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We present a full analysis of a broadband spectral line survey of Sagittarius B2 (Main), one of the most chemically rich regions in the Galaxy located within the giant molecular cloud complex Sgr B2 in the Central Molecular Zone. Our goal is to derive the molecular abundances and temperatures of the high-mass star-forming region Sgr B2(M) and thus its physical and astrochemical conditions. Sgr B2(M) was observed using the Heterodyne Instrument for the Far-Infrared (HIFI) on board the Herschel Space Observatory in a spectral line survey from 480 to 1907 GHz at a spectral resolution of 1.1 MHz, which provides one of the largest spectral coverages ever obtained toward this high-mass star-forming region in the submillimeter with high spectral resolution and includes frequencies > 1 THz unobservable from the ground. We model the molecular emission from the submillimeter to the far-IR using the XCLASS program. For each molecule, a quantitative description was determined taking all emission and absorption features of that species across the entire spectral range into account. Additionally, we derive velocity resolved ortho / para ratios for those molecules for which ortho and para resolved molecular parameters are available. Finally, the temperature and velocity distributions are analyzed and the derived abundances are compared with those obtained for Sgr B2(N) from a similar HIFI survey. A total of 92 isotopologues were identified, arising from 49 different molecules, ranging from free ions to complex organic compounds and originating from a variety of environments from the cold envelope to hot and dense gas within the cores. Sulfur dioxide, methanol, and water are the dominant contributors. For the ortho / para ratios we find deviations from the high temperature values between 13 and 27 %. In total 14 % of all lines remain unidentified., Comment: 67 pages, 102 figures, submitted to A&A

The high-mass star forming sites SgrB2(M) and SgrB2(N) have been the target of numerous studies, revealing e.g. a rich chemistry. We want to characterize their physical and chemical structure using ALMA high-angular resolution observations at mm wavelengths, reaching spatial scales of about 4000 au, and covering the whole band 6 (from 211 to 275 GHz). In order to determine the continuum emission in line-rich sources, we use a new statistical method: STATCONT. We detect 27 continuum sources in SgrB2(M) and 20 in SgrB2(N). We study the continuum emission across the ALMA band 6, and compare it with previous SMA 345 GHz and VLA 40 GHz observations, to study the nature of the sources detected. The brightest sources are dominated by (partially optically thick) dust emission, while there is an important degree of contamination from ionized gas free-free emission in weaker sources. While the total mass in SgrB2(M) is distributed in many fragments, most of the mass in SgrB2(N) arises from a single object, with filamentary-like structures converging towards the center. There seems to be a lack of low-mass dense cores in both regions. We determine H2 volume densities for the cores of about 10^5-10^7 Msun pc^-3, one to two orders of magnitude higher than the stellar densities of super star clusters. In general, SgrB2(N) is chemically richer than SgrB2(M). There seems to be a correlation between the chemical richness and the mass of the fragments, with more massive clumps being more chemically rich. Both SgrB2(N) and SgrB2(M) harbour a cluster of hot molecular cores. We compare the continuum images with predictions from a detailed 3D radiative transfer model that reproduces the structure of SgrB2 from 45 pc down to 100 au. This dataset, together with ongoing projects in the range 5 to 200 GHz, better constrain the 3D structure of SgrB2, and allow us to understand its physical and chemical structure., Comment: Accepted for publication in Astronomy & Astrophysics. 20 pages with 13 figures and 4 tables, plus Appendices with extra figures and tables. (Abstract modified)

We model the dust and free-free continuum emission in the high-mass star-forming region Sagittarius B2 in order to reconstruct the three-dimensional density and dust temperature distribution, as a crucial input to follow-up studies of the gas velocity field and molecular abundances. We employ the three-dimensional radiative transfer program RADMC-3D to calculate the dust temperature self-consistently, provided a given initial density distribution. This density distribution of the entire cloud complex is then recursively reconstructed based on available continuum maps, including both single-dish and high-resolution interferometric maps covering a wide frequency range (40 GHz - 4 THz). The model covers spatial scales from 45 pc down to 100 au, i.e. a spatial dynamic range of 10^5. We find that the density distribution of Sagittarius B2 can be reasonably well fitted by applying a superposition of spherical cores with Plummer-like density profiles. In order to reproduce the spectral energy distribution, we position Sgr B2(N) along the line of sight behind the plane containing Sgr B2(M). We find that the entire cloud complex comprises a total gas mass of 8.0 x 10^6 Msun within a diameter of 45 pc, corresponding to an averaged gas density of 170 Msun/pc^3. We estimate stellar masses of 2400 Msun and 20700 Msun and luminosities of 1.8 x 10^6 Lsun and 1.2 x 10^7 Lsun for Sgr B2(N) and Sgr B2(M), respectively. We report H_2 column densities of 2.9 x 10^24 cm^-2 for Sgr B2(N) and 2.5 x 10^24 cm^-2 for Sgr B2(M) in a 40" beam. For Sgr B2(S), we derive a stellar mass of 1100 Msun, a luminosity of 6.6 x 10^5 Lsun and a H_2 column density of 2.2 x 10^24 cm^-2 in a 40" beam. We calculate a star formation efficiency of 5% for Sgr B2(N) and 50% for Sgr B2(M), indicating that most of the gas content in Sgr B2(M) has already been converted to stars or dispersed., Comment: Accepted for publication in A&A. 30 pages, 24 figures, 6 tables

We investigate the physical and chemical processes at work during the formation of a massive protostar based on the observation of water in an outflow from a very young object previously detected in H2 and SiO in the IRAS 17233-3606 region. We estimated the abundance of water to understand its chemistry, and to constrain the mass of the emitting outflow. We present new observations of shocked water obtained with the HIFI receiver onboard Herschel. We detected water at high velocities in a range similar to SiO. We self-consistently fitted these observations along with previous SiO data through a state-of-the-art, one-dimensional, stationary C-shock model. We found that a single model can explain the SiO and H2O emission in the red and blue wings of the spectra. Remarkably, one common area, similar to that found for H2 emission, fits both the SiO and H2O emission regions. This shock model subsequently allowed us to assess the shocked water column density, N(H2O)=1.2x10^{18} cm^{-2}, mass, M(H2O)=12.5 M_earth, and its maximum fractional abundance with respect to the total density, x(H2O)=1.4x10^{-4}. The corresponding water abundance in fractional column density units ranges between 2.5x10^{-5} and 1.2x10^{-5}, in agreement with recent results obtained in outflows from low- and high-mass young stellar objects., Comment: accepted for publication as a Letter in Astronomy and Astrophysics

