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We analyzed spectral cubes of Callisto's leading and trailing hemispheres, collected with the NIRSpec Integrated Field Unit (G395H) on the James Webb Space Telescope. These spatially resolved data show strong 4.25-micron absorption bands resulting from solid-state 12CO2, with the strongest spectral features at low latitudes near the center of its trailing hemisphere, consistent with radiolytic production spurred by magnetospheric plasma interacting with native H2O mixed with carbonaceous compounds. We detected CO2 rovibrational emission lines between 4.2 and 4.3 microns over both hemispheres, confirming the global presence of CO2 gas in Callisto's tenuous atmosphere. These results represent the first detection of CO2 gas over Callisto's trailing side. The distribution of CO2 gas is offset from the subsolar region on either hemisphere, suggesting that sputtering, radiolysis, and geologic processes help sustain Callisto's atmosphere. We detected a 4.38-micron absorption band that likely results from solid-state 13CO2. A prominent 4.57-micron absorption band that might result from CN-bearing organics is present and significantly stronger on Callisto's leading hemisphere, unlike 12CO2, suggesting these two spectral features are spatially anti-associated. The distribution of the 4.57-micron band is more consistent with a native origin and/or accumulation of dust from Jupiter's irregular satellites. Other, more subtle absorption features could result from CH-bearing organics, CO, carbonyl sulfide (OCS), and Na-bearing minerals. These results highlight the need for preparatory laboratory work and improved surface-atmosphere interaction models to better understand carbon chemistry on the icy Galilean moons before the arrival of NASA's Europa Clipper and ESA's JUICE spacecraft., Comment: Accepted in AAS Planetary Science Journal, January 2024

The New Horizons spacecraft returned images and compositional data showing that terrains on Pluto span a variety of ages, ranging from relatively ancient, heavily cratered areas to very young surfaces with few-to-no impact craters. One of the regions with very few impact craters is dominated by enormous rises with hummocky flanks. Similar features do not exist anywhere else in the imaged solar system. Here we analyze the geomorphology and composition of the features and conclude this region was resurfaced by cryovolcanic processes, of a type and scale so far unique to Pluto. Creation of this terrain requires multiple eruption sites and a large volume of material (>104 km^3) to form what we propose are multiple, several-km-high domes, some of which merge to form more complex planforms. The existence of these massive features suggests Pluto's interior structure and evolution allows for either enhanced retention of heat or more heat overall than was anticipated before New Horizons, which permitted mobilization of water-ice-rich materials late in Pluto's history., Comment: 22 pages, including both main paper and supplement as one pdf

CO2 ice is present on the trailing hemisphere of Ariel but is mostly absent from its leading hemisphere. The leading/trailing hemispherical asymmetry in the distribution of CO2 ice is consistent with radiolytic production of CO2, formed by charged particle bombardment of H2O ice and carbonaceous material in Ariel's regolith. This longitudinal distribution of CO2 on Ariel was previously characterized using 13 near-infrared reflectance spectra collected at 'low' sub-observer latitudes between 30S to 30N. Here, we investigated the distribution of CO2 ice on Ariel using 18 new spectra: two collected over low sub-observer latitudes, five collected at 'mid' sub-observer latitudes (31 - 44N), and eleven collected over 'high' sub-observer latitudes (45 - 51N). Analysis of these data indicates that CO2 ice is primarily concentrated on Ariel's trailing hemisphere. However, CO2 ice band strengths are diminished in the spectra collected over mid and high sub-observer latitudes. This sub-observer latitudinal trend may result from radiolytic production of CO2 molecules at high latitudes and subsequent migration of this constituent to low latitude cold traps. We detected a subtle feature near 2.13 microns in two spectra collected over high sub-observer latitudes, which might result from a 'forbidden' transition mode of CO2 ice that is substantially stronger in well mixed substrates composed of CO2 and H2O ice, consistent with regolith-mixed CO2 ice grains formed by radiolysis. Additionally, we detected a 2.35-micron feature in some low sub-observer latitude spectra, which might result from CO formed as part of a CO2 radiolytic production cycle., Comment: Accepted in Planetary Science Journal

Sputnik Planitia, Pluto's gigantic ice glacier, hosts numerous scientific mysteries, including the presence of thousands of elongated pit structures. We examine various attributes of these pit structures in New Horizons data sets, revealing their length, aspect ratios, and orientation properties; we also study their interior reflectivities, colors, and compositions, and compare these attributes to some other relevant regions on Pluto. We then comment on origin mechanisms of the pits and also the fate of the missing volatiles represented by the pits on Sputnik Planitia., Comment: 36 pages, 14 figures

