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Cassini discovered a plethora of neutral and ionised molecules in Titan's ionosphere including, surprisingly, anions and negatively charged molecules extending up to 13,800 u/q. In this letter we forward model the Cassini electron spectrometer response function to this unexpected ionospheric component to achieve an increased mass resolving capability for negatively charged species observed at Titan altitudes of 950-1300 km. We report on detections consistently centered between 25.8-26.0 u/q and between 49.0-50.1 u/q which are identified as belonging to the carbon chain anions, CN$^-$/C$_3$N$^-$ and/or C$_2$H$^-$/C$_4$H$^-$, in agreement with chemical model predictions. At higher ionospheric altitudes, detections at 73-74 u/q could be attributed to the further carbon chain anions C$_5$N$^-$/C$_6$H$^-$ but at lower altitudes and during further encounters, extend over a higher mass/charge range. This, as well as further intermediary anions detected at $>$100 u, provide the first evidence for efficient anion chemistry in space involving structures other than linear chains. Furthermore, at altitudes below $\sim$1100 km, the low mass anions ($<$150 u/q) were found to deplete at a rate proportional to the growth of the larger molecules, a correlation that indicates the anions are tightly coupled to the growth process. This study adds Titan to an increasing list of astrophysical environments where chain anions have been observed and shows that anion chemistry plays a role in the formation of complex organics within a planetary atmosphere as well as in the interstellar medium., Comment: 8 pages, 3 figures, 1 table, Astrophysical Journal Letter accepted June 01 2017

NASA implemented a Participating Scientist Program and released a solicitation for the Mars Atmosphere and Volatile EvolutioN mission (MAVEN) proposals on February 14, 2013. After a NASA peer review panel evaluated the proposals, NASA Headquarters selected nine on June 12, 2013. The program's intent is to enhance the science return from the mission by including new investigations that broaden and/or complement the baseline investigations, while still addressing key science goals. The selections cover a broad range of science investigations. Included are: a patching of a 3D exosphere model to an improved global ionosphere-thermosphere model to study the generation of the exosphere and calculate the escape rates; the addition of a focused study of upper atmosphere variability and waves; improvement of a multi-fluid magnetohydrodynamic model that will be adjusted according to MAVEN observations to enhance the understanding of the solar-wind plasma interaction; a global study of the state of the ionosphere; folding MAVEN measurements into the Mars International Reference Ionosphere under development; quantification of atmospheric loss by pick-up using ion cyclotron wave observations; the reconciliation of remote and in situ observations of the upper atmosphere; the application of precise orbit determination of the spacecraft to measure upper atmospheric density and in conjunction with other Mars missions improve the static gravity field model of Mars; and an integrated ion/neutral study of ionospheric flows and resultant heavy ion escape. Descriptions of each of these investigations are given showing how each adds to and fits seamlessly into MAVEN mission science design.

The Cassini Plasma Spectrometer (CAPS) instrument made measurements of Titan s plasma environment when the Cassini Orbiter flew through the moon s plasma wake October 26,2004 (flyby TA) and December 13,2004 (flyby TB). Preliminary CAPS ion and electron measurements from these encounters (1,2) are compared with measurements made by the Voyager I Plasma Science Instrument (PLS). The comparisons are used to evaluate previous interpretations and predictions of the Titan plasma environment that have been made using PLS measurements (3,4). The plasma wake trajectories of flybys TA, TB and Voyager 1 are similar because they occurred when Titan was near Saturn s local noon. These similarities make possible direct, meaningful comparisons between the various plasma wake measurements. The inquiries stimulated by the previous interpretations and predictions made using PLS data have produced the following results from the CAPS ion measurements: A) The major ambient ion components of Saturn s rotating magnetosphere in the vicinity of Titan are H+, H2+, and O+. B) Finite gyroradius effects are apparent in ambient 0 as the result of its interaction with Titan s atmosphere. C) The principal pickup ions are composed of H+, H2+, CH4+ and N2+. D) There is clear evidence of slowing down of the ambient plasma due to pickup ion mass loading; and, as the ionopause~ is approached, heavier pickup ions such as N2+ become dominant. The similarities and differences between the magnitudes and structures of the electron densities and temperatures along the three flyby trajectories are described

Prior to Cassini s arrival at Saturn, most of what was known about the composition of the plasma in Saturn s environment was derived from limited measurements by Pioneer 11 and Voyager 1 and 2 in 1979-1981[1-3]. The measurements reported here were made by the Cassini Plasma Spectrometer (CAPS) [4] during the first two Cassini orbits, including the closest approach to Saturn and the rings during the tour, and a close flyby of Titan. The CAPS instrument resolves ion energy/charge from 1 V to 50 kV and ion mass/charge from 1 to approx.100 amu/e, and it measures electron energy from 1 eV to 28 keV. Initial composition measurements of Saturn s magnetosphere show that protons dominate outside approx.8 R(sub s), while inside this radius the plasma is dominated by a mix of water-derived ions and N(+). Over the A and B rings a plasma layer is observed composed of O2(+) and O(+) . The close passage near Titan shows a rich network of both positive and negative molecular ions. We report preliminary analysis of these and other composition findings.