We present new observations of the (6,6) and (9,9) inversion transitions of the hydronium ion toward Sagittarius B2(N) and W31C. Sensitive observations toward Sagittarius B2(N) show that the high, ~ 500 K, rotational temperatures characterizing the population of the highly-excited metastable H3O+ rotational levels are present over a wide range of velocities corresponding to the Sagittarius B2 envelope, as well as the foreground gas clouds between the Sun and the source. Observations of the same lines toward W31C, a line of sight that does not intersect the Central Molecular Zone, but instead traces quiescent gas in the Galactic disk, also imply a high rotational temperature of ~ 380 K, well in excess of the kinetic temperature of the diffuse Galactic interstellar medium. While it is plausible that some fraction of the molecular gas may be heated to such high temperatures in the active environment of the Galactic center, characterized by high X-ray and cosmic ray fluxes, shocks and high degree of turbulence, this is unlikely in the largely quiescent environment of the Galactic disk clouds. We suggest instead that the highly-excited states of the hydronium ion are populated mainly by exoergic chemical formation processes and temperature describing the rotational level population does not represent the physical temperature of the medium. The same arguments may be applicable to other symmetric top rotors, such as ammonia. This offers a simple explanation to the long-standing puzzle of the presence of a pervasive, hot molecular gas component in the central region of the Milky Way. Moreover, our observations suggest that this is a universal process, not limited to the active environments associated with galactic nuclei., Comment: Accepted for publication in The Astrophysical Journal, 10 pages, 4 figures, 3 tables

Aims. The aim of this paper is to study deuterated water in the solar-type protostars NGC1333 IRAS4A and IRAS4B, to compare their HDO abundance distribution with other star-forming regions, and to constrain their HDO/H2O ratios. Methods. Using the Herschel/HIFI instrument as well as ground-based telescopes, we observed several HDO lines covering a large excitation range (Eup/k=22-168 K) towards these protostars and an outflow position. Non-LTE radiative transfer codes were then used to determine the HDO abundance profiles in these sources. Results. The HDO fundamental line profiles show a very broad component, tracing the molecular outflows, in addition to a narrower emission component and a narrow absorbing component. In the protostellar envelope of NGC1333 IRAS4A, the HDO inner (T>100 K) and outer (T<100 K) abundances with respect to H2 are estimated at 7.5x10^{-9} and 1.2x10^{-11}, respectively, whereas, in NGC1333 IRAS4B, they are 1.0x10^{-8} and 1.2x10^{-10}, respectively. Similarly to the low-mass protostar IRAS16293-2422, an absorbing outer layer with an enhanced abundance of deuterated water is required to reproduce the absorbing components seen in the fundamental lines at 465 and 894 GHz in both sources. This water-rich layer is probably extended enough to encompass the two sources as well as parts of the outflows. In the outflows emanating from NGC1333 IRAS4A, the HDO column density is estimated at about (2-4)x10^{13} cm^{-2}, leading to an abundance of about (0.7-1.9)x10^{-9}. An HDO/H2O ratio between 7x10^{-4} and 9x10^{-2} is derived in the outflows. In the warm inner regions of these two sources, we estimate the HDO/H2O ratios at about 1x10^{-4}-4x10^{-3}. This ratio seems higher (a few %) in the cold envelope of IRAS4A, whose possible origin is discussed in relation to formation processes of HDO and H2O., Comment: 16 pages, 13 figures

We present Herschel/HIFI observations of 30 transitions of water isotopologues toward the high-mass star forming region NGC 6334 I. The line profiles of H_2^{16}O, H_2^{17}O, H_2^{18}O, and HDO show a complex pattern of emission and absorption components associated with the embedded hot cores, a lower-density envelope, two outflow components, and several foreground clouds, some associated with the NGC 6334 complex, others seen in projection against the strong continuum background of the source. Our analysis reveals an H2O ortho/para ratio of 3 +/- 0.5 in the foreground clouds, as well as the outflow. The water abundance varies from ~10^{-8} in the foreground clouds and the outer envelope to ~10^{-6} in the hot core. The hot core abundance is two orders of magnitude below the chemical model predictions for dense, warm gas, but within the range of values found in other Herschel/HIFI studies of hot cores and hot corinos. This may be related to the relatively low gas and dust temperature (~100 K), or time dependent effects, resulting in a significant fraction of water molecules still locked up in dust grain mantles. The HDO/H_2O ratio in NGC 6334 I, ~2 10^{-4}, is also relatively low, but within the range found in other high-mass star forming regions., Comment: To appear in the Astrophysical Journal; 15 pages, 10 figures, 7 tables

We aim at deriving the molecular abundances and temperatures of the hot molecular cores in the high-mass star-forming region NGC 6334I and consequently deriving their physical and astrochemical conditions. In the framework of the Herschel guaranteed time key program CHESS, NGC 6334I is investigated by using HIFI aboard the Herschel Space Observatory. A spectral line survey is carried out in the frequency range 480-1907 GHz, and auxiliary interferometric data from the SMA in the 230 GHz band provide spatial information for disentangling the different physical components contributing to the HIFI spectrum. The spectral lines are identified with the aid of former surveys and spectral line catalogs. The observed spectrum is then compared to a simulated synthetic spectrum with XCLASS, assuming local thermal equilibrium, and best fit parameters are derived using the model optimization package MAGIX. A total of 46 molecules are identified, with 31 isotopologues, resulting in about 4300 emission and absorption lines. High- energy levels of the dominant emitter methanol and vibrationally excited HCN are detected. The number of unidentified lines remains low with 75, or less than 2 percent of the lines detected. The modeling suggests that several spectral features need two or more components to be fitted properly. Other components could be assigned to cold foreground clouds or to outflows, most visible in the SiO emission. A chemical variation between the two embedded hot cores is found, with more N-bearing molecules identified in SMA1 and O-bearing molecules in SMA2. Spectral line surveys give powerful insights into the study of the interstellar medium. Different molecules trace different physical conditions like the inner hot core, the envelope, the outflows or the cold foreground clouds. The derived molecular abundances provide further constraints for astrochemical models., Comment: 30 pages including appendix, 49 figures, accepted for publication in Astronomy and Astrophysics

