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Anaerobic wastewater treatment is, in many cases, a justified alternative to typical activated sludge processes, from a technological, economic, and ecological point of view. The optimisation of fermentation reactors is primarily concerned with increasing the biodegradation of organic compounds and biogas production, as well as improving efficiency in the removal of nitrogen and phosphorus compounds. The aim of the research was to determine the impact of using low-cost recycled filling on the efficiency of treating real confectionery wastewater in a vertical anaerobic labyrinth flow bioreactor. The experiments focused on selecting the organic loading rate that would allow for the effective biodegradation and removal of pollutants, as well as the efficient production of biomethane. It was found that the tested reactor can operate efficiently at a maximum organic loading rate (OLR) of 7.0–8.0 g of chemical oxygen demand (COD)/L·d. In this OLR range, high efficiency was guaranteed for both wastewater treatment and biogas production. However, increasing the OLR value to 8.0 g COD/L·d had a significant negative effect on the methane (CH4) content in the biogas. The most efficient variants achieved a biodegradation efficiency of around 90% of the organic compounds, a CH4 content of over 70% in the biogas, and a biogas yield of over 400 L/kg of COD removed. A significant influence of the applied OLR on the ratio of free organic acids (FOS) to total alkaline capacity (TAC) and pH was observed, as well as a strong correlation of these indicators with the specific biogas yield and CH4 content. The application of a solution based on the use of a hybrid system of anaerobic granulated sludge and an anaerobic filter resulted in an efficient treatment process and an almost complete elimination of suspensions from the wastewater. [ABSTRACT FROM AUTHOR]

There is a need to find methods to intensify the anaerobic digestion process. One possibility is the use of pretreatment techniques. Many laboratory tests confirm their effectiveness, but in most cases, there is no verification work carried out on industrial plants. A reliable and complete evaluation of new solutions can only be carried out in plants that reflect operating conditions at a higher readiness technological level. This has a direct impact on the scientific value and, above all, on the high application value of innovative technologies. The aim of our research carried out under laboratory conditions and on a large scale was to determine the technological and energy efficiency of the use of hydrodynamic cavitation in the pretreatment of a waste mixture from dairy farms. It has been shown that hydrodynamic cavitation significantly increases the concentration of organic compounds in the dissolved phase. In the most effective variants, the increase in the content of these indicators was over 90% for both COD and TOC. The degree of solubilisation achieved was 49 ± 2.6% for COD and almost 52 ± 4.4% for TOC. Under laboratory conditions, the highest effects of anaerobic digestion were achieved after 10 min of pretreatment. The amount of biogas was, on average, 367 ± 18 mL/gCOD, and the amount of methane was 233 ± 13 mL/gCOD. Further large-scale optimisation trials showed that after 8 min of hydrodynamic cavitation, the biogas yield was 327 ± 8 L/kgCOD with a CH4 content of 62.9 ± 1.9%. With this variant, the net energy yield was 66.4 ± 2.6 kWh/day, a value that was 13.9% higher than the original variant with 10 min of disintegration and 3.1% higher than the variant without pretreatment. [ABSTRACT FROM AUTHOR]

The characteristics of excess aerobic granular sludge, related to its structure and chemical composition, limit the efficiency of anaerobic digestion. For this reason, pre-treatment methods and compositions with other organic substrates are used. In earlier work, no attempt was made to intensify the methane fermentation of the excess aerobic granular sludge by adding fatty waste materials. The aim of the research was to determine the effects of co-digestion of pre-hydrodynamically cavitated aerobic granular sludge with waste fats on the efficiency of methane fermentation under mesophilic and thermophilic conditions. The addition of waste fats improved the C/N ratio and increased its value to 19. Under mesophilic conditions, the highest effects were observed when the proportion of volatile solids from waste fats was 25%. The amount of biogas produced increased by 17.85% and CH4 by 19.85% compared to the control. The greatest effects were observed in thermophilic anaerobic digestion at 55 °C, where a 15% waste fat content in volatile solids was ensured. This resulted in the production of 1278.2 ± 40.2 mL/gVS biogas and 889.4 ± 29.7 mL/gVS CH4. The CH4 content of the biogas was 69.6 ± 1.3%. The increase in biogas and CH4 yield compared to pure aerobic granular sludge anaerobic digestion was 34.4% and 40.1%, respectively. An increase in the proportion of waste fats in the substrate had no significant effect on the efficiency of methane fermentation. Strong positive correlations (R2 > 0.9) were observed between biogas and CH4 production and the C/N ratio and VS concentration. [ABSTRACT FROM AUTHOR]

The supply of waste glycerol is rising steadily, partially due to the increased global production of biodiesel. Global biodiesel production totals about 47.1 billion liters and is a process that involves the co-production of waste glycerol, which accounts for over 12% of total esters produced. Waste glycerol is also generated during bioethanol production and is estimated to account for 10% of the total sugar consumed on average. Therefore, there is a real need to seek new technologies for reusing and neutralizing glycerol waste, as well as refining the existing ones. Biotechnological means of valorizing waste glycerol include converting it into gas biofuels via anaerobic fermentation processes. Glycerol-to-bioenergy conversion can be improved through the implementation of new technologies, the use of carefully selected or genetically modified microbial strains, the improvement of their metabolic efficiency, and the synthesis of new enzymes. The present study aimed to describe the mechanisms of microbial and anaerobic glycerol-to-biogas valorization processes (including methane, hydrogen, and biohythane) and assess their efficiency, as well as examine the progress of research and implementation work on the subject and present future avenues of research. [ABSTRACT FROM AUTHOR]

The use of aerobic granular sludge is a promising and future-proof solution for wastewater treatment. The implementation of this technology requires the development of efficient and cost-effective methods for the management of excess sludge. The aim of the research was to evaluate the effects of hydrodynamic cavitation on the efficiency of aerobic granular sludge digestion. Respirometric measurements were performed at a temperature of 38 °C and an initial organic load of 5.0 gVS/L. The changes in the properties of the pretreated biomass, the kinetics of methane fermentation, the amount and composition of the biogas produced, and an energetic evaluation of the process were carried out. A significant influence of hydrodynamic cavitation on the transfer of organic compounds into the dissolved phase was demonstrated. The degree of solubilisation was 37% for COD and 42% and for TOC. The efficiency of CH4 production from the pretreated sludge reached a value of 496 ± 12 mL/gVS, which corresponds to an increase of 19.6% compared to the raw biomass. The influence of cavitation on the CH4 content of the biogas was not observed. Strong correlations were found between the efficiency of anaerobic digestion and the concentration of dissolved organic compounds and the hydrodynamic cavitation time used. The gross energy yield was closely correlated with the amount of CH4. The highest comparable values of 3.12 Wh/gTS to 3.18 Wh/gTS were found in the variants in which the hydrodynamic cavitation (HC) time was between 15 min and 50 min. The highest net energy production of 2890 kWh/MgTS was achieved after 15 min of pretreatment. [ABSTRACT FROM AUTHOR]

