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The improvement of photovoltaic and stability performance of tin (Sn)‐based halide perovskite solar cells is impeded by notorious oxidation issues and Anderson localization. Despite previous implements in antioxidation through the incorporation of Lewis base additives, there still exist ongoing uncertainties surrounding its complex interaction mechanisms. A perplexing phenomenon regarding accelerated oxidation in acrylic acid is discovered that deviates from conventional Lewis base–acid reaction. The underlying insights into the deprotonation of acrylic acid followed by the formation of a “tripod” ionic bonding form are provided, which results in amplifying the delocalization effect of electrons of Sn2+. Furthermore, with the assistance of acrylamide and acrolein, synergistic enhancement in terms of the antioxidation and suppression of Anderson localization can be achieved — a concept referred to as “Dual Synergistic Engineering”. This suppresses the oxidation of Sn2+ and reduces Sn4+ content by ≈76%. Meanwhile, the diffusion length is prolonged significantly from 195.9 to 458.9 nm. The optimized all‐inorganic Sn/Pb‐based perovskite solar cells exhibit a power conversion efficiency of above 14% with enhanced stability. These findings provide an alternative viewpoint for comprehending the impact of chemical interaction on oxidation and crystal growth in Sn/Pb‐based perovskites. [ABSTRACT FROM AUTHOR]

Metal Organic Frameworks (MOFs) are organic‐inorganic hybrid materials with exceptionally customizable composition and properties. MOFs intrinsically possess open metal sites, tunable pore size/shape and an ultra‐large specific surface area, and have obtained significant attention over the past 30 years. Furthermore, through the integration of functional moieties such as, molecules, functional groups, noble metal clusters and nanocrystals or nanoparticles into MOFs, the resulting composites have greatly enriched the physical and chemical properties of pure MOFs, enabling their application in a wider range of fields. Triethylamine (TEA) as an organic base has consistently played a fundamental role in the development of MOFs. In this Concept, the versatility of triethylamine when involved in the synthesis of MOFs is discussed. Four sections are used to elaborate on the role of TEA including: (1) Single crystal synthesis; (2) Size and morphology control; (3) Counterion of MOFs; (4) MOFs composites synthesis. In the last part, we highlight the potential of TEA for further developments. [ABSTRACT FROM AUTHOR]

Citric acid (citH4) is a ubiquitous product in nature with an interesting chemistry owing to its three carboxy and one hydroxy groups, which can be deprotonated in a stepwise manner into six kinds of citrate anions involving two protonation isomers. Deprotonated citrates easily coordinate to late‐3d‐metal ions (Mn, Fe, Co, Ni, Cu, and Zn), affording complexes including mono‐, di‐, tri‐, tetra‐, hexa‐, hepta‐, octa‐, nona‐, and 21‐nuclear complexes with a variety of structures. Magnetic interactions between metal centers are mainly generated via superexchange through hydroxylate or carboxylate bridging, whereas weaker magnetic dipole interactions appear in the absence of superexchange interactions. In citrate complexes, both ferromagnetic and antiferromagnetic interactions have been found. Citrate has a great potential to serve as a bridge between spin quantum magnetism and green chemistry. In this review, the structures and magnetism of discrete citrate complexes of late‐3d‐metals, as well as their single‐molecule magnet properties are discussed. [ABSTRACT FROM AUTHOR]

The intricate nature of the surface structure of carbon dots (CDs) hinders a comprehensive understanding of their emission behavior. In this study, we employ two types of CDs created through acid‐alkali treatments, one with surface protonation and the other with surface deprotonation, with the objective of investigating the impact of these surface modifications on carrier behavior using ultrafast spectroscopy techniques. TEM, XRD, FTIR and Raman spectra demonstrate the CDs' structure, featuring graphitic core and abundant surface functional groups. XPS confirms the successful surface modifications of CDs via protonation and deprotonation. Ultrafast transient absorption (TA) spectroscopy reveals that deprotonation modification may decelerate the relaxation process, thereby increasing the visible PL quantum yields (PLQY). Conversely, protonation may accelerate the relaxation process due to the induced low‐energy absorption band, resulting in self‐absorption and reduced PLQY. Furthermore, TA analysis of CDs in mixed solvents with different proportions of ethanol shows the beneficial effect of ethanol in decelerating the relaxation process, leading to an increased PLQY of 33.7 % for deprotonated CDs and 22.1 % for protonated CDs. This study illuminates the intricate relationship between surface deprotonation/protonation modifications and carrier behavior in CDs, offering a potential avenue for the design of high‐brightness CDs for diverse applications. [ABSTRACT FROM AUTHOR]

Advancing the use of alkali‐metal alkoxides as additives to activate organometallic reagents, here we report the synthesis and characterization of a novel potassium zincate [{(PMDETA)KZn(OtBu)Et2}2] obtained by co‐complexation of equimolar amounts of potassium tert‐butoxide, diethyl zinc and the tridentate donor PMDETA (N,N,N',N",N"‐pentamethyldiethylenetriamine). Demonstrating its ability to activate both of the Et groups towards alkyne C−H metalation, this zincate reacts at room temperature with 2 equivalents of phenylacetylene to furnish [(THF)2KZn(CCPh)2(OtBu)}2], whereas, for the homometallic [ZnEt2(TMEDA)] (TMEDA=N,N,N',N'‐tetramethylethylendiamine) only one Et group is reactive towards the same substrate under the same conditions. Investigations on the reactivity of these complexes to undergo N−H amine metalation using 2, 6‐diisopropylphenylamine (NH2Dipp) and 1,2,3,4‐tetrahydroquinoline (THQ(H)) as model substrates revealed that while homometallic [ZnEt2(TMEDA)] is completely inert towards these amines, heterobimetallic [{(PMDETA)KZn(OtBu)Et2}2] reacts through one of its Et groups to form [(THF)2KZn(OtBu)(Et)(NHDipp)] as well as [(THF)4K2Zn(THQ)4]. The latter is obtained as a side product of ligand redistribution of a putative [(THF)nKZn(OtBu)(Et)(THQ)] intermediate. An alternative method to access mixed amide/alkoxide potassium zincates is also described by assessing the co‐complexation of KOtBu with Zn(HMDS)2 in the presence of PMDETA which gave [(PMDETA)KZn(HMDS)2(OtBu)]. [ABSTRACT FROM AUTHOR]