We report the first high spatial resolution submillimeter continuum observations of the Sagittarius B2 cloud complex using the Submillimeter Array (SMA). With the subarcsecond resolution provided by the SMA, the two massive star-forming clumps Sgr B2(N) and Sgr B2(M) are resolved into multiple compact sources. In total, twelve submillimeter cores are identified in the Sgr B2(M) region, while only two components are observed in the Sgr B2(N) clump. The gas mass and column density are estimated from the dust continuum emission. We find that most of the cores have gas masses in excess of 100 M$_{\odot}$ and column densities above 10$^{25}$ cm$^{-2}$. The very fragmented appearance of Sgr B2(M), in contrast to the monolithic structure of Sgr B2 (N), suggests that the former is more evolved. The density profile of the Sgr B2(N)-SMA1 core is well fitted by a Plummer density distribution. This would lead one to believe that in the evolutionary sequence of the Sgr B2 cloud complex, a massive star forms first in an homogeneous core, and the rest of the cluster forms subsequently in the then fragmenting structure., Comment: 4 pages, 2 figures, accepted by A&A letters

While unbiased surveys observable from ground-based telescopes have previously been obtained towards several high mass protostars, very little exists on low mass protostars. To fill up this gap, we carried out a complete spectral survey of the bands at 3, 2, 1 and 0.8 mm towards the solar type protostar IRAS16293-2422. The observations covered about 200\,GHz and were obtained with the IRAM-30m and JCMT-15m telescopes. Particular attention was devoted to the inter-calibration of the obtained spectra with previous observations. All the lines detected with more than 3 sigma and free from obvious blending effects were fitted with Gaussians to estimate their basic kinematic properties. More than 4000 lines were detected (with sigma \geq 3) and identified, yielding a line density of approximatively 20 lines per GHz, comparable to previous surveys in massive hot cores. The vast majority (~2/3) of the lines are weak and due to complex organic molecules. The analysis of the profiles of more than 1000 lines belonging 70 species firmly establishes the presence of two distinct velocity components, associated with the two objects, A and B, forming the IRAS16293-2422 binary system. In the source A, the line widths of several species increase with the upper level energy of the transition, a behavior compatible with gas infalling towards a ~1 Mo object. The source B, which does not show this effect, might have a much lower central mass of ~0.1 Mo. The difference in the rest velocities of both objects is consistent with the hypothesis that the source B rotates around the source A. This spectral survey, although obtained with single-dish telescope with a low spatial resolution, allows to separate the emission from 2 different components, thanks to the large number of lines detected. The data of the survey are public and can be retrieved on the web site http://www-laog.obs.ujf-grenoble.fr/heberges/timasss., Comment: 41 pages (26 pages of online Tables), 7 Tables and 6 Figures

We have examined methanol emission from Orion KL with of the {\em Herschel}/HIFI instrument, and detected two methanol bands centered at 524 GHz and 1061 GHz. The 524 GHz methanol band (observed in HIFI band 1a) is dominated by the isolated $\Delta$J$=$0, K$=-4\rightarrow$-3, v$_t$$=$0 Q branch, and includes 25 E-type and 2 A-type transitions. The 1061 GHz methanol band (observed in HIFI band 4b) is dominated by the $\Delta$J$=$0, K$=7\rightarrow$6, v$_t$$=$0 Q branch transitions which are mostly blended. We have used the isolated E-type v$_t$$=$0 methanol transitions to explore the physical conditions in the molecular gas. With HIFI's high velocity resolution, the methanol emission contributed by different spatial components along the line of sight toward Orion KL (hot core, low velocity flow, and compact ridge) can be distinguished and studied separately. The isolated transitions detected in these bands cover a broad energy range (upper state energy ranging from 80 K to 900 K), which provides a unique probe of the thermal structure in each spatial component. The observations further show that the compact ridge is externally heated. These observations demonstrate the power of methanol lines as probes of the physical conditions in warm regions in close proximity to young stars., Comment: 8 pages, 9 figures, accepted for publication in Astronomy & Astrophysics

We report observations of the reactive molecular ions OH$^+$, H$_2$O$^+$, and H$_3$O$^+$ towards Orion KL with Herschel/HIFI. All three $N=1-0$ fine-structure transitions of OH$^+$ at 909, 971, and 1033GHz and both fine-structure components of the doublet {\it ortho}-H$_2$O$^+$ $1_{11}-0_{00}$ transition at 1115 and 1139GHz were detected; an upper limit was obtained for H$_3$O$^+$. OH$^+$ and H$_2$O$^+$ are observed purely in absorption, showing a narrow component at the source velocity of 9 kms$^{-1}$, and a broad blueshifted absorption similar to that reported recently for HF and {\it para}-H$_{2}^{18}$O, and attributed to the low velocity outflow of Orion KL. We estimate column densities of OH$^+$ and H$_2$O$^+$ for the 9 km s$^{-1}$ component of $9 \pm 3 \times 10^{12}$cm$^{-2}$ and $7 \pm 2 \times 10^{12}$cm$^{-2}$, and those in the outflow of $1.9 \pm 0.7 \times 10^{13}$cm$^{-2}$ and $1.0 \pm 0.3 \times 10^{13}$cm$^{-2}$. Upper limits of $2.4\times 10^{12}$cm$^{-2}$ and $8.7\times 10^{12}$cm$^{-2}$ were derived for the column densities of {\it ortho} and {\it para}-H$_3$O$^+$ from transitions near 985 and 1657GHz. The column densities of the three ions are up to an order of magnitude lower than those obtained from recent observations of W31C and W49N. The comparatively low column densities may be explained by a higher gas density despite the assumption of a very high ionization rate., Comment: 5 pages, 1 figure. Accepted to and to be published in the Herschel HIFI special issue of A\&A Letters

In contrast with numerous studies on the physical and chemical structure of low- and high-mass protostars, much less is known about their intermediate-mass counterparts, a class of objects that could help to elucidate the mechanisms of star formation on both ends of the mass range. We present the first results from a rich HIFI spectral dataset on an intermediate-mass protostar, OMC2-FIR4, obtained in the CHESS (Chemical HErschel SurveyS of star forming regions) key programme. The more than 100 methanol lines detected between 554 and 961 GHz cover a range in upper level energy of 40 to 540 K. Our physical interpretation focusses on the hot core, but likely the cold envelope and shocked regions also play a role in reality, because an analysis of the line profiles suggests the presence of multiple emission components. An upper limit of 10^-6 is placed on the methanol abundance in the hot core, using a population diagram, large-scale source model and other considerations. This value is consistent with abundances previously seen in low-mass hot cores. Furthermore, the highest energy lines at the highest frequencies display asymmetric profiles, which may arise from infall around the hot core., Comment: 2 figures, accepted for publication in the A&A Herschel-HIFI special issue

