421 results on '"Claver C"'
Search Results
2. Non-variable stars inside the ZZ Ceti instability strip
- Author
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Kepler S. O., Giovannini O., Kanaan A., Wood M. A., and Claver C. F.
- Subjects
Astronomy ,QB1-991 - Published
- 1995
- Full Text
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3. Simulation of Astronomical Images from Optical Survey Telescopes using a Comprehensive Photon Monte Carlo Approach
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Peterson, J. R., Jernigan, J. G., Kahn, S. M., Rasmussen, A. P., Peng, E., Ahmad, Z., Bankert, J., Chang, C., Claver, C., Gilmore, D. K., Grace, E., Hannel, M., Hodge, M., Lorenz, S., Lupu, A., Meert, A., Nagarajan, S., Todd, N., Winans, A., and Young, M.
- Subjects
Astrophysics - Instrumentation and Methods for Astrophysics - Abstract
We present a comprehensive methodology for the simulation of astronomical images from optical survey telescopes. We use a photon Monte Carlo approach to construct images by sampling photons from models of astronomical source populations, and then simulating those photons through the system as they interact with the atmosphere, telescope, and camera. We demonstrate that all physical effects for optical light that determine the shapes, locations, and brightnesses of individual stars and galaxies can be accurately represented in this formalism. By using large scale grid computing, modern processors, and an efficient implementation that can produce 400,000 photons/second, we demonstrate that even very large optical surveys can be now be simulated. We demonstrate that we are able to: 1) construct kilometer scale phase screens necessary for wide-field telescopes, 2) reproduce atmospheric point-spread-function moments using a fast novel hybrid geometric/Fourier technique for non-diffraction limited telescopes, 3) accurately reproduce the expected spot diagrams for complex aspheric optical designs, and 4) recover system effective area predicted from analytic photometry integrals. This new code, the photon simulator (PhoSim), is publicly available. We have implemented the Large Synoptic Survey Telescope (LSST) design, and it can be extended to other telescopes. We expect that because of the comprehensive physics implemented in PhoSim, it will be used by the community to plan future observations, interpret detailed existing observations, and quantify systematics related to various astronomical measurements. Future development and validation by comparisons with real data will continue to improve the fidelity and usability of the code., Comment: Accepted for publication in ApJS; 34 pages, 15 figures
- Published
- 2015
- Full Text
- View/download PDF
4. LSST optical beam simulator
- Author
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Tyson, J. A., Sasian, J., Gilmore, K., Bradshaw, A., Claver, C., Klint, M., Muller, G., Poczulp, G., and Resseguie, E.
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Astrophysics - Instrumentation and Methods for Astrophysics - Abstract
We describe a camera beam simulator for the LSST which is capable of illuminating a 60mm field at f/1.2 with realistic astronomical scenes, enabling studies of CCD astrometric and photometric performance. The goal is to fully simulate LSST observing, in order to characterize charge transport and other features in the thick fully depleted CCDs and to probe low level systematics under realistic conditions. The automated system simulates the centrally obscured LSST beam and sky scenes, including the spectral shape of the night sky. The doubly telecentric design uses a nearly unit magnification design consisting of a spherical mirror, three BK7 lenses, and one beam-splitter window. To achieve the relatively large field the beam-splitter window is used twice. The motivation for this LSST beam test facility was driven by the need to fully characterize a new generation of thick fully-depleted CCDs, and assess their suitability for the broad range of science which is planned for LSST. Due to the fast beam illumination and the thick silicon design [each pixel is 10 microns wide and over 100 microns deep] at long wavelengths there can be effects of photon transport and charge transport in the high purity silicon. The focal surface covers a field more than sufficient for a 40x40 mm LSST CCD. Delivered optical quality meets design goals, with 50% energy within a 5 micron circle. The tests of CCD performance are briefly described., Comment: 9 pages, 9 figures
- Published
- 2014
- Full Text
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5. Properties of Ellipticity Correlation with Atmospheric Structure from Gemini South
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Asztalos, S., de Vries, W. H., Rosenberg, L. J, Treadway, T., Burke, D., Claver, C., Saha, A., and Puxley, P.