This document presents the results of a study on the regioselective deprotonation of brominated pyridylthiophene compounds. The researchers found that the position of deprotonation could be switched by adding DMPU as a Lewis base, allowing for the selective deprotonation of each proton on the thiophene moiety. The subsequent halogen dance reaction resulted in the synthesis of four iodinated isomers from a single starting material. This method has potential applications in the synthesis of various substituted pyridylthiophene derivatives. The study was conducted at NAIST and supported by the ARIM Program of MEXT, Japan. [Extracted from the article]

Oxygen vacancy engineering is a promising strategy to enhance the electrocatalytic activities in conventional metal oxide electrocatalysts. However, the utilization of oxygen vacancies in high‐entropy oxides remains unknown, primarily due to the challenges associated with facile introduction of the oxygen vacancies and explanation of their roles in complex high‐entropy systems. Herein, the facile introduction of oxygen vacancies into high‐entropy oxides is realized and the unique high entropy‐driven role of oxygen vacancies for oxygen evolution reaction (OER) process is revealed. A low‐temperature surface carbonization–decarbonization approach is developed to introduce and regulate the oxygen vacancies in high‐entropy spinel oxides (HEOs). The oxygen vacancies in HEOs can both facilitate pre‐oxidation process for faster OH− adsorption and induce the unique bridge site pathway for easier deprotonation, distinctive in conventional oxides where oxygen vacancies favor *OH adsorption yet hinder the deprotonation. Consequently, the as‐prepared high‐entropy spinel oxides with oxygen vacancies (HEOs‐Ov) exhibit superior OER activities, outperforming the HEOs and most reported oxide‐based electrocatalysts. Besides, this universal method can be extended to other spinel oxides with different configuration entropies and can be scaled up. The work paves the way for the exploration of oxygen vacancies in high‐entropy oxides toward electrocatalysis fields. [ABSTRACT FROM AUTHOR]

Chelating agents are commonly employed in microelectronic processes to prevent metal ion contamination. The ligand fragments of a chelating agent largely determine its binding strength to metal ions. Identification of ligands with suitable characteristics will facilitate the design of chelating agents to enhance the capture and removal of metal ions from the substrate in microelectronic processes. This study employed quantum chemical calculations to simulate the binding process between eleven ligands and the hydrated forms of Ni2+, Cu2+, Al3+, and Fe3+ ions. The binding strength between the metal ions and ligands was quantified using binding energy and binding enthalpy. Additionally, we explored the binding interaction mechanisms and explained the differences in binding abilities of the eleven ligands using frontier molecular orbitals, nucleophilic indexes, electrostatic potentials, and energy decomposition calculations based on molecular force fields. Based on our computational results, promising chelating agent structures are proposed, aiming to guide the design of new chelating agents to address metal ion contamination issues in integrated circuit processes. [ABSTRACT FROM AUTHOR]

Reduced isotropic Raman spectra of dilute sodium glycolate in aqueous solutions of NaOH (molalities ranging from 0.03 to 5.65 mol·kg−1 in OH−) have been obtained at temperatures 5, 25, and 45 °C. The Raman spectra yielded evidence of the formation of a doubly-deprotonated glycolate dianion, −O–CH2–COO− (Gly2−) from the decrease in the intensity of the hydroxyl O–H bending mode at 1365 cm−1 with increasing basicity, and the 7 cm−1 shift in the alcohol C–OH stretching mode (from 1079 to 1086 cm−1 at 5 °C). Equilibrium quotients for the second ionization constant of glycolic acid, Q2a,OH, which corresponds to the deprotonation of the glycolate hydroxyl group, were calculated from the peak area of the O–H bending mode as it decreased with higher NaOH molalities. Values for the equilibrium constant and the standard molar enthalpy of reaction at 25 °C: log K2a,OH,298 = − 1.143 ± 0.059, and ΔionH°2a,OH,298 = − 12.5 ± 1.6 kJ·mol−1, were determined by regressing the experimental equilibrium quotients to a simple extended Debye–Hückel activity coefficient model. This is the first reported spectroscopic characterization of Gly2−and the first reported values for log K2a,OH,298 and ΔionH°2a,OH,298. [ABSTRACT FROM AUTHOR]

In contrast, under thermodynamically controlled reaction conditions (60 °C, 10 min) in a flow reactor with (Cy SB 2 sb N) SB 2 sb Zn-2LiCl, zincation proceeds preferentially at the C4-position (Scheme 9). In 2007, the Knochel group demonstrated metalation of a 2-chloro-3-nitropyridine ( B 40 b ) with (TMP) SB 2 sb Zn-2MgCl SB 2 sb -2LiCl B 2 b at -40 °C in 1.5 h followed by a subsequent copper-catalysed allylation with 3-bromocyclohexane (Scheme 10); the final product B 42 b was obtained in 80% yield. [19] Thus for most purposes, TMPZnCl-LiCl B 3 b remains the most convenient and widely applicable zinc base, and has come to be termed a "turbo-zinc" reagent. [59] Sales et al. tested both MgTMP and ZnTMP bases and found that the use of TMP SB 2 sb Zn-2MgCl SB 2 sb -2LiCl B 2 b not only results in higher yields than with TMPMgCl-LiCl (93% I vs. i 65%), but also the reaction proceeds at room temperature rather than at -30 °C. [Extracted from the article]

A 12‐membered zwitterionic tetrastanna(II) cycle 1 having a crown ether‐like topology has been isolated from the deprotonation of 1,1′‐methylenediimidazole (B) with two equivalents of Sn[N(SiMe3)2]2 (A). The solid‐state structure and NMR analysis confirms the tetrastanna(II) cycle 1 to be comprised of two stannate(II) and two stannyliumylidene ion pairs in alternating positions of the heterocycle. Computational analysis shows greater nucleophilicity at the proximally located stannate(II) centers. Nonetheless, the tetrastanna(II) cycle 1 remains poorly reactive due to engagement of SnII lone pair electrons in intramolecular donor‐acceptor interactions. Simple deprotonation reaction between Sn[N(SiMe3)2]2 (A) and N‐(diisopropylphenyl)imidazole (C) in equimolar ratio has led to a stannylene 2, involving the formation of a Sn−C covalent bond with the anionic imidazol‐2‐yl carbon center along with the release of NH(SiMe3)2. Compound 2 exists as a dimer, where the unsubstituted ring nitrogen atom coordinated intermolecularly to the other stannylene center. [ABSTRACT FROM AUTHOR]