We report the detection of more than 48 velocity-resolved ground rotational state transitions of H2(16)O, H2(18)O, and H2(17)O - most for the first time - in both emission and absorption toward Orion KL using Herschel/HIFI. We show that a simple fit, constrained to match the known emission and absorption components along the line of sight, is in excellent agreement with the spectral profiles of all the water lines. Using the measured H2(18)O line fluxes, which are less affected by line opacity than their H2(16)O counterparts, and an escape probability method, the column densities of H2(18)O associated with each emission component are derived. We infer total water abundances of 7.4E-5, 1.0E-5, and 1.6E-5 for the plateau, hot core, and extended warm gas, respectively. In the case of the plateau, this value is consistent with previous measures of the Orion-KL water abundance as well as those of other molecular outflows. In the case of the hot core and extended warm gas, these values are somewhat higher than water abundances derived for other quiescent clouds, suggesting that these regions are likely experiencing enhanced water-ice sublimation from (and reduced freeze-out onto) grain surfaces due to the warmer dust in these sources., Comment: 5 pages, 2 figures

In the past decade, much progress has been made in characterising the processes leading to the enhanced deuterium fractionation observed in the ISM and in particular in the cold, dense parts of star forming regions such as protostellar envelopes. Very high molecular D/H ratios have been found for saturated molecules and ions. However, little is known about the deuterium fractionation in radicals, even though simple radicals often represent an intermediate stage in the formation of more complex, saturated molecules. The imidogen radical NH is such an intermediate species for the ammonia synthesis in the gas phase. Herschel/HIFI represents a unique opportunity to study the deuteration and formation mechanisms of such species, which are not observable from the ground. We searched here for the deuterated radical ND in order to determine the deuterium fractionation of imidogen and constrain the deuteration mechanism of this species. We observed the solar-mass Class 0 protostar IRAS16293-2422 with the heterodyne instrument HIFI as part of the Herschel key programme CHESS (Chemical HErschel Surveys of Star forming regions). The deuterated form of the imidogen radical ND was detected and securely identified with 2 hyperfine component groups of its fundamental transition in absorption against the continuum background emitted from the nascent protostar. The 3 groups of hyperfine components of its hydrogenated counterpart NH were also detected in absorption. We derive a very high deuterium fractionation with an [ND]/[NH] ratio of between 30 and 100%. The deuterium fractionation of imidogen is of the same order of magnitude as that in other molecules, which suggests that an efficient deuterium fractionation mechanism is at play. We discuss two possible formation pathways for ND, by means of either the reaction of N+ with HD, or deuteron/proton exchange with NH., Comment: Accepted; To appear in A&A Herschel/HIFI Special Issue

We present the first high spectral resolution observations of Orion KL in the frequency ranges 1573.4 - 1702.8 GHz (band 6b) and 1788.4 - 1906.8 GHz (band 7b) obtained using the HIFI instrument on board the Herschel Space Observatory. We characterize the main emission lines found in the spectrum, which primarily arise from a range of components associated with Orion KL including the hot core, but also see widespread emission from components associated with molecular outflows traced by H2O, SO2, and OH. We find that the density of observed emission lines is significantly diminished in these bands compared to lower frequency Herschel/HIFI bands., Comment: Accepted for publication in the Herschel HIFI special issue of Astronomy and Astrophysics Letters, 5 pages, 3 figures

Despite the low elemental deuterium abundance in the Galaxy, enhanced molecular D/H ratios have been found in the environments of low-mass star forming regions, and in particular the Class 0 protostar IRAS 16293-2422. The CHESS (Chemical HErschel Surveys of Star forming regions) Key Program aims at studying the molecular complexity of the interstellar medium. The high sensitivity and spectral resolution of the HIFI instrument provide a unique opportunity to observe the fundamental 1,1,1 - 0,0,0 transition of the ortho-D2O molecule, inaccessible from the ground, and to determine the ortho-to-para D2O ratio. We have detected the fundamental transition of the ortho-D2O molecule at 607.35 GHz towards IRAS 16293-2422. The line is seen in absorption with a line opacity of 0.62 +/- 0.11 (1 sigma). From the previous ground-based observations of the fundamental 1,1,0 - 1,0,1 transition of para-D2O seen in absorption at 316.80 GHz we estimate a line opacity of 0.26 +/- 0.05 (1 sigma). We show that the observed absorption is caused by the cold gas in the envelope of the protostar. Using these new observations, we estimate for the first time the ortho to para D2O ratio to be lower than 2.6 at a 3 sigma level of uncertainty, to be compared with the thermal equilibrium value of 2:1., Comment: 5 pages, 5 figures, accepted the A&A HIFI Special Issue as a letter

We present observations of twelve rotational transitions of H2O-16, H2O-18, and H2O-17 toward the massive star-forming region NGC 6334 I, carried out with Herschel/HIFI as part of the guaranteed time key program Chemical HErschel Surveys of Star forming regions (CHESS). We analyze these observations to obtain insights into physical processes in this region. We identify three main gas components (hot core, cold foreground, and outflow) in NGC 6334 I and derive the physical conditions in these components. The hot core, identified by the emission in highly excited lines, shows a high excitation temperature of 200 K, whereas water in the foreground component is predominantly in the ortho- and para- ground states. The abundance of water varies between 4 10^-5 (outflow) and 10^-8 (cold foreground gas). This variation is most likely due to the freeze-out of water molecules onto dust grains. The H2O-18/H2O-17 abundance ratio is 3.2, which is consistent with the O-18/O-17 ratio determined from CO isotopologues. The ortho/para ratio in water appears to be relatively low 1.6(1) in the cold, quiescent gas, but close to the equilibrium value of three in the warmer outflow material (2.5(0.8))., Comment: 7 pages, 3 figures, accepted by A&A

We present initial results from the Herschel GT key program: Herschel observations of EXtra-Ordinary Sources (HEXOS) and outline the promise and potential of spectral surveys with Herschel/HIFI. The HIFI instrument offers unprecedented sensitivity, as well as continuous spectral coverage across the gaps imposed by the atmosphere, opening up a largely unexplored wavelength regime to high-resolution spectroscopy. We show the spectrum of Orion KL between 480 and 560 GHz and from 1.06 to 1.115 THz. From these data, we confirm that HIFI separately measures the dust continuum and spectrally resolves emission lines in Orion KL. Based on this capability we demonstrate that the line contribution to the broad-band continuum in this molecule-rich source is ~20-40% below 1 THz and declines to a few percent at higher frequencies. We also tentatively identify multiple transitions of HD18O in the spectra. The first detection of this rare isotopologue in the interstellar medium suggests that HDO emission is optically thick in the Orion hot core with HDO/H2O ~ 0.02. We discuss the implications of this detection for the water D/H ratio in hot cores., Comment: 6 pages, 5 figures, accepted and to be published in Herschel HIFI special issue of A&A Letters

