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Molecular chains of two-coordinate carbon atoms (cumulenes) have long been targeted, due to interest in the electronic structure and applications of extended π-systems, and their relationship to the carbon allotrope, carbyne. While formal (isoelectronic) B═N for C═C substitution has been employed in two-dimensional (2-D) materials, unsaturated one-dimensional all-inorganic "molecular wires" are unknown. Here, we report high-yielding synthetic approaches to heterocumulenes containing a five-atom BNBNB chain, the geometric structure of which can be modified by choice of end group. The diamido-capped system is bent at the 2-/4-positions, and natural resonance theory calculations reveal significant contributions from B═N(:)-B≡N-B resonance forms featuring a lone pair at N (consistent with observed N-centered nucleophilicity). Molecular modification to generate a linear system best described by a B═N═B═N═B resonance structure involves chemical transformation of the capping groups (using B(C 5 F 5 ) 3 ) to enhance their π-acidity and conjugate the N-lone pairs.

The synthesis of a series of isostructural organometallic complexes featuring Ae-Tr bonds (Ae = Be, Mg; Tr = Al, Ga, In) has been investigated, and their electronic structures probed by quantum chemical calculations. This systematic study allows for comparison, not only of the metal-metal bonding chemistries of the two lightest alkaline earth (Ae) elements, beryllium and magnesium, but also of the three triel (Tr) elements, aluminium, gallium, and indium. Computational analyses (NBO, QTAIM, EDA-NOCV) reveal that Be-Tr bonding is more covalent than Mg-Tr bonding. More strikingly, these calculations predict that the beryllium-indyl complex - featuring the first structurally characterised Be-In bond - should act as a source of nucleophilic beryllium. This has been confirmed experimentally by its reactivity towards methyl iodide, which yields the Be-Me functionality. By extension, the electrophilic character of the beryllium centre in the beryllium-gallyl complex contrasts with the umpoled, nucleophilic behaviour of the beryllium centre in both the -indyl and -aluminyl complexes., Competing Interests: The authors declare no competing interests., (This journal is © The Royal Society of Chemistry.)

Calcium fluoride is the ultimate source of all fluorochemicals. Current synthetic approaches rely on the use of HF, generated from naturally occurring fluorspar and sulfuric acid. Methods for constructing E-F bonds directly from CaF 2 have long been frustrated by its high lattice energy, low solubility and impaired fluoride ion nucleophilicity. Little fundamental understanding of the reactivity of Ca-F moieties is available to guide methodology development; well-defined molecular species containing Ca-F bonds are extremely rare, and existing examples are strongly aggregated and evidence no nucleophilic fluoride delivery. Here, by contrast, we show that by targeting anionic systems of the type [L n (X) 2 CaF] - , monomeric calcium fluoride complexes containing single Ca-F bonds can be synthesized, including via routes involving fluoride abstraction from existing C-F bonds. Comparative structural and spectroscopic studies of mono- and dinuclear systems allow us to define structure-activity relationships for E-F bond formation from molecular calcium fluorides., (© 2024. The Author(s).)

Xanthene-backbone FLPs featuring secondary borane functions -B(Ar X )H (where Ar X =C 6 F 5 (Ar F ) or C 6 Cl 5 (Ar Cl )) have been targeted through reactions of the dihydroboranes Me 2 S ⋅ BAr X H 2 with [4,5-xanth(PR 2 )Li] 2 (R=Ph, i Pr), and investigated in the synthesis of related cationic systems via hydride abstraction. The reactivity of these systems (both cationic and charge neutral) with ammonia have been probed, with a view to probing the potential for proton shuttling via N-H bond 'activation.' We find that in the case of four-coordinate boron systems (cationic or change neutral), the N-H linkage remains intact, supported by a NH⋅⋅⋅P hydrogen bond which is worth up to 17 kcal mol -1 thermodynamically, and enabled by planarization of the flexible xanthene scaffold. For cationic three coordinate systems, N-to-P proton transfer is viable, driven by the ability of the boron centre to stabilise the [NH 2 ] - conjugate base through N-to-B π bonding. This proton transfer can be shown to be reversible in the presence of excess ammonia, depending on the nature of the B-bound Ar X group. It is viable in the case of C 6 F 5 substituents, but is prevented by the more sterically encumbering and secondary donor-stabilising capabilities of the C 6 Cl 5 substituent., (© 2024 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)

