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The heaviest chemical elements are naturally produced by the rapid neutron-capture process (r-process) during neutron star mergers or supernovae. The r-process production of elements heavier than uranium (transuranic nuclei) is poorly understood and inaccessible to experiments, so must be extrapolated using nucleosynthesis models. We examine element abundances in a sample of stars that are enhanced in r-process elements. The abundances of elements Ru, Rh, Pd, and Ag (atomic numbers Z = 44 to 47, mass numbers A = 99 to 110) correlate with those of heavier elements (63 <= Z <= 78, A > 150). There is no correlation for neighboring elements (34 <= Z <= 42 and 48 <= Z <= 62). We interpret this as evidence that fission fragments of transuranic nuclei contribute to the abundances. Our results indicate that neutron-rich nuclei with mass numbers >260 are produced in r-process events., Comment: Authors' version of manuscript published in Science on December 07, 2023

We have derived new detailed abundances of Mg, Ca, and the Fe-group elements Sc through Zn (Z = 21-30) for 37 main sequence turnoff very metal-poor stars ([Fe/H] <= -2.1). We analyzed Keck HIRES optical and near-UV high signal-to-noise spectra originally gathered for a beryllium abundance survey. Using typically about 400 Fe-group lines with accurate laboratory transition probabilities for each star, we have determined accurate LTE metallicities and abundance ratios for neutral and ionized species of the 10 Fe-group elements as well as alpha elements Mg and Ca. We find good neutral/ion abundance agreement for the 6 elements that have detectable transitions of both species in our stars in the 3100-5800 Angstrom range. Earlier reports of correlated Sc-Ti-V relative overabundances are confirmed, and appear to slowly increase with decreasing metallicity. To this element trio we add Zn; it also appears to be increasingly overabundant in the lowest metallicity regimes. Co appears to mimic the behavior of Zn, but issues surrounding its abundance reliability cloud its interpretation., Comment: ApJ, in press

We present new observational benchmarks of rapid neutron-capture process (r-process) nucleosynthesis for elements at and between the first (A ~ 80) and second (A ~ 130) peaks. Our analysis is based on archival ultraviolet and optical spectroscopy of eight metal-poor stars with Se (Z = 34) or Te (Z = 52) detections, whose r-process enhancement varies by more than a factor of 30 (-0.22 <= [Eu/Fe] <= +1.32). We calculate ratios among the abundances of Se, Sr through Mo (38 <= Z <= 42), and Te. These benchmarks may offer a new empirical alternative to the predicted solar system r-process residual pattern. The Te abundances in these stars correlate more closely with the lighter r-process elements than the heavier ones, contradicting and superseding previous findings. The small star-to-star dispersion among the abundances of Se, Sr, Y, Zr, Nb, Mo, and Te (<= 0.13 dex, or 26%) matches that observed among the abundances of the lanthanides and third r-process-peak elements. The concept of r-process universality that is recognized among the lanthanide and third-peak elements in r-process-enhanced stars may also apply to Se, Sr, Y, Zr, Nb, Mo, and Te, provided the overall abundances of the lighter r-process elements are scaled independently of the heavier ones. The abundance behavior of the elements Ru through Sn (44 <= Z <= 50) requires further study. Our results suggest that at least one relatively common source in the early Universe produced a consistent abundance pattern among some elements spanning the first and second r-process peaks., Comment: 16 pages, 3 figures, including 4 appendices. Published in the Astrophysical Journal

We present vanadium (V) abundances for 255 metal-poor stars, derived from high-resolution optical spectra from the Magellan Inamori Kyocera Echelle spectrograph on the Magellan Telescopes at Las Campanas Observatory, the Robert G. Tull Coud\'{e} Spectrograph on the Harlan J. Smith Telescope at McDonald Observatory, and the High Resolution Spectrograph on the Hobby-Eberly Telescope at McDonald Observatory. We use updated V I and V II atomic transition data from recent laboratory studies, and we increase the number of lines examined (from 1 to 4 lines of V I, and from 2 to 7 lines of V II). As a result, we reduce the V abundance uncertainties for most stars by more than 20% and expand the number of stars with V detections from 204 to 255. In the metallicity range $-$4.0 $<$ [Fe/H] $< -$1.0, we calculate the mean ratios [V I/Fe I]$ = -0.10 \pm 0.01 (\sigma = 0.16)$ from 128 stars with $\geq$ 2 V I lines detected, [V II/Fe II] $= +0.13 \pm 0.01 (\sigma = 0.16)$ from 220 stars with $\geq$ 2 V II lines detected, and [V II/V I] $= +0.25 \pm 0.01 (\sigma = 0.15)$ from 119 stars. We suspect this offset is due to non-LTE effects, and we recommend using [V II/Fe II], which is enhanced relative to the solar ratio, as a better representation of [V/Fe]. We provide more extensive evidence for abundance correlations detected previously among scandium, titanium, and vanadium, and we identify no systematic effects in the analysis that can explain these correlations., Comment: 19 pages, 15 figures, 4 tables, accepted for publication in ApJ

We have obtained new detailed abundances of the Fe-group elements Sc through Zn (Z=21-30) in three very metal-poor ([Fe/H] $\approx -3$) stars: BD 03 740, BD -13 3442 and CD -33 1173. High-resolution ultraviolet HST/STIS spectra in the wavelength range 2300-3050\AA\ were gathered, and complemented by an assortment of optical echelle spectra. The analysis featured recent laboratory atomic data for number of neutral and ionized species for all Fe-group elements except Cu and Zn. A detailed examination of scandium, titanium, and vanadium abundances in large-sample spectroscopic surveys indicates that they are positively correlated in stars with [Fe/H]<-$2. The abundances of these elements in BD 03 740, BD -13 3442 and CD -33 1173 and HD 84937. (studied in a previous paper of this series) are in accord with these trends and lie at the high end of the correlations. Six elements have detectable neutral and ionized features, and generally their abundances are in reasonable agreement. For Cr we find only minimal abundance disagreement between the neutral (mean of [Cri/Fe]=+0.01) and ionized species (mean of [Crii/Fe]=+0.08), unlike most studies in the past. The prominent exception is Co, for which the neutral species indicates a significant overabundance (mean of [Co/H]=-2.53), while no such enhancement is seen for the ionized species (mean of [Coii/H]=-2.93). These new stellar abundances, especially the correlations among Sc, Ti, and V, suggest that models of element production in early high-mass metal-poor stars should be revisited., Comment: 30 pages, 11 figures. To appear in the Astrophysical Journal

