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Il progetto per un memoriale al Climat de France di Algeri comporta la lettura, scomposizione e ricomposizione delle forme archetipiche dell’edificio di Fernand Pouillon. Dagli elementi dati e riconosciuti, l’obiettivo è creare una nuova composizione formale contenuta all’interno della corte, cuore della comunità che abita l’edificio. Il posizionamento nel centro della monumentale piazza delle Duecento Colonne riporta lo spazio nella vita quotidiana degli abitanti: il memoriale non è oggetto di contemplazione, ma elemento spaziale accessibile, vivo e malleabile, in cui i fruitori lasciano il loro segno con la continua riappropriazione dello spazio. Il progetto è un anti-monumento, ribaltando il rapporto oggetto/osservatore attraverso una lettura archeologica dell’architettura.

As a rapidly expanding family of 2D materials, MXenes have recently gained considerable attention. Herein, by developing a coating method that enables transfer‐free and layer‐by‐layer film coating, the nonlinear optical absorption (NOA) of Ti3C2Tx MXene films is investigated. Using the Z‐scan technique, the NOA of the MXene films is characterized at ≈800 nm. The results show that there is a strong and layer‐dependent NOA behavior, transitioning from reverse saturable absorption (RSA) to saturable absorption (SA) as the layer number increases from 5 to 30. Notably, the nonlinear absorption coefficient β changes significantly from ≈7.13 × 102 cm GW−1 to ≈−2.69 × 102 cm GW−1 within this range. The power‐dependent NOA of the MXene films is also characterized, and a decreasing trend in β is observed for increasing laser intensity. Finally, the NOA of 2D MXene films at ≈1550 nm is characterized by integrating them onto silicon nitride waveguides, where an SA behavior is observed for the films including 5 and 10 layers of MXene, in contrast to the RSA observed at ≈800 nm. These results reveal intriguing nonlinear optical properties of 2D MXene films, highlighting their versatility and potential for implementing high‐performance nonlinear photonic devices.

L’articolo indaga le ragioni del profondo impatto che le “rivoluzioni colorate” dei primi anni Duemila hanno avuto sulle percezioni politico-strategiche della Russia. Lo scopo del lavoro è quello di mettere in evidenza alcuni aspetti delle “rivoluzioni colorate” suscettibili di rafforzare la tendenza della Russia ad attribuire alle potenze occidentali intenzioni ostili nei suoi confronti, in particolare l’attivismo in Georgia e Ucraina di ONG occidentali già coinvolte nel political warfare condotto dagli Stati Uniti in Polonia negli anni di Reagan (sostegno a Solidarnošc) e ancora in Serbia nel dopo-Guerra fredda (aiuti alle opposizioni attive nel rovesciamento di Slobodan Miloševic nel 2000). L’articolo mostra come le locuzioni “rivoluzione colorata” e “guerra ibrida” siano diventate sinonimi nel recente discorso strategico russo, e come il political warfare statunitense in Polonia e il rovesciamento di Miloševic in Serbia vengano considerati dai russi come dei precedenti delle “rivoluzioni colorate”.

Optical parametric amplification (OPA) represents a powerful solution to achieve broadband amplification in wavelength ranges beyond the scope of conventional gain media, for generating high-power optical pulses, optical microcombs, entangled photon pairs and a wide range of other applications. Here, we demonstrate optical parametric amplifiers based on silicon nitride (Si3N4) waveguides integrated with two-dimensional (2D) layered graphene oxide (GO) films. We achieve precise control over the thickness, length, and position of the GO films using a transfer-free, layer-by-layer coating method combined with accurate window opening in the chip cladding using photolithography. Detailed OPA measurements with a pulsed pump for the fabricated devices with different GO film thicknesses and lengths show a maximum parametric gain of ~24.0 dB, representing a ~12.2 dB improvement relative to the device without GO. We perform a theoretical analysis of the device performance, achieving good agreement with experiment and showing that there is substantial room for further improvement. This work represents the first demonstration of integrating 2D materials on chips to enhance the OPA performance, providing a new way of achieving high performance photonic integrated OPA by incorporating 2D materials.