Though deemed a prospective method, the bioconversion of organic waste to biohydrogen via dark fermentation (DF) has multiple drawbacks and limitations. Technological difficulties of hydrogen fermentation may, in part, be eliminated by making DF a viable method for biohythane production. Aerobic granular sludge (AGS) is a little-known organic waste spurring a growing interest in the municipal sector; its characteristics indicate the feasibility of its use as a substrate for biohydrogen production. The major goal of the present study was to determine the effect of AGS pretreatment with solidified carbon dioxide (SCO2) on the yield of H2 (biohythane) production during anaerobic digestion (AD). It was found that an increasing dose of SCO2 caused an increase in concentrations of COD, N-NH4+, and P-PO43− in the supernatant at the SCO2/AGS volume ratios from 0 to 0.3. The AGS pretreatment at SCO2/AGS ratios within the range of 0.1–0.3 was shown to enable the production of biogas with over 8% H2 (biohythane) content. The highest yield of biohythane production, reaching 481 ± 23 cm3/gVS, was obtained at the SCO2/AGS ratio of 0.3. This variant produced 79.0 ± 6% CH4 and 8.9 ± 2% H2. The higher SCO2 doses applied caused a significant decrease in the pH value of AGS, modifying the anaerobic bacterial community to the extent that diminished anaerobic digestion performance. [ABSTRACT FROM AUTHOR]

Appropriate management is necessary to mitigate the environmental impacts of wastewater sludge. One lesser-known technology concerns the use of solidified CO2 for dewatering, sanitization, and digestion improvement. Solidified CO2 is a normal byproduct of natural gas treatment processes and can also be produced by dedicated biogas upgrading technologies. The way solidified CO2 is sourced is fully in line with the principles of the circular economy and carbon dioxide mitigation. The aim of this review is to summarize the current state of knowledge on the production and application of solid CO2 in the pretreatment and management of sewage sludge. Using solidified CO2 for sludge conditioning causes effective lysis of microbial cells, which destroys activated sludge flocs, promotes biomass fragmentation, facilitates efficient dispersion of molecular associations, modifies cell morphology, and denatures macromolecules. Solidified CO2 can be used as an attractive tool to sanitize and dewater sludge and as a pretreatment technology to improve methane digestion and fermentative hydrogen production. Furthermore, it can also be incorporated into a closed CO2 cycle of biogas production–biogas upgrading–solidified CO2 production–sludge disintegration–digestion–biogas production. This feature not only bolsters the technology's capacity to improve the performance and cost-effectiveness of digestion processes, but can also help reduce atmospheric CO2 emissions, a crucial advantage in terms of environment protection. This new approach to solidified CO2 generation and application largely counteracts previous limitations, which are mainly related to the low cost-effectiveness of the production process. [ABSTRACT FROM AUTHOR]

The increasing concentration of anthropogenic CO2 in the atmosphere is causing a global environmental crisis, forcing significant reductions in emissions. Among the existing CO2 capture technologies, microalgae-guided sequestration is seen as one of the more promising and sustainable solutions. The present review article compares CO2 emissions in the EU with other global economies, and outlines EU's climate policy together with current and proposed EU climate regulations. Furthermore, it summarizes the current state of knowledge on controlled microalgal cultures, indicates the importance of CO2 phycoremediation methods, and assesses the importance of microalgae-based systems for long-term storage and utilization of CO2. It also outlines how far microalgae technologies within the EU have developed on the quantitative and technological levels, together with prospects for future development. The literature overview has shown that large-scale take-up of technological solutions for the production and use of microalgal biomass is hampered by economic, technological, and legal barriers. Unsuitable climate conditions are an additional impediment, forcing operators to implement technologies that maintain appropriate temperature and lighting conditions in photobioreactors, considerably driving up the associated investment and operational costs. [ABSTRACT FROM AUTHOR]

Production and consumption of confectionery products have increased worldwide, thus, effective management of wastewater produced is now an important issue. The confectionery high-load sewage was explored for biogas production in an innovative-design anaerobic reactor with labyrinth flow. The experimental studies were focused on determining the best technological parameters of anaerobic digestion for the effective removal of pollutants and obtaining high CH4 production efficiency. It was found that organic loading rate (OLR) of 5.0–6.0 g COD/L·d contributed to the highest CH4 generation of 94.7 ± 6.1 to 97.1 ± 5.1 L CH4/d, which corresponded to a high COD removal of 75.4 ± 1.5 to 75.0 ± 0.6%. Under such conditions the FOS/TAC ratio was below 0.4, indicating reactor stability, and pH was on the level of 7.15 ± 0.04 at OLR 5.0 g COD/L·d and 7.04 ± 0.07 at OLR 6.0 g COD/L·d. [ABSTRACT FROM AUTHOR]

Microalgal biomass can be used to derive many different types of biofuels. In order to widely commercialize this technology, its limitations and weaknesses must be eliminated. Many technical and economic issues also need to be clarified and unknowns answered. Microalgae-based technologies have been shown to be versatile, efficient and suitable for practical and commercial use. However, the current technological readiness level (TRL) of most microalgae-based bioenergy production systems precludes their quick and widespread implementation. Their development is limited by a combination of factors that must be precisely identified, after which their negative impact on scale-up prospects can be eliminated or minimized. The present study identifies the main barriers to the development of industrial microalgae-production and microalgae-to-biofuel systems. In addition, it proposes measures and efforts necessary to achieve a higher TRL, which will provide investors with sought-after performance and cost-efficiency data for the given project. The main barriers to the development of microalgae cultivation and processing systems have been identified to include: the complex nature of the cultivation process with multiple variables involved; lack of sufficient data from pilot-scale and near-full-scale plants, which often precludes reliable life cycle assessment (LCA); and insufficient legal assistance, advisory assistance, subsidies and funding for innovative projects. Potential ways of improving performance and competitiveness of microalgae-based systems include: process optimization techniques, genetic engineering, yield improvement through advanced process control and monitoring, use of waste as feedstock and dedicated support programs. The presented summary of the current stage of microalgal biofuel production technology development indicates the directions for further research and implementation work, which are necessary for the final verification of the application potential of these solutions. [ABSTRACT FROM AUTHOR]

Recent years have brought significant evolution and changes in wastewater treatment systems. New solutions are sought to improve treatment efficiency, reduce investment/operational costs, and comply with the principles of circular economy and zero waste. Microbial granules can serve as an alternative to conventional technologies. Indeed, there has been fast-growing interest in methods harnessing aerobic (AGS) and anaerobic (AnGS) granular sludge as well as microbial-bacterial granules (MBGS), as evidenced by the number of studies on the subject and commercial installations developed. The present paper identifies the strengths and weaknesses of wastewater treatment systems based on granular sludge (GS) and their potential for energy production, with a particular focus on establishing the R&D activities required for further advance of these technologies. In particular, the impact of granules on bioenergy conversion, including bio-oil recovery efficiency and biomethane/biohydrogen yields, and bioelectrochemical systems must be assessed and optimized. [ABSTRACT FROM AUTHOR]