A new moderately r-process-enhanced metal-poor star, RAVE J093730.5-062655, has been identified in the Milky Way halo as part of an ongoing survey by the R-Process Alliance. The temperature and surface gravity indicate that J0937-0626 is likely a horizontal branch star. At [Fe/H] = -1.86, J0937-0626 is found to have subsolar [X/Fe] ratios for nearly every light, alpha, and Fe-peak element. The low [alpha/Fe] ratios can be explained by an ~0.6 dex excess of Fe; J0937-0626 is therefore similar to the subclass of "iron-enhanced" metal-poor stars. A comparison with Milky Way field stars at [Fe/H] = -2.5 suggests that J0937-0626 was enriched in material from an event, possibly a Type Ia supernova, that created a significant amount of Cr, Mn, Fe, and Ni and smaller amounts of Ca, Sc, Ti, and Zn. The r-process enhancement of J0937-0626 is likely due to a separate event, which suggests that its birth environment was highly enriched in r-process elements. The kinematics of J0937-0626, based on Gaia DR2 data, indicate a retrograde orbit in the Milky Way halo; J0937-0626 was therefore likely accreted from a dwarf galaxy that had significant r-process enrichment., Comment: Accepted for publication in the Astrophysical Journal

The production of about half of the heavy elements found in nature is assigned to a specific astrophysical nucleosynthesis process: the rapid neutron capture process (r-process). Although this idea has been postulated more than six decades ago, the full understanding faces two types of uncertainties/open questions: (a) The nucleosynthesis path in the nuclear chart runs close to the neutron-drip line, where presently only limited experimental information is available, and one has to rely strongly on theoretical predictions for nuclear properties. (b) While for many years the occurrence of the r-process has been associated with supernovae, more recent studies have cast substantial doubts on this environment. Alternative scenarios include the mergers of neutron stars, neutron-star black hole mergers, but possibly also rare classes of supernovae as well as hypernovae/collapsars with polar jet ejecta and also accretion disk outflows related to the collapse of fast rotating massive stars with high magnetic fields. Stellar r-process abundance observations, have provided insights into, and constraints on the frequency of and conditions in the responsible stellar production sites. One of them, neutron star mergers, was just identified and related to the Gravitational Wave event GW170817. High resolution observations, increasingly more precise due to improved experimental atomic data, have been particularly important in defining the heavy element abundance patterns of the old halo stars, and thus determining the extent, and nature, of the earliest nucleosynthesis in our Galaxy. Combining new results and important breakthroughs in the related nuclear, atomic and astronomical fields of science, this review attempts to provide an answer to the question "How Were the Elements from Iron to Uranium Made?" (Abridged), Comment: 96 pages, 42 figures, 2 tables, author copy manuscript published in Reviews of Modern Physics

This paper presents the detailed abundances and r-process classifications of 126 newly identified metal-poor stars as part of an ongoing collaboration, the R-Process Alliance. The stars were identified as metal-poor candidates from the RAdial Velocity Experiment (RAVE) and were followed-up at high spectral resolution (R~31,500) with the 3.5~m telescope at Apache Point Observatory. The atmospheric parameters were determined spectroscopically from Fe I lines, taking into account <3D> non-LTE corrections and using differential abundances with respect to a set of standards. Of the 126 new stars, 124 have [Fe/H]<-1.5, 105 have [Fe/H]<-2.0, and 4 have [Fe/H]<-3.0. Nine new carbon-enhanced metal-poor stars have been discovered, 3 of which are enhanced in r-process elements. Abundances of neutron-capture elements reveal 60 new r-I stars (with +0.3<=[Eu/Fe]<=+1.0 and [Ba/Eu]<0) and 4 new r-II stars (with [Eu/Fe]>+1.0). Nineteen stars are found to exhibit a `limited-r' signature ([Sr/Ba]>+0.5, [Ba/Eu]<0). For the r-II stars, the second- and third-peak main r-process patterns are consistent with the r-process signature in other metal-poor stars and the Sun. The abundances of the light, alpha, and Fe-peak elements match those of typical Milky Way halo stars, except for one r-I star which has high Na and low Mg, characteristic of globular cluster stars. Parallaxes and proper motions from the second Gaia data release yield UVW space velocities for these stars which are consistent with membership in the Milky Way halo. Intriguingly, all r-II and the majority of r-I stars have retrograde orbits, which may indicate an accretion origin., Comment: Accepted for publication in the Astrophysical Journal

We report the discovery of a new actinide-boost star, 2MASS J09544277+5246414, originally identified as a very bright (V = 10.1), extremely metal-poor ([Fe/H] = -2.99) K giant in the LAMOST survey, and found to be highly r-process-enhanced (r-II; [Eu/Fe]= +1.28]), during the snapshot phase of the R-Process Alliance (RPA). Based on a high S/N, high-resolution spectrum obtained with the Harlan J. Smith 2.7-m telescope, this star is the first confirmed actinide-boost star found by RPA efforts. With an enhancement of [Th/Eu] = +0.37, 2MASS J09544277+5246414 is also the most actinide-enhanced r-II star yet discovered, and only the sixth metal-poor star with a measured uranium abundance ([U/Fe] = +1.40). Using the Th/U chronometer, we estimate an age of 13.0+/-4.7 Gyr for this star. The unambiguous actinide-boost signature of this extremely metal-poor star, combined with additional r-process-enhanced and actinide-boost stars identified by the RPA, will provide strong constraints on the nature and origin of the r-process at early times., Comment: 8 pages, 3 figures, 2 tables

