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A new sediment core from Padul, Padul-15-05, provides a long and continuous sedimentary and paleoenvironmental record of the last ∼200 kyr. Here we present a detailed palynological study from this sedimentary sequence with new vegetation and paleoenvironmental data and a climatic interpretation for the last two climatic cycles from the southern Iberian Peninsula in the western Mediterranean region. Pollen analysis from this core shows orbital-scale vegetation oscillations (mainly forced by precession and eccentricity) pointing into insolation as the principal factor controlling vegetation changes at this latitude. The last two glacial-interglacial cycles (from MIS 6 to the present) as well as stadial and interstadial phases are well represented and characterized by significant oscillations in Mediterranean forest in the area, but several differences with respect to other Mediterranean long pollen records can be recognized. Some of these disparities between regions seem to be more related to different precipitation rates linked to the specific geographical features (e.g. strong topographic relief) than to latitudinal differences between the sites. In addition, a lake level reconstruction based on palynological data was developed and compared with the previous reconstruction from this record, representing local environmental changes in the Padul wetland that seems to be related to precipitation/evapotranspiration balance, and therefore, to changes in regional climate conditions. During glacial/stadial conditions recorded by maxima in xerophytes, the p/e increased due to very low evapotranspiration, resulting in high lake levels, while during warmer interglacial/interstadial phases (except for the MIS 5e), mainly represented in this record by maxima in the Mediterranean forest, water level decreased as a result of high evapotranspiration exceeding precipitation input. The comparison of the new Padul-15-05 pollen record with the two previous palynological studies from Padul shows significant differences mainly due to disagreements in the age control of the sequences. This study shows that an accurate age-depth model becomes essential when interpreting long paleoenvironmental and paleoclimate records., This research is supported by the projects CGL2013-47038-R and CGL-2017-85415-R funded by Ministerio de Economía y Competitividad of the Spanish Government, project P11-RNM-7332 from the Junta de Andalucía and the research group RNM0190 (Junta de Andalucía). Jon Camuera acknowledges the PhD funding (BES-2014-069117) provided by the Ministerio de Economía y Competitividad of the Spanish Government under the project CGL2013-47038-R. María J. Ramos-Román also acknowledges the PhD and post-PhD fellowship (P11-RNM-7332) from the Conserjería de Economía, Innovación, Ciencia y Empleo of the Junta de Andalucía. Antonio García-Alix was supported by a Ramón y Cajal fellowship (RYC-2015-18966) from the Ministerio de Economía y Competitividad of the Spanish Government. Thanks to Javier Jaimez for helping with the coring (CIC-UGR). José Carrión thanks the Ministerio de Economía y Competitividad of the Spanish Government (grant number CGL-BOS-2012-34717 and CGL-BOS 2015-68604) and Fundación Séneca (grant number 19434/PI/14).

Padul is one of the few wetland sites in southern Europe and the Mediterranean region that exhibits an unusually large temporal span (>100 kyr) and continuous Quaternary sedimentary record. Previous core-based studies from Padul yielded paleoecological datasets (i.e., pollen and organic geochemistry), but with a poor age control that resulted in rather arbitrary climate inferences. Therefore, precise age control and a multidisciplinary approach is necessary to understand long-term regional environmental and climate change and the associated local response of the Padul wetland environment. Here we present a new long sediment record (Padul-15-05) from this wetland in the southern Iberian Peninsula with the aim of improving the age control of the sedimentary sequence and carrying out up-to-date high-resolution multiproxy analyses. In this study the age control is based on 61 AMS radiocarbon dates for the last ca. 50 kyr BP and on the extent of amino acid racemization (AAR) in mollusc shells extending back ∼118 kyr BP. No numerical ages are available for the bottom part of the core but the sediment accumulation rates (SAR) and the cyclostratigraphic analysis of the multiproxy data suggest that the core preserves a continuous record of the last ∼197 kyr (from late MIS 7 to present) with millennial-scale time resolution. Sedimentological (lithology, magnetic susceptibility, XRD, color), geochemical (XRF, TOC, C/N, % carbonate content) and paleontological (pollen, charophytes, gastropods) data show co-varying cyclical paleoenvironmental changes linked to orbital-scale climatic variability. Silicon, magnetic susceptibility (MS) and total organic carbon (TOC) data show periodicities between ∼26.2–19.6 kyr linked to insolation, which is strongly dominated by precession cycles at this latitude. High values of Si and MS data have been related to high siliciclastic/detrital input from Sierra Nevada range during minima in insolation due to enhanced soil weathering/erosion during regional aridity and lower forest cover recorded by the arboreal pollen, which could also be favored by a minor biogenic productivity. In addition, warm climate conditions during maxima in insolation mostly resulted in negative precipitation/evapotranspiration balance and low lake levels, while cold glacial and stadial periods were mainly characterized by positive precipitation/evapotranspiration balance, and therefore, high lake levels. The improved chronology of the Padul sedimentary sequence along with a multiproxy study permitted us to better relate environmental and vegetation changes to climatic events and to demonstrate how both local (i.e., lake level, sedimentation) and regional (i.e., vegetation) environments responded to orbital-scale climate changes.

