogy, geochemistry and Sr isotopic of host rock, altered marble, stratified tremolite nephrite and intrusive rock in the Dahua stratified tremolite nephrite deposit were studied. The results show: stratified tremolite nephrite mainly consists of aggregates of microcrystalline-cryptocrystalline tremolites with content exceeding 95%. The in situ rare earth elements (REEs) distribution pattern of hydrothermal calcite in the contact position between stratified tremolite nephrite and marble is similar to that of marine carbonate rock, showing obvious enrichment of HREE, which is different from calcite in limestone and marble. 87Sr/86Sr of stratified tremolite nephrite is relatively uniform, with an average value of 0.7070, within the range of Permian seawater. The mean value of Y/Ho in the hydrothermal calcite is 51.24, indicating that the marine fluid has not been impregnated by terrigenous materials. In summary, the hydrothermal fluid rich in Ca and Si is formed after marine carbonate rocks are altered by marine fluids. Hydrothermal fluids alter diabase rocks formed by altered minerals like titanite, chamosite, zoisite, etc. This process leads to the formation of metallogenic hydrothermal fluids abundant in Si, Ca, Fe and Mg. The metallogenic hydrothermal fluids migrate in faults and fractures of marble and crystallize to form tremolite nephrite under suitable ore-forming conditions. [ABSTRACT FROM AUTHOR]

The Sanjiang Tethyan Orogen plays a pivotal role in elucidating the geodynamic processes related to the evolution of the Paleo-Tethys Ocean. Research on the Gicha Complex within this orogen is imperative for comprehending the intricate evolution of the region. This study presents new findings from zircon U‒Pb dating, Hf isotope analysis, and whole-rock elemental analyses of gabbro, olivine gabbro, and the recently discovered mylonitic rhyolite and diabase in the Gicha Complex. The zircon U‒Pb dating yields ages of 703 ± 3 Ma for the diabase, 296 ± 2 Ma for the gabbro, and 231 ± 1 and 228 ± 2 Ma for the mylonitic rhyolite, demonstrating that these rocks record the extended evolution from the breakup of Rodinia to the closure of the Paleo-Tethys Ocean. The Neoproterozoic diabase samples exhibit shoshonitic and arc-like geochemical properties, with positive zircon εHf(t) values ranging from 1.1 to 3.7 and high Th/Yb values ranging from 1.34 to 3.07, suggesting that they were generated by partial melting of enriched subduction-modified lithospheric mantle in an active continental margin. The early Permian gabbro samples are part of the tholeiitic series and exhibit low SiO2 and K2O contents; depletions in Nb, Ta and Ti; and enrichment in Pb, indicating derivation from a combination of depleted mantle peridotite and subduction-related components. The whole-rock geochemical features suggest that these rocks formed in a back-arc setting featuring a small, mature ocean basin. The mylonitic rhyolite samples exhibit weakly peraluminous characteristics (A/CNK = 0.98–1.12) with high-K calc-alkaline geochemical features. The samples are depleted in Ba, Nb, Ta, and Ti and enriched in Th, U, Pb, and LREEs and exhibit negative to positive zircon εHf(t) values ranging from − 0.5 to + 5.9, indicating that they originated from partial melting of Meso-Neoproterozoic juvenile lower crust. Geochronological, petrological, and geochemical analyses indicate that the subduction of oceanic crust occurred along the western margin of the Yangtze Block until the late Neoproterozoic (~ 703 Ma). [ABSTRACT FROM AUTHOR]