24 substituted cyanocompounds and the corresponding anions obtained upon H+-abstraction from diverse positions were subjected to an electron density analysis with the quantum theory of atoms in molecules (QTAIM). All the electron densities were obtained at the B3LYP/6–31 + + G(2d,2p) level on completely optimized geometries. In accordance to experimental evidence, α-H+ abstraction is found as the most favored one (by at least 100 kJ mol−1 in all the tested compounds). The presence of additional resonance electron attractors reduces significantly the α-deprotonation energy, whereas this magnitude is quite insensitive to the inclusion of resonance electron donors. The electron density rearrangement accompanying the deprotonation is apparently in line with the predictions of the resonance model (RM). In fact, a significant part of the electron density gained by expelling the proton is transferred to cyano N and to other groups where significant resonance structures delocalize the negative charge. Nevertheless, some significant modifications have to be introduced on the RM picture when the QTAIM results are studied in detail. [ABSTRACT FROM AUTHOR]

The preservative qualities of individual ionic compounds impacting the infectivity of T4 virions were elucidated. T4 virions were immersed in quasi-pure ionic solutions prior to the adsorption process, and the plaque forming unit (pfu) values of these were measured following the conventional method. In neutral ionic solutions, the minimum and the optimum concentrations of preservative qualities corresponded with the results obtained from the multi-ionic media/buffers. In acid and alkali solutions, phages show tolerances at a pH range of 5–11 in multi-ionic media/buffers. T4 virions show no tolerance in quasi-pure acid, neutral, and weak alkaline conditions. The preservative quality of T4 virions increased in over 10−1 mM OH− solution, equivalent to a pH value over 10, which corresponds to the pKa of the deprotonation of the DNA bases G and T. Infectivity was lost below 10−1 mM OH− and higher than 10 mM OH−. These results imply that maintaining infectivity of a virion may need the flexibility of the intra-capsid DNA by deprotonation. [ABSTRACT FROM AUTHOR]

The pH dependences of the photoluminescence of carbon dots synthesized by the hydrothermal method with polyfunctional and monofunctional (carboxylated and hydroxylated) surfaces have been studied. As a result of the analysis of the obtained photoluminescence and absorption spectra of aqueous suspensions of all studied types of carbon dots at different pH values, a significant effect of the acidity of the environment of nanoparticles on their optical properties was found. It has been found that the greatest changes in the spectral characteristics of absorption and photoluminescence of carbon dots with COOH, OH, and NH2 surface groups appear in the pH ranges of 2–5 and 8–12. The obtained results are explained are explained by the processes of protonation/deprotonation of the surface groups of carbon dots. [ABSTRACT FROM AUTHOR]

N,N'‐dihydroxy‐1,4,5,8‐naphthalenetetracarboxdiimide (NDI−(OH)2) has attracted much attention in recent years, because its doubly deprotonated state, (O−NDI−O)2−, has metal‐coordination ability and characteristic electronic transition useful for designing electronic and optical functions. In contrast, a molecular crystal with the mono‐deprotonated (HO−NDI−O)− ion remains unknown. We herein report an organic crystal containing non‐disproportionated (HO−NDI−O)− ions, which are connected by very strong O−H−O hydrogen bonds. Its lowest energy absorption band (450 to 650 nm) is observed in between that of NDI−(OH)2 (380 nm) and isolated (O−NDI−O)2− (500 to 850 nm) species, consistent with the molecular orbital calculations. This absorption originates from the electronic transition from deprotonated imide‐based orbitals to NDI‐core orbitals, which can be influenced by the hydrogen bonds around imide group. Consequently, the optical properties of NDI−(OH)2 can be modulated by the stepwise deprotonation and hydrogen‐bonding interactions. [ABSTRACT FROM AUTHOR]

[Display omitted] Metal-organic frameworks (MOFs) with conjugation carboxylate ligands as electrocatalysts can significantly improve oxygen evolution reaction (OER), but the role of π-interaction on the reactive sites of OER is often neglected. We intend to unravel the mechanism of how π-interaction enhances OER performance. The results of Rietveld refinement, density functional theory (DFT) calculations, and in-situ Raman spectra show that π-interaction can efficiently modulate the local spin configuration of metal centers, facilitate γ-Ni 1-x Fe x OOH active species with high-valence Ni sites modified by high-spin Fe, accelerate electron transfer, optimize the d-band center together with the beneficial rate-determining step of OER. NiFe-BPDC MOFs/NF with 0.8559 eV π-interaction energy generated γ-Ni 1-x Fe x OOH in only 60 s at 1.4 V, demonstrating that π-interaction promotes the rapid generation of highly active reactive sites. Furthermore, the results of in-situ Raman and electron paramagnetic resonance (EPR) spectra reveal that the deprotonation and deoxygenation steps of OER are accompanied by changes in the oxidation state of metal ions and the generation of oxygen vacancies on the surface of catalysts. In addition, NiFe-BPDC MOFs/NF rapidly completes the deprotonation and deoxygenation steps, and it requires only 288 mV overpotential to reach 100 mA/cm2 with 100 h of stability, suggesting promising industrial application. [ABSTRACT FROM AUTHOR]

A novel, selective and high‐yielding palladium‐catalyzed carbonylative arylation of a variety of weakly acidic (pKa 25–35 in DMSO) benzylic and heterobenzylic C(sp3)−H bonds with aryl bromides has been achieved. This system is applicable to a range of pro‐nucleophiles for access to sterically and electronically diverse α‐aryl or α,α‐diaryl ketones, which are ubiquitous substructures in biologically active compounds. The Josiphos SL‐J001‐1‐based palladium catalyst was identified as the most efficient and selective, enabling carbonylative arylation with aryl bromides under 1 atm CO to provide the ketone products without the formation of direct coupling byproducts. Additionally, (Josiphos)Pd(CO)2 was identified as the catalyst resting state. A kinetic study suggests that the oxidative addition of aryl bromides is the turnover‐limiting step. Key catalytic intermediates were also isolated. [ABSTRACT FROM AUTHOR]

A novel, selective and high‐yielding palladium‐catalyzed carbonylative arylation of a variety of weakly acidic (pKa 25–35 in DMSO) benzylic and heterobenzylic C(sp3)−H bonds with aryl bromides has been achieved. This system is applicable to a range of pro‐nucleophiles for access to sterically and electronically diverse α‐aryl or α,α‐diaryl ketones, which are ubiquitous substructures in biologically active compounds. The Josiphos SL‐J001‐1‐based palladium catalyst was identified as the most efficient and selective, enabling carbonylative arylation with aryl bromides under 1 atm CO to provide the ketone products without the formation of direct coupling byproducts. Additionally, (Josiphos)Pd(CO)2 was identified as the catalyst resting state. A kinetic study suggests that the oxidative addition of aryl bromides is the turnover‐limiting step. Key catalytic intermediates were also isolated. [ABSTRACT FROM AUTHOR]