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Astrophysics - Abstract
Cosmic shear holds great promise for a precision independent measurement of $\Omega\rm_m$, the mass density of the universe relative to the critical density. The signal is expected to be weak, so a thorough understanding of systematic effects is crucial. An important systematic effect is the atmosphere: shear power introduced by the atmosphere is larger than the expected signal. Algorithms exist to extract the cosmic shear from the atmospheric component, though a measure of their success applied to a range of seeing conditions is lacking. To gain insight into atmospheric shear, Gemini South imaging in conjunction with ground condition and satellite wind data were obtained. We find that under good seeing conditions Point-Spread-Function (PSF) correlations persist well beyond the separation typical of high-latitude stars. Under these conditions, ellipticity residuals based on a simple PSF interpolation can be reduced to within a factor of a few of the shot-noise induced ellipticity floor. We also find that the ellipticity residuals are highly correlated with wind direction. Finally, we correct stellar shapes using a more sophisticated procedure and generate shear statistics from stars. Under all seeing conditions in our data set the residual correlations lie everywhere below the target signal level. For good seeing we find that the systematic error attributable to atmospheric turbulence is comparable in magnitude to the statistical error (shape noise) over angular scales relevant to present lensing surveys., Comment: To appear in ApJ April 10, 2007, 659 1
- Published
- 2007
- Full Text
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6. Photometric Identification of Cool White Dwarfs
- Author
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Kilic, M., Winget, D. E., von Hippel, Ted, and Claver, C. F.
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Astrophysics - Abstract
We investigate the use of a narrow-band DDO51 filter for photometric identification of cool white dwarfs. We report photometric observations of 30 known cool white dwarfs with temperatures ranging from 10,000 K down to very cool temperatures (<3500 K). Follow-up spectroscopic observations of a sample of objects selected using this filter and our photometric observations show that DDO51 filter photometry can help select cool white dwarf candidates for follow-up multi--object spectroscopy by rejecting 65% of main sequence stars with the same broad--band colors as the cool white dwarfs. This technique is not selective enough to efficiently feed single--object spectrographs. We present the white dwarf cooling sequence using this filter. Our observations show that very cool white dwarfs form a sequence in the r-DDO vs. r-z color--color diagram and demonstrate that significant improvements are needed in white dwarf model atmospheres., Comment: Accepted for publication in AJ
- Published
- 2004
- Full Text
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7. Identification of Cool White Dwarfs in the NOAO Deep Wide-Field Survey
- Author
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Kilic, M., Winget, D. E., von Hippel, T., and Claver, C. F.
- Subjects
Astrophysics - Abstract
We report our search for the cool white dwarfs belonging to the Galactic disk by extending the NOAO Deep Wide-Field Survey. Narrow-band DDO51 photometry of the Deep Wide-Field Survey's northern field was obtained using the 4m-Mayall Telescope and the MOSAIC imager to separate cool white dwarfs from other stellar types of similar T_eff. Follow-up spectroscopy of four white dwarf candidates from our photometric search resulted in the discovery of two new cool white dwarfs as companions to M dwarfs., Comment: 2 pages, 2 figures, to appear in proceedings of the 13th European Workshop on White Dwarfs
- Published
- 2002
8. DDO Photometry of M71: Carbon and Nitrogen Patterns Among Evolving Giants
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Briley, M. M., Smith, G. H., and Claver, C. F.
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Astrophysics - Abstract
We present V, B-V, and DDO C(41-42) and C(42-45) photometry for a sample of 75 red giants down to M_V = +2 in the relatively metal-rich Galactic globular cluster M71. The C(41-42) colors reveal a bimodal distribution of CN band strengths generally anticorrelated with CH band strength as measured by the C(42-45) color. Both DDO colors agree well with those found in 47 Tucanae -- a nearby globular cluster of similar metallicity -- and suggest nearly identical C and N abundance patterns among the giants of both clusters. A comparison with synthetic DDO colors demonstrates that little change in surface C or N abundance is required to match the colors of the M71 giants over the entire luminosity range observed. Apparently like 47 Tuc (a cluster of much greater mass and central concentration), M71 exhibits an abundance pattern which cannot be solely the result of internal mixing., Comment: To appear in the Astronomical Journal, November 2001. 17 Pages, 5 Figures
- Published
- 2001
- Full Text
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9. Understanding the Cool DA White Dwarf, G29-38
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Kleinman, S. J., Nather, R. E., Winget, D. E., Clemens, J. C., Bradley, P. A., Kanaan, A., Provencal, J. L., Claver, C. F., Watson, T. K., Yanagida, K., Nitta, A., Dixson, J. S., Wood, M. A., Grauer, A. D., Hine, B. P., Fontaine, G., Liebert, James, Sullivan, D. J., Wickramasinghe, D. T., Marar, N. Achilleos. T. M. K., Seetha, S., Ashoka, B. N., Meistas, E., Leibowitz, E. M., Moskalik, P., Krzesinski, J., Solheim, J. -E., Bruvold, A., Kurtz, D. W., Warner, B., Martinez, Peter, Vauclair, G., Dolez, N., Chevreton, M., Barstow, M. A., Kepler, S. O., Giovannini, O., Augusteijn, T., Hansen, C. J., and Kawaler, S. D.
