Search

Recent mid-infrared observations with JWST/MIRI have resulted in the first direct detections of absorption features from silicate clouds in the transmission spectra of two transiting exoplanets, WASP-17 b and WASP-107 b. In this paper, we measure the mid-infrared ($5-12$ $\mu$m) dayside emission spectrum of the benchmark hot Jupiter HD 189733 b with MIRI LRS by combining data from two secondary eclipse observations. We confirm the previous detection of H$_2$O absorption at 6.5 $\mu$m from Spitzer/IRS and additionally detect H$_2$S as well as an absorption feature at 8.7 $\mu$m in both secondary eclipse observations. The excess absorption at 8.7 $\mu$m can be explained by the presence of small ($\sim$0.01 $\mu$m) grains of SiO$_2$[s] in the uppermost layers of HD 189733 b's dayside atmosphere. This is the first direct detection of silicate clouds in HD 189733 b's atmosphere, and the first detection of a distinct absorption feature from silicate clouds on the day side of any hot Jupiter. We find that models including SiO$_2$[s] are preferred by $6-7\sigma$ over clear models and those with other potential cloud species. The high altitude location of these silicate particles is best explained by formation in the hottest regions of HD 189733 b's dayside atmosphere near the substellar point. We additionally find that HD 189733 b's emission spectrum longward of 9 $\mu$m displays residual features not well captured by our current atmospheric models. When combined with other JWST observations of HD 189733 b's transmission and emission spectrum at shorter wavelengths, these observations will provide us with the most detailed picture to date of the atmospheric composition and cloud properties of this benchmark hot Jupiter., Comment: 21 pages, 7 Figures, 3 Tables, Accepted to ApJL

K2-2 b/HIP 116454 b, the first exoplanet discovery by K2 during its Two-Wheeled Concept Engineering Test, is a sub-Neptune (2.5 $\pm$ 0.1 $R_\oplus$, 9.7 $\pm$ 1.2 $M_\oplus$) orbiting a relatively bright (KS = 8.03) K-dwarf on a 9.1 day period. Unfortunately, due to a spurious follow-up transit detection and ephemeris degradation, the transit ephemeris for this planet was lost. In this work, we recover and refine the transit ephemeris for K2-2 b, showing a $\sim40{\sigma}$ discrepancy from the discovery results. To accurately measure the transit ephemeris and update the parameters of the system, we jointly fit space-based photometric observations from NASA's K2, TESS, and Spitzer missions with new photometric observations from the ground, as well as radial velocities from HARPS-N that are corrected for stellar activity using a new modeling technique. Ephemerides becoming lost or significantly degraded, as is the case for most transiting planets, highlights the importance of systematically updating transit ephemerides with upcoming large efforts expected to characterize hundreds of exoplanet atmospheres. K2-2 b sits at the high-mass peak of the known radius valley for sub-Neptunes, and is now well-suited for transmission spectroscopy with current and future facilities. Our updated transit ephemeris will ensure no more than a 13-minute uncertainty through 2030., Comment: Accepted for publication in AJ. 15 pages, 6 figures, 8 tables

The elemental and isotopic abundances of volatiles like carbon, oxygen, and nitrogen may trace a planet's formation location relative to H$_2$O, CO$_2$, CO, NH$_3$, and N$_2$ "snowlines", or the distance from the star at which these volatile elements sublimate. By comparing the C/O and $^{12}$C/$^{13}$C ratios measured in giant exoplanet atmospheres to complementary measurements of their host stars, we can determine whether the planet inherited stellar abundances from formation inside the volatile snowlines, or non-stellar C/O and $^{13}$C enrichment characteristic of formation beyond the snowlines. To date, there are still only a handful of exoplanet systems where we can make a direct comparison of elemental and isotopic CNO abundances between an exoplanet and its host star. Here, we present a $^{12}$C/$^{13}$C abundance analysis for host star WASP-77A (whose hot Jupiter's $^{12}$C/$^{13}$C abundance was recently measured). We use MARCS stellar atmosphere models and the radiative transfer code TurboSpectrum to generate synthetic stellar spectra for isotopic abundance calculations. We find a $^{12}$C/$^{13}$C ratio of $51\pm 6$ for WASP-77A, which is sub-solar ($\sim 91$) but may still indicate $^{13}$C-enrichment in its companion planet WASP-77A b ($^{12}$C/$^{13}$C = 26 $\pm$ 16, previously reported). Together with the inventory of carbon and oxygen abundances in both the host and companion planet, these chemical constraints point to WASP-77A b's formation beyond the H$_2$O and CO$_2$ snowlines and provide chemical evidence for the planet's migration to its current location $\sim$0.024 AU from its host star., Comment: 21 pages, 4 figures, 3 tables Accepted for publication in ApJ (8/14/2024)

Brown dwarfs and planetary-mass companions display rotationally modulated photometric variability, especially those near the L/T transition. This variability is commonly attributed to top-of-atmosphere (TOA) inhomogeneities, with proposed models including patchy thick and thin clouds, planetary-scale jets, or chemical disequilibrium. Surface mapping techniques are powerful tools to probe their atmospheric structures and distinguish between models. One of the most successful methods for stellar surface mapping is Doppler imaging, where the existence of TOA inhomogeneities can be inferred from their varying Doppler shifts across the face of a rotating star. We applied Doppler imaging to the nearest brown dwarf binary WISE 1049AB (aka Luhman 16AB) using time-resolved, high-resolution spectroscopic observations from Gemini IGRINS, and obtained for the first time H and K band simultaneous global weather map for brown dwarfs. Compared to the only previous Doppler map for a brown dwarf in 2014 featuring a predominant mid-latitude cold spot on WISE 1049B and no feature on WISE 1049A, our observations detected persistent spot-like structures on WISE 1049B in the equatorial to mid-latitude regions on two nights, and revealed new polar spots on WISE 1049A. Our results suggest stability of atmospheric features over timescale of days and possible long-term stable or recurring structures. H and K band maps displayed similar structures in and out of CO bands, indicating the cold spots not solely due to chemical hotspots but must involve clouds. Upcoming 30-m extremely large telescopes (ELTs) will enable more sensitive Doppler imaging of dozens of brown dwarfs and even a small number of directly-imaged exoplanets., Comment: 32 pages, 14 figures, accepted for publication in MNRAS

TOI-6255~b (GJ 4256) is an Earth-sized planet (1.079$\pm0.065$ $R_\oplus$) with an orbital period of only 5.7 hours. With the newly commissioned Keck Planet Finder (KPF) and CARMENES spectrographs, we determined the planet's mass to be 1.44$\pm$0.14 $M_{\oplus}$. The planet is just outside the Roche limit, with $P_{\rm orb}/P_{\rm Roche}$ = 1.13 $\pm0.10$. The strong tidal force likely deforms the planet into a triaxial ellipsoid with a long axis that is $\sim$10\% longer than the short axis. Assuming a reduced stellar tidal quality factor $Q_\star^\prime \approx10^7$, we predict that tidal orbital decay will cause TOI-6255 to reach the Roche limit in roughly 400 Myr. Such tidal disruptions may produce the possible signatures of planet engulfment that have been on stars with anomalously high refractory elemental abundances compared to its conatal binary companion. TOI-6255 b is also a favorable target for searching for star-planet magnetic interactions, which might cause interior melting and hasten orbital decay. TOI-6255 b is a top target (Emission Spectroscopy Metric of about 24) for phase curve observations with the James Webb Space Telescope., Comment: 18 pages, 7 figures, 5 tables, accepted to AAS Journals. The first RV mass measurement from the Keck Planet Finder

Transmission spectroscopy has been a workhorse technique over the past two decades to constrain the physical and chemical properties of exoplanet atmospheres. One of its classical key assumptions is that the portion of the atmosphere it probes -- the terminator region -- is homogeneous. Several works in the past decade, however, have put this into question for highly irradiated, hot ($T_{eq}\gtrsim 1000$ K) gas giant exoplanets both empirically and via 3-dimensional modelling. While models predict clear differences between the evening (day-to-night) and morning (night-to-day) terminators, direct morning/evening transmission spectra in a wide wavelength range has not been reported for an exoplanet to date. Under the assumption of precise and accurate orbital parameters on WASP-39 b, here we report the detection of inhomogeneous terminators on the exoplanet WASP-39 b, which allows us to retrieve its morning and evening transmission spectra in the near-infrared ($2-5\ \mu$m) using JWST. We observe larger transit depths in the evening which are, on average, $405 \pm 88$ ppm larger than the morning ones, also having qualitatively larger features than the morning spectrum. The spectra are best explained by models in which the evening terminator is hotter than the morning terminator by $177^{+65}_{-57}$ K with both terminators having C/O ratios consistent with solar. General circulation models (GCMs) predict temperature differences broadly consistent with the above value and point towards a cloudy morning terminator and a clearer evening terminator., Comment: Published in Nature at https://www.nature.com/articles/s41586-024-07768-4. All code to produce plots (with data) can be found at https://github.com/nespinoza/wasp39-terminators