Neutral Fe lines in metal-poor stars yield conflicting abundances depending on whether and how deviations from local thermodynamic equilibrium (LTE) are considered. We have collected new high resolution and high signal-to-noise ultraviolet (UV) spectra of three warm dwarf stars with [Fe/H] = -2.9 with the Space Telescope Imaging Spectrograph on the Hubble Space Telescope. We locate archival UV spectra for three other warm dwarfs with [Fe/H] = -3.3, -2.2, and -1.6, supplemented with optical spectra for all six stars. We calculate stellar parameters using methods that are largely independent of the spectra, adopting broadband photometry, color-temperature relations, Gaia parallaxes, and assumed masses. We use the LTE line analysis code MOOG to derive Fe abundances from hundreds of Fe I and Fe II lines with wavelengths from 2290 to 6430 Angstroms. The [Fe/H] ratios derived separately from Fe I and Fe II lines agree in all six stars, with [Fe II/H] - [Fe I/H] ranging from +0.00 +/- 0.07 to -0.12 +/- 0.09 dex, when strong lines and Fe I lines with lower excitation potential < 1.2 eV are excluded. This constrains the extent of any deviations from LTE that may occur within this parameter range. While our result confirms non-LTE calculations for some warm, metal-poor dwarfs, it may not be generalizable to more metal-poor dwarfs, where deviations from LTE are predicted to be larger. We also investigate trends of systematically lower abundances derived from Fe I lines in the Balmer continuum region (3100-3700 Angstroms), and we conclude that no proposed explanation for this effect can fully account for the observations presently available., Comment: Accepted for publication in the Astrophysical Journal (18 pages, 4 figures, 9 tables)

We have derived new very accurate abundances of the Fe-group elements Sc through Zn (Z = 21-30) in the bright main-sequence turnoff star HD 84937, based on high-resolution spectra covering the visible and ultraviolet spectral regions. New or recent laboratory transition data for 14 species of seven elements have been used. Abundances from more than 600 lines of non-Fe species have been combined with about 550 Fe lines in HD 84937 to yield abundance ratios of high precision. The abundances have been determined from both neutral and ionized transitions, which generally are in agreement with each other. We find no substantial departures from standard LTE Saha ionization balance in this [Fe/H] = -2.32 star. Noteworthy among the abundances are: [Co/Fe] = 0.14 and [Cu/Fe] = -0.83, in agreement with past studies abundance trends in this and other low metallicity stars; and <[Sc,Ti,V/Fe]> = 0.31, which has not been noted previously. A detailed examination of scandium, titanium, and vanadium abundances in large-sample spectroscopic surveys reveals that they are positively correlated in stars with [Fe/H] < -2; HD 84937 lies at the high end of this correlation. These trends constrain the synthesis mechanisms of Fe-group elements. We also examine the GCE abundance trends of the Fe-group elements, including a new nucleosynthesis model with jet-like explosion effects., Comment: 47 pages, 12 figures; accepted for publication in the Astrophysical Journal

We present an elemental-abundance analysis, in the near-ultraviolet (NUV) spectral range, for the bright carbon-enhanced metal-poor (CEMP) stars HD196944 (V = 8.40, [Fe/H] = -2.41) and HD201626 (V = 8.16, [Fe/H] = -1.51), based on data acquired with the Space Telescope Imaging Spectrograph (STIS) on the Hubble Space Telescope. Both of these stars belong to the sub-class CEMP-s, and exhibit clear over-abundances of heavy elements associated with production by the slow neutron-capture process. HD196944 has been well-studied in the optical region, but we are able to add abundance results for six species (Ge, Nb, Mo, Lu, Pt, and Au) that are only accessible in the NUV. In addition, we provide the first determination of its orbital period, P=1325 days. HD201626 has only a limited number of abundance results based on previous optical work -- here we add five new species from the NUV, including Pb. We compare these results with models of binary-system evolution and s-process element production in stars on the asymptotic giant branch, aiming to explain their origin and evolution. Our best-fitting models for HD 196944 (M1,i = 0.9Mo, M2,i = 0.86Mo, for [Fe/H]=-2.2), and HD 201626 (M1,i = 0.9Mo , M2,i = 0.76Mo , for [Fe/H]=-2.2; M1,i = 1.6Mo , M2,i = 0.59Mo, for [Fe/H]=-1.5) are consistent with the current accepted scenario for the formation of CEMP-s stars., Comment: 25 pages, 13 figures; accepted for publication in ApJ

We report the discovery of nine metal-poor stars with high levels of r-process enhancement (+0.81<[Eu/Fe]<+1.13), including six subgiants and three stars on the red horizontal branch. We also analyze four previously-known r-process-enhanced metal-poor red giants. From this sample of 13 stars, we draw the following conclusions. (1) High levels of r-process enhancement are found in a broad range of stellar evolutionary states, reaffirming that this phenomenon is not associated with a chemical peculiarity of red giant atmospheres. (2) Only 1 of 10 stars observed at multiple epochs shows radial velocity variations, reaffirming that stars with high levels of r-process enhancement are not preferentially found among binaries. (3) Only 2 of the 13 stars are highly-enhanced in C and N, indicating that there is no connection between high levels of r-process enhancement and high levels of C and N. (4) The dispersions in [Sr/Ba] and [Sr/Eu] are larger than the dispersions in [Ba/Eu] and [Yb/Eu], suggesting that the elements below the second r-process peak do not always scale with those in the rare earth domain, even within the class of highly-r-process-enhanced stars. (5) The light-element (12

We use the Space Telescope Imaging Spectrograph on board the Hubble Space Telescope to obtain new high-quality spectra covering the 1900 to 2360 Angstrom wavelength range for two metal-poor stars, HD 108317 and HD 128279. We derive abundances of Cu II, Zn II, As I, Se I, Mo II, and Cd II, which have not been detected previously in either star. Abundances derived for Ge I, Te I, Os II, and Pt I confirm those derived from lines at longer wavelengths. We also derive upper limits from the non-detection of W II, Hg II, Pb II, and Bi I. The mean [As/Fe] ratio derived from these two stars and five others in the literature is unchanged over the metallicity range -2.8 < [Fe/H] < -0.6, <[As/Fe]> = +0.28 +/- 0.14 (std. dev. = 0.36 dex). The mean [Se/Fe] ratio derived from these two stars and six others in the literature is also constant, <[Se/Fe]> = +0.16 +/- 0.09 (std. dev. = 0.26 dex). The As and Se abundances are enhanced relative to a simple extrapolation of the iron-peak abundances to higher masses, suggesting that this mass region (75 < A < 82) may be the point at which a different nucleosynthetic mechanism begins to dominate the quasi-equilibrium alpha-rich freezeout of the iron peak. <[CuII/CuI]> = +0.56 +/- 0.23 in HD 108317 and HD 128279, and we infer that lines of Cu I may not be formed in local thermodynamic equilibrium in these stars. The [Zn/Fe], [Mo/Fe], [Cd/Fe], and [Os/Fe] ratios are also derived from neutral and ionized species, and each ratio pair agrees within the mutual uncertainties, which range from 0.15 to 0.52 dex., Comment: Accepted for publication in the Astrophysical Journal. 13 pages, 10 figures