The implementation of appropriate solutions for municipal waste management is still a significant challenge for the operators of technological facilities. Although there are many separate collection procedures and waste neutralisation systems available, it is still necessary to search for new economically and technologically justified solutions. The priority is environmental care and circular economy compliance. An important aspect is recycling and energy recovery from waste as an alternative fuel. Preparation of municipal waste for energy production requires many preliminary unit processes, and one of the most important factors is drying. It should be emphasised that environmental impact assessment is an indispensable aspect of waste management. The aim of long-term research was to determine the effect of bio-drying of municipal waste on the characteristics of technological and precipitation wastewater and its impact on the quality of the aquatic environment. An investigation was carried out between 2015–2021 on a large-scale installation for 200,000 residents. It was proven that during the wastewater treatment plant operation, the concentration of N-NH4 was exceeded. The concentrations of other pollution indicators corresponded to the normative values. The quality of groundwater also deteriorated. A comparative analysis of municipal waste drying methods showed that the bio-drying process has a significantly lower impact on the natural environment than the methods that are lower in the municipal waste management hierarchy. [ABSTRACT FROM AUTHOR]

The rapid growth in dairy production leads to increasing outputs of high-load effluent, necessitating new methods of treating such waste. Anaerobic processes have been increasingly popular but are hamstrung by limited nutrient removal efficiency. The aim of the present study was to investigate whether low-cost recycled filling (LCRF) improves the anaerobic treatment of dairy effluent. The addition of LCRF was found to increase both COD removal (86.1 ± 2.6%–92.8 ± 1.6%) and Ptot. removal (22.1 ± 3.5% to 36.9 ± 4.6%) from the wastewater. The LCRF ensured near-neutral pH and stabilized the structure of the anaerobic microbe community (including Archaea) across all pollutant loads tested. This translated to efficient biogas production and high methane content in the LCRF reactors, peaking at 0.35 ± 0.01 m3/kg CODremoved and 68.2 ± 0.6% (respectively) in the best-performing variant. [ABSTRACT FROM AUTHOR]

Municipal facilities can generate odors caused by substances such as fatty acids, organosulfur compounds, aldehydes, and inorganic gases, especially H2S. Identifying an effective and cost-efficient solution to the problem is a priority for communities in areas at risk of exposure to odors. The aim of this study was to evaluate the effect of advanced oxidation processes (AOPs) involving Fenton's reagents (Fe2+/H2O2, Fe3+/H2O2) on wastewater profiles and their capacity to reduce putrescibility, H2S emissions, and odor concentration in the air. The Fe2+/H2O2 system proved to be the most efficient in terms of inhibiting the process of redox conditions development, removing organic matter in the wastewater, inhibiting H2S formation, and reducing odor emissions. H2S generation in raw wastewater was triggered as early as on day 2 of anaerobic retention, with levels of 5.6 ppm to 64 ppm. After introduction of 0.1 g Fe2+/dm3 and 2.0 g H2O2/dm3, no H2S was detected in the gas for 8 days. The odor concentration (OC) of raw wastewater (2980 ± 110 oue/m3) was reduced by 96.3 ± 1.9% to a level of 100 ± 15 oue/m3. The Fe2+/H2O2 system maintained its oxidizing capacity up until day 7, with OC reduction by 96.0 ± 0.8% to a level of 120 ± 10 oue/m3. On day 10, the OC showed a marked increase to a level 1310 ± 140 oue/m3. The conducted research has proven that Fenton-based AOP systems are a technologically and commercially viable method of deodorization of sewage facilities. [ABSTRACT FROM AUTHOR]

Renewable energy is becoming a widely discussed topic in the European Union (EU), due to a desire to reduce the negative effects of fossil fuels on climate change and biodiversity. About 60% of the total renewable energy produced in the EU is derived from biomass. Anaerobic digestion (AD) is an important pathway to convert biomass into biogas and then into bioenergy. Helianthus salicifolius is a perennial plant, whose biomass can serve as a co-substrate in biogas plants. Biomass composition, in addition to the biomethane and biogas potential, were investigated in raw green biomass and silage obtained from Helianthus salicifolius plants grown under different types (mineral and organic) and doses (0, 85, 170 kg N ha−1) of nitrogen fertilization. The biomethane production efficiency from Helianthus salicifolius was recorded for 25 days and found to range on average between 169.4 NL kg−1 VS for raw biomass and 193.2 NL kg−1 VS for silage. It follows from the current study that ensiling increases substrate digestibility and has a positive impact on methane concentration, but the biomethane and biogas production outputs from those substrates did not differ significantly at the end of the process. [ABSTRACT FROM AUTHOR]

Microalgae-based technologies have huge potential for application in the environment sector and the bio-energy industry. However, their cost-efficiency has to be improved by drawing on design and operation data for large-scale installations. This paper presents a technical concept of an installation for large-scale microalgae culture on digestate liquor, and the results of a pilot-scale study to test its performance. The quality of non-treated digestate has been shown to be insufficient for direct use as a growth medium due to excess suspended solids, turbidity, and organic matter content, which need to be reduced. To that end, this paper proposes a system based on mechanical separation, flotation, and pre-treatment on a biofilter. The culture medium fed into photobioreactors had the following parameters after the processing: COD—340 mgO2/dm3, BOD5—100 mgO2/dm3, TN—900 mg/dm3, and TP—70 mg/dm3. The installation can produce approx. 720 kgVS/day of microalgal biomass. A membrane unit and a thickening centrifuge (thickener) were incorporated into the design to separate and dehydrate the microalgal biomass, respectively. The total energy consumption approximated 1870 kWh/day. [ABSTRACT FROM AUTHOR]

During methane fermentation of sludge subjected to chemical disintegration with a reactant dose of 3.0 mL of STERIDIAL W-10/L, the highest value of daily biogas production (0.28 L) was observed on the tenth day of the process. Sewage Sludge Managements Technologies Zawieja and Warwag [[4]] aimed to determine the effect of chemical disintegration with peracetic acid on biogas production efficiency using methane fermentation of pretreated sludge. The development of wastewater treatment methods and the processing of sewage sludge is associated with the search for new, efficient and technologically justified solutions, the use of which will be an alternative to the systems used thus far. The SMF had a significant impact on methane production efficiency, the fermentation rate level, removal rate and the structure of the anaerobic bacteria consortium, but it did not affect cumulative biogas production [[6]]. [Extracted from the article]