We report results from 8 hours of JWST/MIRI LRS spectroscopic monitoring directly followed by 7 hours of JWST/NIRSpec prism spectroscopic monitoring of the benchmark binary brown dwarf WISE 1049AB, the closest, brightest brown dwarfs known. We find water, methane, and CO absorption features in both components, including the 3.3 $\mu$m methane absorption feature and a tentative detection of small grain ($<$ 1$\mu$m) silicate absorption at $>$8.5 $\mu$m in WISE 1049A. Both components vary significantly ($>$1$\%$), with WISE 1049B displaying larger variations than WISE 1049A. Using K-means clustering, we find three main transition points in wavelength for both components of the binary: 1) change in behavior at $\sim$2.3 $\mu$m coincident with a CO absorption bandhead, 2) change in behavior at 4.2 $\mu$m, close to the CO fundamental band at $\lambda >$ 4.4 $\mu$m, and 3) change in behavior at 8.3-8.5 $\mu$m, potentially corresponding to silicate absorption. We interpret the lightcurves observed with both NIRSpec and MIRI as likely stemming from 1) a deep pressure level driving the double-peaked variability seen in WISE 1049B at wavelengths $<$2.3 $\mu$m and $>$8.5 $\mu$m, 2) an intermediate pressure level shaping the lightcurve morphology between 2.3 and 4.2 $\mu$m, and 3) a higher-altitude pressure level producing single-peaked and plateaued lightcurve behavior between 4.2 and 8.5 $\mu$m., Comment: 28 pages, 27 figures, accepted to MNRAS

We present an in-depth, high-resolution spectroscopic analysis of the M dwarf K2-18 that hosts a sub-Neptune exoplanet in its habitable zone. We show our technique to accurately normalize the observed spectrum, which is crucial for a proper spectral fitting. We also introduce a new automatic, line-by-line model-fitting code, AutoSpecFit, that performs an iterative ${\chi}^{2}$ minimization process to measure individual elemental abundances of cool dwarfs. We apply this code to the star K2-18, and measure the abundance of 10 elements - C, O, Na, Mg, Al, K, Ca, Sc, Ti, and Fe. We find these abundances moderately supersolar, except for Fe with a slightly subsolar abundance. The accuracy of the inferred abundances is limited by the systematic errors due to uncertain stellar parameters. We also derive the abundance ratios associated with several planet-building elements such as Al/Mg, Ca/Mg, Fe/Mg, and (a solar-like) C/O=0.568 $\pm$ 0.026, which can be used to constrain the chemical composition and the formation location of the exoplanet. On the other hand, the planet K2-18 b has attracted considerable interest, given the JWST measurements of its atmospheric composition. Early JWST studies reveal an unusual chemistry for the atmosphere of this planet, which is unlikely to be driven by formation in a disk of unusual composition. The comparison between the chemical abundances of K2-18 b from future JWST analyses and those of the host star can provide fundamental insights into the formation of this planetary system., Comment: 29 pages, 14 figures, Accepted to the Astrophysical Journal (ApJ)

The recent inference of sulphur dioxide (SO$_2$) in the atmosphere of the hot ($\sim$1100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations suggests that photochemistry is a key process in high temperature exoplanet atmospheres. This is due to the low ($<$1 ppb) abundance of SO$_2$ under thermochemical equilibrium, compared to that produced from the photochemistry of H$_2$O and H$_2$S (1-10 ppm). However, the SO$_2$ inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 $\mu$m, and therefore the detection of other SO$_2$ absorption bands at different wavelengths is needed to better constrain the SO$_2$ abundance. Here we report the detection of SO$_2$ spectral features at 7.7 and 8.5 $\mu$m in the 5-12 $\mu$m transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS). Our observations suggest an abundance of SO$_2$ of 0.5-25 ppm (1$\sigma$ range), consistent with previous findings. In addition to SO$_2$, we find broad water vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 $\mu$m. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy element content (metallicity) for WASP-39b of $\sim$7.1-8.0 $\times$ solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range., Comment: Published in Nature

We present optical spectroscopy of 710 solar neighborhood stars collected over twenty years to catalog chromospheric activity and search for stellar activity cycles. The California Legacy Survey stars are amenable to exoplanet detection using precise radial velocities, and we present their Ca II H and K time series as a proxy for stellar and chromospheric activity. Using the HIRES spectrometer at Keck Observatory, we measured stellar flux in the cores of the Ca II H and K lines to determine S-values on the Mt. Wilson scale and the log(R'HK) metric, which is comparable across a wide range of spectral types. From the 710 stars, with 52,372 observations, 285 stars are sufficiently sampled to search for stellar activity cycles with periods of 2-25 years, and 138 stars show stellar cycles of varying length and amplitude. S-values can be used to mitigate stellar activity in the detection and characterization of exoplanets. We use them to probe stellar dynamos and to place the Sun's magnetic activity into context among solar neighborhood stars. Using precise stellar parameters and time-averaged activity measurements, we find tightly constrained cycle periods as a function of stellar temperature between log(R'HK) of -4.7 and -4.9, a range of activity in which nearly every star has a periodic cycle. These observations present the largest sample of spectroscopically determined stellar activity cycles to date., Comment: 40 pages, 26 figures, submitted to ApJS

Exoplanets hosting M dwarfs are the best targets to characterize Earth-like or super-Earth planetary atmospheres with the James Webb Space Telescope (JWST). We determine detailed stellar parameters ($T_{\rm eff}$, log$g$, and $\xi$) and individual abundances of twelve elements for four cool M dwarfs hosting exoplanets TOI-1685, GJ 436, GJ 3470, and TOI-2445, scheduled for future observations by the JWST. The analysis utilizes high-resolution near-infrared spectra from the SDSS-IV APOGEE survey between 1.51-1.69$\mu$. Based on 1D-LTE plane-parallel models, we find that TOI-2445 is slightly metal-poor ([Fe/H] = -0.16$\pm$0.09), while TOI-1685, GJ 436 and GJ 3470 are more metal-rich ([Fe/H] = 0.06$\pm$0.18, 0.10$\pm$0.20 dex, 0.25$\pm$0.15). The derived C/O ratios for TOI-2445, TOI-1685, GJ 436, and GJ 3470 are 0.526$\pm$0.027, 0.558$\pm$0.097, 0.561$\pm$0.029, and 0.638$\pm$0.015, respectively. From results for 28 M dwarfs analyzed homogeneously from APOGEE spectra, we find exoplanet-hosting M dwarfs exhibit a C/O abundance ratio approximately 0.01 to 0.05 higher than those with non-detected exoplanets, at limits of a statistically significant offset. A linear regression of [Fe/H] \textit{vs.} C/O distribution reveals a noticeable difference in the angular coefficient between FGK dwarfs (0.27) and M dwarfs (0.13). Assuming our abundance ratios of Ca/Mg, Si/Mg, Al/Mg, and Fe/Mg, we determine a mass of 3.276$^{+0.448}_{-0.419}$$M_{\oplus}$ for TOI-2445 b, having density (6.793$^{+0.005}_{-0.099}$ g.cm$^{-3}$) and core mass fraction (0.329$_{-0.049}^{+0.028}$) very similar to Earth's. We also present an atlas of 113 well-defined spectral lines to analyze M dwarfs in the $H$-band and a comprehensive evaluation of uncertainties from variations in the atmospheric parameters, signal-to-noise, and pseudo-continuum., Comment: 32 pages, 3 figures. Accepted to the Astrophysical Journal (ApJ)

The Transiting Exoplanet Survey Satellite (TESS) has discovered hundreds of new worlds, with TESS planet candidates now outnumbering the total number of confirmed planets from $\textit{Kepler}$. Owing to differences in survey design, TESS continues to provide planets that are better suited for subsequent follow-up studies, including mass measurement through radial velocity (RV) observations, compared to Kepler targets. In this work, we present the TESS-Keck Survey's (TKS) Mass Catalog: a uniform analysis of all TKS RV survey data which has resulted in mass constraints for 126 planets and candidate signals. This includes 58 mass measurements that have reached $\geq5\sigma$ precision. We confirm or validate 32 new planets from the TESS mission either by significant mass measurement (15) or statistical validation (17), and we find no evidence of likely false positives among our entire sample. This work also serves as a data release for all previously unpublished TKS survey data, including 9,204 RV measurements and associated activity indicators over our three year survey. We took the opportunity to assess the performance of our survey, and found that we achieved many of our goals including measuring the mass of 38 small ($<4R_{\oplus}$) planets, nearly achieving the TESS mission's basic science requirement. In addition, we evaluated the performance of the Automated Planet Finder (APF) as survey support and observed meaningful constraints on system parameters due to its more uniform phase coverage. Finally, we compared our measured masses to those predicted by commonly used mass-radius relations and investigated evidence of systematic bias., Comment: 51 pages (22 of text), 24 figures