This paper investigates the applicability of organic and inorganic thermal parameters in a range of thermal conditions, from diagenesis to epizone, and in HP LT settings within the framework of continental subduction and exhumation in the southern Apennines, where independent thermobarometric constraints are available. Two juxtaposed tectonic units, the HP--LT Lungro--Verbicaro Unit (in the hanging wall) and the non-metamorphic Pollino--Ciagola Unit (in the footwall) have been analysed. For the Lungro--Verbicaro Unit, clay mineral thermal parameters and vitrinite reflectance underestimate metamorphic conditions (constrained by petrology), suggesting that, in relatively HP units, these indicators are 'retarded' and strongly depend on P--Tevolution through time. On the other hand, the K-white mica b cell dimension provides a robust estimate of peak pressure. Fluid inclusion textures indicate a fast isothermal decompression during exhumation. Two-phase inclusions from early stage syntectonic veins were trapped after isothermal exhumation at a pressure of 0.3 GPa. For the Pollino--Ciagola Unit, the correlation of analysed parameters effectively unravels the thermal evolution, with maximum palaeotemperatures of c. 150[degrees]C. Apatite fission tracks provide details of the final stages of exhumation, indicating that both units were coherently exhumed in the Late Miocene, following the tectonic emplacement of the Lungro--Verbicaro Unit on top of the Pollino--Ciagola Unit. Supplementary material: X-ray diffraction data (whole-rock composition, quantitative analysis of the doi: 10.1144/0016-76492009-137.

In the southern Apennines fold-and-thrust belt, thermal indicators record exhumation of sedimentary units from depths locally in excess of 5 km. The thrust belt is made of allochthonous sedimentary units that overlie a 6-8-km-thick, carbonate footwall succession. The latter, continuous with the foreland Apulian Platform, is deformed by reverse faults involving the underlying basement. Therefore, a switch from thin-skinned to thick-skinned thrusting occurred as the Apulian Platform carbonates--and the underlying thick continental lithosphere--were deformed during the latest shortening stages. Apatite fission track data, showing cooling ages ranging between 9.2 [+ or -] 1.0 and 1.5 [+ or -] 0.8 Ma, indicate that exhumation marks these late tectonic stages, probably initiating with the buttressing of the allochthonous wedge against the western margin of the Apulian Platform. Pliocene-Pleistocene foreland advancing of the allochthonous units exceeds the total amount of slip that, based on cross-section balancing and restoration, could be transferred to the base of the allochthon from the underlying thick-skinned structures. This suggests that emplacement of the allochthon above the western portion of the Apulian Platform carbonates was followed by gravitational readjustments within the allochthonous wedge, coeval--and partly associated with--thick-skinned shortening at depth. The related denudation processes are interpreted to have played a primary role in tectonic exhumation. Keywords: low-temperature thermochronology, thin-skinned thrusting, thick-skinned thrusting, gravitational instability, extensional faulting.

The alternative relationships thai can exist between a mountain from and the adjacent foreland basin have been recognized liar many years. However, seismic reflection data from such areas are commonly of poor quality and therefore structural models may contain large uncertainties. In view of scientific and commercial interest in mountain belts, we have reviewed the methods for discriminating between alternative interpretations using a case study from the Montagna dei Fiori in the central Apennines, Italy. In this area Mesozoic and Tertiary carbonate sediments arc juxtaposed with a foredeep basin containing up to 7 km of Messinian and Plio-Pleistocene siliciclastic sediments. A new structural model liar this area demonstrates how the structures in this area form a kinematically closed system in which displacement is transferred from the thrust belt to blind structures beneath the present-day foreland. Growth strata show that Pliocene shortening was initially rapid (15 mm [a.sup.-1] followed by slower rates during the final stages of deformation. Variations in structural elevation indicate a component of basement involvement during thrusting, and this is further supported by magnetic modelling. The results illustrate the interaction of thin- and thick-skinned structures in the central Apennines, and the methods for discriminating between alternative structural models.

Biopolymers obtained from renewable resources are an interesting alternative to conventional polymers obtained from fossil resources, as they are sustainable and environmentally friendly. Poly(lactic acid) (PLA) is a biodegradable aliphatic polyester produced from 100% renewable plant resources and plays a key role in the biopolymer market, and is experiencing ever-increasing use worldwide. Unfortunately, this biopolymer has some usage limitations when compared with traditional polymers; therefore, blending it with other biopolymers, such as poly(butylene succinate) (PBS), poly(butylene succinate-co-butylene adipate) (PBSA), poly(butylene adipate-co-butylene terephthalate) (PBAT) and different poly(hydroxyalkanoates) (PHA), is considered an interesting method to improve it significantly, customize its properties and extend the range of its applications. The following review highlights, in its first part, the physico-chemical and mechanical properties of PLA in comparison to the other biopolymers listed above, highlighting the various drawbacks of PLA. The second part of the review deals with recent developments, results, and perspectives in the field of PLA-based blends.

