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There is increasing interest in the role of metal halide perovskites for heterogeneous catalysis. Here, we report a Ge-based 2D perovskite material that shows intrinsic water stability realized through organic cation engineering. Incorporating 4-phenylbenzilammonium (PhBz) we demonstrate, by means of extended experimental and computational results, that PhBz2GeBr4 and PhBz2GeI4 can achieve relevant air and water stability. The creation of composites embedding graphitic carbon nitride (g-C3N4) allows a proof of concept for light-induced hydrogen evolution in an aqueous environment by 2D Ge-based perovskites thanks to the effective charge transfer at the heterojunction between the two semiconductors.

Metal halide perovskites (MHPs), in particular lead-based perovskites, have earned recognized fame in several fields for their outstanding optoelectronic properties, including direct generation of free charge carriers, optimal ambipolar charge carrier transport properties, high absorption coefficient, point-defect tolerance, and compositional versatility. Nowadays, this class of materials represents a real and promising alternative to silicon for photovoltaic technologies. This worthy success led to a growing interest in the exploration of MHPs in other hot research fields, such as solar-driven photocatalytic water splitting towards hydrogen production. Nevertheless, many of these perovskites show air and moisture instability problems that considerably hinder their practical application for photocatalytic water splitting. Moreover, if chemical instability is a problem that can be in part mitigated by the optimization of the chemical composition and crystal structure, the presence of lead represents a real problem for the practical application of MHPs in commercial devices due to environmental and healthcare issues. To successfully overcome these problems, lead-free metal halide perovskites (LFMHPs) have gained increasing interest thanks to their optoelectronic properties, comparable to lead-based materials, and their more eco-friendly nature. Among all the lead-free perovskite alternatives, this mini-review considers bismuth-based perovskites and perovskite derivatives with a specific focus on solar-driven photocatalysis application for H

A forecasting and hazard assessment system for oil dispersion from Italian oil rigs was set up within the framework of a national research project. The system is based on 3D hydrodynamic, mesoscale resolving models providing forcing fields for a Lagrangian module of oil dispersion and slick evolution (oil transport and transformation). The tool provides,daily, the outputs of numerical simulations of possible oil spills from extraction platform sites. In this work we present the results for the 3 platforms closest to the Italian coast. Aside the operational usage, the numerical outputs are also stored and adopted to compute statistics of the slick distributions in the coastal and marine areas of interest. The hazard was assessed by means of two different indices (Hazard Index and Occurrence Index) based on the operational system outputs, for the estimation of the hazard at sea (marine hazard or aerial hazard). As short forecasts (2 days long) often do not allow the oil to reach the coast, an extra set of long-period simulations has been performed in order to compute a third Hazard Index (Coastal Hazard Index) suitable to estimate the hazard along the shorelines.\\ The adopted methodology allowed, as a whole, to assess both coastal and marine oil spill hazard due to oil spill extraction activities. The indices constitute a basic informative layer on which the environmental risk could be also evaluated, once opportunely combined with coastal vulnerability and sensitivity layers.

A high resolution submesoscale resolving ocean model was implemented in a limited area north of Island of Elba where a maritime exercise, named Serious Game 1 (SG1), took place on May 2014 in the framework of the project MEDESS-4MS (Mediterranean Decision Support System for Marine Safety). During the exercise, CTD data have been collected responding to the necessity of a Rapid Environmental Assessment, i.e. to a rapid evaluation of the marine conditions able to provide sensible information for initialisation of modelling tools, in the scenario of possible maritime accidents. The aim of this paper is to evaluate the impact of such mesoscale-resolving CTD observations on short-term forecasts of the surface currents, within the framework of possible oil-spill related emergencies. For this reason, modelling outputs were compared with Lagrangian observations at sea: the high resolution modelled currents, together with the ones of the coarser sub-regional model WMED, are used to force the MEDSLIK-II oil-spill model to simulate drifter trajectories. Both ocean models have been assessed by comparing the prognostic scalar and vector fields as an independent CTD data set and with real drifter trajectories acquired during SG1. The diagnosed and prognosed circulation reveals that the area was characterised by water masses of Atlantic origin influenced by small mesoscale cyclonic and anti-cyclonic eddies, which govern the spatial and temporal evolution of the drifter trajectories and of the water masses distribution. The assimilation of CTD data into the initial conditions of the high resolution model highly improves the accuracy of the short-term forecast in terms of location and structure of the thermocline and positively influence the ability of the model in reproducing the observed paths of the surface drifters.