Exoplanet discoveries have revealed a dramatic diversity of planet sizes across a vast array of orbital architectures. Sub-Neptunes are of particular interest; due to their absence in our own solar system, we rely on demographics of exoplanets to better understand their bulk composition and formation scenarios. Here, we present the discovery and characterization of TOI-1437 b, a sub-Neptune with a 18.84 day orbit around a near-Solar analog (Mstar = 1.10 +/- 0.10 Msun, Rstar = 1.17 +/- 0.12 Rsun). The planet was detected using photometric data from the Transiting Exoplanet Survey Satellite (TESS) mission and radial velocity follow-up observations were carried out as a part of the TESS-Keck Survey (TKS) using both the HIRES instrument at Keck Observatory and the Levy Spectrograph on the Automated Planet Finder (APF) telescope. A combined analysis of these data reveal a planet radius of Rp = 2.24 +/- 0.23 Rearth and a mass measurement of Mp = 9.6 +/- 3.9 Mearth). TOI-1437 b is one of few (~50) known transiting sub-Neptunes orbiting a solar-mass star that has a radial velocity mass measurement. As the formation pathway of these worlds remains an unanswered question, the precise mass characterization of TOI-1437 b may provide further insight into this class of planet., Comment: This arxiv update reflects the version of the manuscript that was accepted for publication in The Astronomical Journal

The extreme environments of ultra-short-period planets (USPs) make excellent laboratories to study how exoplanets obtain, lose, retain, and/or regain gaseous atmospheres. We present the confirmation and characterization of the USP TOI-1347 b, a $1.8 \pm 0.1$ R$_\oplus$ planet on a 0.85 day orbit that was detected with photometry from the TESS mission. We measured radial velocities of the TOI-1347 system using Keck/HIRES and HARPS-N and found the USP to be unusually massive at $11.1 \pm 1.2$ M$_\oplus$. The measured mass and radius of TOI-1347 b imply an Earth-like bulk composition. A thin H/He envelope (>0.01% by mass) can be ruled out at high confidence. The system is between 1 and 1.8 Gyr old; therefore, intensive photoevaporation should have concluded. We detected a tentative phase curve variation (3$\sigma$) and a secondary eclipse (2$\sigma$) in TESS photometry, which if confirmed could indicate the presence of a high-mean-molecular-weight atmosphere. We recommend additional optical and infrared observations to confirm the presence of an atmosphere and investigate its composition., Comment: 22 pages, 9 figures, accepted for publication in The Astronomical Journal

We present a dedicated transit and radial velocity survey of planets orbiting subgiant stars observed by the TESS Mission. Using $\sim$$16$ nights on Keck/HIRES, we confirm and characterize $12$ new transiting planets -- $\rm TOI-329\,b$, $\rm HD\,39688\,b$ ($\rm TOI-480$), $\rm TOI-603\,b$, $\rm TOI-1199\,b$, $\rm TOI-1294\,b$, $\rm TOI-1439\,b$, $\rm TOI-1605\,b$, $\rm TOI-1828\,b$, $\rm HD\,148193\,b$ ($\rm TOI-1836$), $\rm TOI-1885\,b$, $\rm HD\,83342\,b$ ($\rm TOI-1898$), $\rm TOI-2019\,b$ -- and provide updated properties for 9 previously confirmed TESS subgiant systems ($\rm TOI-197$, $\rm TOI-954$, $\rm TOI-1181$, $\rm TOI-1296$, $\rm TOI-1298$, $\rm TOI-1601$, $\rm TOI-1736$, $\rm TOI-1842$, $\rm TOI-2145$). We also report the discovery of an outer, non-transiting planet, $\rm TOI-1294\,c$ ($P=160.1\pm2.5$ days, $M_{\mathrm{p}}=148.3^{+18.2}_{-16.4} \,M_{\oplus}$), and three additional stars with long-term RV trends. We find that at least $19\pm8\%$ of subgiants in our sample of $21$ stars have outer companions, comparable to main-sequence stars. We perform a homogeneous analysis of the stars and planets in the sample, with median uncertainties of $3\%$, $8\%$ and $15\%$ for planet radii, masses and ages, doubling the number of known planets orbiting subgiant stars with bulk densities measured to better than $10\%$. We observe a dearth of giant planets around evolved stars with short orbital periods, consistent with tidal dissipation theories that predict the rapid inspiral of planets as their host stars leave the main sequence. We note the possible evidence for two distinct classes of hot Jupiter populations, indicating multiple formation channels to explain the observed distributions around evolved stars. Finally, continued RV monitoring of planets in this sample will provide a more comprehensive understanding of demographics for evolved planetary systems., Comment: 22 pages, 9 figures, 9 tables

We present and confirm TOI-1751 b, a transiting sub-Neptune orbiting a slightly evolved, solar-type, metal-poor star ($T_{eff} = 5996 \pm 110$ K, $log(g) = 4.2 \pm 0.1$, V = 9.3 mag, [Fe/H] = $-0.40 \pm 0.06$ dex) every 37.47 d. We use TESS photometry to measure a planet radius of $2.77_{-0.07}^{+0.15}~\rm{R_\oplus}$. We also use both Keck/HIRES and APF/Levy radial velocities (RV) to derive a planet mass of $14.5_{-3.14}^{+3.15} ~\rm{M_\oplus}$, and thus a planet density of $3.6 \pm 0.9 \, {\rm g}\,{\rm cm}^{-3}$. There is also a long-period ($\sim400~\rm{d}$) signal that is observed in only the Keck/HIRES data. We conclude that this long-period signal is not planetary in nature, and is likely due to the window function of the Keck/HIRES observations. This highlights the role of complementary observations from multiple observatories to identify and exclude aliases in RV data. Finally, we investigate potential compositions of this planet, including rocky and water-rich solutions, as well as theoretical irradiated ocean models. TOI-1751 b is a warm sub-Neptune, with an equilibrium temperature of $\sim 820$ K. As TOI-1751 is a metal-poor star, TOI-1751 b may have formed in a water-enriched formation environment. We thus favor a volatile-rich interior composition for this planet., Comment: 30 pages, 9 figures. Accepted for publication in AJ

The Transiting Exoplanet Survey Satellite (TESS) continues to dramatically increase the number of known transiting exoplanets, and is optimal for monitoring bright stars amenable to radial velocity (RV) and atmospheric follow-up observations. TOI-1386 is a solar-type (G5V) star that was detected via TESS photometry to exhibit transit signatures in three sectors with a period of 25.84 days. We conducted follow-up RV observations using Keck/HIRES as part of the TESS-Keck Survey (TKS), collecting 64 RV measurements of TOI-1386 with the HIRES spectrograph over 2.5 years. Our combined fit of the TOI-1386 photometry and RV data confirm the planetary nature of the detected TESS signal, and provide a mass and radius for planet b of $0.148\pm0.019$ $M_J$ and $0.540\pm0.017$ $R_J$, respectively, marking TOI-1386 b as a warm sub-Saturn planet. Our RV data further reveal an additional outer companion, TOI-1386 c, with an estimated orbital period of 227.6 days and a minimum mass of $0.309\pm0.038$ $M_J$. The dynamical modeling of the system shows that the measured system architecture is long-term stable, although there may be substantial eccentricity oscillations of the inner planet due to the dynamical influence of the outer planet., Comment: Accepted for publication in The Astronomical Journal. 15 pages, 7 figures

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $\mu$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$\sigma$ upper limit of 1-6 parts per million, depending on model assumptions)., Comment: 61 pages, 13 figures, 4 tables. This preprint has been submitted to and accepted in principle for publication in Nature Astronomy without significant changes