The discovery of melamine by Justus von Liebig was fundamental for the development of several fields of chemistry. The vast majority of compounds with melamine or melamine derivatives appear as adducts. Herein, we focus on the development of novel compounds containing anionic melamine species, namely the melaminates. For this purpose, we analyze the reaction of SbCl3 with melamine by differential scanning calorimetry (DSC). The whole study includes the synthesis and characterization of three antimony compounds that are obtained during the deprotonation process of melamine to melaminate with the reaction sequence from SbCl4(C9N18H19) (1) via (SbCl4(C6N12H13))2 (2) to SbCl(C3N6H4) (3). Compounds are characterized by single-crystal X-ray diffraction (SXRD), powder X-ray diffraction (PXRD), and infrared spectroscopy (IR). The results give an insight into the mechanism of deprotonation of melamine, with the replacement of one, two, or eventually three hydrogen atoms from the three amino groups of melamine. The structure of (3) suggests that metal melaminates are likely to form supramolecular structures or metal-organic frameworks (MOFs). [ABSTRACT FROM AUTHOR]

The reaction of magnesium turnings and 6,6‐di‐para‐tolylpentafulvene was investigated. Under mild conditions, the magnesium dissolves, forming the MgII complex 1 with a π‐η5 : σ‐κ1 coordinating ligand of the dimerized pentafulvene, analyzed by NMR and XRD investigations. As a magnesium pentafulvene complex was a possible intermediate, amines were employed as intercepting agents. Thereby, the amines were formally deprotonated by elemental magnesium, yielding the first examples of Cp'Mg(THF)2NR2 complexes. This reaction competes with the formation of 1 and a consecutive formal [1,5]‐H‐shift forming an ansa‐magnesocene. Employing amines with low basicity gave quantitative conversion to the amide complexes. [ABSTRACT FROM AUTHOR]

The deprotonative functionalization of α,α‐difluoromethyl ketones is described herein. Using a catalytic organosuperbase and a silane additive, the corresponding difluoroenolate could be generated and trapped with aldehydes to deliver various α,α‐difluoro‐β‐hydroxy ketones in high yields. This new strategy tolerates numerous functional groups and represents the access to the difluoroenolate by direct deprotonation of the difluoromethyl unit. The diastereoselective version of the reaction was also investigated with d.r. up to 93 : 7. Several transformations were performed to demonstrate the synthetic potential of these α,α‐difluoro‐β‐hydroxy ketones. In addition, this method has been extended to the use of other electrophiles such as imines and chalcogen derivatives, and a difluoromethyl sulfoxide as nucleophile, thus leading to a diversity of difluoromethylene compounds. [ABSTRACT FROM AUTHOR]

The deprotonative functionalization of α,α‐difluoromethyl ketones is described herein. Using a catalytic organosuperbase and a silane additive, the corresponding difluoroenolate could be generated and trapped with aldehydes to deliver various α,α‐difluoro‐β‐hydroxy ketones in high yields. This new strategy tolerates numerous functional groups and represents the access to the difluoroenolate by direct deprotonation of the difluoromethyl unit. The diastereoselective version of the reaction was also investigated with d.r. up to 93 : 7. Several transformations were performed to demonstrate the synthetic potential of these α,α‐difluoro‐β‐hydroxy ketones. In addition, this method has been extended to the use of other electrophiles such as imines and chalcogen derivatives, and a difluoromethyl sulfoxide as nucleophile, thus leading to a diversity of difluoromethylene compounds. [ABSTRACT FROM AUTHOR]

Betanidin (Bd) is a nitrogenous metabolite with significant bioactive potential influenced by pH. Its free radical scavenging activity and deprotonation pathway are crucial to studying its physicochemical properties. Motivated by the published discrepancies about the best deprotonation routes in Bd, this work explores all possible pathways for proton extractions on that molecule, by using the direct approach method based on pKa. The complete space of exploration is supported by a linear relation with constant slope, where the pKa is written in terms of the associated deprotonated molecule energy. The deprotonation rounds 1, ..., 6 define groups of parallel linear models with constant slope. The intercepts of the models just depend on the protonated energy for each round, and then the pKa can be trivially ordered and explained by the energy. We use the direct approximation method to obtain the value of pKa. We predict all possible outcomes based on a linear model of the energy and some related verified assumptions. We also include a new measure of similarity or dissimilarity between the protonated and deprotonated molecules, via a geometric–chemical descriptor called the Riemann–Mulliken distance (RMD). The RMD considers the cartesian coordinates of the atoms, the atomic mass, and the Mulliken charges. After exploring the complete set of permutations, we show that the successive deprotonation process does not inherit the local energy minimum and that the commutativity of the paths does not hold either. The resulting clusterization of pKa can be explained by the local acid and basic groups of the BD, and the successive deprotonation can be predicted by using the chemical explained linear models, which can avoid unnecessary optimizations. Another part of the research uses our own algorithm based on shape theory to determine the protein's active site automatically, and molecular dynamics confirmed the results of the molecular docking of Bd in protonated and anionic form with the enzyme aldose reductase (AR). Also, we calculate the descriptors associated with the SET and SPLET mechanisms. [ABSTRACT FROM AUTHOR]

N -Sulfinyl metalloenamines, generated by deprotonating α-linear N - tert -butanesulfinyl ketimines, reacted with nitroalkenes via stereoselective conjugate addition to give Michael adducts with opposite stereochemistry to that obtained using α-branched sulfinylketimines. In the presence of excess base (2.5 equiv t -BuOK), the adducts derived from α-linear ketimines were further stereoselectively deprotonated to afford the corresponding kinetically favorable N -sulfinyl (Z)-enamine derivatives in good yields with good stereoselectivities. A reaction model was proposed to rationalize the observed stereochemistry. [ABSTRACT FROM AUTHOR]

The thermal behaviour of an uvite from San Piero in Campo (Elba Island, Italy) was investigated at room pressure through in situ high-temperature powder X-ray diffraction (PXRD), until the breakdown conditions were reached. The variation of uvite structural parameters (unit-cell parameters and mean bond distances) was monitored together with site occupancies and we observed the thermally induced Fe oxidation process counterbalanced by (OH)− deprotonation, which starts at 450 °C and is completed at 650 °C. The uvite breakdown reaction occurs between 800 and 900 °C. The breakdown products were identified at room temperature by PXRD and the breakdown reaction can be described as follows: tourmaline → indialite + yuanfuliite + plagioclase + “boron-mullite” phase + hematite. [ABSTRACT FROM AUTHOR]