In this study, field descriptions of the dolerite dykes cross‐cutting the Pan‐African basement (DPB) and the dolerite and gabbroic dykes cross‐cutting the Cretaceous sedimentary basin (DGCSB) are used together with petrographic, bulk‐rock geochemistry, as well as Sr–Nd–Pb isotopic data to constrain the geodynamic setting and origin of these mafic (basanite, basalt and basaltic andesite in composition) rocks that outcrop in the Figuil–Léré area. The DPB dykes are alkaline with SiO2 of 46.63–49.03 wt% and MgO of 3.93–7.11 wt%. In contrast, the DGCSB dykes are subalkaline with SiO2 ranging between 50.24 and 53.16 wt% and MgO fluctuating between 5.22 and 7.90 wt%, comparable to dykes described in other regions of the Cameroon Line (CL). The rocks studied belong to the tholeiitic series and were emplaced in within‐plate basalts (WPB) and mid‐ocean ridge basalts (MORBs) setting. The variations in major and trace elements from the basanite to basaltic andesite compositions are dependable with fractional crystallization (FC) of different mineral phases such as opaque minerals, olivine, clinopyroxene, amphibole and alkali feldspar. Most samples exhibit negative Nb–Ta and positive Sr anomalies, which together with the negative correlation between MgO and 87Sr/86Sr, and isotopic ratio of 206Pb/204Pb <19.5 (18.27–19.49) suggests interactions of crustal components. Nevertheless, this contamination seems limited because there is a positive correlation between SiO2 and 143Nd/144Nd plot and low Ba contents (72–210 ppm) of the samples compared to the mid‐continental crust (259–628 ppm). Trace element modelling proposes a derivation of the Figuil–Léré dykes from parental melts generated by 4%–15% partial melting of a source containing garnet peridotite in the mixed lithospheric–asthenospheric mantle. The isotopic data of the dykes studied with hybrid magma composition are characterized by more radiogenic 87Sr/86Sr, 143Nd/144Nd and 206Pb/204Pb isotopic ratios with a dominant mixing of depleted MORB mantle (DMM)–enriched mantle 1 (EM1)–enriched mantle 2 (EM2), like those of other mafic dykes of the CL. [ABSTRACT FROM AUTHOR]

Occupational safety risk assessment is always the basic stage of the systematic approach of reducing the impact of undesired events (work injuries and occupational illnesses), by decreasing both their likelihood of occurrence and the gravity/severity of the generated impact. Eighteen years ago, when, as a consequence of the regulatory changes induced by our country's accession into the European Union, the risk assessment became mandatory/compulsory. Since then some progress was factually realized in the spirit of applying different risk analysis techniques in all Romanian organizations. Even if there are many aspects that are requiring further improvement, an effectively validated and nationally accepted indigenous tool is nowadays available. This method was put in practice in this research paper, in order to analyse, evaluate and assess the safety risks related to several of the main activities/jobs in a diabase open pit mine exploiting construction stone in a certain province of the country. Based on the results obtained, it has become feasible to propose realistic measures aimed at preventing the identified and quantified risks located in the field of unacceptable risks and protecting exposed workers to their effects. The case study developed and synthesized in this article confirms the capability of the risk assessment process to facilitate the substantiation of the decisions regarding the allocation of resources towards the minimization of the risks encountered in the work processes by different categories of workers in the mining companies. [ABSTRACT FROM AUTHOR]

Geological mapping of over 50 km2 area has been carried out in and around Obulapuram area, SE of Sandur Schist Belt. The Sandur Schist Belt (SSB), a part of Eastern Dharwar Craton (EDC) is a NW–SE trending lens-shaped late Archaean volcano-sedimentary belt. The litho-types exposed include peninsular gneiss of PGC, fuchsite quartzite, meta-basalt with intercalation of amphibolite, phyllite, metagabbro and quartzite, banded magnetite quartzite (BMQ), banded hematite quartzite (BHQ) belonging to the Donimalai Formation of Sandur Group. Granites, dolerite dykes, gabbro dykes and quartz veins are younger intrusives. Basement Peninsular Gneiss and intrusive granite are exposed towards the southern and eastern side of the study area. The area has undergone two phases of deformation, of which the earlier D1 deformation is quite pronounced producing the NW–SE trending S0∥S1 regional structures of the area. D1 deformation is responsible for the development of tight isoclinal and macroscopic (F1) folds. D2 deformation resulted in the development of open to close mesoscopic (F2) folds and broad warps with axial traces along ENE-WSW direction and crenulation cleavage (S2). The area is predominantly characterised by regional green schist facies of metamorphism, which increases to amphibolite facies near the contact of the schist belt with gneisses and intrusive granites. [ABSTRACT FROM AUTHOR]