- Subjects
Astrophysics - Abstract
The white dwarfs are promising laboratories for the study of cosmochronology and stellar evolution. Through observations of the pulsating white dwarfs, we can measure their internal structures and compositions, critical to understanding post main sequence evolution, along with their cooling rates, allowing us to calibrate their ages directly. The most important set of white dwarf variables to measure are the oldest of the pulsators, the cool DAVs, which have not previously been explored through asteroseismology due to their complexity and instability. Through a time-series photometry data set spanning ten years, we explore the pulsation spectrum of the cool DAV, G29-38 and find an underlying structure of 19 (not including multiplet components) normal-mode, probably l=1 pulsations amidst an abundance of time variability and linear combination modes. Modelling results are incomplete, but we suggest possible starting directions and discuss probable values for the stellar mass and hydrogen layer size. For the first time, we have made sense out of the complicated power spectra of a large-amplitude DA pulsator. We have shown its seemingly erratic set of observed frequencies can be understood in terms of a recurring set of normal-mode pulsations and their linear combinations. With this result, we have opened the interior secrets of the DAVs to future asteroseismological modelling, thereby joining the rest of the known white dwarf pulsators., Comment: 29 pages including 5 figures To appear in ApJ 1 Mar 98
- Published
- 1997
- Full Text
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10. The 9 Aurigae System
- Author
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Krisciunas, K., Aspin, C., Geballe, T. R., Akazawa, H., Claver, C. F., Guinan, E. F., Landis, H. J., Luedeke, K. D., Ohkura, N., Ohshima, O., and Skillman, D. R.
- Subjects
Astrophysics - Abstract
The F0 V star 9 Aur A exhibits an irregular variability of amplitude $\approx $0.1 magnitude at optical wavelengths. The variations are too slow for it to be a $\delta$ Scuti-type star. There is no evidence for a close, interacting companion or ring of dust, either from infrared, ultraviolet, or speckle data. The photometric variability of 9 Aur A is similar to two other early F dwarf stars: $\gamma$ Doradus and HD 96008. 9 Aur B appears to be an M dwarf, 9 Aur C is an early- to mid-K dwarf star, and 9 Aur E, if it is a member of the system, probably is a normal white dwarf. 9 Aur D is most likely an unrelated and distant K giant. [See note added in press regarding a fourth member of this class of ``variables without a cause", and short term variations of the radial velocity of 9 Aur.], Comment: 16 pages plus 2 tables plus 6 figures Edinburgh Astronomy Preprint 6/93
- Published
- 1993
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11. Immobilized Pd metal-complex on polymeric resin with high surface areas for recyclable catalyst: Effect of the immobilization method on nature of palladium species
- Author
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Universitat Rovira i Virgili, Mella, C; Pecchi, G; Godard, C; Claver, C; Márquez, A; Campos, CH, Universitat Rovira i Virgili, and Mella, C; Pecchi, G; Godard, C; Claver, C; Márquez, A; Campos, CH
- Abstract
A critical query on literature is the approach used to immobilize homogeneous catalysts to improve their efficiency and recyclability. This work aims to compare the immobilization level of a kind of Pd-N,N′-bis(salicylidene)-o-phenylenediamine complex on high surfaces of polymeric resins to provide heterogenous catalysts for Mizorocki-Heck reaction. The preparation method involves two strategies: (i) polymerization of the ligand before the complex-synthesis in a “multi-step (MS)” approach and (ii) a direct “one-step” (OS) immobilization by polymerization of the metal-containing monomers (MCMs) as co-monomer. Both approaches effectively yield polymers with a larger surface area, over 700 m2 g−1, and suitable thermic properties to use in the proposed reaction. In addition, the characterization of the polymers by XRD, XPS, and TEM demonstrates notable differences in Pd species on polymer support associated with the methodological approach to immobilizing the metal complex.