Phosphine‐catalyzed (4+2) annulation of the acidic hydrogen‐tethered allylic carbonates with electron‐deficient alkenes was achieved. Various electron‐deficient alkenes and allylic carbonates were well tolerated under mild reaction conditions, providing a variety of polysubstituted spirocyclohexenes, spirocyclohexanones or cyclohexanones in moderate to high yields. The scale‐up reactions and further transformations of the products had been performed. The acidic hydrogen‐tethered allylic carbonates displayed nice reactivity and will find more applications. [ABSTRACT FROM AUTHOR]

Sequential processing of monolithiated tertiary propargylamines with 2-(vinyloxy)ethyl isothiocyanate and t -BuOK–DMSO results in the introduction of a highly reactive 2-(vinyloxy)ethyl group at the position 1 of the pyrrole ring thus formed. In this way, a series of new 5-sulfanyl-1-[2-(vinyloxy)ethyl]-1 H -pyrrol-2-amines were obtained in a yield of up to 92%. The latter in the presence of t -BuOK–DMSO system (110–120 °C, 10–15 min) eliminates vinyl alcohol to give rare-functionalized 1-vinylpyrroles, namely 5-sulfanyl-1-vinyl-1 H -pyrrol-2-amines, inaccessible by the known methods. [ABSTRACT FROM AUTHOR]

The excited‐state intramolecular proton transfer chromophores were regarded as good materials for laser action generation due to their inherent four‐level photocycle. The excitation‐dependent properties of these compounds enable light amplification from two distinct forms: both enol and keto, making it possible to obtain dual fluorescence emission. Herein, we report that a third option is possible for the first time stimulated emission was realized with a deprotonated ESIPT molecule based on a novel rigidified 2‐(2'‐hydroxyphenyl)benzothiazole derivative, triggering the possibility to fabricate real‐time tunable active material. Through the rational engineering of the ratio of each emissive species, a red‐green‐blue device was fabricated with the possibility of white light generation. The degenerated two‐wave mixing setup was applied to construct a continuously tunable distributed feedback laser. [ABSTRACT FROM AUTHOR]

The synthesis of the unsymmetric macrocyclic tetrakismidazolium salts H4‐4(PF6)4 and H4‐5(PF6)4 featuring a 2,6‐pyridinylene‐ and a 2‐bromo‐1,3‐xylylene‐bridged bisimidazolium unit is described. Reaction of macrocycle H4‐4(PF6)4 with Ag2O yields the tetranuclear complex [6](PF6)4 composed of four AgI ions sandwiched in between two tetra‐NHC ligands. The 2,6‐pyridinylene‐bridged bisimidazolium moiety of the macrocycles can be site‐selectively deprotonated and metallated with RuII or RhI to give the pincer complexes [8](PF6)3‐[11](PF6)3. Introduction of a second metal in these complexes by deprotonation/metallation and oxidative addition to the 2‐bromo‐1,3‐xylylene‐bridged bisimidazolium moiety of the macrocycles proved not possible. [ABSTRACT FROM AUTHOR]

The acidic hydrogen‐tethered allylic carbonates were successfully applied in phosphine catalysis. Their (4+2) annulation reaction with sulfamate‐derived cyclic imines under phosphine catalysis worked well to produce tetrahydropyridine‐fused heterocyclic compounds in high yields. A moderate ee was obtained in the initial screening. The zwitterionic intermediate produced through in‐situ deprotonation functioned as a four‐membered synthon. [ABSTRACT FROM AUTHOR]

Olefins are important building blocks and are widely utilized in synthetic organic chemistry. Owing to its omnipresence and unique reactivity, the functionalization of alkenes has become a powerful method for constructing complex organic molecules. In this context, direct chelation‐assisted C−H olefination at the inert C−H bonds represents the most straightforward synthetic method for introducing the alkenyl group into organic compounds in a highly regio‐ and stereoselective manner. Despite the remarkable advances in chelation‐assisted C−H olefination reaction, most of the successful transformations are restricted to activated or electronically biased olefins such as acrylates, styrenes, acrylamides, vinyl sulfones, and vinyl phosphonates. Literature reports on chelation‐assisted C−H olefination with unactivated or electronically unbiased alkenes are limited due to poor intrinsic reactivity and regioselectivity issues. Despite significant challenges, the past few years have witnessed tremendous growth. The present review describes the recent advances in the chelation‐assisted C−H olefination and allylation of aromatics, alkenes, and heteroaromatics with unactivated alkenes via the concerted‐metallation‐ deprotonation pathway.Transition metals such as palladium, rhodium, iridium and cobalt are widely used for these kind of transformations. The scope, mechanistic investigation, and limitation of the alkenylation and allylation reactions are discussed elaborately. The present review includes all the reported C−H olefination and allylation reactions with unactivated olefins via the base‐assisted deprotonation pathway. [ABSTRACT FROM AUTHOR]

Synthesis of aromatic thiol groups bearing N,N -spiro bridged bis cyclotriphosphazenes, investigation of their reaction mechanism and absorption-fluorescence properties. [Display omitted] • Deprotonation reactions of arylthio substituted cyclotriphosphazenes (3a , b and 4a , b) were investigated. • The effects of substituents on deprotonation reactions were discussed, considering product diversity. • Possible reaction pathways were suggested for the reactions to proceed. • The crystal structures of N,N bicyclotriphosphazenes (5a-I) and (5b-I) were characterized by single crystal X-ray diffraction technique. • Photophysical properties of the compounds were determined using UV/vis and fluorescence spectroscopies. In this study, bis (1a, b) and tetrakis (2a, b) cyclotriphosphazenes containing aryl thio groups were reacted with n -butyl amine. Deprotonation reactions of the obtained mono amino bis phenylthio (3a, b) and bis naphthylthio (4a, b) cyclotriphosphazenes were carried out in the presence of NaH base. New N,N -spiro bridged biscyclotriphosphazenes containing bis geminal phenylthio (5a-I and 5a-II) and naphthythio (5b-I and 5b-II) groups were created. Characterization of the newly synthesized compounds was performed by MALDI-TOF, 31P and 1H NMR spectroscopy, and single-crystal X-Ray crystallography (5a-I and 5b-I). Photophysical properties of compounds 1a, b, 2a, b , 5a-I, and 5b-I were determined using UV/vis and fluorescence spectroscopies. At the same time, the structures of N,N -spiro bridged biscyclophosphazenes were comprehensively evaluated with the structures of previously synthesized biscyclophosphazenes containing different functional groups. [ABSTRACT FROM AUTHOR]