We present an elemental-abundance analysis, in the near-ultraviolet (NUV) spectral range, for the extremely metal-poor star BD+44 493, a 9th magnitude sub-giant with [Fe/H] = -3.8 and enhanced carbon, based on data acquired with the Space Telescope Imaging Spectrograph on the Hubble Space Telescope. This star is the brightest example of a class of objects that, unlike the great majority of carbon-enhanced metal-poor (CEMP) stars, does not exhibit over-abundances of heavy neutron-capture elements (CEMP-no). In this paper, we validate the abundance determinations for a number of species that were previously studied in the optical region, and obtain strong upper limits for beryllium and boron, as well as for neutron-capture elements from zirconium to platinum, many of which are not accessible from ground-based spectra. The boron upper limit we obtain for BD+44 493, logeps(B) < -0.70, the first such measurement for a CEMP star, is the lowest yet found for very and extremely metal-poor stars. In addition, we obtain even lower upper limits on the abundances of beryllium, logeps(Be) < -2.3, and lead, logeps(Pb) < -0.23 ([Pb/Fe] < +1.90), than those reported by previous analyses in the optical range. Taken together with the previously measured low abundance of lithium, the very low upper limits on Be and B suggest that BD+44 493 was formed at a very early time, and that it could well be a bona-fide second-generation star. Finally, the Pb upper limit strengthens the argument for non-s-process production of the heavy-element abundance patterns in CEMP-no stars., Comment: 18 pages, 12 figures; accepted for publication in ApJ

Elements heavier than the iron group are found in nearly all halo stars. A substantial number of these elements, key to understanding neutron-capture nucleosynthesis mechanisms, can only be detected in the near-ultraviolet. We report the results of an observing campaign using the Space Telescope Imaging Spectrograph on board the Hubble Space Telescope to study the detailed heavy element abundance patterns in four metal-poor stars. We derive abundances or upper limits from 27 absorption lines of 15 elements produced by neutron-capture reactions, including seven elements (germanium, cadmium, tellurium, lutetium, osmium, platinum, and gold) that can only be detected in the near-ultraviolet. We also examine 202 heavy element absorption lines in ground-based optical spectra obtained with the Magellan Inamori Kyocera Echelle Spectrograph on the Magellan-Clay Telescope at Las Campanas Observatory and the High Resolution Echelle Spectrometer on the Keck I Telescope on Mauna Kea. We have detected up to 34 elements heavier than zinc. The bulk of the heavy elements in these four stars are produced by r-process nucleosynthesis. These observations affirm earlier results suggesting that the tellurium found in metal-poor halo stars with moderate amounts of r-process material scales with the rare earth and third r-process peak elements. Cadmium often follows the abundances of the neighboring elements palladium and silver. We identify several sources of systematic uncertainty that must be considered when comparing these abundances with theoretical predictions. We also present new isotope shift and hyperfine structure component patterns for Lu II and Pb I lines of astrophysical interest., Comment: Accepted for publication in the Astrophysical Journal Supplement Series (24 pages, 19 figures, 12 tables)

Using near-ultraviolet spectra obtained with the Space Telescope Imaging Spectrograph onboard the Hubble Space Telescope, we detect neutral tellurium in three metal-poor stars enriched by products of r-process nucleosynthesis, BD+17 3248, HD 108317, and HD 128279. Tellurium (Te, Z=52) is found at the second r-process peak (A=130) associated with the N=82 neutron shell closure, and it has not been detected previously in Galactic halo stars. The derived tellurium abundances match the scaled solar system r-process distribution within the uncertainties, confirming the predicted second peak r-process residuals. These results suggest that tellurium is predominantly produced in the main component of the r-process, along with the rare earth elements., Comment: Accepted for publication in the Astrophysical Journal Letters (5 pages, 2 figures)

Abundance observations indicate the presence of rapid-neutron capture (i.e., r-process) elements in old Galactic halo and globular cluster stars. Recent observations of the r-process-enriched star BD +17 3248 include new abundance determinations for the neutron-capture elements Cd I (Z=48), Lu II (Z = 71) and Os II (Z = 76), the first detections of these elements in metal-poor r-process-enriched halo stars. Combining these and previous observations, we have now detected 32 n-capture elements in BD +17 3248. This is the most of any metal-poor halo star to date. For the most r-process-rich (i.e. [Eu/Fe] ~= 1) halo stars, such as CS 22892-052 and BD +17 3248, abundance comparisons show that the heaviest stable n-capture elements (i.e., Ba and above, Z >= 56) are consistent with a scaled solar system r-process abundance distribution. The lighter n-capture element abundances in these stars, however, do not conform to the solar pattern. These comparisons, as well as recent observations of heavy elements in metal-poor globular clusters, suggest the possibility of multiple synthesis mechanisms for the n-capture elements. The heavy element abundance patterns in most metal-poor halo stars do not resemble that of CS 22892-052, but the presence of heavy elements such as Ba in nearly all metal-poor stars without s-process enrichment indicates that r-process enrichment in the early Galaxy is common., Comment: 16 pages, 7 figures; To appear in the Carnegie Observatories Astrophysics Series, Vol 5: RR Lyrae Stars, Metal-Poor Stars and The Galaxy. ed. A. McWilliam (Pasadena: Carnegie Observatories)