Over the last decade, precise exoplanet transmission spectroscopy has revealed the atmospheres of dozens of exoplanets, driven largely by observatories like the Hubble Space Telescope. One major discovery has been the ubiquity of atmospheric aerosols, often blocking access to exoplanet chemical inventories. Tentative trends have been identified, showing that the clarity of planetary atmospheres may depend on equilibrium temperature. Previous work has often grouped dissimilar planets together in order to increase the statistical power of any trends, but it remains unclear from observed transmission spectra whether these planets exhibit the same atmospheric physics and chemistry. We present a re-analysis of a smaller, more physically similar sample of 15 exo-Neptune transmission spectra across a wide range of temperatures (200-1000 K). Using condensation cloud and hydrocarbon haze models, we find that the exo-Neptune population is best described by low cloud sedimentation efficiency ($\mathrm{f_{sed}}\sim0.1$) and high metallicity ($100\times$ Solar). There is an intrinsic scatter of $\sim0.5$ scale height, perhaps evidence of stochasticity in these planets' formation processes. Observers should expect significant attenuation in transmission spectra of Neptune-size exoplanets, up to 6 scale heights for equilibrium temperatures between 500 and 800 K. With JWST's greater wavelength sensitivity, colder (<500 K) planets should be high-priority targets given their clearer atmospheres, and the need to distinguish between the "super-puffs" and more typical gas-dominated planets., Comment: Published in ApJL. 11 pages, 3 figures, 4 tables

Recent work on the characterization of small exoplanets has allowed us to accumulate growing evidence that the sub-Neptunes with radii greater than $\sim2.5\,R_\oplus$ often host H$_2$/He-dominated atmospheres both from measurements of their low bulk densities and direct detections of their low mean-molecular-mass atmospheres. However, the smaller sub-Neptunes in the 1.5-2.2 R$_\oplus$ size regime are much less understood, and often have bulk densities that can be explained either by the H$_2$/He-rich scenario, or by a volatile-dominated composition known as the "water world" scenario. Here, we report the detection of water vapor in the transmission spectrum of the $1.96\pm0.08$ R$_\oplus$ sub-Neptune GJ9827d obtained with the Hubble Space Telescope. We observed 11 HST/WFC3 transits of GJ9827d and find an absorption feature at 1.4$\mu$m in its transit spectrum, which is best explained (at 3.39$\sigma$) by the presence of water in GJ9827d's atmosphere. We further show that this feature cannot be caused by unnoculted star spots during the transits by combining an analysis of the K2 photometry and transit light-source effect retrievals. We reveal that the water absorption feature can be similarly well explained by a small amount of water vapor in a cloudy H$_2$/He atmosphere, or by a water vapor envelope on GJ9827d. Given that recent studies have inferred an important mass-loss rate ($>0.5\,$M$_\oplus$/Gyr) for GJ9827d making it unlikely to retain a H-dominated envelope, our findings highlight GJ9827d as a promising water world candidate that could host a volatile-dominated atmosphere. This water detection also makes GJ9827d the smallest exoplanet with an atmospheric molecular detection to date., Comment: Published in ApJL, 11 pages, 6 figures

We present the discovery of TOI-1420b, an exceptionally low-density ($\rho = 0.08\pm0.02$ g cm$^{-3}$) transiting planet in a $P = 6.96$ day orbit around a late G dwarf star. Using transit observations from TESS, LCOGT, OPM, Whitin, Wendelstein, OAUV, Ca l'Ou, and KeplerCam along with radial velocity observations from HARPS-N and NEID, we find that the planet has a radius of $R_p$ = 11.9 $\pm$ 0.3 $R_\Earth$ and a mass of $M_p$ = 25.1 $\pm$ 3.8 $M_\Earth$. TOI-1420b is the largest-known planet with a mass less than $50M_\Earth$, indicating that it contains a sizeable envelope of hydrogen and helium. We determine TOI-1420b's envelope mass fraction to be $f_{env} = 82^{+7}_{-6}\%$, suggesting that runaway gas accretion occurred when its core was at most $4-5\times$ the mass of the Earth. TOI-1420b is similar to the planet WASP-107b in mass, radius, density, and orbital period, so a comparison of these two systems may help reveal the origins of close-in low-density planets. With an atmospheric scale height of 1950 km, a transmission spectroscopy metric of 580, and a predicted Rossiter-McLaughlin amplitude of about $17$ m s$^{-1}$, TOI-1420b is an excellent target for future atmospheric and dynamical characterization.

We present the first isotopic abundances of both $^{13}$CO and C$^{18}$O in solar twin stars and test the results against several galactic chemical evolution (GCE) models with different nucleosynthesis prescriptions. First, we compare M-band spectra from IRTF/iSHELL to synthetic spectra generated from custom solar atmosphere models using the PHOENIX atmosphere code. Next, we compare our calculated abundances to GCE models that consider isotopic yields from massive stars, asymptotic giant branch (AGB) stars and fast-rotating stars. The $^{12}$C/$^{13}$C ratios determined for this sample of solar twins are consistent with predictions from the selected GCE models; however, the $^{16}$O/$^{18}$O ratios tentatively contradict these predictions. This project constitutes the first in a stellar chemical abundance series seeking to: (1) support the James Webb Space Telescope (JWST) as it characterizes exoplanet atmospheres, interiors, and biosignatures by providing host star abundances (2) identify how unexplored stellar abundances reveal the process of galactic chemical evolution and correlate with star formation, interior, age, metallicity, and activity; and (3) provide improved stellar ages using stellar abundance measurements. By measuring elemental and isotopic abundances in a variety of stars, we not only supply refined host star parameters, but also provide the necessary foundations for complementary exoplanet characterization studies and ultimately contribute to the exploration of galactic, stellar, and planetary origins and evolution., Comment: 21 pages, 6 figures. Published in ApJ 8/29/2023

To date, thousands of planets have been discovered, but there are regions of the orbital parameter space that are still bare. An example is the short period and intermediate mass/radius space known as the Neptunian desert, where planets should be easy to find but discoveries remain few. This suggests unusual formation and evolution processes are responsible for the planets residing here. We present the discovery of TOI-332 b, a planet with an ultra-short period of $0.78$ d that sits firmly within the desert. It orbits a K0 dwarf with an effective temperature of $5251 \pm 71$ K. TOI-332 b has a radius of $3.20^{+0.16}_{-0.12}$ R$_{\oplus}$, smaller than that of Neptune, but an unusually large mass of $57.2 \pm 1.6$ M$_{\oplus}$. It has one of the highest densities of any Neptune-sized planet discovered thus far at $9.6^{+1.1}_{-1.3}$ gcm$^{-3}$. A 4-layer internal structure model indicates it likely has a negligible hydrogen-helium envelope, something only found for a small handful of planets this massive, and so TOI-332 b presents an interesting challenge to planetary formation theories. We find that photoevaporation cannot account for the mass loss required to strip this planet of the Jupiter-like envelope it would have been expected to accrete. We need to look towards other scenarios, such as high-eccentricity migration, giant impacts, or gap opening in the protoplanetary disc, to try and explain this unusual discovery., Comment: 20 pages, 14 figures, 6 tables, accepted for publication in MNRAS

We present ground and space-based photometric observations of TOI-270 (L231-32), a system of three transiting planets consisting of one super-Earth and two sub-Neptunes discovered by TESS around a bright (K-mag=8.25) M3V dwarf. The planets orbit near low-order mean-motion resonances (5:3 and 2:1), and are thus expected to exhibit large transit timing variations (TTVs). Following an extensive observing campaign using 8 different observatories between 2018 and 2020, we now report a clear detection of TTVs for planets c and d, with amplitudes of $\sim$10 minutes and a super-period of $\sim$3 years, as well as significantly refined estimates of the radii and mean orbital periods of all three planets. Dynamical modeling of the TTVs alone puts strong constraints on the mass ratio of planets c and d and on their eccentricities. When incorporating recently published constraints from radial velocity observations, we obtain masses of $M_{\mathrm{b}}=1.48\pm0.18\,M_\oplus$, $M_{c}=6.20\pm0.31\,M_\oplus$ and $M_{\mathrm{d}}=4.20\pm0.16\,M_\oplus$ for planets b, c and d, respectively. We also detect small, but significant eccentricities for all three planets : $e_\mathrm{b} =0.0167\pm0.0084$, $e_{c} =0.0044\pm0.0006$ and $e_{d} = 0.0066\pm0.0020$. Our findings imply an Earth-like rocky composition for the inner planet, and Earth-like cores with an additional He/H$_2$O atmosphere for the outer two. TOI-270 is now one of the best-constrained systems of small transiting planets, and it remains an excellent target for atmospheric characterization., Comment: 22 pages, 7 figures