In its 16 years of scientific measurements, the Spitzer Space Telescope performed a number of ground-breaking infrared measurements of Solar System objects. In this second of two papers, we describe results from Spitzer observations of asteroids, dust rings, and planets that provide new insight into the formation and evolution of our Solar System. The key Spitzer results presented here can be grouped into three broad classes: characterizing the physical properties of asteroids, notably including a large survey of Near Earth Objects; detection and characterization of several dust/debris disks in the Solar System; and comprehensive characterization of ice giant (Uranus, Neptune) atmospheres. Many of these observations provide critical foundations for future infrared space-based observations., Comment: Published in Nature Astronomy, Volume 4, page 940. This arXiv version pre-dates the proofs corrections; the final published version is available at https://rdcu.be/b8fgs [Updated on October 28 to get the right figures in this version]

In its 16 years of scientific measurements, the Spitzer Space Telescope performed a number of ground breaking and key infrared measurements of Solar System objects near and far. Targets ranged from the smallest planetesimals to the giant planets, and have helped us reform our understanding of these objects while also laying the groundwork for future infrared space-based observations like those to be undertaken by the James Webb Space Telescope in the 2020s. In this first Paper, we describe how the Spitzer Space Telescope advanced our knowledge of Solar System formation and evolution via observations of small outer Solar System planetesimals, i.e., Comets, Centaurs, and Kuiper Belt Objects (KBOs). Relics from the early formation era of our Solar System, these objects hold important information about the processes that created them. The key Spitzer observations can be grouped into 3 broad classes: characterization of new Solar System objects (comets D/ISON 2012 S1, C/2016 R2, 1I/`Oumuamua); large population surveys of known object sizes (comets, Centaurs, and KBOs); and compositional studies via spectral measurements of body surfaces and emitted materials (comets, Centaurs, and KBOs)., Comment: Published in Nature Astronomy, Volume 4, page 930. This arXiv version pre-dates the proofs corrections; the final published version is availabe at https://rdcu.be/b8fgx

We investigated whether sulfur-bearing species are present on the icy Galilean moon Callisto by analyzing eight near-infrared reflectance spectra collected over a wide range of sub-observer longitudes. We measured the band areas and depths of a 4-micron feature in these spectra, which has been attributed to sulfur dioxide (SO2), as well as carbonates, in previously collected datasets of this moon. All eight spectra we collected display the 4-micron band. The four spectra collected over Callisto's leading hemisphere display significantly stronger 4-micron bands compared to the four trailing hemisphere spectra (> 3-sigma difference). We compared the central wavelength position and shape of Callisto's 4-micron band to laboratory spectra of various sulfur-bearing species and carbonates. Our comparison demonstrates that Callisto's 4-micron band has a spectral signature similar to thermally-altered sulfur, as well as a 4.025 micron feature attributed to disulfanide (HS2). Our analysis therefore supports the presence of S-bearing species on Callisto but is not consistent with the presence of SO2. The significantly stronger 4-micron band detected on Callisto's leading hemisphere could result from collisions with H2S-rich dust grains that originate on Jupiter's retrograde irregular satellites or implantation of magnetospheric S ions that originate from volcanic activity on Io. Alternatively, S-bearing species could be native to Callisto and are exposed by dust collisions and larger impacts that drive regolith overturn, primarily on its leading side.

We investigated whether ammonia-rich constituents are present on the surface of the Uranian moon Ariel by analyzing 32 near-infrared reflectance spectra collected over a wide range of sub-observer longitudes and latitudes. We measured the band areas and depths of a 2.2-{\micron} feature in these spectra, which has been attributed to ammonia-bearing species on other icy bodies. Ten spectra display prominent 2.2-{\micron} features with band areas and depths > 2{\sigma}. We determined the longitudinal distribution of the 2.2-{\micron} band, finding no statistically meaningful differences between Ariel's leading and trailing hemispheres, indicating that this band is distributed across Ariel's surface. We compared the band centers and shapes of the five Ariel spectra displaying the strongest 2.2-{\micron} bands to laboratory spectra of various ammonia-bearing and ammonium-bearing species, finding that the spectral signatures of the Ariel spectra are best matched by ammonia-hydrates and flash frozen ammonia-water solutions. Our analysis also revealed that four Ariel spectra display 2.24-{\micron} bands (> 2{\sigma} band areas and depths), with band centers and shapes that are best matched by ammonia ice. Because ammonia should be efficiently removed over short timescales by ultraviolet photons, cosmic rays, and charged particles trapped in Uranus' magnetosphere, the possible presence of this constituent supports geologic activity in the recent past, such as emplacement of ammonia-rich cryolavas and exposure of ammonia-rich deposits by tectonism, impact events, and mass wasting.