We report the detection of Cd I (Z = 48), Lu II (Z = 71), and Os II (Z = 76) in the metal-poor star BD+173248. These abundances are derived from an ultraviolet spectrum obtained with the Space Telescope Imaging Spectrograph on the Hubble Space Telescope. This is the first detection of these neutron-capture species in a metal-poor star enriched by the r-process. We supplement these measurements with new abundances of Mo I, Ru I, and Rh I derived from an optical spectrum obtained with the High Resolution Echelle Spectrograph on Keck. Combined with previous abundance derivations, 32 neutron-capture elements have been detected in BD+173248, the most complete neutron-capture abundance pattern in any metal-poor star to date. The light neutron-capture elements (38 <= Z <= 48) show a more pronounced even-odd effect than expected from current Solar system r-process abundance predictions. The age for BD+173248 derived from the Th II/Os II chronometer is in better agreement with the age derived from other chronometers than the age derived from Th II/Os I. New Hf II abundance derivations from transitions in the ultraviolet are lower than those derived from transitions in the optical, and the lower Hf abundance is in better agreement with the scaled Solar system r-process distribution., Comment: 6 pages, 4 figures. Accepted for publication in ApJ (Part 2).

We present here the initial results of a new study of massive star yields of Fe-peak elements. We have compiled from the literature a database of carefully determined solar neighborhood stellar abundances of seven iron-peak elements, Ti, V, Cr, Mn, Fe, Co, and Ni and then plotted [X/Fe] versus [Fe/H] to study the trends as functions of metallicity. Chemical evolution models were then employed to force a fit to the observed trends by adjusting the input massive star metallicity-sensitive yields of Kobayashi et al. Our results suggest that yields of Ti, V, and Co are generally larger as well as anticorrelated with metallicity, in contrast to the Kobayashi et al. predictions. We also find the yields of Cr and Mn to be generally smaller and directly correlated with metallicity compared to the theoretical results. Our results for Ni are consistent with theory, although our model suggests that all Ni yields should be scaled up slightly. The outcome of this exercise is the computation of a set of integrated yields, i.e., stellar yields weighted by a slightly flattened time-independent Salpeter initial mass function and integrated over stellar mass, for each of the above elements at several metallicity points spanned by the broad range of observations. These results are designed to be used as empirical constraints on future iron-peak yield predictions by stellar evolution modelers. Special attention is paid to the interesting behavior of [Cr/Co] with metallicity -- these two elements have opposite slopes -- as well as the indirect correlation of [Ti/Fe] with [Fe/H]. These particular trends, as well as those exhibited by the inferred integrated yields of all iron-peak elements with metallicity, are discussed in terms of both supernova nucleosynthesis and atomic physics., Comment: 27 pages, 6 figures; Accepted for Publication in the Astrophysical Journal

The WGLA of the AAS (http://www.aas.org/labastro/) promotes collaboration and exchange of knowledge between astronomy and planetary sciences and the laboratory sciences (physics, chemistry, and biology). Laboratory data needs of ongoing and next generation planetary science missions are carefully evaluated and recommended in this white paper submitted by the WGLA to Planetary Decadal Survey.

We examine the Pb and Th abundances in 27 metal-poor stars (-3.1 < [Fe/H] < -1.4) whose very heavy metal (Z > 56) enrichment was produced only by the rapid (r-) nucleosynthesis process. New abundances are derived from HST/STIS, Keck/HIRES, and VLT/UVES spectra and combined with other measurements from the literature to form a more complete picture of nucleosynthesis of the heaviest elements produced in the r-process. In all cases, the abundance ratios among the rare earth elements and the 3rd r-process peak elements considered (La, Eu, Er, Hf, and Ir) are constant and equivalent to the scaled solar system r-process abundance distribution. We compare the stellar observations with r-process calculations within the classical "waiting-point" approximation. In these computations a superposition of 15 weighted neutron-density components in the range 23 < log(n_n) < 30 is fit to the r-process abundance peaks to successfully reproduce both the stable solar system isotopic distribution and the stable heavy element abundance pattern between Ba and U in low-metallicity stars. Under these astrophysical conditions, which are typical of the "main" r-process, we find very good agreement between the stellar Pb r-process abundances and those predicted by our model. For stars with anomalously high Th/Eu ratios (the so-called actinide boost), our observations demonstrate that any nucleosynthetic deviations from the main r-process affect--at most--only the elements beyond the 3rd r-process peak, namely Pb, Th, and U. Our theoretical calculations also indicate that possible r-process abundance "losses" by nuclear fission are negligible for isotopes along the r-process path between Pb and the long-lived radioactive isotopes of Th and U., Comment: Accepted for publication in the Astrophysical Journal. 22 pages, 10 figures

Laboratory astrophysics and complementary theoretical calculations are the foundations of astronomy and astrophysics and will remain so into the foreseeable future. The mission enabling impact of laboratory astrophysics ranges from the scientific conception stage for airborne and space-based observatories, all the way through to the scientific return of these missions. It is our understanding of the under-lying physical processes and the measurements of critical physical parameters that allows us to address fundamental questions in astronomy and astrophysics. In this regard, laboratory astrophysics is much like detector and instrument development at NASA. These efforts are necessary for the success of astronomical research being funded by NASA. Without concomitant efforts in all three directions (observational facilities, detector/instrument development, and laboratory astrophysics) the future progress of astronomy and astrophysics is imperiled. In addition, new developments in experimental technologies have allowed laboratory studies to take on a new role as some questions which previously could only be studied theoretically can now be addressed directly in the lab. With this in mind we, the members of the AAS Working Group on Laboratory Astrophysics (WGLA), have prepared this White Paper on the laboratory astrophysics infrastructure needed to maximize the scientific return from NASA's space and Earth sciences program., Comment: White Paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the National Academy of Science, Space Sciences Board, Ad Hoc Committee studying "The Role and Scope of Mission-Enabling Activities in NASA's Space and Earth Science Missions"