By exploiting the electronic capabilities of the N-heterocyclic boryloxy (NHBO) ligand, we have synthesized "naked" acyclic gallyl [Ga{OB(NDippCH) 2 } 2 ] - and indyl [In{OB(NDippCH) 2 } 2 ] - anions (as their [K(2.2.2-crypt)] + salts) through K + abstraction from [KGa{OB(NDippCH) 2 } 2 ] and [KIn{OB(NDippCH) 2 } 2 ] using 2.2.2-crypt. These systems represent the first O-ligated gallyl/indyl systems, are ultimately accessed from cyclopentadienyl Ga I /In I precursors by substitution chemistry, and display nucleophilic reactivity which is strongly influenced by the presence (or otherwise) of the K + counterion., (© 2024 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)

Owing to its high toxicity, the chemistry of element number four, beryllium, is poorly understood. However, as the lightest elements provide the basis for fundamental models of chemical bonding, there is a need for greater insight into the properties of beryllium. In this context, the chemistry of the homo-elemental Be-Be bond is of fundamental interest. Here the ligand metathesis chemistry of diberyllocene (1; CpBeBeCp)-a stable complex with a Be-Be bond-has been investigated. These studies yield two complexes with Be-Be bonds: Cp*BeBeCp (2) and [K{(HCDippN) 2 BO} 2 ]BeBeCp (3; Dipp = 2,6-diisopropylphenyl). Quantum chemical calculations indicate that the Be-Be bond in 3 is polarized to such an extent that the complex could be formulated as a mixed-oxidation state Be 0 /Be II complex. Correspondingly, it is demonstrated that 3 can transfer the 'beryllyl' anion, [BeCp] - , to an organic substrate, by analogy with the reactivity of sp 2 -sp 3 diboranes. Indeed, this work reveals striking similarities between the homo-elemental bonding linkages of beryllium and boron, despite the respective metallic and non-metallic natures of these elements., (© 2024. The Author(s).)

Bimetallic compounds containing direct metal-group 13 element bonds have been shown to display unprecedented patterns of cooperative reactivity towards small molecules, which can be influenced by the identity of the group 13 element. In this context, we present here a systematic appraisal of group 13 metallo-ligands of the type [(NON)E] - (NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene) for E=Al, Ga and In, through a comparison of structural and spectroscopic parameters associated with the trans L or X ligands in linear d 10 complexes of the types LM{E(NON)} and XM'{E(NON)}. These studies are facilitated by convenient syntheses (from the In(I) precursor, InCp) of the potassium indyl species [{K(NON)In}⋅KCp] n (1) and [(18-crown-6) 2 K 2 Cp] [(NON)In] (1'), and lead to the first structural characterisation of Ag-In and Hg-E (E=Al, In) covalent bonds. The resulting structural, spectroscopic and quantum chemical probes of Ag/Hg complexes are consistent with markedly stronger σ-donor capabilities of the aluminyl ligand, [(NON)Al] - , over its gallium and indium counterparts., (© 2024 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)

While the nucleophilic addition of ammonia to ketones is an archetypal reaction in classical organic chemistry, the reactivity of heavier group 14 carbonyl analogues (R 2 E=O; E=Si, Ge, Sn, or Pb) with NH 3 remains sparsely investigated, primarily due to the synthetic difficulties in accessing heavier ketone congeners. Herein, we present a room-temperature stable boryl-substituted amidinato-silanone {(HCDippN) 2 B}{PhC(tBuN) 2 }Si=O (Dipp=2,6-iPr 2 C 6 H 3 ) (together with its germanone analogue), formed from the corresponding silylene under a N 2 O atmosphere. This system reacts cleanly with ammonia in 1,2-fashion to give an isolable sila-hemiaminal complex {(HCDippN) 2 B}{PhC(tBuN) 2 }Si(OH)(NH 2 ). Quantum chemical calculations reveal that the formation of this sila-hemiaminal is crucially dependent on the nature of the ancillary ligand scaffold. It is facilitated thermodynamically by the hemi-lability of the amidinate ligand (which allows for the formation of an energetically critical intramolecular N⋅⋅⋅HO hydrogen bond within the product) and is enabled mech-anistically by a process in which the silanone initially acts in umpolung fashion as a base (rather than an acid), due to the strongly electron-releasing and sterically bulky nature of the ancillary boryl ligand., (© 2024 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)