The application of curvature attributes on seismic horizons or 3D seismic volumes has been discussed in the literature in several ways. Such discussion largely ignores the detail of parameter selection that must be made by the working interpreter or the expert processor. Parameter selection such as window size and filtering methods for seismic curvature estimates have not been extensively compared in the literature and have never been validated using quantitative ground truthing to log or drilling data. Of even greater relevance to the interpreter is the lack of discussion of curvature parameters as they are relevant to interpretive and operational concerns. We focus on the seismic most-positive curvature attribute, its parameterization, and filtering for the overpressured tight sand target in the Falher F formation of the deep basin of Alberta, Canada. This sand has numerous natural fractures that constitute an occasional drilling hazard due to mud losses. Various parameterizations on horizon- and volume-based curvature extractions are made and examined in the context of the drilling results of four horizontal wells, one of which has image log fracture density along the lateral portion of the well. We compared different lateral (and vertical where applicable) window sizes in the initial curvature estimates, as well as different postcurvature filtering approaches including unfiltered, Gaussian-filtered, and Fourier-filtered products. The different curvature attribute estimates have been evaluated by way of map comparisons, cross-section seismic line comparisons, and correlations with the upscaled fracture density log data. We found that our horizon-based estimates of positive curvature suffered from mechanical artifacts related to the horizon picking process, and the volume-based methods were generally superior. Of the volume-based methods, we found that the Fourier-filtered curvature estimates were the most stable through smaller analysis windows. Gaussian-filtering methods on volumetric curvature gave results of varying quality. Unfiltered volumetric curvature estimates were only stable when very large time windows were used, which affected the time localization of the estimate. The comparisons give qualitative and quantitative perspective regarding the best parameters of curvature to predict the key properties of geologic target, which in this case are the potentially hazardous natural fractures within the overpressured Falher F sandstone.

Heinrich Stadial 1 (HS1) is one of the most extreme climate periods of the last glacial cycle, generating extremely low sea surface temperatures (SST) and significant changes in terrestrial landscape (e.g., vegetation). Previous studies show that overall cold/dry conditions occurred during HS1, but the lack of high-resolution records precludes whether climate was stable or instead characterized by instability. A high-resolution paleoclimatic record from Padul (southern Iberian Peninsula), supported by a robust chronology, shows that climate during HS1 was non-stationary and centennial-scale variability in moisture is superimposed on this overall cold climatic period. In this study we improve the resolution and suggest a novel subdivision of HS1 in 7 sub-phases, including: i) 3 sub-phases (a.1–a.3) during an arid early phase (HS1a; ∼18.4–17.2 kyr BP), ii) a humid middle phase (HS1b; ∼17.2–16.7 kyr BP), and iii) 3 sub-phases (c.1–c.3) during an arid late phase (HS1c; ∼16.7–15.6 kyr BP). This climatic subdivision is regionally supported by SST oscillations from the Mediterranean Sea, suggesting a strong land-ocean relationship. A cyclostratigraphic analysis of our pollen data indicates that HS1 climate variability, and thus this subdivision, is characterized by &sim:2000 and ∼800-yr periodicities, suggesting solar forcing controlling climate in this area.

A high-resolution multi-proxy approach, integrating pollen, inorganic and organic geochemical and sedimentological analyses, has been carried out on the Holocene section of the Padul sedimentary record in the southern Iberian Peninsula reconstructing vegetation, environment and climate throughout the last ~ 11.6 cal kyr BP in the western Mediterranean. The study of the entire Holocene allows us to determine the significant climate shift that occurred during the middle-to-late Holocene transition. The highest occurrence of deciduous forest in the Padul area from ~ 9.5 to 7.6 cal kyr BP represents the Holocene humidity optimum probably due to enhanced winter precipitation during a phase of highest seasonal anomaly and maximum summer insolation. Locally, insolation maxima induced high evaporation, counterbalancing the effect of relatively high precipitation, and triggered very low water table in Padul and the deposition of peat sediments. A transitional environmental change towards more regional aridity occurred from ~ 7.6 to 4.7 cal kyr BP and then aridification enhanced in the late Holocene most likely related to decreasing summer insolation. This translated into higher water levels and a sedimentary change at ~ 4.7 cal kyr BP in the Padul wetland, probably related to reduced evaporation during summer in response to decreased in seasonality. Millennial-scale variability is superimposed on the Holocene long-term trends. The Mediterranean forest regional climate proxy studied here shows significant cold-arid events around ~ 9.6, 8.5, 7.5, 6.5 and 5.4 cal kyr BP with cyclical periodicities (~1100 and 2100 yr) during the early and middle Holocene. A change is observed in the periodicity of these cold-arid events towards ~1430 yr in the late Holocene, with forest declines around ~ 4.7–4, 2.7 and 1.3 cal kyr BP. The comparison between the Padul-15-05 data with published North Atlantic and Mediterranean paleoclimate records suggests common triggers for the observed climate variability, with the early and middle Holocene forest declines at least partially controlled by external forcing (i.e. solar activity) and the late Holocene variability associated with internal mechanisms (oceanic-atmospheric).

Urbanization, agriculture, and other land transformations can affect water quality, decrease species biodiversity, and increase metal and nutrient concentrations in aquatic systems. Metal pollution, in particular, is a reported consequence of elevated anthropogenic inputs, especially from urbanized areas. The objectives of this study were to quantify metal (Cu, Al, Cd, Ni, and Pb) concentrations in the waters and biota of four streams in South Georgia, USA, and relate metal concentrations to land use and abiotic and biotic stream processes. Additionally, macrophytes, invertebrates, and fish were identified to assess biodiversity at each site. Metal concentrations in the three trophic levels differed among sites and species, correlating to differences in land use surrounding the rivers. The highest metal concentrations (except Al) were found in the streams most impacted by urbanization and development. Al concentrations were highest in streams surrounded by land dominated by forested areas. Metal content in macrophytes reflected metal concentrations in the water and was at least three orders of magnitude higher than any other trophic level. Despite metal concentration differences, all four streams contained similar water quality and were healthy based on macroinvertebrate community structure. This study provides insight into the impact of urbanization and the fate and effects of metals in river ecosystems with varying degrees of anthropogenic impact.