The aim of the study was to investigate the potential of microalgal cultivation on anaerobic liquid digestate as a growth medium. The two methods of liquid digestate treatment including centrifugation and distillation and the two algal strains (Chlorella vulgaris and Arthrospira platensis) were compared. Additionally, the volume of the liquid digestate used to prepare the culture medium constituted from 10 to 50% of the medium volume. The study demonstrated that the highest C. vulgaris and A. platensis biomass productions of 2490 mg TS/L and 2990 mg/L, respectively, were obtained by adding 50% of distilled digestate to a growth medium. Regarding centrifuged liquid digestate, only 10% dilution was required to obtain the maximum final biomass concentration. A. platensis removed 81.1% and 66.4% of the total nitrogen from medium prepared on distilled and centrifuged digestate, respectively, while C. vulgaris ensured 64.1% and 47.1% of removal, respectively. The phosphorus removal from both culture media was higher than 94.2% with A. platensis, while it was 70.4% from distilled and 87.4% from centrifuged media with C. vulgaris. The study confirmed a great potential of microalgal biomass production on anaerobic liquid digestate with a high treatment efficiency of digestate. [ABSTRACT FROM AUTHOR]

The opinion, that the use of foil reactors for the aerobic biostabilization of municipal wastes is not a valid method, due to vulnerability to perforation, and risk of uncontrolled release of exhaust gasses, was verified. This study aimed to determine the intensity of greenhouse gas (GHG) emissions to the atmosphere from the surface of foil reactors in relation to the extent of foil surface perforation. Three scenarios were tested: intact (airtight) foil reactor, perforated foil reactor, and torn foil reactor. Each experimental variant was triplicated, and the duration of each experiment cycle was 5 weeks. Temperature measurements demonstrated a significant decrease in temperature of the biostabilization in the torn reactor. The highest emissions of CO 2 , CO and SO 2 were observed at the beginning of the process, and mostly in the torn reactor. During the whole experiment, observed emissions of CO, H 2 S, NO, NO 2 , and SO 2 were at a very low level which in extreme cases did not exceed 0.25 mg t −1 .h −1 (emission of gasses mass unit per waste mass unit per unit time). The lowest average emissions of greenhouse gases were determined in the case of the intact reactor, which shows that maintaining the foil reactors in an airtight condition during the process is extremely important. [ABSTRACT FROM AUTHOR]

Nutrient removal effectiveness from anaerobic digestion effluents (ADEs) by Chlorella sp. cultivation and microalgae biomass productivity were evaluated in this study. The results showed that the highest Chlorella sp. biomass productivities of 386.5 µ 24.1 mg dry weight/L⋅d and 338.3 µ 11.0 mg dry weight/L⋅d were respectively obtained with the anaerobically digested effluent of municipal wastewater sludge and effluent from a fermentation tank treating dairy wastewater. Lower (p < 0.05) microalgal growth was achieved with anaerobically digested effluents of maize silage and swine slurry and cattle manure. The increase of the initial ammonia nitrogen concentration in ADEs to the level of 160 mg/L did not encourage Chlorella sp. productivity because of phosphorus limitation. The removal efficiencies of ammonia nitrogen, total nitrogen, total phosphorus, and chemical oxygen demand (COD) reached 99.7%, 98.6%, 88.2%, and 58.7%, respectively, depending on the source of ADE, but not on the initial ammonia nitrogen concentrations. [ABSTRACT FROM AUTHOR]

This study compared the effects on biogas production of suspended sludge versus a combination of suspended sludge and immobilized biomass, and microwave versus convection heating. Biogas production was the highest in the hybrid bioreactor heated by microwaves (385 L/kg VS) and also the most stable, as shown by the FOS/TAC ratio and pH. Regardless of the type of heating, biogas production was 8% higher with immobilized biomass than without. Although the lag phase of biogas production was shorter with microwave heating than without, the log phase was longer, and biogas production in the microwave heated bioreactors took about twice as long (ca. 40 days) to plateau as in the conventionally heated bioreactors. These differences in the profile of biogas production are likely due to the athermal effects of microwave irradiation. [ABSTRACT FROM AUTHOR]

Microwave (MW) processing was used to cure a sol-gel type silicone resin coating that normally requires thermal curing over 250 °C. The study focused on coatings applied on polycarbonate and poly(methyl methacrylate) substrates and processing temperatures did not exceed 100 °C when using Silicone Carbide, Carbon, and Aluminium susceptors at 5% concentration by weight. Heating performance of the susceptors in bulk silicone resin matrix as well as in thin layers was compared. The results presented show that the heating response of the additives measured in bulk was significant. However, results for thin layers indicated that the effects of MW heating on the coatings containing the susceptors were limited, and samples microwaved at 800 W for 4 h imparted insignificant increase of the coating hardness. This outcome was supported by AFM Phase images which revealed no distinctive layer near the susceptor particles. This suggests that the heat dissipation to the substrate and air with limited heating performance of the susceptors does not allow for an effective in-situ curing in thin layer. [ABSTRACT FROM AUTHOR]

The aim of the study was to determine the influence of the light source on the taxonomic structure and chemical composition of the harvested biomass, and on the fermentative biogas/methane production. Cultivation of a mixed microalgae culture was carried out in closed vertical photobioreactors equipped with different light sources. The effectiveness of anaerobic digestion was analysed by respirometric measurements. The harvested microalgae biomass was characterized by various taxonomic structures and varied chemical composition depending on the light source used during cultivation stage. In variants where warm white LED lighting and red light were used, species from the Cyanoprokaryota division predominated, characterized by a high concentration of organic compounds and nitrogen in the biomass. TOC values amounted to almost 430 mg/g TS. In the remaining variants, Chlorophyta predominated, and TOC values were in the range of 388.0–411.3 mg/g TS. A significantly higher biogas/methane production ( p = 0.05) was found in variants in which biomass with Cyanoprokaryota predominating was tested. The biogas yield was in the range of 383.2 L/kg VS to 400.8 L/kg VS, and the methane content was close to 55%. A lower effectiveness of biogas and methane formation were observed in variants with Chlorophyta as a predominating taxonomic group. [ABSTRACT FROM AUTHOR]

Biogas production is one of the solutions for replacing fossil fuels, which promotes the widespread use of green energy. The aim of this study was to determine the potential of Silphium perfoliatum as an energy crop for biogas production, as well as the effect of different fertilization doses (0, 85 and 170 kg N ha−1) on the production potential (NL CH4 kg−1 VS) of Silphium perfoliatum. The study investigated the use of different feedstocks, such as raw and ensiled Silphium perfoliatum biomass. The methane production ranged between 193.59 and 243.61 NL CH4 kg−1 VS. The highest biogas production potential was achieved with the biomasses which were cultivated with the highest fertilization dose (170 kg N ha−1), both for raw and ensiled crop biomasses, although the difference from the other fertilization doses was not significant. The feedstock (biomass and silage) and digestate parameters were investigated as well. The use of Silphium perfoliatum for biogas production seems very promising since its methane production potential was found to be similar to that of the most common energy crop, such as maize, indicating that Silphium perfoliatum can compete in the future with maize. [ABSTRACT FROM AUTHOR]