The large steric profile of the N-heterocyclic boryloxy ligand, -OB(NDippCH) 2 , and its ability to stabilize the metal-centered HOMO, are exploited in the synthesis of the first example of a "naked" acyclic aluminyl complex, [K(2.2.2-crypt)][Al{OB(NDippCH) 2 } 2 ]. This system, which is formed by substitution at Al I (rather than reduction of Al III ), represents the first O-ligated aluminyl compound and is shown to be capable of hitherto unprecedented reversible single-site [4 + 1] cycloaddition of benzene. This chemistry and the unusual regioselectivity of the related cycloaddition of anthracene are shown to be highly dependent on the availability (or otherwise) of the K + countercation.

A tetraboryl digermene synthesized by the reaction between a dianionic digermanide nucleophile and a boron halide electrophile is dimeric both in the solid state and in hydrocarbon solution. It features both a planar 'alkene-like' geometry for the Ge 2 B 4 core, and an exceptionally short GeGe double bond. These structural features are consistent with the known electronic properties of the boryl group, and with lowest energy ( in silico ) fragmentation into two triplet bis(boryl)germylene fragments.

The complex diberyllocene, CpBeBeCp (Cp, cyclopentadienyl anion), has been the subject of numerous chemical investigations over the past five decades yet has eluded experimental characterization. We report the preparation and isolation of the compound by the reduction of beryllocene (BeCp 2 ) with a dimeric magnesium(I) complex and determination of its structure in the solid state by means of x-ray crystallography. Diberyllocene acts as a reductant in reactions that form beryllium-aluminum and beryllium-zinc bonds. Quantum chemical calculations indicate parallels between the electronic structure of diberyllocene and the simple homodiatomic species diberyllium (Be 2 ).

The reduction of the boryl-substituted Sn II bromide {(HCDippN) 2 B}Sn(IPrMe)Br with 1.5 equivalents of potassium graphite leads to the generation of the cyclic tetratin tetraboryl system K 2 [Sn 4 {B(NDippCH) 2 } 4 ], a homo-metallic heavier analogue of the cyclobutadiene dianion. This system is non-aromatic as determined by Nucleus Independent Chemical Shift Calculations (NICS(0)=-0.28, NICS(1)=-3.17), with the primary contributing resonance structures shown by Natural Resonance Theory (NRT) to involve a Sn=Sn double bond and 1,2-localized negative charges. Abstraction of the K + cations or oxidation leads to contraction or cleavage of the Sn 4 unit, respectively, while protonation generates the neutral dihydride 1,2-Sn 4 {B(NDippCH) 2 } 4 H 2 (a heavier homologue of cyclobutene) in a manner consistent with the predicted charge distribution in the [Sn 4 {B(NDippCH) 2 } 4 ] 2- dianion., (© 2023 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.)

The reactions of anionic aluminium or gallium nucleophiles {K[E(NON)]} 2 (E = Al, 1 ; Ga, 2 ; NON = 4,5-bis(2,6-diisopropylanilido)-2,7-di tert -butyl-9,9-dimethylxanthene) with beryllocene (BeCp 2 ) led to the displacement of one cyclopentadienyl ligand at beryllium and the formation of compounds containing Be-Al or Be-Ga bonds (NON)EBeCp (E = Al, 3 ; Ga, 4 ). The Be-Al bond in the beryllium-aluminyl complex [2.310(4) Å] is much shorter than that found in the small number of previous examples [2.368(2) to 2.432(6) Å], and quantum chemical calculations suggest the existence of a non-nuclear attractor (NNA) for the Be-Al interaction. This represents the first example of a NNA for a heteroatomic interaction in an isolated molecular complex. As a result of this unusual electronic structure and the similarity in the Pauling electronegativities of beryllium and aluminium, the charge at the beryllium center (+1.39) in 3 is calculated to be less positive than that of the aluminium center (+1.88). This calculated charge distribution suggests the possibility for nucleophilic behavior at beryllium and correlates with the observed reactivity of the beryllium-aluminyl complex with N,N' -diisopropylcarbodiimide─the electrophilic carbon center of the carbodiimide undergoes nucleophilic attack by beryllium, thereby yielding a beryllium-diaminocarbene complex.