• Water molecule chains are built within PBI membrane. • The proton conductivity of PBI is enhanced by over 1400%. • The free volume is enlarged via scissoring hydrogen bonds between PBI chains. • Assembled VRFB achieves a CE of 99.7 % and an EE of 83.3 % at 80 mA cm−2. • This study establishes an understanding of proton transfer in VRFB membranes. Optimizing the proton conductivity of polybenzimidazole (PBI) membrane is of great significance to realize vanadium redox flow battery (VRFB) with the superior performance and low cost for commercialization. However, the fundamental reason of the poor proton conductivity of PBI, which severely hinders its application in VRFB, is not addressed yet. To tackle this issue, hydrogen bonds between PBI chains are scissored through a deprotonation strategy by using KOH/ethanol as the casting solvent in this study, weakening the interaction between PBI chains and enlarging the free volume to build water molecule chains inside. The water molecule chains effectively promote the proton transfer under Grotthuss mechanism, increasing the proton conductivity by over 1400 %. The energy efficiency of the VRFB assembled with the engineered membrane is improved from 71.5 % to 83.3 % under 80 mA cm−2, in addition to preserving the membrane's ability to inhibit the permeability of vanadium ions as well as maintaining the structural stability. This study innovates a facile strategy for membrane optimization, and the profound analysis of structure–property relationship of PBI membrane is highly critical for guiding the development of membrane. [ABSTRACT FROM AUTHOR]

A palladium‐catalyzed [4+2] cycloaddition of hydroxy‐tethered allyl carbonates with five types of electron‐deficient alkenes has been achieved, in which a type of new hydroxy‐tethered allyl carbonates acted as valuable precursors for the formation of 1,4‐C,O‐dipole allylpalladium intermediates. The reaction proceeded efficiently under mild reaction conditions to provide the corresponding tetrahydropyran derivatives in moderate to high yields with excellent diastereoselectivities. [ABSTRACT FROM AUTHOR]

In this study, we demonstrate the structural evolution of a two-dimensional (2D) supramolecular assembly system, which is steered by the thermally activated deprotonation of the primary organic building blocks on a Ag(111) surface. Scanning tunneling microscopy revealed that a variety of structures, featuring distinct structural, chiral, and intermolecular bonding characters, emerged with the gradual thermal treatments. According to our structural analysis, in combination with density function theory calculations, the structural evolution can be attributed to the successive deprotonation of the organic building blocks due to the inductive effect. Our finding offers a facile strategy towards controlling the supramolecular assembly pathways and provides a comprehensive understanding of the 2D crystal engineering on surfaces. [ABSTRACT FROM AUTHOR]

A total synthesis of lamellarins U and A3 is described. The synthesis features the interruption of a halogen dance reaction of a metalated α,β-dibromopyrrole. The pyrrolylmagnesium reagent, generated by deprotonative metalation by using (TMP)MgCl·LiCl (TMP = 2,2,6,6-tetramethylpiperidide) as the base, was transmetalated to the corresponding organozinc species without causing the halogen dance reaction, which underwent a Negishi coupling to incorporate an aryl group onto the pyrrole ring. The arylated α,β-dibromopyrrole was then converted into lamellarins U and A3 through an α-selective halogen–magnesium exchange followed by carboxylation and subsequent palladium-mediated cyclization. The late-stage introduction of another aryl group was performed using a Kosugi–Migita–Stille coupling to provide lamellarins U and A3. [ABSTRACT FROM AUTHOR]

Heterocycles are widespread in pharmaceuticals but methods for their transition metal‐catalyzed functionalization remain limited. This report describes a general, mild, and effective nickel‐catalyzed benzylic allylation and benzylation of 14 types of heterocyclic aromatic compounds, including pyridines, pyrazines, pyrimidines, pyridazines, triazines, benzimidazoles, oxazoles, thiazoles, as well as 3,3‐dimethyl‐indoles. The exquisite selectivity for benzylic sites at the 2‐position is hypothesized to be controlled by coordination of a heterocyclic nitrogen to Zn(TMP)2 subverting generally presumed pKa's of benzylic protons. Furthermore, the broad range of heterocyclic substrates, the diversity of electrophiles, and excellent functional group compatibility suggest its future application to synthesis of complex molecules and library diversification in drug discovery. [ABSTRACT FROM AUTHOR]

Heterocycles are widespread in pharmaceuticals but methods for their transition metal‐catalyzed functionalization remain limited. This report describes a general, mild, and effective nickel‐catalyzed benzylic allylation and benzylation of 14 types of heterocyclic aromatic compounds, including pyridines, pyrazines, pyrimidines, pyridazines, triazines, benzimidazoles, oxazoles, thiazoles, as well as 3,3‐dimethyl‐indoles. The exquisite selectivity for benzylic sites at the 2‐position is hypothesized to be controlled by coordination of a heterocyclic nitrogen to Zn(TMP)2 subverting generally presumed pKa's of benzylic protons. Furthermore, the broad range of heterocyclic substrates, the diversity of electrophiles, and excellent functional group compatibility suggest its future application to synthesis of complex molecules and library diversification in drug discovery. [ABSTRACT FROM AUTHOR]

Rational design and isolation of two hitherto unknown highly stable single conformer of ferrocene incorporated meso‐aryl substituted singly N‐methyl N‐confused‐calixphyrins have been achieved in quantitative yields. The solid‐state crystal structure reveals the obvious trans‐geometry for the meso‐protons with the possibility for both the macrocycles to exist either racemic or enantiomer forms. However, thorough solution‐state spectroscopic characterization strongly concludes the experimental isolation of a single isomer for both the macrocycles. The drastic modification of UV‐vis spectral patterns upon imine pyrrole N protonation and amine pyrrole NH deprotonation of both the calixphyrins could pave way for these macrocycles to act as opto‐electronic materials. The conformational preorganization and protonation and deprotonation induced conformational reorganization have been extensively studied by solution state spectroscopic techniques, solid state X‐ray crystal structure and in depth DFT level theoretical calculations. [ABSTRACT FROM AUTHOR]