An operational ocean forecasting system provided numerical predictions on the main hydrodynamics in the seas around Sicily. The system is evaluated using an independent dataset of sea surface tempe...

A twin numerical experiment was conducted in the seas around the island of Sardinia (Western Mediterranean) to assess the impact, at regional and coastal scales, of the use of relative winds (i.e., taking into account ocean surface currents) in the computation of heat and momentum fluxes through standard (Fairall et al., 2003) bulk formulas. The Regional Ocean Modelling System (ROMS) was implemented at 3 km resolution in order to well resolve mesoscale processes, which are known to have a large influence in the dynamics of the area. Small changes (few percent points) in terms of spatially averaged fluxes correspond to quite large differences of such quantities (about 15 %) in spatial terms and in terms of kinetics (more than 20 %). As a consequence, wind power input P is also reduced by ~ 14 % on average. Quantitative validation with satellite SST suggests that such a modification of the fluxes improves the model solution especially in the western side of the domain, where mesoscale activity (as suggested by eddy kinetic energy) is stronger. Surface currents change both in their stable and fluctuating part. In particular, the path and intensity of the Algerian Current and of the Western Sardinia Current (WSC) are impacted by the modification in fluxes. Both total and eddy kinetic energies of the surface current field are reduced in the experiment where fluxes took into account the surface currents. The main dynamical correction is observed in the SW area, where the different location and strength of the eddies influence the path and intensity of the WSC. Our results suggest that, even at local scales and in temperate regions, it would be preferable to take into account such a contribution in flux computations. The modification of the original code, substantially cost-less in terms of numerical computation, improves the model response in terms of surface fluxes (SST validated) and it also likely improves the dynamics as suggested by qualitative comparison with satellite data.

Oil extraction platforms are potential sources of oil spills. For this reason, an oil spill forecasting system was set up to support the management of emergencies from the oil fields in the Italian seas. The system provides ready-to-use products to the relevant response agencies and optimizes the anti-pollution resources by assessing hazards and risks related to this issue. The forecasting system covers seven working oil platforms in the Sicily Channel and middle/low Adriatic Sea. It is composed of a numerical chain involving nested ocean models from regional to coastal spatial scales and an oil spill model. The system provides two online services, one automatic and a second dedicated to possible real emergencies or exercises on risk preparedness and responding. The automatic service produces daily short-term simulations of hypothetical oil spill dispersion, transport, and weathering processes from each extraction platform. Products, i.e., risk maps, animations, and a properly called bulletin, are available on a dedicated web-portal. The hazard estimations are computed by performing geo-statistical analysis on the daily forecasts database. The second service is activated in near-real-time producing oil spill simulations for the following 48 h.

This work explores the importance of considering tidal dynamics when modelling the general circulation in the Messina Strait, a narrow passage connecting the Tyrrhenian and the Ionian subbasins in the Western Mediterranean Sea. The tides and the induced water circulation in this Strait are among the most intense oceanographic processes in the Mediterranean Sea. The quantification of these effects can be particularly relevant for operational oceanographic systems aimed to provide short-term predictions of the main hydrodynamics in the Western Mediterranean subbasins. A numerical approach based on the use of a high-resolution hydrodynamic model was followed to reproduce the tides propagation and the wind-induced and thermohaline water circulation within the Strait and in surrounding areas. A set of numerical simulations was carried out to quantify the role of the Strait dynamics on the larger-scale water circulation. The obtained results confirmed the importance of a correct representation of the hydrodynamics in the Messina Strait even when focusing on predicting the water circulation in the external sea traits. In fact, model results show that tidal dynamics deeply impact the reproduction of the instantaneous and residual circulation pattern, waters thermohaline properties and transport dynamics both inside the Messina Strait and in the surrounding coastal and open waters.