Voyager images of the icy satellites of Saturn, Dione and Enceladus, suggest they have been geologically active and are not only composed of ice. Recent observations by HST have shown the presence of ozone at both Dione and Rhea which also implies the presence of molecular oxygen at these bodies. The Cassini Plasma Spectrometer (CAPS) will provide the capability to determine the global composition of these bodies by measuring the pickup ions produced by the ionization of their sputter produced atmospheres. We will present a model of these atmospheres and associated pickup ions and demonstrate CAPS ability to distinguish the freshly produced picked up ions from the ambient plasma. Such ions are expected to form a ring distribution that will have a uniquely different energy-angle dependence than the ambient plasma ions. In the case of Dione we expect the potential for a moderate strength interaction for which both Voyager 1 and Pioneer 11 spacecraft measured ion cyclotron waves centered on the Dione L shell and near the equatorial plane. Since Enceladus may be the source of the E-ring, some surprises may be encountered during its close encounter with the Cassini spacecraft. In the case of Dione we will show that a wake pass at 500 km altitude is more than an order of magnitude better than an upstream pass at 500 km altitude. Pickup ion detection for minor ion species such as NH3+ is possible for 500 km altitude wake pass but not for a 500 km altitude upstream pass at closest approach. For navigation reasons a 100 km pass is not allowed and therefore it is essential to have a wake pass to maximize the science return for a targeted flyby with Dione. The CAPS observations when combined with magnetometer, plasma wave and energetic particle observations will allow us to estimate the source of ions into Saturn's magnetosphere due to these two bodies and to characterize the nature of the interaction with Saturn's magnetosphere.

High-spatial resolution Chandra x-ray observations have demonstrated that most of Jupiter's northern auroral x-rays come from a hot spot located significantly poleward of the latitudes connected to the inner magnetosphere. This hot spot appears fixed in magnetic latitude and longitude and coincides with a region exhibiting anomalous ultraviolet and infrared emissions. The hot spot also exhibited approximately 45 minute quasi-periodic oscillations, a period similar to those reported for high-latitude radio and energetic electron bursts observed by near-Jupiter spacecraft. These results invalidate the idea that jovian auroral x-ray emissions are mainly excited by steady precipitation of energetic heavy ions from the inner magnetosphere. Instead, the x-rays appear to result from currently unexplained processes in the outer magnetosphere that produce highly localized and highly variable emissions over an extremely wide range of wavelengths. The Chandra observations also revealed for the first time x-ray emission (about 0.1 GW) from the Io Plasma Torus, as well as very faint x-ray emission (about 1-2 MW) from the Galilean moons Io, Europa, and possibly Ganymede. The emission from the moons is almost certainly due to Kalpha emission of surface atoms (and possibly impact atoms) excited by the impact of highly energetic protons, oxygen, and sulfur atoms and ions from the Torus. The Torus emission is less well understood at present, although bremsstrahlung from the non-thermal tail of the electron distribution may provide a significant fraction. In any case, further observations, already accepted and in the process of being planned, with Chandra, some with the moderate energy resolution of the CCD camera, together with simultaneous Hubble Space Telescope observations and hopefully ground-based IRTF observations should soon provide greater insight into these various processes.

The {\sl Chandra X-ray Observatory) observed the Jovian system on 25-26 Nov 1999 with the Advanced CCD Imaging Spectrometer (ACIS), in support of the Galileo flyby of Io, and on 18 Dec 2000 with the imaging array of the High Resolution Camera (HRC-I), in support of the Cassini flyby of Jupiter. These sensitive, very high spatial-resolution X-ray observations have revealed that Jupiter's northern x-ray aurora originates at a spot fixed in a coordinate system rotating with the planet at latitude (60--70 deg north) and longitude (160--180 deg System III). Contrary to previous expectations, this location is poleward of the main FUV auroral oval and the foot of the Io Flux Tube, and is apparently connected magnetically to a region of the outer magnetosphere beyond $\sim$30 Jupiter radii. The northern auroral x-ray emission varies with a period $\sim$45 minute and has a an average power of $\sim$1 GW. The earlier view that Jupiter's x-ray aurora resulted from the precipitation of heavy ions from the outer edge of the lo Plasma Torus is now in doubt. Jupiter's disk also emits x-rays with a power of $\sim$2 GW, perhaps resulting from reprocessing of solar x-rays in its atmosphere. These observations reveal for the first time x-ray emission from the Io Plasma Torus, with a power of $\sim$0.1 Gw. The origin of this emission is not currently understood, although bremmstrahlung from non-thermal electrons may play a significant role. Finally, we report the discovery of very faint ($\sim$1--2 MW) soft x-ray emission from the Galilean satellites Io, Europa, and probably Ganymede, most likely as a result of bombardment of their surfaces by energetic ($ greater than $10 keV) H, O, and S ions from the region of the Io Plasma Torus.