The discharge of toxic cyanide ions in the environment and their uptake by life is inevitable due to industrialization. Therefore, its detection below the permissible limit is significant. Diphenyl ether‐based chromophores have been synthesized and optimized to highlight the proton abstraction mechanism for detecting anions. Absorption studies in the presence of different solvents (H2O, MeOH, ACN, DMSO, CHCl3 and semi‐aqueous ACN) and pH (10 to 4) confirmed the proton abstraction mechanism validated using 1H NMR titration, IR studies and DFT calculations. The effect of substituents on the diphenyl ether motifs highlighted the selectivity of anions under different solvent conditions. Finally, compound‐2 [2‐(2‐methoxyphenoxy)‐5‐nitrobenzoic acid] and compound‐2 c [3‐methoxy‐4‐(2‐nitrophenoxy) benzoic acid] in ACN medium detected F− (280 nM, 17 μM) AcO− (41 nM, 40 μM) and CN− (50 nM. 1.5 μM) ions in nM and μM range respectively. However, the semi‐aqueous medium (5 % water in ACN) gave selective detection of the CN− ion up to 100 nM for the compound‐2 in a 1 : 1 stoichiometry. The use of an aqueous medium in the case of compound‐2 c did not show detection for any of the ions. [ABSTRACT FROM AUTHOR]

The density functional theory (DFT) calculations have been performed on a new set of organic Brønsted acids based on 9H-fluorene scaffold. The optimal structures and acidity of the compounds have been calculated by using DFT/B3LYP/6–31 + + G(d,p) computational method. The acidity of the designed compounds was obtained in the range of 276–328 kcal/mol that the fluorene scaffold bearing ketenimine group 17 and trifilic group 20 with ΔHacid of 276.3 and 285.4 kcal/mol, respectively, were found to be within the range of superacids, being more acidic than simple fluorene and mineral acids. The designed compounds and the corresponding conjugate bases were also examined from the aromaticity indices point of view. The tautomerization process for some designed structures was investigated by DFT calculations. Molecular electrostatic potential analysis for the designed acids and the corresponding conjugate bases was also used for charge distribution analysis. [ABSTRACT FROM AUTHOR]

Does the hybridization of the surface of carbon nanoparticles (CNPs) affect the properties of the surface carboxyl and hydroxyl groups and the features of their deprotonation in water? To answer these questions in this work the structures of graphite-and diamond-like carbon cells with OH and COOH groups optimized by the DFT method were studied. It was found that in the same suspensions the OH and COOH groups deprotonate easier being on carbon with sp2 hybridization rather than sp3. Theoretical estimates have shown that in aqueous suspensions of CNPs, "isolated" carboxyl COOH groups on sp2/sp3 hybridized carbon sites have pKa in the ranges of 3.5–4.5/4.5–5, and the hydroxyl OH groups – in the ranges of 8.5–10/15–18, respectively. The conclusions made on the basis of theoretical calculations about the features of deprotonation of surface groups of CNPs are experimentally confirmed by the changes of the zeta-potentials of oxidized detonation nanodiamonds with the change of the pH of the environment. [ABSTRACT FROM AUTHOR]

This study investigated the adsorption mechanisms of boron on protonated and deprotonated graphene with oxygen-containing functional groups. Six representative adsorption conformations of boron predominant species (B(OH) 3 (B3) and B(OH) 4 − (B4)) on graphene were proposed. Protonation and deprotonation of graphene had significant effects on boron adsorption. Deprotonation of hydroxyl-modified (G20-OH) and carboxyl-modified graphene (G20-COOH) with 20 carbon rings decreased B3 and B4 adsorption. Protonation of G20-OH enhanced B3 adsorption. The adsorption interface, mainly around hydrogen atoms associated with protonated groups, exhibited a sharp gradient, due to the increased electron density from O H bond formation. B3 showed stronger electron sharing, emphasizing robust interactions. Hydrogen bonding dominated G20-OH2-B3, while G20-O-B4 exhibited more substantial hydrogen bond interactions. In summary, hydrogen bond strength was crucial in B3 adsorption, while electrostatic repulsion hindered B4 adsorption on deprotonated graphene. These findings highlight the importance of graphene protonated and deprotonated states in effectively removing various pKa contaminants. [Display omitted] • Protonation of hydroxyl-modified graphene enhanced the adsorption of B(OH) 3. • Deprotonation of oxygen-containing groups modified graphene reduced adsorption. • Interaction forces led to differences in the adsorption of B(OH) 3 and B(OH) 4 −. • Hydrogen bond strength played a crucial role in B(OH) 3 adsorption on graphene. • Electrostatic repulsion hindered B(OH) 4 − adsorption on deprotonated graphene. [ABSTRACT FROM AUTHOR]

[Display omitted] • The interactions between amino acid-species and Ca minerals/Ca2+ were investigated. • High Ca2+ concentrations achieved after 3 mins of leaching assisted by amino acids. • Gly's buffering capacity and Ca chelation led to the highest 114.8 g-CaCO 3 /kg-CFA. • Amino acids incorporated in CaCO 3 crystals impact the mineralogy and morphology. An amino acid-mediated Ca2+ leaching-CO 2 mineralization process was proposed to address the challenges associated with slow kinetics and extensive consumption of exogenous reagents in CO 2 mineralization. While the underlying reaction mechanism between amino acid and alkaline minerals/metals remains unclear, this study explored the interactions between amino acid-species and Ca-bearing minerals/Ca2+ by investigating the evolution of active compounds from the perspectives of thermodynamic equilibrium analysis and experimental study. Thermodynamic equilibrium analysis showed that the active Ca-bearing minerals of coal fly ash (CFA) varied in the systems of ammonium salt, acid, and amino acid, e.g., the active phases in glycine were portlandite (Ca(OH) 2), lime (CaO), and gehlenite (2CaO*Al 2 O 3 *SiO 2). High Ca2+ concentrations of 0.26 M, 0.14 M, and 0.1 M can be achieved after 3 min of leaching assisted by amino acids of Glycine (Gly), L-Alanine (Ala), and L-Arginine (Arg), respectively, which implied the kinetics and thermodynamical feasibility. This phenomenon was demonstrated to relate to the fact that Gly and Ala had minimal pH buffering capacity in the early leaching stage. The deprotonated forms of Gly and Ala with a higher affinity with Ca2+ increased from 0.03 % and 0.04 % to 33.9 % and 12.88 %, respectively, thereby promoting Ca2+ leaching. The Ca2+ utilization efficiencies from CFA were 26.45 %, 15.0 %, and 13.3 % for Gly, Ala, and Arg, respectively. Gly achieved the best CaCO 3 yield of 114.8 g/kg, due to the combined effects of Gly's buffering capacity and strong chelation effect for Ca2+, which drove forward the dissolution of the active phase and precipitation of CaCO 3. [ABSTRACT FROM AUTHOR]