We report a detection of the fundamental rotational transition of hydrogen fluoride in absorption towards Orion KL using Herschel/HIFI. After the removal of contaminating features associated with common molecules ("weeds"), the HF spectrum shows a P-Cygni profile, with weak redshifted emission and strong blue-shifted absorption, associated with the low-velocity molecular outflow. We derive an estimate of 2.9 x 10^13 cm^-2 for the HF column density responsible for the broad absorption component. Using our best estimate of the H2 column density within the low-velocity molecular outflow, we obtain a lower limit of ~1.6 x 10^-10 for the HF abundance relative to hydrogen nuclei, corresponding to 0.6% of the solar abundance of fluorine. This value is close to that inferred from previous ISO observations of HF J=2--1 absorption towards Sgr B2, but is in sharp contrast to the lower limit of 6 x 10^-9 derived by Neufeld et al. (2010) for cold, foreground clouds on the line of sight towards G10.6-0.4., Comment: 5 pages, 3 figures, paper to be published in the Herschel special issue of A&A letters

We have observed CH absorption lines ($J=3/2, N=1 \leftarrow J=1/2, N=1$) against the continuum source Sgr~B2(M) using the \textit{Herschel}/HIFI instrument. With the high spectral resolution and wide velocity coverage provided by HIFI, 31 CH absorption features with different radial velocities and line widths are detected and identified. The narrower line width and lower column density clouds show `spiral arm' cloud characteristics, while the absorption component with the broadest line width and highest column density corresponds to the gas from the Sgr~B2 envelope. The observations show that each `spiral arm' harbors multiple velocity components, indicating that the clouds are not uniform and that they have internal structure. This line-of-sight through almost the entire Galaxy offers unique possibilities to study the basic chemistry of simple molecules in diffuse clouds, as a variety of different cloud classes are sampled simultaneously. We find that the linear relationship between CH and H$_2$ column densities found at lower $A_V$ by UV observations does not continue into the range of higher visual extinction. There, the curve flattens, which probably means that CH is depleted in the denser cores of these clouds., Comment: Accepted for publication in A&A, HIFI Special Issue

In contrast to extensively studied dense star-forming cores, little is known about diffuse gas surrounding star-forming regions. We study molecular gas in the high-mass star-forming region NGC6334I, which contains diffuse, quiescent components that are inconspicuous in widely used molecular tracers such as CO. We present Herschel/HIFI observations of CH toward NGC6334I observed as part of the CHESS key program. HIFI resolves the hyperfine components of its J=3/2-1/2 transition, observed in both emission and absorption. The CH emission appears close to the systemic velocity of NGC6334I, while its measured linewidth of 3 km/s is smaller than previously observed in dense gas tracers such as NH3 and SiO. The CH abundance in the hot core is 7 10^-11, two to three orders of magnitude lower than in diffuse clouds. While other studies find distinct outflows in, e.g., CO and H2O toward NGC6334I, we do not detect outflow signatures in CH. To explain the absorption signatures, at least two absorbing components are needed at -3.0 and +6.5 km/s with N(CH)=7 10^13 and 3 10^13 cm^-2. Two additional absorbing clouds are found at +8.0 and 0.0 km/s, both with N(CH)=2 10^13 cm^-2. Turbulent linewidths for the four absorption components vary between 1.5 and 5.0 km/s in FWHM. We constrain physical properties of our CH clouds by matching our CH absorbers with other absorption signatures. In the hot core, molecules such as H2O and CO trace gas that is heated and dynamically influenced by outflow activity, whereas CH traces more quiescent material. The four CH absorbers have column densities and turbulent properties consistent with diffuse clouds: two are located near NGC6334, and two are unrelated foreground clouds. Local density and dynamical effects influence the chemical composition of physical components of NGC6334, causing some components to be seen in CH but not in other tracers, and vice versa., Comment: Accepted by A&A Letters; 5 pages, 1 figure; v2: minor textual and typographical changes

We present Herschel/HIFI observations of the fundamental rotational transitions of ortho- and para-H$_2^{16}$O and H$_2^{18}$O in absorption towards Sagittarius~B2(M) and W31C. The ortho/para ratio in water in the foreground clouds on the line of sight towards these bright continuum sources is generally consistent with the statistical high-temperature ratio of 3, within the observational uncertainties. However, somewhat unexpectedly, we derive a low ortho/para ratio of $2.35 \pm 0.35$, corresponding to a spin temperature of $\sim$27~K, towards Sagittarius~B2(M) at velocities of the expanding molecular ring. Water molecules in this region appear to have formed with, or relaxed to, an ortho/para ratio close to the value corresponding to the local temperature of the gas and dust., Comment: Accepted for publication in A&A, HIFI Special Issue; 5 pages, 3 figures

We report the first detection of chloronium, H$_2$Cl$^+$, in the interstellar medium, using the HIFI instrument aboard the \emph{Herschel} Space Observatory. The $2_{12}-1_{01}$ lines of ortho-H$_2^{35}$Cl$^+$ and ortho-H$_2^{37}$Cl$^+$ are detected in absorption towards NGC~6334I, and the $1_{11}-0_{00}$ transition of para-H$_2^{35}$Cl$^+$ is detected in absorption towards NGC~6334I and Sgr~B2(S). The H$_2$Cl$^+$ column densities are compared to those of the chemically-related species HCl. The derived HCl/H$_2$Cl$^+$ column density ratios, $\sim$1--10, are within the range predicted by models of diffuse and dense Photon Dominated Regions (PDRs). However, the observed H$_2$Cl$^+$ column densities, in excess of $10^{13}$~cm$^{-2}$, are significantly higher than the model predictions. Our observations demonstrate the outstanding spectroscopic capabilities of HIFI for detecting new interstellar molecules and providing key constraints for astrochemical models., Comment: Accepted for publication in A&A, HIFI Special Issue; 4 pages, 2 figures, 1 table

H2O+ has been observed in its ortho- and para- states toward the massive star forming core Sgr B2(M), located close to the Galactic center. The observations show absorption in all spiral arm clouds between the Sun and Sgr B2. The average o/p ratio of H2O+ in most velocity intervals is 4.8, which corresponds to a nuclear spin temperature of 21 K. The relationship of this spin temperature to the formation temperature and current physical temperature of the gas hosting H2O+ is discussed, but no firm conclusion is reached. In the velocity interval 0 to 60 km/s, an ortho/para ratio of below unity is found, but if this is due to an artifact of contamination by other species or real is not clear., Comment: A&A, HIFI special issue, accepted