Laboratory astrophysics and complementary theoretical calculations are the foundations of astronomy and astrophysics and will remain so into the foreseeable future. The impact of laboratory astrophysics ranges from the scientific conception stage for ground-based, airborne, and space-based observatories, all the way through to the scientific return of these projects and missions. It is our understanding of the under-lying physical processes and the measurements of critical physical parameters that allows us to address fundamental questions in astronomy and astrophysics. In this regard, laboratory astrophysics is much like detector and instrument development at NASA, NSF, and DOE. These efforts are necessary for the success of astronomical research being funded by the agencies. Without concomitant efforts in all three directions (observational facilities, detector/instrument development, and laboratory astrophysics) the future progress of astronomy and astrophysics is imperiled. In addition, new developments in experimental technologies have allowed laboratory studies to take on a new role as some questions which previously could only be studied theoretically can now be addressed directly in the lab. With this in mind we, the members of the AAS Working Group on Laboratory Astrophysics, have prepared this State of the Profession Position Paper on the laboratory astrophysics infrastructure needed to ensure the advancement of astronomy and astrophysics in the next decade., Comment: Position paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the State of the Profession (Facilities, Funding and Programs Study Group) of the Astronomy and Astrophysics Decadal Survey (Astro2010)

We have derived new abundances of the rare-earth elements Pr, Dy, Tm, Yb, and Lu for the solar photosphere and for five very metal-poor, neutron-capture r-process-rich giant stars. The photospheric values for all five elements are in good agreement with meteoritic abundances. For the low metallicity sample, these abundances have been combined with new Ce abundances from a companion paper, and reconsideration of a few other elements in individual stars, to produce internally-consistent Ba, rare-earth, and Hf (56<= Z <= 72) element distributions. These have been used in a critical comparison between stellar and solar r-process abundance mixes., Comment: 48 pages, 11 figures, 12 tables: To appear in the Astrophysical Journal Supplement

As the panel on Planetary Systems and Star Formation (PSF) is fully aware, the next decade will see major advances in our understanding of these areas of research. To quote from their charge, these advances will occur in studies of solar system bodies (other than the Sun) and extrasolar planets, debris disks, exobiology, the formation of individual stars, protostellar and protoplanetary disks, molecular clouds and the cold ISM, dust, and astrochemistry. Central to the progress in these areas are the corresponding advances in laboratory astro- physics which are required for fully realizing the PSF scientific opportunities in the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics and chemistry which produce the observed spectra and describe the astrophysical processes. We discuss four areas of laboratory astrophysics relevant to the PSF panel: atomic, molecular, solid matter, and plasma physics. Section 2 describes some of the new opportunities and compelling themes which will be enabled by advances in laboratory astrophysics. Section 3 provides the scientific context for these opportunities. Section 4 discusses some experimental and theoretical advances in laboratory astrophysics required to realize the PSF scientific opportunities of the next decade. As requested in the Call for White Papers, we present in Section 5 four central questions and one area with unusual discovery potential. We give a short postlude in Section 6., Comment: White paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the PSF SFP of the Astronomy and Astrophysics Decadal Survey (Astro2010)

As the Galactic Neighborhood (GAN) panel is fully aware, the next decade will see major advances in our understanding of this area of research. To quote from their charge, these advances will occur in studies of the galactic neighborhood, including the structure and properties of the Milky Way and nearby galaxies, and their stellar populations and evolution, as well as interstellar media and star clusters. Central to the progress in these areas are the corresponding advances in laboratory astrophysics that are required for fully realizing the GAN scientific opportunities within the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics and chemistry that produces the observed astrophysical processes. The 5 areas of laboratory astrophysics that we have identified as relevant to the GAN panel are atomic, molecular, solid matter, plasma, and nuclear physics. In this white paper, we describe in Section 2 some of the new scientific opportunities and compelling scientific themes that will be enabled by advances in laboratory astrophysics. In Section 3, we provide the scientific context for these opportunities. Section 4 briefly discusses some of the experimental and theoretical advances in laboratory astrophysics required to realize the GAN scientific opportunities of the next decade. As requested in the Call for White Papers, Section 5 presents four central questions and one area with unusual discovery potential. Lastly, we give a short postlude in Section 6., Comment: White paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the GAN SFP of the Astronomy and Astrophysics Decadal Survey (Astro2010)

As the Stars and Stellar Evolution (SSE) panel is fully aware, the next decade will see major advances in our understanding of these areas of research. To quote from their charge, these advances will occur in studies of the Sun as a star, stellar astrophysics, the structure and evolution of single and multiple stars, compact objects, SNe, gamma-ray bursts, solar neutrinos, and extreme physics on stellar scales. Central to the progress in these areas are the corresponding advances in laboratory astrophysics, required to fully realize the SSE scientific opportunities within the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics that produces the observed astrophysical processes. The 6 areas of laboratory astrophysics, which we have identified as relevant to the CFP panel, are atomic, molecular, solid matter, plasma, nuclear physics, and particle physics. In this white paper, we describe in Section 2 the scientific context and some of the new scientific opportunities and compelling scientific themes which will be enabled by advances in laboratory astrophysics. In Section 3, we discuss some of the experimental and theoretical advances in laboratory astrophysics required to realize the SSE scientific opportunities of the next decade. As requested in the Call for White Papers, Section 4 presents four central questions and one area with unusual discovery potential. Lastly, we give a short postlude in Section 5., Comment: White paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the SSE SFP of the Astronomy and Astrophysics Decadal Survey (Astro2010)

As the Cosmology and Fundamental Physics (CFP) panel is fully aware, the next decade will see major advances in our understanding of these areas of research. To quote from their charge, these advances will occur in studies of the early universe, the microwave background, the reionization and galaxy formation up to virialization of protogalaxies, large scale structure, the intergalactic medium, the determination of cosmological parameters, dark matter, dark energy, tests of gravity, astronomically determined physical constants, and high energy physics using astronomical messengers. Central to the progress in these areas are the corresponding advances in laboratory astrophysics which are required for fully realizing the CFP scientific opportunities within the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics which produce the observed astrophysical processes. The 5 areas of laboratory astrophysics which we have identified as relevant to the CFP panel are atomic, molecular, plasma, nuclear, and particle physics. Here, Section 2 describes some of the new scientific opportunities and compelling scientific themes which will be enabled by advances in laboratory astrophysics. In Section 3, we provide the scientific context for these opportunities. Section 4 briefly discusses some of the experimental and theoretical advances in laboratory astrophysics required to realize the CFP scientific opportunities of the next decade. As requested in the Call for White Papers, Section 5 presents four central questions and one area with unusual discovery potential. Lastly, we give a short postlude in Section 6., Comment: White paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the CFP SFP of the Astronomy and Astrophysics Decadal Survey (Astro2010)