A twin numerical experiment was conducted in the seas of Sardinia (Western Mediterranean) to assess the impact, at coastal scales, of the use of relative winds (i.e. taking into account ocean surface currents) in the computation of heat and momentum fluxes through bulk formulas. The model, the Regional Ocean Modeling System (ROMS), was implemented at 2 km of resolution in order to well resolve (sub-)mesoscale dynamics. Small changes (1–2%) in terms of spatially-averaged fluxes correspond to quite large spatial differences of such quantities (up to 15–20%) and to comparably significant differences in terms of mean velocities of the surface currents. Wind power input of the wind stress to the ocean surface P results also reduced by a 15%, especially where surface currents are stronger. Quantitative validation with satellite SST suggests that such a modification on the fluxes improves the model solution especially in areas of cyclonic circulation, where the heat fluxes correction is predominant in respect to the dynamical correction. Surface currents changes above all in their fluctuating part, while the stable part of the flow show changes mainly in magnitude and less in its path. Both total and eddy kinetic energies of the surface current field results reduced in the experiment where fluxes took into account for surface currents. Dynamically, the largest correction is observed in the SW area where anticyclonic eddies approach the continental slope. This reduction also impacts the vertical dynamics and specifically the local upwelling that results diminished both in spatial extension as well in magnitude. Simulations suggest that, even at local scales and in temperate regions, it is preferable to take into account for such a component in fluxes computation. Results also confirm the tight relationship between local coastal upwelling and eddy-slope interactions in the area.

Il successo delle azioni di mitigazione nell'affrontare gli effetti inquinanti di eventuali sversamenti di idrocarburi in mare è strettamente dipendente dall'efficacia dei sistemi di monitoraggio e di previsione della circolazione marina in ambiente costiero. La previsione delle traiettorie seguite dalle sostanze rilasciate in mare può essere effettuata mediante l'applicazione di algoritmi semi empirici, che partendo dall'intensità dei venti forniscono una stima del percorso seguito dalle masse d'acqua superficiali, oppure mediante l'applicazione di sofisticati modelli matematici/numerici in grado di riprodurre la circolazione delle acque e, quindi, simulare la dispersione delle sostanze in esse disciolte e/o disperse. In questo contesto, il gruppo di Oceanografia Operativa dell'Istituto per l'Ambiente Marino Costiero del Consiglio Nazionale delle Ricerche di Oristano cura la catena operativa di simulazione numerica della circolazione marina tridimensionale ad area limitata a scala sub-regionale per il Mediterraneo Centrale e bacino Occidentale. Nel presente lavoro, supportato nell''ambito del Programma Operativo Nazionale "Ricerca e Competitività" 2007-2013, Progetto "Sviluppo di Tecnologie per la 'Situational Sea Awareness' - TESSA, vengono presentati alcuni scenari di simulazione numerica di trasporto, diffusione e dispersione di idrocarburi in mare, attraverso l'accoppiamento del modello lagrangiano MEDSLIK II nella catena operativa di analisi e previsione numerica della circolazione marina a scala sub-regionale del Gruppo di Oceanografia Operativa di Oristano

In data 9 settembre 2014 il gruppo di oceanografia dell'Istituto per l'Ambiente Marino Costiero (IAMC) di Torregrande (Oristano), del Consiglio Nazionale delle Ricerche (CNR), ha partecipato alla esercitazione di Search and Rescue (SAR) denominata "Squalo 2014". L'esercitazione è stata organizzata e coordinata dalla Direzione Marittima della Guardia Costiera di Cagliari e ha visto la partecipazione di numerosi enti (civili e militari) preposti alle operazioni di salvataggio e/o di supporto logistico. La partecipazione del CNR ha visto come obiettivo specifico la caratterizzazione idrodinamica dell'area di studio utilizzando osservazioni Lagrangiane e modelli numerici di simulazione. L'obiettivo a lungo termine è la ideazione e la realizzazione di un sistema di supporto alle decisioni (Decisional Support System) capace di determinare l'area di ricerca ottimale (area di probabilità). Questo sarà possibile unendo tecniche di simulazione numerica di tipo deterministico (modelli idrodinamici costieri e moduli di dispersione Lagrangiana) con metodi statistici per la stima dell'errore ed il calcolo delle probabilità. Compatibilmente con le risorse disponibili (finanziarie, computazionali ed umane), l'intenzione è di proseguire la ricerca iniziata nel corso della esercitazione, testando un modello SAR denominato "Leeway" che ha le potenzialità per consentire lo sviluppo del suddetto DSS