- Published
- 2023
12. Bringing Selectivity in H/D Exchange Reactions Catalyzed by Metal Nanoparticles through Modulation of the Metal and the Ligand Shell
- Author
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Universitat Rovira i Virgili, Martinez-Espinar, F; Salom-Català, A; Bresó-Femenia, E; Claver, C; Baletto, F; Ricart, JM; Chaudret, B; Carbó, JJ; Godard, C; Castillon, S, Universitat Rovira i Virgili, and Martinez-Espinar, F; Salom-Català, A; Bresó-Femenia, E; Claver, C; Baletto, F; Ricart, JM; Chaudret, B; Carbó, JJ; Godard, C; Castillon, S
- Abstract
Ru and Rh nanoparticles catalyze the selective H/D exchange in phosphines using D2 as the deuterium source. The position of the deuterium incorporation is determined by the structure of the P-based substrates, while activity depends on the nature of the metal, the properties of the stabilizing agents, and the type of the substituent on phosphorus. The appropriate catalyst can thus be selected either for the exclusive H/D exchange in aromatic rings or also for alkyl substituents. The selectivity observed in each case provides relevant information on the coordination mode of the ligand. Density functional theory calculations provide insights into the H/D exchange mechanism and reveal a strong influence of the phosphine structure on the selectivity. The isotope exchange proceeds via C-H bond activation at nanoparticle edges. Phosphines with strong coordination through the phosphorus atom such as PPh3 or PPh2Me show preferred deuteration at ortho positions of aromatic rings and at the methyl substituents. This selectivity is observed because the corresponding C-H moieties can interact with the nanoparticle surface while the phosphine is P-coordinated, and the C-H activation results in stable metallacyclic intermediates. For weakly coordinating phosphines such as P(o-tolyl)3, the interaction with the nanoparticle can occur directly through phosphine substituents, and then, other deuteration patterns are observed.
- Published
- 2023
13. 2.7.1 Biphasic Systems
- Author
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Claver, C., additional, Godard, C., additional, and Lombardía, A., additional
- Published
- 2018
- Full Text
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14. Mechanistic Insights of Photocatalytic CO2 Reduction: Experimental versus Computational Studies
- Author
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Universitat Rovira i Virgili, Masdeu-Bultó AM; Reguero M; Claver C, Universitat Rovira i Virgili, and Masdeu-Bultó AM; Reguero M; Claver C
- Abstract
To stop the global warming, a complementary alternative to the decrease of CO2 production is the reduction of its amount in the atmosphere by capture and transformation into consumer products. One of the most interesting primary products is CO, used to synthesise liquid fuels. Perhaps the most attractive way of reducing CO2 to CO is the photocatalytic route. To know the details of the mechanism of this reaction can help in the design of more efficient catalytic systems. In this review, we compile the studies, undertaken from both computational and experimental approaches, of the reaction mechanism of the photoreduction of CO2 to CO by molecular catalytic systems based on transition metal complexes. The combination of experimental and computational studies can be crucial to achieve the goal aimed.
- Published
- 2022
15. Controlled One-pot Synthesis of PdAg Nanoparticles and Their Application in the Semi-hydrogenation of Acetylene in Ethylene-rich Mixtures
- Author
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Universitat Rovira i Virgili, Delgado JA; Benkirane O; de Lachaux S; Claver C; Ferré J; Curulla-Ferré D; Godard C, Universitat Rovira i Virgili, and Delgado JA; Benkirane O; de Lachaux S; Claver C; Ferré J; Curulla-Ferré D; Godard C
- Abstract
In the present paper, we report the synthesis of highly functionalized nanomaterials carefully nanoengineered to catalyze the semi-hydrogenation of acetylene in ethylene-rich mixtures. Surface functionalization and structure modification of a series of bimetallic PdAg nanoparticles was performed using HHDMA as stabilizer and alloying the active palladium phase with silver. Bimetallic PdAg NPs with adjustable Pd/Ag ratio were prepared in water through a novel one-pot methodology using hydrogen gas as a benign reducing agent and cyanide as additive. UV-Vis studies indicated the formation of the bimetallic nanostructures through a sequential displacement-galvanic reduction process mediated by cyanide. The series of colloidal NPs were deposited onto alumina and successfully applied as catalysts in the selective hydrogenation of acetylene in ethylene rich mixtures. Geometric and electronic promotion of Ag over Pd based catalysts was evidenced by the increase of the ethylene selectivity with the Ag content. The reactivity of these materials demonstrated the applicability of HHDMA stabilized NPs in a gas phase reaction of industrial interest and the success of combining several strategies for the enhancement of the alkene selectivity.