JWST has ushered in an era of unprecedented ability to characterize exoplanetary atmospheres. While there are over 5,000 confirmed planets, more than 4,000 TESS planet candidates are still unconfirmed and many of the best planets for atmospheric characterization may remain to be identified. We present a sample of TESS planets and planet candidates that we identify as "best-in-class" for transmission and emission spectroscopy with JWST. These targets are sorted into bins across equilibrium temperature $T_{\mathrm{eq}}$ and planetary radius $R{_\mathrm{p}}$ and are ranked by transmission and emission spectroscopy metric (TSM and ESM, respectively) within each bin. In forming our target sample, we perform cuts for expected signal size and stellar brightness, to remove sub-optimal targets for JWST. Of the 194 targets in the resulting sample, 103 are unconfirmed TESS planet candidates, also known as TESS Objects of Interest (TOIs). We perform vetting and statistical validation analyses on these 103 targets to determine which are likely planets and which are likely false positives, incorporating ground-based follow-up from the TESS Follow-up Observation Program (TFOP) to aid the vetting and validation process. We statistically validate 23 TOIs, marginally validate 33 TOIs to varying levels of confidence, deem 29 TOIs likely false positives, and leave the dispositions for 4 TOIs as inconclusive. 14 of the 103 TOIs were confirmed independently over the course of our analysis. We provide our final best-in-class sample as a community resource for future JWST proposals and observations. We intend for this work to motivate formal confirmation and mass measurements of each validated planet and encourage more detailed analysis of individual targets by the community., Comment: Submitted to AJ. Machine-readable versions of Tables 2 and 3 are included. 40 pages, 7 figures, 3 tables

With JWST's successful deployment and unexpectedly high fuel reserves, measuring the masses of sub-Neptunes transiting bright, nearby stars will soon become the bottleneck for characterizing the atmospheres of small exoplanets via transmission spectroscopy. Using a carefully curated target list and more than two years' worth of APF-Levy and Keck-HIRES Doppler monitoring, the TESS-Keck Survey is working toward alleviating this pressure. Here we present mass measurements for 11 transiting planets in eight systems that are particularly suited to atmospheric follow-up with JWST. We also report the discovery and confirmation of a temperate super-Jovian-mass planet on a moderately eccentric orbit. The sample of eight host stars, which includes one subgiant, spans early-K to late-F spectral types ($T_\mathrm{eff} =$ 5200--6200 K). We homogeneously derive planet parameters using a joint photometry and radial velocity modeling framework, discuss the planets' possible bulk compositions, and comment on their prospects for atmospheric characterization., Comment: Accepted for publication in The Astronomical Journal on 2023-Jun-22. 60 pages, 17 Tables, 28 Figures

We present the stellar and planetary properties for 85 TESS Objects of Interest (TOIs) hosting 108 planet candidates which comprise the TESS-Keck Survey (TKS) sample. We combine photometry, high-resolution spectroscopy, and Gaia parallaxes to measure precise and accurate stellar properties. We then use these parameters as inputs to a lightcurve processing pipeline to recover planetary signals and homogeneously fit their transit properties. Among these transit fits, we detect significant transit-timing variations among at least three multi-planet systems (TOI-1136, TOI-1246, TOI-1339) and at least one single-planet system (TOI-1279). We also reduce the uncertainties on planet-to-star radius ratios $R_p/R_\star$ across our sample, from a median fractional uncertainty of 8.8$\%$ among the original TOI Catalog values to 3.0$\%$ among our updated results. With this improvement, we are able to recover the Radius Gap among small TKS planets and find that the topology of the Radius Gap among our sample is broadly consistent with that measured among Kepler planets. The stellar and planetary properties presented here will facilitate follow-up investigations of both individual TOIs and broader trends in planet properties, system dynamics, and the evolution of planetary systems., Comment: Accepted at The Astronomical Journal; 21 pages, 9 figures

Carbon monoxide (CO) is predicted to be the dominant carbon-bearing molecule in giant planet atmospheres, and, along with water, is important for discerning the oxygen and therefore carbon-to-oxygen ratio of these planets. The fundamental absorption mode of CO has a broad double-branched structure composed of many individual absorption lines from 4.3 to 5.1 $\mathrm{\mu}$m, which can now be spectroscopically measured with JWST. Here we present a technique for detecting the rotational sub-band structure of CO at medium resolution with the NIRSpec G395H instrument. We use a single transit observation of the hot Jupiter WASP-39b from the JWST Transiting Exoplanet Community Early Release Science (JTEC ERS) program at the native resolution of the instrument ($R \,{\sim} 2700$) to resolve the CO absorption structure. We robustly detect absorption by CO, with an increase in transit depth of 264 $\pm$ 68 ppm, in agreement with the predicted CO contribution from the best-fit model at low resolution. This detection confirms our theoretical expectations that CO is the dominant carbon-bearing molecule in WASP-39b's atmosphere, and further supports the conclusions of low C/O and super-solar metallicities presented in the JTEC ERS papers for WASP-39b., Comment: 11 pages, 5 figures, accepted for publication in ApJL

The newfound ability to detect SO2 in exoplanet atmospheres presents an opportunity to measure sulfur abundances and so directly test between competing modes of planet formation. In contrast to carbon and oxygen, whose dominant molecules are frequently observed, sulfur is much less volatile and resides almost exclusively in solid form in protoplanetary disks. This dichotomy leads different models of planet formation to predict different compositions of gas giant planets. Whereas planetesimal-based models predict roughly stellar C/S and O/S ratios, pebble accretion models more often predict superstellar ratios. To explore the detectability of SO2 in transmission spectra and its ability to diagnose planet formation, we present a grid of atmospheric photochemical models and corresponding synthetic spectra for WASP-39b (where SO2 has been detected). Our 3D grid contains 11^3 models (spanning 1--100x the solar abundance ratio of C, O, and S) for thermal profiles corresponding to the morning and evening terminators, as well as mean terminator transmission spectra. Our models show that for a WASP-39b-like O/H and C/H enhancement of ~10x Solar, SO2 can only be seen for C/S and O/S <~1.5, and that WASP-39b's reported SO2 abundance of 1--10 ppm may be more consistent with planetesimal accretion than with pebble accretion models (although some pebble models also manage to predict similarly low ratios). More extreme C/S and O/S ratios may be detectable in higher-metallicity atmospheres, suggesting that smaller and more metal-rich gas and ice giants may be particularly interesting targets for testing planet formation models. Future studies should explore the dependence of SO2 on a wider array of planetary and stellar parameters, both for the prototypical SO2 planet WASP-39b, as well as for other hot Jupiters and smaller gas giants., Comment: 9 pages, 6 figures, 1 table, and 1331 models and spectra at https://zenodo.org/record/7760360. Revised per referee report, and accepted to ApJL

We present observations of the 1.35+/-0.07 Earth-radius planet L 98-59 c using Wide Field Camera~3 on the Hubble Space Telescope. L 98-59 is a nearby (10.6 pc), bright (H=7.4 mag), M3V star that harbors three small, transiting planets. As one of the closest known transiting multi-planet systems, L 98-59 offers one of the best opportunities to probe and compare the atmospheres of rocky planets that formed in the same stellar environment. We measured the transmission spectrum of L 98-59 c during a single transit, with the extracted spectrum showing marginal evidence for wavelength-dependent transit depth variations which would indicate the presence of an atmosphere. Forward modeling was used to constrain possible atmospheric compositions of the planet based on the shape of the transmission spectrum. Although L 98-59 is a fairly quiet star, we have seen evidence for stellar activity, and therefore we cannot rule out a scenario where the source of the signal originates with inhomogeneities on the host-star surface. While intriguing, our results are inconclusive and additional data is needed to verify any atmospheric signal. Fortunately, additional data will soon be collected from both HST and JWST. Should this result be confirmed with additional data, L 98-59 c would be the first planet smaller than 2 Earth-radii with a detected atmosphere, and among the first small planets with a known atmosphere to be studied in detail by the JWST., Comment: Submitted to AAS Journals

Close-in giant exoplanets with temperatures greater than 2,000 K (''ultra-hot Jupiters'') have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble and Spitzer Space Telescopes. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS instrument on JWST. The data span 0.85 to 2.85 $\mu$m in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at $>$6$\sigma$ confidence) and evidence for optical opacity, possibly due to H$^-$, TiO, and VO (combined significance of 3.8$\sigma$). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy element abundance (''metallicity'', M/H = 1.03$_{-0.51}^{+1.11}$ $\times$ solar), and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the sub-stellar point that decreases steeply and symmetrically with longitude toward the terminators., Comment: JWST ERS bright star observations. Uploaded to inform JWST Cycle 2 proposals. Manuscript under review. 50 pages, 14 figures, 2 tables