As the Galaxies across Cosmic Time (GCT) panel is fully aware, the next decade will see major advances in our understanding of these areas of research. To quote from their charge, these advances will occur in studies of the formation, evolution, and global properties of galaxies and galaxy clusters, as well as active galactic nuclei and QSOs, mergers, star formation rate, gas accretion, and supermassive black holes. Central to the progress in these areas are the corresponding advances in laboratory astrophysics that are required for fully realizing the GCT scientific opportunities within the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics that produce the observed astrophysical processes. The 5 areas of laboratory astrophysics that we have identified as relevant to the CFP panel are atomic, molecular, solid matter, plasma, nuclear, and particle physics. In this white paper, we describe in Section 2 some of the new scientific opportunities and compelling scientific themes that will be enabled by advances in laboratory astrophysics. In Section 3, we provide the scientific context for these opportunities. Section 4 briefly discusses some of the experimental and theoretical advances in laboratory astrophysics required to realize the GCT scientific opportunities of the next decade. As requested in the Call for White Papers, Section 5 presents four central questions and one area with unusual discovery potential. Lastly, we give a short postlude in Section 6., Comment: White paper submitted by the AAS Working Group on Laboratory Astrophysics (WGLA) to the GCT SFP of the Astronomy and Astrophysics Decadal Survey (Astro2010)

We present the first detailed abundance analysis of the metal-poor giant HKII 17435-00532. This star was observed as part of the University of Texas long-term project "Chemical Abundances of Stars in the Halo" (CASH). A spectrum was obtained with the High Resolution Spectrograph (HRS) on the Hobby-Eberly Telescope with a resolving power of R~15,000. Our analysis reveals that this star may be located on the red giant branch, red horizontal branch, or early asymptotic giant branch. We find that this metal-poor ([Fe/H]=-2.2) star has an unusually high lithium abundance (log eps (Li)=+2.1), mild carbon ([C/Fe]=+0.7) and sodium ([Na/Fe]=+0.6) enhancement, as well as enhancement of both s-process ([Ba/Fe]=+0.8) and r-process ([Eu/Fe]=+0.5) material. The high Li abundance can be explained by self-enrichment through extra mixing that connects the convective envelope with the outer regions of the H-burning shell. If so, HKII 17435-00532 is the most metal-poor star in which this short-lived phase of Li enrichment has been observed. The Na and n-capture enrichment can be explained by mass transfer from a companion that passed through the thermally-pulsing AGB phase of evolution with only a small initial enrichment of r-process material present in the birth cloud. Despite the current non-detection of radial velocity variations (over ~180 days), it is possible that HKII 17435-00532 is in a long-period or highly-inclined binary system, similar to other stars with similar n-capture enrichment patterns., Comment: 29 pages, 8 figures. Accepted for publication in ApJ. A full version of table 3 is available from the first author upon request

We have derived isotopic fractions of europium, samarium, and neodymium in two metal-poor giants with differing neutron-capture nucleosynthetic histories. These isotopic fractions were measured from new high resolution (R ~ 120,000), high signal-to-noise (S/N ~ 160-1000) spectra obtained with the 2dCoude spectrograph of McDonald Observatory's 2.7m Smith telescope. Synthetic spectra were generated using recent high-precision laboratory measurements of hyperfine and isotopic subcomponents of several transitions of these elements and matched quantitatively to the observed spectra. We interpret our isotopic fractions by the nucleosynthesis predictions of the stellar model, which reproduces s-process nucleosynthesis from the physical conditions expected in low-mass, thermally-pulsing stars on the AGB, and the classical method, which approximates s-process nucleosynthesis by a steady neutron flux impinging upon Fe-peak seed nuclei. Our Eu isotopic fraction in HD 175305 is consistent with an r-process origin by the classical method and is consistent with either an r- or an s-process origin by the stellar model. Our Sm isotopic fraction in HD 175305 suggests a predominantly r-process origin, and our Sm isotopic fraction in HD 196944 is consistent with an s-process origin. The Nd isotopic fractions, while consistent with either r-process or s-process origins, have very little ability to distinguish between any physical values for the isotopic fraction in either star. This study for the first time extends the n-capture origin of multiple rare earths in metal-poor stars from elemental abundances to the isotopic level, strengthening the r-process interpretation for HD 175305 and the s-process interpretation for HD196944., Comment: 40 pages, 16 figures. Accepted for publication in ApJ. Full versions of tables 4 and 5 are available from the first author upon request

Abundances of heavier elements (barium and beyond) in many neutron-capture-element-rich halo stars accurately replicate the solar system r-process pattern. However, abundances of lighter neutron-capture elements in these stars are not consistent with the solar system pattern. These comparisons suggest contributions from two distinct types of r-process synthesis events -- a so called main r-process for the elements above the 2nd r-process peak and a weak r-process for the lighter neutron-capture elements. We have performed r-process theoretical predictions to further explore the implications of the solar and stellar observations. We find that the isotopic composition of barium and the elemental Ba/Eu abundance ratios in r-process-rich low metallicity stars can only be matched by computations in which the neutron densities are in the range 23< log n_n < 28, values typical of the main r-process. For r-process conditions that successfully generate the heavy element pattern extending down to A=135, the relative abundance of I129 produced in this mass region appears to be at least 90% of the observed solar value. Finally, in the neutron number density ranges required for production of the observed solar/stellar 3rd r-process-peak (A~200), the predicted abundances of inter-peak element hafnium (Z=72, A~180) follow closely those of 3rd-peak elements and lead. Hf, observable from the ground and close in mass number to the 3rd r-process-peak elements, might also be utilized as part of a new nuclear chronometer pair, Th/Hf, for stellar age determinations., Comment: 42 pages, 2 tables, 12 figures; To appear in the Astrophysical Journal