[Display omitted] • Microencapsulation facilitates the use of vitamins in food applications. • To know the material, the technique, and the release mechanism can ensure the success of microencapsulation. • Microencapsulation prolongs the stability of vitamins for better utilization. • Structurally modified coating materials allow a higher release of vitamins under digestible conditions. Vitamins are responsible for providing biological properties to the human body; however, their instability under certain environmental conditions limits their utilization in the food industry. The objective was to conduct a systematic review on the use of biopolymers and lipid bases in microencapsulation processes, assessing their impact on the stability, controlled release, and viability of fortified foods with microencapsulated vitamins. The literature search was conducted between the years 2013–2023, gathering information from databases such as Scopus, PubMed, Web of Science and publishers including Taylor & Francis, Elsevier, Springer and MDPI; a total of 49 articles were compiled The results were classified according to the microencapsulation method, considering the following information: core, coating material, solvent, formulation, process conditions, particle size, efficiency, yield, bioavailability, bioaccessibility, in vitro release, correlation coefficient and references. It has been evidenced that gums are the most frequently employed coatings in the protection of vitamins (14.04%), followed by alginate (10.53%), modified chitosan (9.65%), whey protein (8.77%), lipid bases (8.77%), chitosan (7.89%), modified starch (7.89%), starch (7.02%), gelatin (6.14%), maltodextrin (5.26%), zein (3.51%), pectin (2.63%) and other materials (7.89%). The factors influencing the release of vitamins include pH, modification of the coating material and crosslinking agents; additionally, it was determined that the most fitting mathematical model for release values is Weibull, followed by Zero Order, Higuchi and Korsmeyer-Peppas; finally, foods commonly fortified with microencapsulated vitamins were described, with yogurt, bakery products and gummy candies being notable examples. [ABSTRACT FROM AUTHOR]

A single hydrothermal reaction was used to create BiOI/BiOBr composites, which demonstrated good sunlight-driven photocatalytic degradation activity of tetracycline (TC) over a broad pH range and the degradation efficiency can be stable at about 90%. Moreover,·O 2 - has been identified as the most important active ingredient in the photocatalytic system. Density functional theory (DFT) calculations were used to investigate the electron transfer mechanism of BiOX heterojunctions on a molecular scale, as well as to propose possible photocatalytic degradation mechanisms and reaction sites for tetracycline in different deprotonated forms at a wide range of pH values. The quantitative structure-activity relationship (QSAR) was also used to assess the toxicity of the intermediates. In summary, this study presents new concepts for investigating the photodegradation behavior of antibiotics throughout a wide pH range, which is predicted to be employed for surface water remediation. [Display omitted] • A simple solvo thermal technique was used to prepare BiOI/BiOBr heterojunctions. • Type II heterojunctions facilitate electron transfer to promote ROS generation. • It demonstrates the high efficiency of photocatalysis over a wide pH range. • Intermediate identification and T.E.S.T calculations verify ecotoxicity fade. [ABSTRACT FROM AUTHOR]

Developing low‐cost oxygen evolution reaction (OER) catalysts with high efficiency and understanding the underlying reaction mechanism are critical for electrochemical conversion technologies. Here, an anodized Prussian blue analogue (PBA) containing Ni and Co is reported as a promising OER electrocatalyst in alkaline media. Detailed post‐mortem characterizations indicate the transformation from PBA to Ni(OH)2 during the anodic process, with the amorphous shell of the PBA facilitating the transformation by promoting greater structural flexibility. Further study with operando Raman and X‐ray photoelectron spectroscopy reveal the increase of anodic potential improves the degree of deprotonation of the transformed core‐shell PBA, leading to an increase of Ni valence. Density functional theory calculations suggest that the increase of Ni valence results in a continuous increase in the adsorption strength of oxygen‐containing species, exhibiting a volcano relationship against the OER activity. Based on the experiments and calculated results, an OER mechanism for the transformed product is proposed. The fully activated catalyst also works as the cathode and the anode for a water‐splitting electrolysis cell with a high output current density of 13.7 mA cm−2 when a cell voltage of 1.6 V applied. No obvious performance attenuation is observed after 40 h of catalysis. [ABSTRACT FROM AUTHOR]

Stationary luminescence and pulse fluorometry methods were used to study the spectral-kinetic and photophysical properties of a 9-methyl-10-hydroxyacridine(1,8)dione derivative dye (9,10-ACD) in polar protic and aprotic solvents at 293 and 77 K. We are the first to report a new long-wavelength fluorescence band (LF, 670–710 nm) in both polar protic (methanol and ethanol) and aprotic solvents (N,N-dimethylformamide and dimethyl sulfoxide) at room temperature. This band is attributed to the high-lying singlet excited state (in the range 460–490 nm) responsible for the short-wavelength fluorescence band (SF). The LF is not found in low-polar (methylene chloride, polar aprotic (acetonitrile) and highly viscous protic solvents (glycerol) at 293 K as well as at 77 K in ethanol. This band arises as a result of deprotonation of a molecule in an excited state and emission of the resultant anion in the long-wavelength region. Analysis of the spectral and kinetic data for SF decay and the LF rise indicates a mechanism, in which the dye anion formation depends on the basicity of the polar solvent. Possible practical applications of this spectral effect in biology, medicine, and analytical chemistry are proposed. [ABSTRACT FROM AUTHOR]

A chemical sensor that can induce near-infrared red-shifted response represents a promising strategy for the design and development of anion probes. In this work, novel CH-controlled colorimetric probe 3 based on anthracene carboximide was developed for near-infrared detection of cyanide. Probe 3 consisted of CHCN binding site to anthracene carboximide fluorophore, and showed a significant visual change from yellow-green (535 nm) to deep violet (825 nm) with a larger redshift (≈ 290 nm) and fluorescence quenching at 480 nm and 520 nm upon interacting with cyanide. Job curves determined 1:1 binding stoichiometry of probe 3 with cyanide. Additonally, probe 3 detected cyanide ion conveniently in aqueous solution and could be reused after trifluoroacetic acid treatment. Colorimetric test paper was used to detect cyanide in aqueous solutions. The C–H deprotonation sensing mechanism was confirmed by 1H NMR titration. The near-infrared detection of cyanide by CH-controlled probes was founded for the first time. [ABSTRACT FROM AUTHOR]