- Published
- 2022
16. Calibrating white dwarf cosmochronology
- Author
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Claver, C. F., Winget, D. E., Araki, H., editor, Brézin, E., editor, Ehlers, J., editor, Frisch, U., editor, Hepp, K., editor, Jaffe, R. L., editor, Kippenhahn, R., editor, Weidenmüller, H. A., editor, Wess, J., editor, Zittartz, J., editor, Beiglböck, W., editor, Koester, Detlev, editor, and Werner, Klaus, editor
- Published
- 1995
- Full Text
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17. Whole Earth Telescope Observations of the DBV White Dwarf PG1115+158: Preliminary Results
- Author
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Clemens, J. C., Barstow, M. A., Nather, R. E., Winget, D. E., Bradley, P. A., Claver, C. F., Dixon, J. S., Kanaan, A., Kleinman, S. J., Provencal, J., Wood, M. A., Sullivan, D., Wickramasinghe, D. T., Ferrario, L., Marar, T. M. K., Seetha, S., Ashoka, B. N., Leibowitz, E., Mendelson, H., O’Donoghue, D., Buckley, D. A., Chen, A.-L., Zola, S., Krzesinski, J., Moskalik, P., Vauclair, G., Fremy, J.-R., Chevreton, M., Kepler, S. O., Odilon, G., and Barstow, Martin A., editor
- Published
- 1993
- Full Text
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18. Observation of a Variable, ZZ Ceti White Dwarf: GD154
- Author
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Pfeiffer, B., Vauclair, G., Dolez, N., Chevreton, M., Fremy, J. R., Herpe, G., Barstow, M., Kleinman, S. J., Watson, T. K., Belmonte, J. A., Kepler, S. O., Kan-Aan, A., Giovannini, O., Nather, R. E., Winget, D. E., Provencal, J., Clemens, J. C., Bradley, P., Dixson, J., Grauer, A. D., Fontaine, G., Bergeron, P., Wesemael, F., Claver, C. F., Matzeh, T., Leibowitz, E., Moskalik, P., Takeuti, M., editor, and Buchler, J.-R., editor
- Published
- 1993
- Full Text
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19. Whole Earth Telescope Observations of the Interacting White Dwarf Binary System AM CVn: First Results
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Solheim, J.-E., Emanuelsen, P.-I., Vauclair, G., Dolez, N., Chevreton, M., Barstow, M., Sansom, A. E., Tweedy, R. W., Kepler, S. O., Kanaan, A., Fontaine, G., Bergeron, P., Grauer, A. D., Provencal, J. L., Winget, D. E., Nather, R. E., Bradley, P. A., Claver, C. F., Clemens, J. C., Kleinman, S. J., Hine, B. P., Marar, T. M. K., Seetha, S., Ashoka, B. N., Leibowitz, E. M., Mazeh, T., Vauclair, Gérard, editor, and Sion, Edward, editor
- Published
- 1991
- Full Text
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20. A Measurement of the Evolutionary Timescale of the Cool White Dwarf G117-B15A with Wet
- Author
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Kepler, S. O., Kanaan, A., Winget, D. E., Nather, R. E., Bradley, P. A., Clemens, J. C., Kleinman, S. J., Claver, C. F., Provencal, J. L., Grauer, A. D., Fontaine, G., Bergeron, P., Wesemael, F., Wood, M. A., Vauclair, G., Marar, T. M. K., Seetha, S., Ashoka, B. N., Mazeh, T., Leibowitz, E., Dolez, N., Chevreton, M., Barstow, M. A., Sansom, A. E., Tweedy, R. W., Hine, B. P., Solheim, J.-E., Emanuelsen, P.-I., Vauclair, Gérard, editor, and Sion, Edward, editor
- Published
- 1991
- Full Text
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21. Carbon Abundances of M92 Red Giant Branch Stars
- Author
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Bellman, Susan, Briley, Michael M., Smith, Graeme H., and Claver, C. F.