Abstract: The aim of this study was to determine the possibility of applying psychrophilic bacteria for hydrogen production in whey biofermentation process. Experiments were conducted in 500-mL anaerobic respirometers at a temperature of 20 °C. The initial organic load of fermentation tanks reached 10 g COD/L. Depending on the experimental variant, analyses were carried out for psychrophilic bacteria isolated from underground water and from demersal lake water that represented Gammaproteobacteria class – Rahnella aquatilis (9 strains) and Firmicutes phylum: Carnobacterium maltaromaticum, Trichococcus collinsii and Clostridium algidixylanolyticum. The effectiveness of biogas production was diversified and strain-specific, ranging from 126.48 to 4737.72 mL/g bacterial biomass. The highest concentration of H2 in biogas, ranging from 65.15% to 69.12% and effectiveness of H2 production from 1587.47 to 3087.57 mL/g bacterial biomass, were determined for R. aquatilis strains isolated from the demersal lake water. The lowest H2 concentration in the gaseous metabolites, i.e. 15.46% to 20.70%, was noted for bacteria of the phylum Firmicutes. [Copyright &y& Elsevier]

This study was undertaken in order to determine the effects of the constant magnetic field (CMF) on the effectiveness of dairy wastewater treatment under anaerobic conditions. It demonstrated that increasing the value of the magnetic flux in the analyzed range resulted in an increasing effectiveness of the fermentation process. Magnets with induction of 0.38 [T] elicited significant changes in the analyzed parameters of methane fermentation. The magnetic field (MF) was observed to positively affect the sedimentation process of anaerobic sludge, reduced COD concentration in the effluent, and biogas production rate. In the most effective variant, the content of suspended matter in the treated wastewaters was reduced by 26.1% and the effectiveness of COD removal increased by 14.0%, compared to the variant without the application of the physical factor. Magnetic induction of 0.431 caused significant changes in the analyzed parameters of the methane fermentation process. [ABSTRACT FROM AUTHOR]

Abstract: The use of algae as a potential substrate in biogas production processes has been discussed sporadically, therefore this manuscript provides an overview of reference data published so far on that matter. The goal of this review is to present possibilities of applying algae biomass for biogas production purposes and to determine the effectiveness of the fermentation process of algae belonging to various taxonomic groups, originating from various biocenoses and characterized by different morphology and properties. Finally, this work reports on methods and technological solutions for algae biomass production as well as impediments and opportunities stemming from algae biomass use in biogas production technologies. [Copyright &y& Elsevier]

Anaerobic wastewater treatment is still a dynamically developing technology ensuring the effective degradation of organic compounds and biogas production. As evidenced in the large scale-up, this technological solution surpasses aerobic methods in many aspects. Its advantages stem from the feasibility of operation at a high organic load rate, the smaller production of difficult-to-manage sewage sludge, the smaller space and cubature required, and the high-methane biogas ultimately produced. The exploitation of anaerobic reactors is in line with the assumption of a circular economy, material recycling by reduced CO2 emissions and energy consumption, and the production of renewable energy. Despite their unquestionable advantages, there is still a need to seek novel approaches and improve the currently exploited installations. The key avenues of research entail improvements in the stability of bioreactor operations and the enhancement of bioreactor adaptability to changing and unfavorable process parameters. The versatility of such systems would also be greatly improved by increasing nitrogen and phosphorus removal rates. Attempts have been made to achieve these goals by setting up separate zones within bioreactors for the individual steps of methane fermentation, incorporating active fillings to promote nutrient removal, and introducing chemical and physical treatments. An interesting solution is also the use of microwave radiation to stimulate temperature conditions and induce non-thermal phenomena, such as enhancing the enzymatic activity of methanogenic microflora. Another prospective approach is to integrate digesters into microalgal biomass production systems. The aim of this review paper is to present the thus-far technological knowledge about anaerobic wastewater treatment, including standard solutions and innovative ones, the effectiveness of which has been corroborated in pilot-scale installations. [ABSTRACT FROM AUTHOR]

Hydrogen is an environmentally friendly biofuel which, if widely used, could reduce atmospheric carbon dioxide emissions. The main barrier to the widespread use of hydrogen for power generation is the lack of technologically feasible and—more importantly—cost-effective methods of production and storage. So far, hydrogen has been produced using thermochemical methods (such as gasification, pyrolysis or water electrolysis) and biological methods (most of which involve anaerobic digestion and photofermentation), with conventional fuels, waste or dedicated crop biomass used as a feedstock. Microalgae possess very high photosynthetic efficiency, can rapidly build biomass, and possess other beneficial properties, which is why they are considered to be one of the strongest contenders among biohydrogen production technologies. This review gives an account of present knowledge on microalgal hydrogen production and compares it with the other available biofuel production technologies. [ABSTRACT FROM AUTHOR]

The priority faced by energy systems in road transport is to develop and implement clean technologies. These actions are expected to reduce emissions and slow down climate changes. An alternative in this case may be the use of biodiesel produced from microalgae. However, its production and use need to be justified economically and technologically. The main objective of this study was to determine the emissions from an engine powered by biodiesel produced from the bio-oil of Chlorella protothecoides cultured with different methods, i.e., using a pure chemical medium (BD-ABM) and a medium based on the effluents from an anaerobic reactor (BD-AAR). The results obtained were compared to the emissions from engines powered by conventional biodiesel from rapeseed oil (BD-R) and diesel from crude oil (D-CO). The use of effluents as a medium in Chlorella protothecoides culture had no significant effect on the properties of bio-oil nor the composition of FAME. In both cases, octadecatrienoic acid proved to be the major FAME (50% wt/wt), followed by oleic acid (ca. 22%) and octadecadienoic acid (over 15%). The effluents from UASB were found to significantly reduce the biomass growth rate and lipid content of the biomass. The CO2 emissions were comparable for all fuels tested and increased linearly along with an increasing engine load. The use of microalgae biodiesel resulted in a significantly lower CO emission compared to the rapeseed biofuel and contributed to lower NOx emission. Regardless of engine load tested, the HC emission was the highest in the engine powered by diesel. At low engine loads, it was significantly lower when the engine was powered by microalgae biodiesel than by rapeseed biodiesel. [ABSTRACT FROM AUTHOR]

Microalgae-mediated CO2 sequestration has been a subject of numerous research works and has become one of the most promising strategies to mitigate carbon dioxide emissions. However, feeding flue and exhaust gas into algae-based systems has been shown to destroy chloroplasts, as well as disrupt photosynthesis and other metabolic processes in microalgae, which directly limits CO2 uptake. CO2 biosequestration in existing photobioreactors (PBRs) is also limited by the low biomass concentration in the growth medium. Therefore, there is a real need to seek alternative solutions that would be competitive in terms of performance and cost-effectiveness. The present paper reports the results of experiments aimed to develop an innovative trickle bed reactor that uses immobilized algae to capture CO2 from flue and exhaust gas (IMC-CO2PBR). In the experiment, ambient air enriched with technical-grade CO2 to a CO2 concentration of 25% v/v was used. The microalgae immobilization technology employed in the experiment produced biomass yields approximating 100 g DM/dm3. A relationship was found between CO2 removal rates and gas volume flux: almost 40% of CO2 was removed at a feed of 25 dm3 of gas per hour, whereas in the 200 dm3/h group, the removal efficiency amounted to 5.9%. The work includes a determination of basic process parameters, presentation of a developed functional model and optimized lighting system, proposals for components to be used in the system, and recommendations for an automation and control system for a full-scale implementation. [ABSTRACT FROM AUTHOR]