Boryltin compounds featuring the metal in the+1 or 0 oxidation states can be synthesized from the carbene-stabilized tin(II) bromide (boryl)Sn(NHC)Br (boryl={B(NDippCH) 2 }; NHC=C{(N i PrCMe) 2 }) by the use of strong reducing agents. The formation of the mono-carbene stabilized distannyne and donor-free distannide systems (boryl)SnSn(IPrMe)(boryl) (2) and K 2 [Sn 2 (boryl) 2 ] (3), using Mg(I) and K reducing agents mirrors related germanium chemistry. In contrast to their lighter congeners, however, systems of the type [Sn(boryl)] n are unstable with respect to disproportionation. Carbene abstraction from 2 using BPh 3 , and two-electron oxidation of 3 both result in the formation of a 2 : 1 mixture of the Sn(II) compound Sn(boryl) 2 , and the hexatin cluster, Sn 6 (boryl) 4 (4). A viable mechanism for this rearrangement is shown by quantum chemical studies to involve a vinylidene intermediate (analogous to the isolable germanium compound, (boryl) 2 Ge=Ge), which undergoes facile atom transfer to generate Sn(boryl) 2 and trinuclear [Sn 3 (boryl) 2 ]. The latter then dimerizes to give the observed hexametallic product 4, with independent studies showing that similar trigermanium species aggregate in analogous fashion., (© 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.)

We report on the insertion of alkynes into heterometallic M-M' bonds, producing (aluminylalkenyl)copper compounds which possess differential reactivity at the two derived M-C functions. Uniquely, this system is capable of controlling access to isolable syn or anti dimetallated alkenes, by employing either kinetic or thermodynamic control. Subsequent derivatization with CO is both stereoselective (to syn systems) and regioselective (to Cu-C bonds), leading to the formation of the first structurally characterized examples of copper acyl compounds - aided by the cooperative reactivity of the proximal aluminium centre.

Homologation of carbon monoxide is central to the heterogeneous Fischer-Tropsch process for the production of hydrocarbon fuels. C-C bond formation has been modeled by homogeneous systems, with [C n O n ] 2- fragments ( n = 2-6) formed by two-electron reduction being commonly encountered. Here, we show that four- or six-electron reduction of CO can be accomplished by the use of anionic aluminum(I) ("aluminyl") compounds to give both topologically linear and branched C 4 /C 6 chains. We show that the mechanism for homologation relies on the highly electron-rich nature of the aluminyl reagent and on an unusual mode of interaction of the CO molecule, which behaves primarily as a Z-type ligand in initial adduct formation. The formation of [C 6 O 6 ] 4- from [C 4 O 4 ] 4- shows for the first time a solution-phase CO homologation process that brings about chain branching via complete C-O bond cleavage, while a comparison of the linear [C 4 O 4 ] 4- system with the [C 4 O 4 ] 6- congener formed under more reducing conditions models the net conversion of C-O bonds to C-C bonds in the presence of additional reductants.

We report on the synthesis of a distannyne supported by a pincer ligand bearing pendant amine donors that is capable of reversibly activating E-H bonds at one or both of the tin centres through dissociation of the hemi-labile N-Sn donor/acceptor interactions. This chemistry can be exploited to sequentially (and reversibly) assemble mixed-valence chains of tin atoms of the type ArSn{Sn(Ar)H} n SnAr (n=1, 2). The experimentally observed (decreasing) propensity towards chain growth with increasing chain length can be rationalized both thermodynamically and kinetically by the electron- withdrawing properties of the -Sn(Ar)H- backbone units generated via oxidative addition., (© 2021 Wiley-VCH GmbH.)