We study the emergent spectral fluxes of transiting hot Jupiters, using secondary eclipses from Spitzer. To achieve a large and uniform sample, we have re-analyzed all secondary eclipses for all hot Jupiters observed by Spitzer at 3.6- and/or 4.5 microns. Our sample comprises 457 eclipses of 122 planets, including eclipses of 13 planets not previously published. We use these eclipse depths to calculate the spectral fluxes emergent from the exoplanetary atmospheres, and thereby infer temperature and spectral properties of hot Jupiters. We find that an abrupt rise in brightness temperature, similar to a phase change, occurs on the day side atmospheres of the population at an equilibrium temperature between 1714K and 1818K (99-percent confidence limits). The amplitude of the rise is 291 +/-49 Kelvins, and two viable causes are the onset of magnetic drag that inhibits longitudinal heat redistribution, and/or the rapid dissipation of day side clouds. We also study hot Jupiter spectral properties with respect to metallicity and temperature inversions. Models exhibiting 4.5 micron emission from temperature inversions reproduce our fluxes statistically for the hottest planets, but the transition to emission is gradual, not abrupt. The Spitzer fluxes are sensitive to metallicity for planets cooler than approximately 1200 Kelvins, and most of the hot Jupiter population falls between model tracks having solar to 30X-solar metallicity., Comment: 29 pages, 12 figures, 4 tables (3 are MR), accepted for the Astronomical Journal

The population of planets smaller than approximately $1.7~R_\oplus$ is widely interpreted as consisting of rocky worlds, generally referred to as super-Earths. This picture is largely corroborated by radial-velocity (RV) mass measurements for close-in super-Earths but lacks constraints at lower insolations. Here we present the results of a detailed study of the Kepler-138 system using 13 Hubble and Spitzer transit observations of the warm-temperate $1.51\pm0.04~R_\oplus$ planet Kepler-138 d ($T_{\mathrm{eq, A_B=0.3}}$~350 K) combined with new Keck/HIRES RV measurements of its host star. We find evidence for a volatile-rich "water world" nature of Kepler-138 d, with a large fraction of its mass contained in a thick volatile layer. This finding is independently supported by transit timing variations, RV observations ($M_d=2.1_{-0.7}^{+0.6}~M_\oplus$), as well as the flat optical/IR transmission spectrum. Quantitatively, we infer a composition of $11_{-4}^{+3}$\% volatiles by mass or ~51% by volume, with a 2000 km deep water mantle and atmosphere on top of a core with an Earth-like silicates/iron ratio. Any hypothetical hydrogen layer consistent with the observations ($<0.003~M_\oplus$) would have swiftly been lost on a ~10 Myr timescale. The bulk composition of Kepler-138 d therefore resembles those of the icy moons rather than the terrestrial planets in the solar system. We conclude that not all super-Earth-sized planets are rocky worlds, but that volatile-rich water worlds exist in an overlapping size regime, especially at lower insolations. Finally, our photodynamical analysis also reveals that Kepler-138 c ($R_c=1.51 \pm 0.04~R_\oplus$, $M_c=2.3_{-0.5}^{+0.6}~M_\oplus$) is a slightly warmer twin of Kepler-138 d, i.e., another water world in the same system, and we infer the presence of Kepler-138 e, a likely non-transiting planet at the inner edge of the habitable zone., Comment: Published in Nature Astronomy. 4 main figures, 10 extended data figures, 13 supplementary figures. 4 tables

TOI-270d is a temperate sub-Neptune discovered by the Transiting Exoplanet Survey Satellite (TESS) around a bright (J=9.1mag) M3V host star. With an approximate radius of 2RE and equilibrium temperature of 350K, TOI-270d is one of the most promising small exoplanets for atmospheric characterisation using transit spectroscopy. Here we present a primary transit observation of TOI-270d made with the Hubble Space Telescope (HST) Wide Field Camera 3 (WFC3) spectrograph across the 1.126-1.644 micron wavelength range, and a 95% credible upper limit of $8.2 \times 10^{-14}$ erg s$^{-1}$ cm$^{-2}$ A$^{-1}$ arcsec$^{-2}$ for the stellar Ly-alpha emission obtained using the Space Telescope Imaging Spectrograph (STIS). The transmission spectrum derived from the TESS and WFC3 data provides evidence for molecular absorption by a hydrogen-rich atmosphere at 4-sigma significance relative to a featureless spectrum. The strongest evidence for any individual absorber is obtained for H2O, which is favoured at 3-sigma significance. When retrieving on the WFC3 data alone and allowing for the possibility of a heterogeneous stellar brightness profile, the detection significance of H2O is reduced to 2.8-sigma. Further observations are therefore required to robustly determine the atmospheric composition of TOI-270d and assess the impact of stellar heterogeneity. If confirmed, our findings would make TOI-270d one of the smallest and coolest exoplanets to date with detected atmospheric spectral features., Comment: Accepted for publication in AAS journals on November 22, 2022 (received July 5, 2022; revised October 30, 2022)

The Kepler and TESS missions revealed a remarkable abundance of sub-Neptune exoplanets. Despite this abundance, our understanding of the nature and compositional diversity of sub-Neptunes remains limited, to a large part because atmospheric studies via transmission spectroscopy almost exclusively aimed for low-density sub-Neptunes and even those were often affected by high-altitude clouds. The recent TESS discovery of the hot, dense TOI-824b ($2.93\,R_\oplus$ and $18.47\,M_\oplus$) opens a new window into sub-Neptune science by enabling the study of a dense sub-Neptune via secondary eclipses. Here, we present the detection of TOI-824b's hot day side via Spitzer secondary eclipse observations in the $3.6$ and $4.5\,\mathrm{\mu m}$ channels, combined with a reanalysis of its interior composition. The measured eclipse depths (142$^{+57}_{-52}$ and 245$^{+75}_{-77}$ ppm) and brightness temperatures (1463$^{+183}_{-196}$ and 1484$^{+180}_{-202}$ K) indicate a poor heat redistribution ($f>$ 0.49) and a low Bond albedo (A$_{B}<$ 0.26). We conclude that TOI-824b could be an "exposed Neptune mantle": a planet with a Neptune-like water-rich interior that never accreted a hydrogen envelope or that subsequently lost it. The hot day-side temperature is then naturally explained by a high-metallicity envelope re-emitting the bulk of the incoming radiation from the day side. TOI-824b's density is also consistent with a massive rocky core that accreted up to 1% of hydrogen, but the observed eclipse depths favor our high-metallicity GCM simulation to a solar-metallicity GCM simulation with a likelihood ratio of 7:1. The new insights into TOI-824b's nature suggest that the sub-Neptune population may be more diverse than previously thought, with some of the dense hot sub-Neptunes potentially not hosting a hydrogen-rich envelope as generally assumed for sub-Neptunes., Comment: Accepted for publication in The Astrophysical Journal, 14 pages, 5 figures

Transmission spectroscopy provides insight into the atmospheric properties and consequently the formation history, physics, and chemistry of transiting exoplanets. However, obtaining precise inferences of atmospheric properties from transmission spectra requires simultaneously measuring the strength and shape of multiple spectral absorption features from a wide range of chemical species. This has been challenging given the precision and wavelength coverage of previous observatories. Here, we present the transmission spectrum of the Saturn-mass exoplanet WASP-39b obtained using the SOSS mode of the NIRISS instrument on the JWST. This spectrum spans $0.6 - 2.8 \mu$m in wavelength and reveals multiple water absorption bands, the potassium resonance doublet, as well as signatures of clouds. The precision and broad wavelength coverage of NIRISS-SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favoring a heavy element enhancement ("metallicity") of $\sim 10 - 30 \times$ the solar value, a sub-solar carbon-to-oxygen (C/O) ratio, and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are best explained by wavelength-dependent, non-gray clouds with inhomogeneous coverage of the planet's terminator., Comment: 48 pages, 12 figures, 2 tables. Under review at Nature

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability. However, no unambiguous photochemical products have been detected in exoplanet atmospheres to date. Recent observations from the JWST Transiting Exoplanet Early Release Science Program found a spectral absorption feature at 4.05 $\mu$m arising from SO$_2$ in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M$_J$) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of $\sim$1100 K. The most plausible way of generating SO$_2$ in such an atmosphere is through photochemical processes. Here we show that the SO$_2$ distribution computed by a suite of photochemical models robustly explains the 4.05 $\mu$m spectral feature identified by JWST transmission observations with NIRSpec PRISM (2.7$\sigma$) and G395H (4.5$\sigma$). SO$_2$ is produced by successive oxidation of sulphur radicals freed when hydrogen sulphide (H$_2$S) is destroyed. The sensitivity of the SO$_2$ feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of $\sim$10$\times$ solar. We further point out that SO$_2$ also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations., Comment: 39 pages, 14 figures, accepted to be published in Nature

Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution, and high precision that, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST's Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0 - 4.0 $\mu$m, exhibit minimal systematics, and reveal well-defined molecular absorption features in the planet's spectrum. Specifically, we detect gaseous H$_2$O in the atmosphere and place an upper limit on the abundance of CH$_4$. The otherwise prominent CO$_2$ feature at 2.8 $\mu$m is largely masked by H$_2$O. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1-100$\times$ solar (i.e., an enrichment of elements heavier than helium relative to the Sun) and a sub-stellar carbon-to-oxygen (C/O) ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation or disequilibrium processes in the upper atmosphere., Comment: 35 pages, 13 figures, 3 tables, Nature, accepted