The calculation method commonly used in the industry takes into consideration mainly fuel consumption (excluding electricity) and the amount of removed moisture which is reflected in the unit MJ·(Mg·%)−1. This is not a scientific approach because the result will change if the basic moisture is different (drying from 21% to 18% will consume less energy than drying from 18% to 15%). This paper aims to compare the energy consumption of two industrial continuous flow grain dryers powered by LPG and hard coal based on a comprehensive approach to energy efficiency calculation enriched with electricity consumption, flow measurements, and control of grain moisture. It could be useful for manufacturers who could use this method to generate more reliable data in their product datasheets, and it could also be legally regulated as an appropriate tool for calculating the energy consumption of agricultural grain dryers. According to the approach presented in this paper, the S428.CS construction powered by LPG gas had an energy consumption that was 6.14% lower than the DT2532 dryer construction, which used hard coal. [ABSTRACT FROM AUTHOR]

Photosynthetic microbial fuel cells (pMFCs) are hybrid systems that enable simultaneous wastewater treatment under anaerobic conditions and the generation of electricity by utilizing the potential difference in the anaerobic anode chamber and the oxygenated cathode chamber. Dairy wastewater with a concentration of 2000 mg COD/L was treated in the anode of a batch pMFC. In the cathode chamber, Chlorella vulgaris or Arthrospira platensis was cultivated in synthetic medium, and next in diluted effluent from the anode chamber. The highest power density of 91 mW/m2 was generated by the pMFC with the cultivation of Arthrospira platensis. Higher values of dissolved oxygen remained during the dark phase in the cathodic medium with Arthrospira platensis cultivation than with Chlorella vulgaris. This depletion of oxygen significantly decreased voltage generation, which during the light phase increased again to the maximum values. The COD removal achieved in the anodic chamber was 87%. The efficiency of nitrogen removal in the cathode chamber during the cultivation of Arthrospira platensis and Chlorella vulgaris was about 78% and 69%, respectively. The efficiency of phosphorus removal in the cathode chamber with the cultivation of Arthrospira plantensis and Chlorella vulgaris was 58% and 43%, respectively. This study has shown that the introduction of Arthrospira platensis into the cathode chamber is more effective than that of Chlorella vulgaris. [ABSTRACT FROM AUTHOR]

The present study aimed to determine the effect of a 17.6 mT static magnetic field (SMF) on the efficiency of anaerobic digestion (AD) of municipal sewage sludge (MSS). The SMF had a significant impact on methane (CH4) production efficiency, the levels of fermentation rate (ηFMSS) vs. removal rate (ηVS), and the structure of the anaerobic bacteria consortium, but it did not affect cumulative biogas production. The highest CH4 yield (431 ± 22 dm3CH4/kgVS) and the highest methane content in the biogas (66.1% ± 1.9%) were found in the variant in which the SMF exposure time was 144 min/day. This variant also produced the highest ηFMSS and ηVS values, reaching 73.8% ± 2.3% and ηVS 36.9% ± 1.6%, respectively. Longer anaerobic sludge retention time in the SMF area significantly decreased AD efficiency and caused a significant reduction in the number of methanogens in the anaerobic bacteria community. The lowest values were observed for SMF exposure time of 432 min/day, which produced only 54.8 ± 1.9% CH4 in the biogas. A pronounced reduction was recorded in the Archaea (ARC915) and Methanosaeta (MX825) populations in the anaerobic sludge, i.e., to 20% ± 11% and 6% ± 2%, respectively. [ABSTRACT FROM AUTHOR]

Technological solutions allowing the increase of the technological efficiency of anaerobic methods of wastewater treatment are still under investigation. The weaknesses of these solutions can be limited by the use of active fillings. The aim of the present study was to determine the impact of fluidized active filling on the effectiveness of anaerobic treatment of sugar-industry effluent, the production efficiency and the qualitative composition of the biogas produced. High, comparable (p = 0.05) effluent treatment results were observed at tested organic load rates between 4.0 and 6.0 kg COD (Chemical Oxygen Demand)/m3·d. The COD removal rate reached over 74%, biogas yields ranged from 356 ± 25 to 427 ± 14 dm3/kg CODremoved and the average methane contents were approximately 70%. A significant decrease in effluent treatment efficiency and methane fermentation was observed after increasing the organic load rate to 8.0 kg COD/m3·d, which correlated with decreased pH and FOS/TAC (volatile organic acid and buffer capacity ratio) increased to 0.44 ± 0.2. The use of fluidized active filling led to phosphorus removal with an efficiency ranged from 64.4 ± 2.4 to 81.2 ± 8.2% depending on the stage. Low concentration of total suspended solids in the treated effluent was also observed. [ABSTRACT FROM AUTHOR]

The aim of this study was the performance evaluation of anaerobic digestion of dairy wastewater in a multi-section horizontal flow reactor (HFAR) equipped with microwave and ultrasonic generators to stimulate biochemical processes. The effects of increasing organic loading rate (OLR) ranging from 1.0 g chemical oxygen demand (COD)/L·d to 4.0 g COD/L·d on treatment performance, biogas production, and percentage of methane yield were determined. The highest organic compounds removals (about 85% as COD and total organic carbon—TOC) were obtained at OLR of 1.0–2.0 g COD/L·d. The highest biogas yield of 0.33 ± 0.03 L/g COD removed and methane content in biogas of 68.1 ± 5.8% were recorded at OLR of 1.0 g COD/L·d, while at OLR of 2.0 g COD/L·d it was 0.31 ± 0.02 L/COD removed and 66.3 ± 5.7%, respectively. Increasing of the OLR led to a reduction in biogas productivity as well as a decrease in methane content in biogas. The best technological effects were recorded in series with an operating mode of ultrasonic generators of 2 min work/28 min break. More intensive sonication reduced the efficiency of anaerobic digestion of dairy wastewater as well as biogas production. A low nutrient removal efficiency was observed in all tested series of the experiment, which ranged from 2.04 ± 0.38 to 4.59 ± 0.68% for phosphorus and from 9.67 ± 3.36 to 20.36 ± 0.32% for nitrogen. The effects obtained in the study (referring to the efficiency of wastewater treatment, biogas production, as well as to the results of economic analysis) proved that the HFAR can be competitive to existing industrial technologies for food wastewater treatment. [ABSTRACT FROM AUTHOR]