The soft x-ray energy band (less than 4 keV) is an important spectral regime for planetary remote sensing, as a wide variety of solar system objects are now known to shine at these wavelengths. These include Earth, Jupiter, comets, moons, Venus, and the Sun. Earth and Jupiter, as magnetic planets, are observed to emanate strong x-ray emissions from their auroral (polar) regions, thus providing vital information on the nature of precipitating particles and their energization processes in planetary magnetospheres. X rays from low latitudes have also been observed on these planets, resulting largely from atmospheric scattering and fluorescence of solar x-rays. Cometary x-rays are now a well established phenomena, more than a dozen comets have been observed at soft x-ray energies, with the accepted production mechanism being charge-exchange between heavy solar wind ions and cometary neutrals. Also, Lunar x-rays have been observed and are thought to be produced by scattering and fluorescence of solar x-rays from the Moon's surface. With the advent of sophisticated x-ray observatories, e.g., Chandra and XMM-Newton, the field of planetary x-ray astronomy is advancing at a much faster pace. The Chandra X-ray Observatory (CXO) has recently captured soft x-rays from Venus. Venusian x-rays are most likely produced through fluorescence of solar x-rays by C and O atoms in the upper atmosphere. Very recently, using CXO we have discovered soft x-rays from the moons of Jupiter-Io, Europa, and probably Ganymede. The plausible source of the x-rays from the Galilean satellites is bombardment of their surfaces by energetic (greater than 10 KeV) ions from the inner magnetosphere of Jupiter. The Io plasma Torus (IPT) is also discovered by CXO to be a source of soft x-rays by CXO have revealed a mysterious pulsating (period approx. 45 minutes) x-ray hot spot is fixed in magnetic latitude and longitude and is magnetically connected to a region in the outer magnetosphere of Jupiter. These surprising results have called into question our understanding of Jovian auroral x-rays. In this paper, we will present a comparative view of the x-ray observations on planets, comets, and moons, with emphasis on recent results from CXO, and discuss the proposed source mechanisms.

X-ray emissions from Jupiter have been observed for over 20 years. Jovian x-ray emissions are associated with high-latitude aurora and with solar fluorescence and/or an energetic particle source at low-latitudes as identified by past Einstein and ROSAT observations. Enhanced auroral x-rays were also observed to be associated with the impact of Comet Shoemaker-Levy 9. The high-latitude x-ray emissions are best explained by energetic sulfur and oxygen ion precipitation from the Jovian magnetosphere, a suggestion that has been confirmed by recent Chandra ACIS observations. Exciting new information about Jovian x-ray emissions has been made possible with Chandra's High Resolution Camera. We report here for the first time the detection of a forty minute oscillation associated with the Jovian x-ray aurora. With the help of ultraviolet auroral observations from Hubble Space Telescope, we pinpoint the auroral mapping of the x-rays and provide new information on the x-ray source mechanism.

Observations of jovian x-rays made with the Earth-orbiting Chandra x-ray observatory on 18 December 2000 in support of the Cassini flyby of Jupiter demonstrate that most of Jupiters northern auroral x-rays come from a hot spot located poleward of the main auroral oval and magnetically connected to a region in the outer magnetosphere beyond 30 jovian radii. The hot spot is fixed in magnetic latitude and longitude and occurs in a region where anomalous infrared1-5and ultraviolet6 emissions have been observed. The auroral x-ray emissions were observed to pulsate with an approximately 40-minute period, a period similar to that reported for high-latitude radio and energetic electron bursts observed by Ulysses7, and by Galileo and Cassini8. These results call into question the prevailing view that the jovian x-ray emissions are excited by the steady precipitation of energetic heavy ions from the outer edge of the Io plasma torus and are forcing a reconsideration of our understanding of the source mechanisms and energetics of the jovian x-ray aurora.

We report the discovery of soft (0.25 - 2 keV) x-ray emission from the moons Io and Europa, probably Ganymede, and from the Io Plasma Torus (IPT). Bombardment by energetic (greater than 10 keV) H, O, and S ions from the region of the IPT seems the likely source of the x-ray emission from the Galilean moons. According to our estimates, fluorescent x-ray emission excited by solar x-rays, even during flares from the active Sun, charge-exchange processes, previously invoked to explain Jupiter's x-ray aurora and cometary x-ray emission, and ion stripping by dust grains fall to account for the observed emission. On the other hand, bremsstrahlung emission of soft X-rays from non-thermal electrons in the few hundred to few thousand eV range may account for a substantial fraction of the observed x-ray flux from the IPT.