The outflow driven by the low-mass class 0 protostar L1157 is the prototype of the so-called chemically active outflows. The bright bowshock B1 in the southern outflow lobe is a privileged testbed of magneto-hydrodynamical (MHD) shock models, for which dynamical and chemical processes are strongly interdependent. We present the first results of the unbiased spectral survey of the L1157-B1 bowshock, obtained in the framework of the key program "Chemical Herschel Surveys of Star Forming Regions" (CHESS). The main aim is to trace the warm and chemically enriched gas and to infer the excitation conditions in the shock region. The CO 5-4 and H2O lines have been detected at high-spectral resolution in the unbiased spectral survey of the HIFI-Band 1b spectral window (555-636 GHz), presented by Codella et al. in this volume. Complementary ground-based observations in the submm window help establish the origin of the emission detected in the main-beam of HIFI, and the physical conditions in the shock.}{Both lines exhibit broad wings, which extend to velocities much higher than reported up to now. We find that the molecular emission arises from two regions with distinct physical conditions: an extended, warm (100K), dense (3e5 cm-3) component at low-velocity, which dominates the water line flux in Band~1; a secondary component in a small region of B1 (a few arcsec) associated with high-velocity, hot (> 400 K) gas of moderate density ((1.0-3.0)e4 cm-3), which appears to dominate the flux of the water line at 179mu observed with PACS. The water abundance is enhanced by two orders of magnitude between the low- and the high-velocity component, from 8e-7 up to 8e-5. The properties of the high-velocity component agree well with the predictions of steady-state C-shock models., Comment: Accepted for Publication in Astronomy and Astrophysics (Herschel Special Issue)

We report on the initial analysis of a Herschel/PACS full range spectrum of Neptune, covering the 51-220 micrometer range with a mean resolving power of ~ 3000, and complemented by a dedicated observation of CH4 at 120 micrometers. Numerous spectral features due to HD (R(0) and R(1)), H2O, CH4, and CO are present, but so far no new species have been found. Our results indicate that (i) Neptune's mean thermal profile is warmer by ~ 3 K than inferred from the Voyager radio-occultation; (ii) the D/H mixing ratio is (4.5+/-1) X 10**-5, confirming the enrichment of Neptune in deuterium over the protosolar value (~ 2.1 X 10**-5); (iii) the CH4 mixing ratio in the mid stratosphere is (1.5+/-0.2) X 10**-3, and CH4 appears to decrease in the lower stratosphere at a rate consistent with local saturation, in agreement with the scenario of CH4 stratospheric injection from Neptune's warm south polar region; (iv) the H2O stratospheric column is (2.1+/-0.5) X 10**14 cm-2 but its vertical distribution is still to be determined, so the H2O external flux remains uncertain by over an order of magnitude; and (v) the CO stratospheric abundance is about twice the tropospheric value, confirming the dual origin of CO suspected from ground-based millimeter/submillimeter observations., Comment: Accepted for publication in Astronomy & Astrophysics (special issue on Herschel first results)

We identify a prominent absorption feature at 1115 GHz, detected in first HIFI spectra towards high-mass star-forming regions, and interpret its astrophysical origin. The characteristic hyperfine pattern of the H2O+ ground-state rotational transition, and the lack of other known low-energy transitions in this frequency range, identifies the feature as H2O+ absorption against the dust continuum background and allows us to derive the velocity profile of the absorbing gas. By comparing this velocity profile with velocity profiles of other tracers in the DR21 star-forming region, we constrain the frequency of the transition and the conditions for its formation. In DR21, the velocity distribution of H2O+ matches that of the [CII] line at 158\mu\m and of OH cm-wave absorption, both stemming from the hot and dense clump surfaces facing the HII-region and dynamically affected by the blister outflow. Diffuse foreground gas dominates the absorption towards Sgr B2. The integrated intensity of the absorption line allows us to derive lower limits to the H2O+ column density of 7.2e12 cm^-2 in NGC 6334, 2.3e13 cm^-2 in DR21, and 1.1e15 cm^-2 in Sgr B2., Comment: Accepted for publication in A&A

In recent years, organic molecules of increasing complexity have been found toward the prolific Galactic center source Sagittarius B2. We wish to explore the degree of complexity that the interstellar chemistry can reach in star-forming regions. We carried out a complete line survey of the hot cores Sgr B2(N) and (M) with the IRAM 30 m telescope in the 3 mm range. We analyzed this spectral survey in the LTE approximation. We modeled the emission of all known molecules simultaneously, which allows us to search for less abundant, more complex molecules. We compared the derived column densities with the predictions of a coupled gas-phase and grain-surface chemical code. We report the first detection in space of ethyl formate (C2H5OCHO) and n-propyl cyanide (C3H7CN) toward Sgr B2(N). The abundances of ethyl formate and n-propyl cyanide relative to H2 are estimated to be 3.6e-9 and 1.0e-9, respectively. Our chemical modeling suggests that the sequential, piecewise construction of ethyl and n-propyl cyanide from their constituent functional groups on the grain surfaces is their most likely formation route. Ethyl formate is primarily formed on the grains by adding CH3 to functional-group radicals derived from methyl formate, although ethanol may also be a precursor. The detection in Sgr B2(N) of the next stage of complexity in two classes of complex molecule, esters and alkyl cyanides, suggests that greater complexity in other classes of molecule may be present in the interstellar medium. {Abridged}, Comment: 7 figures, 15 tables, including online material. Accepted for publication in Astronomy & Astrophysics

We present new radio continuum observations, taken at 1.4 GHz with the Very Large Array, and new observations in the CO line, taken with the Plateau de Bure interferometer, of two regions of the spiral galaxy NGC 3627. Comparing these observations with archival Spitzer and H_{alpha} data we study the correlation of the radio continuum (RC), infrared-8 um and CO emissions at a spatial resolution of 100 pc. We compare the point-by-point variations of the RC, CO, and 8um brightnesses in two distinct regions of 2 kpc \times 2 kpc in size of NGC 3627. We examined scale much lower than the electron diffusion scale, where a break down of the correlations would be expected. However no evidence for such correlation break down has been found. The RC emission follows well the distribution of CO and the widths of several structures, measured along slices across them, are comparable. Furthermore, we found that down to a spatial scale of 100 pc the radio continuum emission is correlated with dust emissions at 4.5, 5.8, and 8 um, that traces different dust temperatures. We present a new perspective with which visualizing and studying the RC-CO-24 um and RC-CO-8 um correlations, by using a three-dimensional representation. We fit the observed data with a three dimensional line, obtaining a rms of 0.25 dex. The observed correlation enhances the complexity of the electrons diffusion, losses and injection mechanisms, and of their connection to star formation processes, described by molecular and dust emissions. We plan to further investigate this connection using spatially resolved spectral index studies at low radio frequencies where the thermal emission component is seemingly negligible., Comment: 17 pages, 17 figures (low resolution). Accepted for publication in A&A. Some language and reference changes done. High resolution version of the paper is available at: http://erg.ca.astro.it/~rpaladin/PAPER/NGC3627/AA9135.ps

