1. Characterisation of the bound lipids at the wool fibre surface by time of flight secondary ion mass spectrometry (ToF-SIMS)
- Author
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D.A. Rankin and Chris Carr
- Subjects
chemistry.chemical_classification ,Potassium hydroxide ,Polymers and Plastics ,Materials Science (miscellaneous) ,chemistry.chemical_element ,Fatty acid ,Thioester ,Oxygen ,Industrial and Manufacturing Engineering ,Ion ,Secondary ion mass spectrometry ,chemistry.chemical_compound ,Hydroxylamine ,chemistry ,Polymer chemistry ,Organic chemistry ,General Agricultural and Biological Sciences ,Alkyl - Abstract
Negative ion time of flight secondary ion mass spectrometry (ToF-SIMS) analysis of rigorously cleaned untreated, hydroxylamine and potassium hydroxide (KOH)-treated wool fabrics, produced with minimal finishing, has revealed the possible presence of hitherto unidentified bound acids at the surface of the wool fibre. Spectral peaks have been assigned to C8 through to C22 fatty acids, the odd numbered acids of which have been assigned to anteiso acids, (a), akin to the anteiso acid 18-methyleicosanoic acid known to be the dominant fatty acid bound to keratin fibre surfaces. This has included the assignment of some small peaks to hydroxylated aC18H36(OH)COS− and aC20H40(OH)COS− species, where the hydroxyl group is attached to the asymmetric 16 or 18 numbered carbon atom in the alkyl chain, respectively. The study has confirmed that many of the acids are bound to the fibre surface by thioester linkages (about 70%) and that the remainder is bound by oxygen ester acyl linkages. ToF-SIMS analysis of hydroxylamin...
- Published
- 2013
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