The aim of this study was to determine the effects on methane production of the addition of microalgae biomass of Arthrospira platensis and Platymonas subcordiformis to the common feedstock used in agricultural biogas plants (cattle manure, maize silage). Anaerobic biodegradability tests were carried out using respirometric reactors operated at an initial organic loading rate of 5.0 kg volatile solids (VS)/m3, temperature of 35°C, and a retention time of 20 days. A systematic increase in the biogas production efficiency was found, where the ratio of microalgae biomass in the feedstock increased from 0% to 40% (%VS). Higher microalgae biomass ratio did not have a significant impact on improving the efficiency of biogas production, and the biogas production remained at a level comparable with 40% share of microalgae biomass in the feedstock. This was probably related to the carbon to nitrogen (C/N) ratio decrease in the mixture of substrates. The use of Platymonas subcordiformis ensured higher biogas production, with the maximum value of 1058.8 ± 25.2 L/kg VS. The highest content of methane, at an average concentration of 65.6% in the biogas produced, was observed in setups with Arthrospira plantensis biomass added at a concentration of between 20%–40% to the feedstock mixture. [ABSTRACT FROM AUTHOR]

One of the most important factors determining the profitability of microalgae biomass production is the use of inexpensive and available source of nutrients. The aim of the study was to determine the possibility of using anaerobic digestion effluents (ADE) from the fermentation of distillery stillage, maize silage and bovine slurry as a nutrient in the production of microalgae Chlorella vulgaris biomass. The highest biomass production of 2319 mg TS/dm3 was obtained during the cultivation of microalgae in the medium consisting of the effluents originating from the fermentation with a high share of bovine slurry. Significantly lower Chlorella vulgaris biomass growth was noted during cultivation in the medium composed of effluents obtained after dewatering of anaerobic sludge from the methane fermentation reactor fed with distillery stillage. In these series, an increase of the initial concentration of N-NH4 in the medium to a level of 160 mg/dm3 significantly reduced microalgae growth. The high efficiency of P-PO4 removal from 87–100% was noted. The study proved that anaerobic digestion effluents might be used as a nutrient source for efficient biomass production of Chlorella vulgaris after optimization of ammonium nitrogen dose. [ABSTRACT FROM AUTHOR]

The hybrid bioreactor heated by microwave or conventional by hot water jacket is presented. The reactor consisted of two functional sections. The upper section was constituted by an unsinkable anaerobic biological bed, whereas the bottom section – by suspended anaerobic activated sludge. Both sections were closed in one casing. The study was conducted in mesophilic (35 °C) and thermophilic (55 °C) conditions. Depending on the method of heating, the homogeneity of the temperature field in both functional parts of the reactor was determined. In mesophilic conditions only at measurement points located directly under the wave-guide the temperatures were significantly higher than in the other zones inside the reactor. This implies that it is possible to homogenous heat of the bioreactor in semi-technical scale by microwave irradiation. Under thermophilic conditions a homogenous field of temperature was obtained in the upper and in the bottom section of the bioreactor, however, significant differences were found in values of the temperature between the particular sections of the bioreactor. [ABSTRACT FROM AUTHOR]

This study aimed to analyze the coupled effect of electromagnetic microwave radiation and sodium hydroxide on the structure of a lignocellulosic complex of Virginia mallow and to determine the susceptibility of the pretreated substrate to anaerobic degradation. Effects of substrate digestion with conventional and microwave heating were compared as well. NaOH dose increase from 0.02 g·g t.s −1. to 0.2 g·g t.s −1. caused biogas production to increase in both heating variants. In turn, NaOH dose increase to 0.4 g·g t.s −1. resulted in diminished biogas production in variants with both microwave and conventional heating, i.e. by 15.3% and 20.8%, respectively. The highest biogas production effectiveness was achieved during fermentation of the substrate conditioned using microwave radiation coupled with the addition of NaOH in a dose of 0.2 g·g t.s −1., and the result obtained was by 10% higher compared to the conventionally-heated sample and by 39.4% higher compared to the microwave-heated and chemically-untreated sample. The coupled use of microwave heating and alkaline treatment allowed achieving a higher volume of biogas produced. Methane content in gaseous bacterial metabolites ranged from 58 to 61%, irrespective of NaOH dose and heating method. • The highest biogas production was obtained after microwave heating with NaOH in a dose of 0.2 g/g t.s. • The coupled use of pretreatment methods allowed achieving a higher volume of biogas produced. • Methane fermentation inhibition observed could be due to the excess of Na+ ions. [ABSTRACT FROM AUTHOR]

The study investigated the influence of static magnetic field on sedimentation of activated sludge, coagulation efficiency in the bioreactors and dewaterability of the sludge. The sedimentation was improved when magnetizers were applied on the bioreactor and on the settling tank. The application of magnetizers only on the settling tank decreased the sedimentation properties of the sludge. The filamentous bacteria Type 0092 dominated in both bioreactors, but the significant differences were observed in its length. No effect of the static magnetic field on coagulation with the utilization of iron-based coagulant was observed. However, the static magnetic field enhanced coagulation with the utilization of aluminum-based coagulant. The results suggest that increased sedimentation of colloids and activated sludge, can in practice mean a reduction in the size of the necessary equipment for sedimentation with an unchanged efficiency of the process. Moreover, static magnetic field significantly reduced the COD concentration in filtrate and shorted capillary suction time during the dewaterability of waste activated sludge. [ABSTRACT FROM AUTHOR]

This paper reports the results of measurements and calculations of heat production from geothermal waters in a Polish geothermal plant in Bańska in the years 2010–2013. Statistical analysis was used to create a regression model and an artificial neural network model. The models allow us to predict the volume of heat produced, depending on outside air temperature. In addition, the study indicates that geothermal energy is one of the most predictable sources of renewable energy, which is important from the point of view of reliability of exploitation. Production of energy from renewable sources, which include geothermal energy, fits the current trends in the energy policy of the Polish state. [ABSTRACT FROM AUTHOR]

The conversion of chemical energy contained in organic matter into electricity has become an object of interest for many scientists worldwide. This technology is used in microbial fuel cells (MFC). Apart from generating electrical energy, these cells can be used simultaneously for wastewater treatment. Although the technology is constantly being improved, currently functioning microbial fuel cells cannot provide appropriate output parameters to use on an industrial scale. One of the barriers is so-called extracellular electron transfer, which in turn depends on the electrode type used, its material, shape, and size. According to current literature, carbon, graphite, stainless steel, and ceramics are the most frequently used electrode materials. However, more and more often, scientists are turning to other, unusual materials, the production of which uses the newest technologies, and one of them is graphene. This material is modified in different ways and connected with other materials, and the results of this seem to be very promising. Scientists manage to get a higher level of extracellular electron transfer and, hence, higher output parameters of the whole system. This article describes chosen technologies and attempts made by scientists worldwide to use graphene in MFC and their results. [ABSTRACT FROM AUTHOR]