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems. Access to an exoplanet's chemical inventory requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based and high-resolution ground-based facilities. Here we report the medium-resolution (R$\sim$600) transmission spectrum of an exoplanet atmosphere between 3-5 $\mu$m covering multiple absorption features for the Saturn-mass exoplanet WASP-39b, obtained with JWST NIRSpec G395H. Our observations achieve 1.46x photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO$_2$ (28.5$\sigma$) and H$_2$O (21.5$\sigma$), and identify SO$_2$ as the source of absorption at 4.1 $\mu$m (4.8$\sigma$). Best-fit atmospheric models range between 3 and 10x solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO$_2$, underscore the importance of characterising the chemistry in exoplanet atmospheres, and showcase NIRSpec G395H as an excellent mode for time series observations over this critical wavelength range., Comment: 44 pages, 11 figures, 3 tables. Resubmitted after revision to Nature

We present the Distant Giants Survey, a three-year radial velocity (RV) campaign to measure P(DG|CS), the conditional occurrence of distant giant planets (DG; M_p ~ 0.3 - 13 M_J, P > 1 year) in systems hosting a close-in small planet (CS; R_p < 10 R_E). For the past two years, we have monitored 47 Sun-like stars hosting small transiting planets detected by TESS. We present the selection criteria used to assemble our sample and report the discovery of two distant giant planets, TOI-1669 b and TOI-1694 c. For TOI-1669 b we find that Msin i = 0.573 +/- 0.074 M_J, P = 502 +/- 16 days, and e < 0.27, while for TOI-1694 c, Msin i = 1.05 +/- 0.05 M_J, P = 389.2 +/- 3.9 days, and e = 0.18 +/- 0.05. We also confirmed the 3.8-day transiting planet TOI-1694 b by measuring a true mass of M = 26.1 +/- 2.2 M_E. We also confirmed the 3.8-day transiting planet TOI-1694 b by measuring a true mass of M = 26.1 +/- 2.2 M_E. At the end of the Distant Giants Survey, we will incorporate TOI-1669 b and TOI-1694 c into our calculation of P(DG|CS), a crucial statistic for understanding the relationship between outer giants and small inner companions.

Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (i.e., elements heavier than helium, also called "metallicity"), and thus formation processes of the primary atmospheres of hot gas giants. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO2 but have not yielded definitive detections due to the lack of unambiguous spectroscopic identification. Here we present the detection of CO2 in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science Program (ERS). The data used in this study span 3.0 to 5.5 {\mu}m in wavelength and show a prominent CO2 absorption feature at 4.3 {\mu}m (26{\sigma} significance). The overall spectrum is well matched by one-dimensional, 10x solar metallicity models that assume radiative-convective-thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide, and hydrogen sulfide in addition to CO2, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 {\mu}m that is not reproduced by these models., Comment: 27 pages, 6 figures, Accepted for publication in Nature, data and models available at https://doi.10.5281/zenodo.6959427

The increasing numbers of rocky, terrestrial exoplanets known to orbit nearby stars (especially M dwarfs) has drawn increased attention to the possibility of studying these planets' surface properties, and atmospheric compositions & escape histories. Here we report the detection of the secondary eclipse of the terrestrial exoplanet GJ1252b using the Spitzer Space Telescope's IRAC2 4.5 micron channel. We measure an eclipse depth of 149(+25/-32) ppm, corresponding to a day-side brightness temperature of 1410(+91/-125) K and consistent with the prediction for no atmosphere. Comparing our measurement to atmospheric models indicates that GJ1252b has a surface pressure of <10 bar, substantially less than Venus. Assuming energy-limited escape, even a 100 bar atmosphere would be lost in <1 Myr, far shorter than estimated age of 3.9+/-0.4 Gyr. The expected mass loss could be overcome by mantle outgassing, but only if the mantle's carbon content were >7% by mass - over two orders of magnitude greater than that found in Earth. We therefore conclude that GJ1252b has no significant atmosphere. Model spectra with granitoid or feldspathic surface composition, but with no atmosphere, are disfavored at >2 sigma. The eclipse occurs just +1.4(+2.8/-1.0) min after orbital phase 0.5, indicating e cos omega=+0.0025(+0.0049/-0.0018), consistent with a circular orbit. Tidal heating is therefore likely to be negligible to GJ1252b's global energy budget. Finally, we also analyze additional, unpublished TESS transit photometry of GJ1252b which improves the precision of the transit ephemeris by a factor of ten, provides a more precise planetary radius of 1.180+/-0.078 R_E, and rules out any transit timing variations with amplitudes <1 min., Comment: ApJL in press. 16 pages, 12 figures, 10 eclipses, 1 bandpass. Models will be available at journal website

Using a data-driven machine learning tool we report $T_{\text{eff}}$, $\log{(g)}$, $v\sin{(i)}$, and elemental abundances for 15 elements (C, N, O, Na, Mg, Al, Si, Ca, Ti, V, Cr, Mn, Fe, Ni, Y) for a sample of 25 exoplanet host stars targeted by JWST's first year of observations. The chemical diversity of these stars show that, while a number of their companion planets may have formed in a disk with chemistry similar to Solar, some JWST targets likely experienced different disk compositions. This sample is part of a larger forthcoming catalog that will report homogeneous abundances of $\sim$4,500 FGK stars derived from Keck/HIRES spectra., Comment: 3 pages. Submitted to Research Notes of the AAS

Multi-planet systems orbiting M dwarfs provide valuable tests of theories of small planet formation and evolution. K2-3 is an early M dwarf hosting three small exoplanets (1.5-2.0 Earth radii) at distances of 0.07-0.20 AU. We measure the high-energy spectrum of K2-3 with HST/COS and XMM-Newton, and use empirically-driven estimates of Ly-alpha and extreme ultraviolet flux. We use EXOFASTv2 to jointly fit radial velocity, transit, and SED data. This constrains the K2-3 planet radii to 4% uncertainty and the masses of K2-3b and c to 13% and 30%, respectively; K2-3d is not detected in RV measurements. K2-3b and c are consistent with rocky cores surrounded by solar composition envelopes (mass fractions of 0.36% and 0.07%), H2O envelopes (55% and 16%), or a mixture of both. However, based on the high-energy output and estimated age of K2-3, it is unlikely that K2-3b and c retain solar composition atmospheres. We pass the planet parameters and high-energy stellar spectrum to atmospheric models. Dialing the high-energy spectrum up and down by a factor of 10 produces significant changes in trace molecule abundances, but not at a level detectable with transmission spectroscopy. Though the K2-3 planets span the small planet radius valley, the observed system architecture cannot be readily explained by photoevaporation or core-powered mass loss. We instead propose 1) the K2-3 planets are all volatile-rich, with K2-3d having a lower density than typical of super-Earths, and/or 2) the K2-3 planet architecture results from more stochastic processes such as planet formation, planet migration, and impact erosion., Comment: 15 pages, 7 figure, published in AJ, HLSPs at https://archive.stsci.edu/hlsp/mstarpanspec

We report the discovery of an eccentric hot Neptune and a non-transiting outer planet around TOI-1272. We identified the eccentricity of the inner planet, with an orbital period of 3.3 d and $R_{\rm p,b} = 4.1 \pm 0.2$ $R_\oplus$, based on a mismatch between the observed transit duration and the expected duration for a circular orbit. Using ground-based radial velocity measurements from the HIRES instrument at the Keck Observatory, we measured the mass of TOI-1272b to be $M_{\rm p,b} = 25 \pm 2$ $M_\oplus$. We also confirmed a high eccentricity of $e_b = 0.34 \pm 0.06$, placing TOI-1272b among the most eccentric well-characterized sub-Jovians. We used these RV measurements to also identify a non-transiting outer companion on an 8.7-d orbit with a similar mass of $M_{\rm p,c}$ sin$i= 27 \pm 3$ $M_\oplus$ and $e_c \lesssim 0.35$. Dynamically stable planet-planet interactions have likely allowed TOI-1272b to avoid tidal eccentricity decay despite the short circularization timescale expected for a close-in eccentric Neptune. TOI-1272b also maintains an envelope mass fraction of $f_{\rm env} \approx 11\%$ despite its high equilibrium temperature, implying that it may currently be undergoing photoevaporation. This planet joins a small population of short-period Neptune-like planets within the "Hot Neptune Desert" with a poorly understood formation pathway., Comment: Accepted at The Astronomical Journal; 17 pages, 11 figures