Famous for the extraordinary richness of its molecular content, the Sgr B2 molecular cloud complex is the prime target in the long-standing search for ever more complex species. We have completed a molecular line survey of the hot dense cores Sgr B2(N) and Sgr B2(M) in the 3 mm wavelength range with the IRAM 30 m telescope. We performed the analysis of this huge data set by modeling the whole spectrum at once in the LTE approximation. Ongoing analyses yield an average line density of about 100 features/GHz above 3 sigma for Sgr B2(N), emitted and/or absorbed by a total of 51 molecular species. We find lines from 60 rare isotopologues and from 41 vibrationally excited states in addition to the main species, vibrational ground state lines. For Sgr B2(M), we find about 25 features/GHz above 3 sigma, from 41 molecular species plus 50 isotopologues and 20 vibrationally excited states. Thanks to the constant updates to the Cologne Database for Molecular Spectroscopy, we are working our way through the assignment of the unidentified features, currently 40% and 50% above 3 sigma for Sgr B2(N) and Sgr B2(M), respectively., Comment: 4 pages, 2 figures, to appear in the proceedings of the conference "Molecules in Space & Laboratory" held in Paris, France, 14-18 May 2007

Amino acids are building blocks of proteins and therefore key ingredients for the origin of life. The simplest amino acid, glycine, has long been searched for in the interstellar medium but has not been unambiguously detected so far. Since the search for glycine has turned out to be extremely difficult, we aimed at detecting a chemically related species (possibly a direct precursor), amino acetonitrile. With the IRAM 30m telescope we carried out a complete line survey of the hot core regions Sgr B2(N) and (M) in the 3 mm range, plus partial surveys at 2 and 1.3 mm. We analyzed our 30m line survey in the LTE approximation and modeled the emission of all known molecules simultaneously. We identified spectral features at the frequencies predicted for amino acetonitrile lines having intensities compatible with a unique rotation temperature. We also used the VLA to look for cold, extended emission from amino acetonitrile. We detected amino acetonitrile in Sgr B2(N) in our 30m telescope line survey and conducted confirmatory observations of selected lines with the IRAM PdB and the ATCA interferometers. The emission arises from a known hot core, the Large Molecule Heimat, and is compact with a source diameter of 2 arcsec (0.08 pc). We derived a column density of 2.8e16 cm-2, a temperature of 100 K, and a linewidth of 7 km s-1. Based on the simultaneously observed continuum emission, we calculated a density of 1.7e8 cm-3, a mass of 2340 Msun, and an amino acetonitrile fractional abundance of 2.2e-9. The high abundance and temperature may indicate that amino acetonitrile is formed by grain surface chemistry. We did not detect any hot, compact amino acetonitrile emission toward Sgr B2(M) or any cold, extended emission toward Sgr B2, with column-density upper limits of 6e15 and 3e12-14 cm-2, respectively. (abridged), Comment: 30 pages, 8 figures, accepted for publication in Astronomy and Astrophysics (A&A). Version 2: minor changes (one author affiliation added, one reference updated). Version 3: minor changes (typos) for final version

NGC6334I and I(N) have been observed with the Swedish-ESO Submillimetre Telescope, SEST, at wavelengths of 3, 2, and 1.3 mm. Especially NGC6334 I shows rich emission from many different molecules, comparable in line density to prototypical hot cores such as Orion-KL and SgrB2(N). In addition, a 4' by 4' region enfolding NGC 6334 I and I(N) has been mapped at a wavelength of 3 mm (75 to 116 GHz) with the Mopra telescope., Comment: 2 pages, 2 figures, to appear in Conference Proceedings "Molecules in Space and Laboratory"

We present VLA and PdBI subarcsecond images (0.15"-0.6") of the radiocontinuum emission at 7 mm and of the SO2 J=19_{2,18}-18_{3,15} and J=27_{8,20}-28_{7,21} lines toward the Cepheus A HW2 region. The SO2 images reveal the presence of a hot core internally heated by an intermediate mass protostar, and a circumstellar rotating disk around the HW2 radio jet with size 600AUx100AU and mass of 1M_sun. Keplerian rotation for the disk velocity gradient of 5 kms-1 requires a 9 M_sun central star, which cannot explain the total luminosity observed in the region. This may indicate that the disk does not rotate with a Keplerian law due to the extreme youth of this object. Our high sensitivity radiocontinuum image at 7 mm shows in addition to the ionized jet, an extended emission to the west (and marginally to the south) of the HW2 jet, filling the south-west cavity of the HW2 disk. From the morphology and location of this free-free continuum emission at centimeter and millimeter wavelengths (spectral index of 0.4-1.5), we propose that the disk is photoevaporating due to the UV radiation from the central star. All this indicates that the Cepheus A HW2 region harbors a cluster of massive stars. Disk accretion seems to be the most plausible way to form massive stars in moderate density/luminosity clusters., Comment: 4 pages, 2 figures, accepted for publication in ApJL

Due to its relatively small distance (725 pc), the Cepheus A East star-forming region is an ideal laboratory to study massive star formation processes. Based on its morphology, it has been suggested that the flattened molecular gas distribution around the YSO HW2 may be a 350-AU-radius massive protostellar disk. Goal of our work is to ascertain the nature of this structure. We have employed the Plateau de Bure Interferometer to acquire (sub-)arcsecond-resolution imaging of high-density and shock tracers, such as methyl cyanide (CH3CN) and silicon monoxide (SiO), towards the HW2 position. On the 1-arcsecond (about 725 AU) scale, the flattened distribution of molecular gas around HW2 appears to be due to the projected superposition, on the plane of the sky, of at least three protostellar objects, of which at least one is powering a molecular outflow at a small angle with respect to the line of sight. The presence of a protostellar disk around HW2 is not ruled out, but such structure is likely to be detected on a smaller spatial scale, or using different molecular tracers., Comment: 6 pages, 5 figures, accepted for publication in Astronomy & Astrophysics

Unbiased molecular line surveys are a powerful tool for analyzing the physical and chemical parameters of astronomical objects and are the only means for obtaining a complete view of the molecular inventory for a given source. The present work stands for the first such investigation of a photon-dominated region. The first results of an ongoing millimeter-wave survey obtained towards the Orion Bar are reported. The APEX telescope in combination with the APEX-2A facility receiver was employed in this investigation. We derived the physical parameters of the gas through LVG analyses of the methanol and formaldehyde data. Information on the sulfur and deuterium chemistry of photon-dominated regions is obtained from detections of several sulfur-bearing molecules and DCN., Comment: APEX A&A special issue, accepted