- Published
- 2001
- Full Text
- View/download PDF
22. 1.1.2 Asymmetric Hydroformylation of Alkenes
- Author
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Godard, C., additional, Perandones, B. F., additional, and Claver, C., additional
- Published
- 2014
- Full Text
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23. Asymmetric Carbonylations
- Author
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Godard, C., primary, Perandones, B.F., additional, Gual, A., additional, and Claver, C., additional
- Published
- 2013
- Full Text
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24. Identification of Cool White Dwarfs in the Noao Deep Wide-Field Survey
- Author
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Kilic, M., Winget, D. E., Von Hippel, T., Claver, C. F., de Martino, Domitilla, editor, Silvotti, Roberto, editor, Solheim, Jan-Erik, editor, and Kalytis, Romualdas, editor
- Published
- 2003
- Full Text
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25. Metal Complexes as Catalysts for Addition of Carbon Monoxide
- Author
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Van Leeuwen, P.W.N.M., primary and Claver, C., additional
- Published
- 2003
- Full Text
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26. Hybrid Metalloporphyrin Magnetic Nanoparticles as Catalysts for Sequential Transformation of Alkenes and CO2 into Cyclic Carbonates
- Author
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Masdeu, A., Dias, L., Carrilho, R., Henriques, C., Calvete, M. J., Claver, C., Rossi, L., Pereira, M., Innovation in Catalysis, Química Física i Inorgànica, and Universitat Rovira i Virgili
- Subjects
metalloporphyrins ,Chemistry ,1867-3880 ,Nanopartícules ,Magnetic nanoparticles ,Química - Abstract
open access The synthesis and full characterization of manganese and chromium metalloporphyrins and hybrid magnetic nanocomposites prepared thereof is described. Their application in homogeneous and heterogeneous sequential epoxidation/CO2 cycloaddition reactions by using O2 or H2O2 as the oxidant showed high activity and selectivity for the preparation of a variety of cyclic carbonates directly from olefins. The combination of manganese and chromium nanocomposites allowed us to set the keystone for the development of a reusable dual catalytic system to transform olefins into cyclic carbonates
- Published
- 2018
27. Hybrid Metalloporphyrin Magnetic Nanoparticles as Catalysts for Sequential Transformation of Alkenes and CO2 into Cyclic Carbonates
- Author
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Innovation in Catalysis, Química Física i Inorgànica, Universitat Rovira i Virgili, Masdeu, A. ; Dias, L. ; Carrilho, R. ; Henriques, C. ; Calvete, M. J. ; Claver, C. ; Rossi, L. ; Pereira, M., Innovation in Catalysis, Química Física i Inorgànica, Universitat Rovira i Virgili, and Masdeu, A. ; Dias, L. ; Carrilho, R. ; Henriques, C. ; Calvete, M. J. ; Claver, C. ; Rossi, L. ; Pereira, M.
- Abstract
open access, The synthesis and full characterization of manganese and chromium metalloporphyrins and hybrid magnetic nanocomposites prepared thereof is described. Their application in homogeneous and heterogeneous sequential epoxidation/CO2 cycloaddition reactions by using O2 or H2O2 as the oxidant showed high activity and selectivity for the preparation of a variety of cyclic carbonates directly from olefins. The combination of manganese and chromium nanocomposites allowed us to set the keystone for the development of a reusable dual catalytic system to transform olefins into cyclic carbonates
- Published
- 2018
28. The unusual helium variable AM Canum Venaticorum
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Provencal, J. L, Winget, D. E, Nather, R. E, Robinson, E. L, Solheim, J.-E, Clemens, J. C, Bradley, J. L, Kleinman, S. J, Kanaan, A, and Claver, C. F
- Subjects
Astrophysics - Abstract
The unusual variable star AM CVn has puzzled astronomers for over 40 years. This object, both a photometric and spectroscopic variable, is believed to contain a pair of hydrogen-deficient white dwarfs of extreme mass ratio, transferring material via an accretion disk. We examine the photometric properties of AM CVn, analyzing 289 hours of high-speed photometric data spanning 1976 to 1992. The power spectrum displays significant peaks at 988.7, 1248.8, 1902.5, 2853.8, 3805.2, 4756.5, and 5707.8 microHz (1011.4, 800.8, 525.6, 350.4, 262.8, 210.2, and 175.2 s). We find no detectable power at 951.3 microHz (1051 s), the previously reported main frequency. The 1902.5, 2853.9, and 3805.2 microHz peaks are multiplets, with frequency splitting in each case of 20.77 +/- 0.05 microHz. The 1902.5 microHz seasonal pulse shapes are identical, within measurement noise, and maintain the same amplitude and phase as a function of color. We have determined the dominant frequency to be 1902.50902 +/- 0.00001 microHz with dot P = +1.71 (+/- 0.04) x 10(exp -11) s/s. We discuss the implications of these findings on a model for AM CVn.