The characteristics of biomass as renewable energy or bioindustry feedstock are very important from their final utilization point of view. This study aimed to evaluate the effects of fertilization on biomass characteristics and chemical composition during three-year field and laboratory trials. Two perennial herbaceous crops (Silphium perfoliatum L. and Helianthus salicifolius A. Dietr.) cultivated using different types (organic and mineral) and doses (0, 85, 170 kg ha–1 N) of fertilizers were investigated. The analyzed factors significantly influenced most of the investigated features of collected biomass. The application of fertilizers increased the fixed carbon and volatile matter content, higher heating value, chlorine, hemicellulose and cellulose content. The moisture content of green S. perfoliatum biomass harvested in September (75.8%) was 14.78% higher than in the case of H. salicifolius. The highest higher heating value (18.69 MJ kg–1 DM) and the lowest ash content (mean 4.72% DM) was obtained from H. salicifolius for the biomass fertilized at a dose of 170 kg ha–1 N with mineral fertilizer. Under mineral fertilization, the highest carbon content (47.88% DM) was obtained from H. salicifolius. However, the total nitrogen content in the S. perfoliatum biomass was the highest (1.41% DM) in 2019 for biomass treated with mineral fertilization in the dose of 170 kg ha–1 N. The highest content of hemicellulose (15.36% DM) was noted in H. salicifolius biomass, while cellulose and lignin contents were higher in S. perfoliatum (24.47% and 8.29% DM, respectively). • The biomass of herbaceous crops was characterized in terms of bioenergy production. • The S. perfoliatum contained more moisture, ash, chlorine, cellulose and lignin. • The H. salicifolius contained more carbon, hydrogen, sulphur and hemicellulose. • The organic and mineral fertilisers decreased the moisture, ash and lignin content. • The fertilization increased the higher heating value, chlorine and cellulose content. [ABSTRACT FROM AUTHOR]

Perennial herbaceous crops (PHC) are increasingly often perceived as a competitive biomass source or as a co-substrate for biogas plants. The aim of the study was to determine the dry biomass yield, the biogas and methane production efficiency, potential energy yield and economic analysis for two PHC species, depending on the fertilisation type and nitrogen level in three successive cultivation years. The mean dry matter yield of Silphium perfoliatum was significantly higher (by 19.4%) compared to the mean yield of Helianthus salicifolius. The application of organic (digestate) and mineral fertilisers and a higher nitrogen level have significantly contributed to increasing dry matter yield compared to the plots without fertilisation. However, fertilisation have no significant impact on the biogas or methane efficiency. The highest biogas efficiency for S. perfoliatum and H. salicifolius biomass was 372.8 m3 Mg−1 DM and 280.9 m3 Mg−1 DM, respectively. The biogas, methane and energy potential yield of S. perfoliatum was significantly higher (over 50%) compared to the values of H. salicifolius. Meanwhile, the potential income from energy generation from S. perfoliatum was higher by 482%. Therefore, S. perfoliatum proved to be a more prospective PHC species as a biomass source for biogas plants. The Silphium perfoliatum yield was higher by 19.4% compared to Helianthus salicifolius The organic and mineral fertilisation increased the biomass yield by 62 and 129% Methane production efficiency from S. perfoliatum was higher by 28.9% Methane yield for S. perfoliatum was higher by 52% compared to H. salicifolius Total energy yield for S. perfoliatum was higher in each fertilisation option [ABSTRACT FROM AUTHOR]

The development of biogas upgrading technologies is now an essential issue in recovering fuel-grade methane. Nowadays, trends in biogas upgrading include investigations of low-cost and renewable materials as sorbents for biogas enrichment to produce biomethane. Therefore, in this work, wastewater anaerobic sludge stabilized with calcium oxide was used as the bio-waste sorbent to capture carbon dioxide from biogas, employing a fixed bed column. The biogas flow rate was the parameter considered for examining the breakthrough responses. It was observed that breakthrough time decreases with increasing biogas inflow rate from 570 ± 10 min at 5 mL/min to 120 ± 12 min at 35 mL/min. The maximum sorption capacity of 127.22 ± 1.5 mg CO2/g TS of sorbent was estimated at 15 mL/min. Biomethane concentration in biogas increased from 56.5 ± 1.7 v% in the raw biogas to 98.9 ± 0.2 v% with simultaneous low carbon dioxide content of 0.44 ± 0.2 v%. A strong positive correlation (R2 = 0.9919) between the sorption capacity and the biogas flow rate was found in the range of biogas inflow rates between 5 mL/min and 15 mL/min. Moreover, the correlation analysis showed a strong negative relationship (R2 = 0.9868) between breakthrough time and the mass of carbon dioxide removal, and the biogas flow rates ranged from 10 mL/min to 20 mL/min. [ABSTRACT FROM AUTHOR]

• MF module was hydraulically most efficient when treating liquid fraction of digestate. • Biomass yield was the highest when microalgae grew on MF at 0.4 MPa permeate. • High pH of UF permeate reduced microalgae growth by 50% • UF permeate for Chlorella vulgaris cultivation was the most efficient at 0.2 MPa. • Low nutrient content in two-stage filtration permeates inhibited microalgae growth. To make microalgae cultivation economically feasible, different waste streams that may serve as cultivation media are being searched for. The aim of this study was membrane filtration of the liquid fraction of digestate (LFD) to produce permeate that will be an effective medium for the cultivation of Chlorella vulgaris. Microfiltration (MF) and ultrafiltration (UF) with ceramic membranes were used in one- and two-stage systems at transmembrane pressures (TMP) of 0.2, 0.3, and 0.4 MPa. The hydraulic capacities of the membrane modules allowed MF at 0.2 MPa to be selected as the most feasible variant of the one-stage variants. The use of MF permeates for microalgae cultivation resulted in the highest biomass yield, due to optimum pH (about 8.8), low color, and high nutrient concentration (about 290 mg/dm3 of ammonium and about 22 mg/dm3 of orthophosphates). The high pH (about 9.7) of the UF permeates, which increased the concentration of free ammonia, reduced microalgae growth by 50% compared to the growth noted with the MF permeates. Due to the low nutrient concentration, the use of permeates from the two-stage systems resulted in microalgae growth more than two times lower than the use of MF permeates. Mathematical modeling indicated that the component of the cultivation medium that most significantly affected microalgae growth was the initial ammonium concentration. [ABSTRACT FROM AUTHOR]

This paper presents the results of a multifaceted analysis of the application of catalytic additives to hemp pellets' combustion in a low-power boiler. The research concerns the effects of five catalytic additives applied inside the boiler's combustion chamber—based on TiO2, MnO2, Cu(NO3)2 × 3H2O, H2PtCl6 solution, and 99.5% pure urea solution—on the quality of hemp pellets' combustion process. For this purpose, technical and elemental analyses of the used fuel were performed. The chemical composition of exhaust gases (NOx, CO, SO2, and PM content) was also examined using an exhaust gas analyzer and a dust meter. The highest reductions in emissions of individual pollutants were for CO (−113%; combustion with Ad3), NOx (−66%; combustion with Ad 4), SO2 (−48%; combustion with Ad3), and PM (−78%; combustion with Ad1). The study also determined the amount of avoided costs due to the use of catalytic additives, as well as the annual prevented CO2 emissions to the atmosphere. Due to rising fuel and energy prices, this study could be helpful for biomass boiler owners who would like to burn locally available raw materials and increase the combustion process' efficiency. [ABSTRACT FROM AUTHOR]