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Accumulation of microplastics (MPs) in aquatic environments is an issue of emerging concern. After research initially focused on marine systems, more and more studies have been published investigating the abundance of MPs in freshwater environments in recent years.The objective of our research is to examine, whether the Mulde river represents an input pathway for MP particles to the Elbe discharge system. Our hypothesis is that the chemical industries located in the catchment area of the Mulde act as a discharge source of primary MPs which are subsequently transported downstream towards the Elbe. Accordingly, there should be more (primary) MPs just downstream of the river mouth, compared to upstream. Therefore, 2 sediment samples and 18 water samples from the Elbe river upstream and downstream the Mulde confluence were taken and analysed on their MP contents.To extract MPs, sample preparation requires various steps including drying, size-fractionation, reduction of organic matter and density separation. The gained fractions are then filtered through glass microfibres paper using a vacuum pump. The dried filters are photographed and examined for MPs under a digital microscope. Representative particles are picked and measured. Finally, we determine their polymer type by pyrolysis or µFTIR.A key result is that both, sediment and water samples, show a substantial increase in primary MPs (especially spheres) just downstream the mouth of the Mulde. Regarding the sampling technique of water samples, we observe differences in the amount and shape of MP particles between filter cascades and filter nets.

Aquatic ecosystems are globally contaminated with microplastics (MP). However, comparative data on MP levels in freshwater systems is still scarce. Therefore, the aim of this study is to quantify MP abundance in water and sediment of the German river Elbe using visual, spectroscopic (Fourier-transform infrared spectroscopy) and thermo analytical (pyrolysis gas chromatography mass spectrometry) methods. Samples from eleven German sites along the German part of the Elbe were collected, both in the water and sediment phase, in order to better understand MP sinks and transport mechanisms. MP concentrations differed between the water and sediment phase. Sediment concentrations (mean: 3,350,000 particles m−3, 125–5000 μm MP) were in average 600,000-fold higher than water concentrations (mean: 5.57 particles m−3, 150–5000 μm MP). The abundance varied between the sampling sites: In sediments, the abundance decreased in the course of the river while in water samples no such clear trend was observed. This may be explained by a barrage retaining sediments and limiting tidal influence in the upstream parts of the river. Particle shape differed site-specifically with one site having exceptionally high quantities of spheres, most probably due to industrial emissions of PS-DVB resin beads. Suspended MP consisted predominantly of polyethylene and polypropylene whereas sediments contained a higher diversity of polymer types. Determined MP concentrations correspond well to previous results from other European rivers. In a global context, MP levels in the Elbe relate to the lower (water) to middle section (sediment) of the global range of MP concentrations determined for rivers worldwide. This highlights that elevated MP levels are not only found in single countries or continents, but that MP pollution is an issue of global concern.