- Published
- 1995
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29. Preimpact characterization of Comet P/Shoemaker-Levy 9
- Author
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Cochran, Anita L, Whipple, Arthur L, Macqueen, Phillip J, Shelus, Peter J, Whited, Randy W, and Claver, C. F
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Astronomy - Abstract
At McDonald Observatory, we have undertaken a major program of observation of Comet P/Shoemaker-Levy 9 in order to charcterize the dynamics and physical make-up of the fragments prior to their disappearance in July 1994 when they collide with Jupiter. Obserations have included astrometry, photometry, and spectroscopy. Our astrometric observations have been important for deriving accurate orbits for the individual fragments. With the photometry, we have derived (B-V) and (V-R) colors for a number of fragemnts. We show that they are slightly redder than the Sun in (B-V) and similar to the Sun in (V-R); they may show differences in colors for the individual fragments. We detected no gas with our spectroscopic observations and have derived sensitive upper limits on the quantity of gas. Our observations are consistent with the parent being a comet, as classified, but cannot rule out certain types of asteroids as progenitors.
- Published
- 1994
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30. Whole earth telescope observations of the DBV white dwarf GD 358
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Winget, D. E, Nather, R. E, Clemens, J. C, Provencal, J. L, Kleinman, S. J, Bradley, P. A, Claver, C. F, Dixson, J. S, Montgomery, M. H, and Hansen, C. J
- Subjects
Astrophysics - Abstract
We report on the analysis of 154 hours of early continuous high-speed photometry on the pulsating DB white dwarf (DBV) GD 358, obtained during the Whole Earth Telescope (WET) run of 1990 May. The power spectrum of the light curve is dominated by power in the range from 1000 to 2400 microHz with more than 180 significant peaks in the total spectrum. We identify all of the triplet frequencies as degree l = 1, and from the details of their spacings we derive the total stellar mass as 0.61 + or - 0.03 solar mass, the mass of the outer helium envelope as 2.0 + or - 1.0 x 10(exp -6) M(sub *), the absolute luminosity as 0.050 + or - 0.012 solar luminosity and the distance as 42 + or - 3 pc. We find strong evidence for differential rotation in the radial direction -- the outer envelope is rotating at least 1.8 times faster than the core -- and we detect the presence of a weak magnetic field with a strength of 1300 + or - 300 G. We also find a significant power at the sums and differences of the dominant frequencies, indicating nonlinear processes are significant, but they have a richness and complexity that rules out resonant mode coupling as a major cause.
- Published
- 1994
- Full Text
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31. NHC-stabilised Rh nanoparticles: Surface study and application in the catalytic hydrogenation of aromatic substrates
- Author
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Blondeau, P., Martinez-Espinar, F., Nolis, P., Chaudret, B., Claver, C., Castillón, S., Godard, C., Departament de Quimica Fisica i Inorganica, Universitat Rovira i Virgili, Laboratoire de physique et chimie des nano-objets (LPCNO), Institut National des Sciences Appliquées - Toulouse (INSA Toulouse), Institut National des Sciences Appliquées (INSA)-Université de Toulouse (UT)-Institut National des Sciences Appliquées (INSA)-Université de Toulouse (UT)-Institut de Chimie de Toulouse (ICT), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Institut de Recherche sur les Systèmes Atomiques et Moléculaires Complexes (IRSAMC), Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Departament de Quimica Analitica i Quimica Organica, Servei de Ressonància Magnètica Nuclear, Facultat de Ciències, Universitat Autònoma de Barcelona, Universitat Autònoma de Barcelona (UAB), Centre Tecnològic de Química, Institut de Recherche sur les Systèmes Atomiques et Moléculaires Complexes (IRSAMC), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut National des Sciences Appliquées - Toulouse (INSA Toulouse), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie de Toulouse (ICT-FR 2599), Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Institut de Chimie du CNRS (INC), Síntesis Orgànica Estereoselectiva, Organometàl.lics i Catàlisi Homogènia, Grup de Quimiometria, Qualimetria i Nanosensors, Química Física i Inorgànica, and Química Analítica i Química Orgànica