We investigate whether the surfaces of the classical moons of Uranus are compositionally stratified, with a thin veneer of mostly tiny H2O ice grains (<= 2 micron diameters) mantling a lower layer composed of larger grains of H2O ice, dark material, and CO2 ice (~10 - 50 micron diameters). Near-infrared observations (~1 - 2.5 microns) have determined that the H2O ice-rich surfaces of these moons are overprinted by concentrated deposits of CO2 ice, found almost exclusively on their trailing hemispheres. However, best fit spectral models of longer wavelength datasets (~3 - 5 microns) indicate that the spectral signature of CO2 ice is largely absent, and instead, the exposed surfaces of these moons are composed primarily of tiny H2O ice grains. To investigate possible compositional layering of these moons, we have collected new data using the Infrared Array Camera (IRAC) onboard the Spitzer Space Telescope (~3 - 5 microns). Spectral modeling of these new data is consistent with prior analyses, suggesting that the exposed surfaces of the Uranian moons are primarily composed of tiny H2O ice grains. Furthermore, analysis of these new data reveal that the trailing hemispheres of these moons are brighter than their leading hemispheres over the 3 to 5 micron wavelength range, except for Miranda, which displays no hemispherical asymmetries in its IRAC albedos. Our analyses also revealed that the surface of Ariel displays five distinct, regional-scale albedo zones, possibly consistent with the spatial distribution of CO2 ice on this moon. We discuss possible processes that could be enhancing the observed leading/trailing albedo asymmetries exhibited by these moons, as well as processes that could be driving the apparent compositional stratification of their near surfaces., Comment: To be published in Icarus [2019, accepted]. 10 tables and 7 figures

The New Horizons encounter with the cold classical Kuiper Belt object (KBO) 2014 MU69 (informally named 'Ultima Thule,' hereafter Ultima) on 1 January 2019 will be the first time a spacecraft has ever closely observed one of the free-orbiting small denizens of the Kuiper Belt. Related to but not thought to have formed in the same region of the Solar System as the comets that been explored so far, it will also be the largest, most distant, and most primitive body yet visited by spacecraft. In this letter we begin with a brief overview of cold classical KBOs, of which Ultima is a prime example. We give a short preview of our encounter plans. We note what is currently known about Ultima from earth-based observations. We then review our expectations and capabilities to evaluate Ultima's composition, surface geology, structure, near space environment, small moons, rings, and the search for activity.

Future remote sensing of exoplanets will be enhanced by a thorough investigation of our solar system Ice Giants (Neptune-size planets). What can the configuration of the magnetic field tell us (remotely) about the interior, and what implications does that field have for the structure of the magnetosphere; energy input into the atmosphere, and surface geophysics (for example surface weathering of satellites that might harbour sub-surface oceans). How can monitoring of auroral emission help inform future remote observations of emission from exoplanets? Our Solar System provides the only laboratory in which we can perform in-situ experiments to understand exoplanet formation, dynamos, systems and magnetospheres., Comment: Exoplanet Science Strategy White Paper, submitted to the National Academies of Sciences, Engineering and Medicine, Space Studies Board, 9 March 2018

NASA's New Horizons spacecraft has revealed the complex geology of Pluto and Charon. Pluto's encounter hemisphere shows ongoing surface geological activity centered on a vast basin containing a thick layer of volatile ices that appears to be involved in convection and advection, with a crater retention age no greater than $\approx$10 Ma. Surrounding terrains show active glacial flow, apparent transport and rotation of large buoyant water-ice crustal blocks, and pitting, likely by sublimation erosion and/or collapse. More enigmatic features include tall mounds with central depressions that are conceivably cryovolcanic, and ridges with complex bladed textures. Pluto also has ancient cratered terrains up to ~4 Ga old that are extensionally fractured and extensively mantled and perhaps eroded by glacial or other processes. Charon does not appear to be currently active, but experienced major extensional tectonism and resurfacing (probably cryovolcanic) nearly 4 billion years ago. Impact crater populations on Pluto and Charon are not consistent with the steepest proposed impactor size-frequency distributions proposed for the Kuiper belt.

The spectral position of the 3.6 micron continuum peak measured on Cassini-VIMS I/F spectra is used as a marker to infer the temperature of the regolith particles covering the surfaces of Saturn's icy satellites. This feature is characterizing the crystalline water ice spectrum which is the dominant compositional endmember of the satellites' surfaces. Laboratory measurements indicate that the position of the 3.6 micron peak of pure water ice is temperature-dependent, shifting towards shorter wavelengths when the sample is cooled, from about 3.65 micron at T=123 K to about 3.55 micron at T=88 K. A similar method was already applied to VIMS Saturn's rings mosaics to retrieve ring particles temperature (Filacchione et al., 2014). We report here about the daytime temperature variations observed on the icy satellites as derived from three different VIMS observation types. Temperature maps are built by mining the complete VIMS dataset collected in years 2004-2009 (pre-equinox) and in 2009-2012 (post equinox) by selecting pixels with max 150 km/pixel resolution. VIMS-derived temperature maps allow to identify thermal anomalies across the equatorial lens of Mimas and Tethys., Comment: 42 pages, 15 figures. Accepted for publication in Icarus journal on February 8th 2016