The cosmic-ray ionization rate (zeta) of dense molecular clouds is a key parameter for their dynamics and chemistry. Variations of zeta are well established, but it is unclear if these are related to source column density or to Galactic location. Using the APEX telescope, we have mapped the 364 GHz line of H3O+ in the Sgr B2 region and observed the 307 GHz line at selected positions. With the IRAM 30-m telescope we have observed the 203 GHz line of H2O-18 at the same positions. Strong H3O+ emission is detected over a ~3x2 pc region, indicating H3O+ column densities of 10^15 - 10^16 cm^-2 in an 18" beam. The H3O+ abundance of ~3 x 10^-9 and H3O+/H2O ratio of ~1/50 in the Sgr B2 envelope are consistent with models with zeta ~4 x 10^-16 s^-1, 3x lower than derived from H3+ observations toward Sgr A, but 10x that of local dense clouds. The ionization rates of interstellar clouds thus seem to be to first order determined by the ambient cosmic-ray flux, while propagation effects cause a factor of ~3 decrease from diffuse to dense clouds., Comment: Accepted by A&A Letters (APEX special issue); four A4 pages, two figures

High-mass star-forming regions are known to have a rich molecular spectrum from many species. Some of the very highly excited lines are emitted from very hot and dense gas close to the central object(s). The physics and chemistry of the inner cores of two high mass star forming regions, NGC6334(I) and G327.3-0.6, shall be characterized. Submillimeter line surveys with the APEX telescope provide spectra which sample many molecular lines at high excitation stages. Partial spectral surveys were obtained, the lines were identified, physical parameters were determined through fitting of the spectra. Both sources show similar spectra that are comparable to that of the only other high mass star forming region ever surveyed in this frequency range}, Orion-KL, but with an even higher line density. Evidence for very compact, very hot sources is found., Comment: APEX A&A special issue, accepted

We present IRAM 30m and JCMT observations of HDO lines towards the solar-type protostar IRAS 16293-2422. Five HDO transitions have been detected on-source, and two were unfruitfully searched for towards a bright spot of the outflow of IRAS 16293-2422. We interpret the data by means of the Ceccarelli, Hollenbach and Tielens (1996) model, and derive the HDO abundance in the warm inner and cold outer parts of the envelope. The emission is well explained by a jump model, with an inner abundance of 1e-7 and an outer abundance lower than 1e-9 (3 sigma). This result is in favor of HDO enhancement due to ice evaporation from the grains in theinner envelope. The deuteration ratio HDO/H2O is found to be f_in=3% and f_out < 0.2% (3 sigma) in the inner and outer envelope respectively and therefore, the fractionation also undergoes a jump in the inner part of the envelope. These results are consistent with the formation of water in the gas phase during the cold prestellar core phase and storage of the molecules on the grains, but do not explain why observations of H2O ices consistently derive a H2O ice abundance of several 1e-5 to 1e-4, some two orders of magnitude larger than the gas phase abundance of water in the hot core around IRAS 16293-2422., Comment: 9 pages, 6 figures accepted by A&A

Here we report the detection, with the Caltech Submillimeter Observatory, of the 894-GHz HDO(111-000) transition, observed in absorption against the background continuum emission of the SgrB2 cores M and N. Radiative transfer modeling of this feature, together with the published data set of mm and submm HDO and H2O-18 transitions, suggests that ground-state absorption features from deuterated and non-deuterated water trace different gas components along the line of sight. In particular, while the HDO line seems to be produced by the large column densities of gas located in the SgrB2 warm envelope, the H2O-18 ground-state transition detected by SWAS and KAO at 548 GHz (Neufeld et al. 2000; Zmuidzinas et al. 1995) is instead a product of the hot, diffuse, thin gas layer lying in the foreground of the SgrB2 complex., Comment: 4 pages, 2 figures. (Co)authored by members of the MPIfR (Sub)millimeter Astronomy Group. To appear in the Proceedings of the 4th Cologne-Bonn-Zermatt-Symposium "The Dense Interstellar Medium in Galaxies" eds. S. Pfalzner, C. Kramer, C. Straubmeier, & A. Heithausen (Springer: Berlin)

We report the detection, with the Caltech Submillimeter Observatory, of the 894-GHz HDO(111-000) transition, observed in absorption against the background continuum emission of the SgrB2 cores M and N. Radiative transfer modeling of this feature, together with the published data set of mm and submm HDO and H2O-18 transitions, suggests that ground-state absorption features from deuterated and non-deuterated water trace different gas components along the line of sight. In particular, while the HDO line seems to be produced by the large column densities of gas located in the SgrB2 warm envelope, the H2O-18 ground-state transition detected by SWAS and KAO at 548 GHz (Neufeld et al. 2000; Zmuidzinas et al. 1995a) is instead a product of the hot, diffuse, thin gas layer lying in the foreground of the SgrB2 complex., Comment: Accepted by A&A

(Abridged) We present evidence that low-mass starless cores, the simplest units of star formation, are systematically differentiated in their chemical composition. Molecules including CO and CS almost vanish near the core centers, where the abundance decreases by one or two orders of magnitude. At the same time, N2H+ has a constant abundance, and the fraction of NH3 increases toward the core center. Our conclusions are based on a study of 5 mostly-round starless cores (L1498, L1495, L1400K, L1517B, and L1544), which we have mappedin C18O(1-0), C17O(1-0), CS(2-1), C34S(2-1), N2H+(1-0), NH3(1,1) and (2,2), and the 1.2 mm continuum. For each core we have built a model that fits simultaneously the radial profile of all observed emission and the central spectrum for the molecular lines. The observed abundance drops of CO and CS are naturally explained by the depletion of these molecules onto dust grains at densities of 2-6 10^4 cm-3. N2H+ seems unaffected by this process up to densities of several 10^5, while the NH3 abundance may be enhanced by reactions triggered by the disappearance of CO from the gas phase. With the help of our models, we show that chemical differentiation automatically explains the discrepancy between the sizes of CS and NH3 maps, a problem which has remained unexplained for more than a decade. Our models, in addition, show that a combination of radiative transfer effects can give rise to the previously observed discrepancy in the linewidth of these two tracers. Although this discrepancy has been traditionally interpreted as resulting from a systematic increase of the turbulent linewidth with radius, our models show that it can arise in conditions of constant gas turbulence., Comment: 25 pages, 9 figures, accepted by ApJ