We report on the discovery and characterisation of three planets orbiting the F8 star HD~28109, which sits comfortably in \tess's continuous viewing zone. The two outer planets have periods of $\rm 56.0067 \pm 0.0003~days$ and $\rm 84.2597_{-0.0008}^{+0.0010}~days$, which implies a period ratio very close to that of the first-order 3:2 mean motion resonance, exciting transit timing variations (TTVs) of up to $\rm 60\,mins$. These two planets were first identified by \tess, and we identified a third planet in the \textcolor{black}{\tess photometry} with a period of $\rm 22.8911 \pm 0.0004~days$. We confirm the planetary nature of all three planetary candidates using ground-based photometry from Hazelwood, ASTEP and LCO, including a full detection of the $\rm \sim9\,h$ transit of HD~28109 c from Antarctica. The radii of the three planets are \textcolor{black}{$\rm R_b=2.199_{-0.10}^{+0.098} ~R_{\oplus}$, $\rm R_c=4.23\pm0.11~ R_{\oplus}$ and $\rm R_d=3.25\pm0.11 ~R_{\oplus}$}; we characterise their masses using TTVs and precise radial velocities from ESPRESSO and HARPS, and find them to be $\rm M_b=18.5_{-7.6}^{+9.1}~M_{\oplus}$, $\rm M_c=7.9_{-3.0}^{+4.2}~M_{\oplus}$ and $\rm M_d=5.7_{-2.1}^{+2.7}~M_{\oplus}$, making planet b a dense, massive planet while c and d are both under-dense. We also demonstrate that the two outer planets are ripe for atmospheric characterisation using transmission spectroscopy, especially given their position in the CVZ of JWST. The data obtained to date are consistent with resonant (librating) and non-resonant (circulating) solutions; additional observations will show whether the pair is actually locked in resonance or just near-resonant., Comment: 19 pages, 14 figures

Multi-planet systems are valuable arenas for investigating exoplanet architectures and comparing planetary siblings. TOI-1246 is one such system, with a moderately bright K dwarf ($\rm{V=11.6,~K=9.9}$) and four transiting sub-Neptunes identified by TESS with orbital periods of $4.31~\rm{d},~5.90~\rm{d},~18.66~\rm{d}$, and $~37.92~\rm{d}$. We collected 130 radial velocity observations with Keck/HIRES and TNG/HARPS-N to measure planet masses. We refit the 14 sectors of TESS photometry to refine planet radii ($\rm{2.97 \pm 0.06~R_\oplus},\rm{2.47 \pm 0.08~R_\oplus}, \rm{3.46 \pm 0.09~R_\oplus}$, $\rm{3.72 \pm 0.16~R_\oplus}$), and confirm the four planets. We find that TOI-1246 e is substantially more massive than the three inner planets ($\rm{8.1 \pm 1.1 M_\oplus}$, $\rm{8.8 \pm 1.2 M_\oplus}$, $\rm{5.3 \pm 1.7 M_\oplus}$, $\rm{14.8 \pm 2.3 M_\oplus}$). The two outer planets, TOI-1246 d and TOI-1246 e, lie near to the 2:1 resonance ($\rm{P_{e}/P_{d}=2.03}$) and exhibit transit timing variations. TOI-1246 is one of the brightest four-planet systems, making it amenable for continued observations. It is one of only six systems with measured masses and radii for all four transiting planets. The planet densities range from $\rm{0.70 \pm 0.24}$ to $3.21 \pm 0.44 \rm{g/cm^3}$, implying a range of bulk and atmospheric compositions. We also report a fifth planet candidate found in the RV data with a minimum mass of 25.6 $\pm$ 3.6 $\rm{M_\oplus}$. This planet candidate is exterior to TOI-1246 e with a candidate period of 93.8 d, and we discuss the implications if it is confirmed to be planetary in nature., Comment: Accepted at The Astronomical Journal; 33 pages, 10 figures

We report the first detection of CO emission at high spectral resolution in the day-side infrared thermal spectrum of an exoplanet. These emission lines, found in the atmosphere of the transiting ultra hot Jupiter (UHJ) WASP-33 b, provide unambiguous evidence of its thermal inversion. Using spectra from the MMT Exoplanet Atmosphere Survey (MEASURE, $R\sim15,000$), covering pre- and post-eclipse phases, we cross-correlate with 1D PHOENIX spectral templates to detect CO at S/N = 7.9 ($v_{sys}=0.15^{+0.64}_{-0.65}$ km/s, $K_{p}=229.5^{+1.1}_{-1.0}$ km/s). Moreover, using cross-correlation-to-log-likelihood mapping, we find that the scaling parameter which controls the spectral line contrast changes with phase. We thus use the general circulation model SPARC/MITgcm post-processed by the 3D gCMCRT radiative transfer code to interpret this variation, finding it consistent with an eastward-shifted hot spot. Pre-eclipse, when the hot spot faces Earth, the thermal profiles are shallower leading to smaller line contrast despite greater overall flux. Post-eclipse, the western part of the day-side faces Earth and has much steeper thermal profiles, leading to larger line contrast despite less overall flux. This demonstrates that within the log-likelihood framework, even relatively moderate resolution spectra can be used to understand the 3D nature of close-in exoplanets, and that resolution can be traded for photon-collecting power when the induced Doppler-shift is sufficiently large. We highlight CO as a good probe of UHJ thermal structure and dynamics that does not suffer from stellar activity, unlike species that are also present in the host star e.g. iron lines., Comment: 24 pages, 21 figures, accepted to MNRAS

The NASA K2 mission, salvaged from the hardware failures of the Kepler telescope, has continued Kepler's planet-hunting success. It has revealed nearly 500 transiting planets around the ecliptic plane, many of which are the subject of further study, and over 1000 additional candidates. Here we present the results of an ongoing project to follow-up and statistically validate new K2 planets, in particular to identify promising new targets for further characterization. By analyzing the reconnaissance spectra, high-resolution imaging, centroid variations, and statistical likelihood of the signals of 91 candidates, we validate 60 new planets in 46 systems. These include: a number of planets amenable to transmission spectroscopy (K2-384 f, K2-387 b, K2-390 b, K2-403 b, and K2-398 c), emission spectroscopy (K2-371 b, K2-370 b, and K2-399 b), and both (K2-405 b and K2-406 b); several systems with planets in or close to mean motion resonances (K2-381, K2-398) including a compact, TRAPPIST-1-like system of five small planets orbiting a mid-M dwarf (K2-384); an ultra-short period sub-Saturn in the hot Saturn desert (K2-399 b); and a super-Earth orbiting a moderately bright (V=11.93), metal-poor ([Fe/H]=-0.579+/-0.080) host star (K2-408 b). In total we validate planets around 4 F stars, 26 G stars, 13 K stars, and 3 M dwarfs. In addition, we provide a list of 37 vetted planet candidates that should be prioritized for future follow-up observation in order to be confirmed or validated., Comment: 50 pages, 14 figures, 7 tables, accepted in AJ; replaced to fix error in planet name (thanks Travis!) and error in figure label

We explore the transit timing variations (TTVs) of the young (22 Myr) nearby AU Mic planetary system. For AU Mic b, we introduce three Spitzer (4.5 $\mu$m) transits, five TESS transits, 11 LCO transits, one PEST transit, one Brierfield transit, and two transit timing measurements from Rossiter-McLaughlin observations; for AU Mic c, we introduce three TESS transits. We present two independent TTV analyses. First, we use EXOFASTv2 to jointly model the Spitzer and ground-based transits and to obtain the midpoint transit times. We then construct an O--C diagram and model the TTVs with Exo-Striker. Second, we reproduce our results with an independent photodynamical analysis. We recover a TTV mass for AU Mic c of 10.8$^{+2.3}_{-2.2}$ M$_{E}$. We compare the TTV-derived constraints to a recent radial-velocity (RV) mass determination. We also observe excess TTVs that do not appear to be consistent with the dynamical interactions of b and c alone, and do not appear to be due to spots or flares. Thus, we present a hypothetical non-transiting "middle-d" candidate exoplanet that is consistent with the observed TTVs, the candidate RV signal, and would establish the AU Mic system as a compact resonant multi-planet chain in a 4:6:9 period commensurability. These results demonstrate that the AU Mic planetary system is dynamically interacting producing detectable TTVs, and the implied orbital dynamics may inform the formation mechanisms for this young system. We recommend future RV and TTV observations of AU Mic b and c to further constrain the masses and to confirm the existence of possible additional planet(s)., Comment: Corrected typos; revised Section 3, 4, and 5 to reflect reanalysis, results unchanged. Submitted to AAS Journals Nov 11th, 2020; favorable referee report received Jan 3rd; final draft accepted for publication in the AJ Apr 19th