Al Cameron, who died recently (October 3, 2005) at 80, was one of the giants in astrophysics. His insights were profound and his interests were wide-ranging. Originally trained as a nuclear physicist, he made major contributions in a number of fields, including nuclear reactions in stars, nucleosynthesis, the abundances of the elements in the Solar System, and the origin of the Solar System and the Moon. In 1957, Cameron and, independently, Burbidge, Burbidge, Fowler and Hoyle, wrote seminal papers on nuclear astrophysics. Most of our current ideas concerning element formation in stars have followed from those two pioneering and historical works. Al also made many contributions in the field of Solar System physics. Particularly noteworthy in this regard was Cameron's work on the formation of the Moon. Al was also a good friend and mentor of young people. Al Cameron will be missed by many in the community both for his scientific contributions and for his friendship., Comment: 8 pages, 6 figures; To appear in the Proceedings of the International Symposium on Nuclear Astrophysics - Nuclei in the Cosmos - IX (2006)

Abundance observations indicate the presence of often surprisingly large amounts of neutron capture (i.e., s- and r-process) elements in old Galactic halo and globular cluster stars. These observations provide insight into the nature of the earliest generations of stars in the Galaxy -- the progenitors of the halo stars -- responsible for neutron-capture synthesis. Comparisons of abundance trends can be used to understand the chemical evolution of the Galaxy and the nature of heavy element nucleosynthesis. In addition age determinations, based upon long-lived radioactive nuclei abundances, can now be obtained. These stellar abundance determinations depend critically upon atomic data. Improved laboratory transition probabilities have been recently obtained for a number of elements. These new gf values have been used to greatly refine the abundances of neutron-capture elemental abundances in the solar photosphere and in very metal-poor Galactic halo stars. The newly determined stellar abundances are surprisingly consistent with a (relative) Solar System r-process pattern, and are also consistent with abundance predictions expected from such neutron-capture nucleosynthesis., Comment: 8 pages, 2 figures, 1 table. To appear in the Proceedings of the NASA Laboratory Astrophysics Workshop in Las Vegas, NV (February 2006)

Employing high resolution spectra obtained with the near-UV sensitive detector on the Keck I HIRES, supplemented by data obtained with the McDonald Observatory 2-d coude, we have performed a comprehensive chemical composition analysis of the bright r-process-rich metal-poor red giant star HD221170. Analysis of 57 individual neutral and ionized species yielded abundances for a total of 46 elements and significant upper limits for an additional five. Model stellar atmosphere parameters were derived with the aid of ~200 Fe-peak transitions. From more than 350 transitions of 35 neutron-capture (Z > 30) species, abundances for 30 neutron-capture elements and upper limits for three others were derived. Utilizing 36 transitions of La, 16 of Eu, and seven of Th, we derive ratios of log epsilon(Th/La) = -0.73 (sigma = 0.06) and log epsilon(Th/Eu) = -0.60 (sigma = 0.05), values in excellent agreement with those previously derived for other r-process-rich metal-poor stars such as CS22892-052, BD+17 3248, and HD115444. Based upon the Th/Eu chronometer, the inferred age is 11.7 +/- 2.8 Gyr. The abundance distribution of the heavier neutron-capture elements (Z >= 56) is fit well by the predicted scaled solar system r-process abundances, as also seen in other r-process-rich stars. Unlike other r-process-rich stars, however, we find that the abundances of the lighter neutron-capture elements (37 < Z < 56) in HD221170 are also statistically in better agreement with the abundances predicted for the scaled solar r-process pattern., Comment: 22 pages, 12 figures (10 colour), 6 tables, accepted by ApJ

Employing spectra obtained with the new Keck I HIRES near-UV sensitive detector, we have performed a comprehensive chemical composition analysis of the binary blue metal-poor star CS29497-030. Abundances for 29 elements and upper limits for an additional seven have been derived, concentrating on elements largely produced via neutron-capture nucleosynthesis. Included in our analysis are the two elements that define the termination point of the slow neutron-capture process, lead and bismuth. We determine an extremely high value of [Pb/Fe] = +3.65 +/- 0.07 (sigma = 0.13) from three features, supporting the single-feature result obtained in previous studies. We also detect Bi for the first time in a metal-poor star. Our derived Bi/Pb ratio is in accord with those predicted from the most recent FRANEC calculations of the slow neutron-capture process in low-mass AGB stars. We find that the neutron-capture elemental abundances of CS29497-030 are best explained by an AGB model that also includes very significant amounts of pre-enrichment of rapid neutron-capture process material in the protostellar cloud out of which the CS29497-030 binary system formed. Thus, CS29497-030 is both an ``r+s'' and ``extrinsic AGB'' star. Furthermore, we find that the mass of the AGB model can be further constrained by the abundance of the light odd-element [Na/Fe] which is sensitive to the neutron excess., Comment: 7 pages = 4 + 2 colour encapsulated postscript figures + 1 table; to appear in ApJ Letters; additional jpeg figure available at ftp://www.astro.caltech.edu/users/iii/cs29497030

We present new abundance determinations of neutron-capture elements Ge, Zr, Os, Ir, and Pt in a sample of 11 metal-poor (-3.1 <= [Fe/H] <= -1.6) Galactic halo giant stars, based on Hubble Space Telescope UV and Keck I optical high-resolution spectroscopy. The stellar sample is dominated by r-process-rich stars such as the well-studied CS 22892-052 and bd+173248, but also includes the r-process-poor, bright giant HD 122563. Our results demonstrate that abundances of the 3rd r-process peak elements Os, Ir and Pt in these metal-poor halo stars are very well-correlated among themselves, and with the abundances of the canonical r-process element Eu (determined in other studies), thus arguing for a common origin or site for r-process nucleosynthesis of heavier (Z>56) elements. However, the large (and correlated) scatters of [Eu,Os,Ir,Pt/Fe] suggests that the heaviest neutron-capture r-process elements are not formed in all supernovae. In contrast, the Ge abundances of all program stars track their Fe abundances, very well. An explosive process on iron-peak nuclei (e.g., the alpha-rich freeze-out in supernovae), rather than neutron capture, appears to have been the dominant synthesis mechanism for this element at low metallicities -- Ge abundances seem completely uncorrelated with Eu., Comment: 35 pages, 5 tables, 7 figures; To appear in the Astrophysical Journal