The Alto Molise area belongs to the Apennine orogenic belt, which has been developing since the Late Cretaceous as a result of the Europe-Africa collision. This area is characterized by the complex superposition of different palaeogeographic domains that developed during the Mesozoic along the passive southern margin of Tethys Ocean. These domains have been subdivided into four main structural units; from shallowest to deepest they are: the Sannio pelagic basin, the Latium-Abruzzi carbonate platform, the Molise pelagic basin and the Apulia carbonate platform Units. Until the present study, the tectonic relationship among these units was thought to have been mainly determined by Early Messinian to Late Pliocene thrusting. This paper reports the results of a new geometric and kinematic analysis of the Alto Molise area. This new interpretation of the Alto Molise structural style indicates that strike-slip tectonics played a primary role during post-Pliocene times, greatly modifying the previous Alto Molise thrust structures. Two main tectonic events are recorded, consisting of the Pliocene thrusting of the Molise domain onto the Apulia platform followed by the post-Pliocene disruption and rotation of the pre-existing compressional structures by N-S-oriented, high-angle, right-lateral strike-slip faults. These faults are manifest in the Apulia platform as narrow shear zones, but propagate towards the surface into wider belts of strike-slip and oblique-slip deformation. We have compared our results with published structural, palaeomagnetic and anisotropy of magnetic susceptibility (AMS) data from the Central Apennines. This comparison suggests that the superposition of the younger strike-slip tectonic deformation on the older fold and thrust structures in the Alto Molise area is consistent with block-rotation of a segmented orogen, applied to the whole Apennine system. Keywords: Pliocene, Pleistocene, Italy, Apennines, orogeny, strike-slip faults.

Ultrasound (US) is the primary tool for evaluating patients with thyroid nodules, and the risk of malignancy assessed is based on US features. These features help determine which patients require fine-needle aspiration (FNA) biopsy. Classification systems for US features have been developed to facilitate efficient interpretation, reporting, and communication of thyroid US findings. These systems have been validated by numerous studies and are reviewed in this article. Additionally, this overview provides a comprehensive description of the clinical and laboratory evaluation of patients with thyroid nodules, various imaging modalities, grayscale US features, color Doppler US, contrast-enhanced US (CEUS), US elastography, FNA biopsy assessment, and the recent introduction of molecular testing. The potential of artificial intelligence in thyroid US is also discussed.

Cities all over the world have developed on different geological-geomorphological substrates. Different kinds of human activities have operated for millennia as geomorphic agents, generating numerous and various erosion landforms and huge anthropogenic deposits. Considering the increasing demand for land and the expansion of the built-up areas involving and disturbing any kind of natural system inside and surrounding the actual urban areas, it is not negligible how important the dynamics of the urban environment and its physical evolution are. In this context, this manuscript addresses insights into eight case studies of urban geomorphological analyses of cities in Italy, Greece, and Brazil. The studies are based on surveying and mapping geomorphological processes and landforms in urban areas, supporting both geo-hazard assessment, historical evolution, and paleomorphologies, as well as disseminating knowledge of urban geoheritage and educating about the anthropogenic impact on urban sustainability. We hypothesize that urban geomorphological analysis of several case studies addresses the physical environment of modern cities in a multi-temporal, multidisciplinary, and critical way concerning global changes. Thus, this study aims to illustrate and propose a novel approach to urban geomorphological investigation as a model for the understanding and planning of the physical urban environment on a European and global scale.

Atypical deployment of social gaze is present early on in toddlers with autism spectrum disorders (ASDs). Yet, studies characterizing the developmental dynamic behind it are scarce. Here, we used a data-driven method to delineate the developmental change in visual exploration of social interaction over childhood years in autism. Longitudinal eye-tracking data were acquired as children with ASD and their typically developing (TD) peers freely explored a short cartoon movie. We found divergent moment-to-moment gaze patterns in children with ASD compared to their TD peers. This divergence was particularly evident in sequences that displayed social interactions between characters and even more so in children with lower developmental and functional levels. The basic visual properties of the animated scene did not account for the enhanced divergence. Over childhood years, these differences dramatically increased to become more idiosyncratic. These findings suggest that social attention should be targeted early in clinical treatments.

The WWOX gene encodes a 414-amino-acid protein composed of two N-terminal WW domains and a C-terminal short-chain dehydrogenase/reductase (SDR) domain. WWOX protein is highly conserved among species and mainly expressed in the cerebellum, cerebral cortex, brain stem, thyroid, hypophysis, and reproductive organs. It plays a crucial role in the biology of the central nervous system, and it is involved in neuronal development, migration, and proliferation. Biallelic pathogenic variants in WWOX have been associated with an early infantile epileptic encephalopathy known as WOREE syndrome. Both missense and null variants have been described in affected patients, leading to a reduction in protein function and stability. The most severe WOREE phenotypes have been related to biallelic null/null variants, associated with the complete loss of function of the protein. All affected patients showed brain anomalies on magnetic resonance imaging (MRI), suggesting the pivotal role of WWOX protein in brain homeostasis and developmental processes. We provided a literature review, exploring both the clinical and radiological spectrum related to WWOX pathogenic variants, described to date. We focused on neuroradiological findings to better delineate the WOREE phenotype with diagnostic and prognostic implications.