- Subjects
rhodium nanoparticles ,Phenol ,NHC ,NHCs ,Pyridine ,Quinoline ,Química ,0021-9517 ,Surface ,Chemistry ,Aromatic ketone ,Rodi ,Nanoparticles ,Rhodium ,[CHIM.COOR]Chemical Sciences/Coordination chemistry ,Hydrogenation ,Hidrogenació - Abstract
International audience; New Rh-NPs stabilised by N-Heterocyclic Carbenes (NHC) were synthesized by decomposition of [Rh(η3-C3H5)3] under H2 atmosphere and fully characterized. Surface studies by FT-IR and NMR spectroscopy employing isotopically labelled ligands were also performed. The Rh0.2 NPs are active catalysts in the reduction of various aromatic substrates. In the reduction of phenol, high selectivities to cyclohexanone or cyclohexanol were obtained depending on the reaction conditions. However, this catalytic system exhibited much lower activity in the hydrogenation of substituted phenols. Pyridine was easily hydrogenated under mild conditions and interestingly, the hydrogenation of 4-methyl and 4-trifluoromethylpyridine resulted slower than that of 2-methylpyridine. The hydrogenation of 1-(pyridin-2-yl)propan-2-one provided the β-enaminone 13a in high yield as a consequence of the partial reduction of the pyridine ring followed by isomerization. Quinoline could be either partially hydrogenated to 1,2,3,4-tetrahydroquinoline or fully reduced to decahydroquinoline by adjusting the reaction conditions.
- Published
- 2017
- Full Text
- View/download PDF
32. Whole Earth Telescope observations of V471 Tauri - The nature of the white dwarf variations
- Author
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Clemens, J. C, Nather, R. E, Winget, D. E, Robinson, E. L, Wood, M. A, Claver, C. F, Provencal, J, Kleinman, S. J, Bradley, P. A, and Frueh, M. L
- Subjects
Astronomy - Abstract
Time-series photometric observations of the binary star V471 Tauri were conducted using the Whole Earth Telescope observing network. The purpose was to determine the mechanism responsible for causing the 555 and 277 s periodic luminosity variations exhibited by the white dwarf in this binary. Previous observers have proposed that either g-mode pulsations or rotation of an accreting magnetic white dwarf could cause the variations, but were unable to decide which was the correct model. The present observations have answered this question. Learning the cause of the white dwarf variations has been possible because of the discovery of a periodic signal at 562 s in the Johnson U-band flux of the binary. By identifying this signal as reprocessed radiation and using its phase to infer the phase of the shorter wavelength radiation which produces it, made it possible to compare the phase of the 555 s U-band variations to the phase of the X-ray variations. It was found that U-band maximum coincides with X-ray minimum. From this result it was concluded that the magnetic rotator model accurately describes the variations observed, but that models involving g-mode pulsations do not.
- Published
- 1992
- Full Text
- View/download PDF
33. A detection of the evolutionary time scale of the DA white dwarf G117 - B15A with the Whole Earth Telescope
- Author
-
Kepler, S. O, Fontaine, G, Bergeron, P, Winget, D. E, Nather, R. E, Bradley, P. A, Claver, C. F, Grauer, A. D, Vauclair, G, and Marar, T. M. K
- Subjects
Astrophysics - Abstract
The time rate of change for the main pulsation period of the 13,000 K DA white dwarf G117 - B15A has been detected using the Whole Earth Telescope (WET). The observed rate of period change, P(dot) = (12.0 + or - 3.5) x 10 to the -15th s/s, is somewhat larger than the published theoretical calculations of the rate of period change due to cooling, based on carbon core white dwarf models. Other effects that could contribute to the observed rate of period change are discussed.
- Published
- 1991
- Full Text
- View/download PDF
34. Asteroseismology of the DOV star PG 1159 - 035 with the Whole Earth Telescope
- Author
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Winget, D. E, Nather, R. E, Clemens, J. C, Provencal, J, Kleinman, S. J, Bradley, P. A, Wood, M. A, Claver, C. F, Frueh, M. L, and Grauer, A. D
- Subjects
Astrophysics - Abstract
Results are reported from 264.1 hr of nearly continuous time-series photometry on the pulsating prewhite dwarf star (DPV) PG 1159 - 035. The power spectrum of the data set is completely resolved into 125 individual frequencies; 101 of them are identified with specific quantized pulsation modes, and the rest are completely consistent with such modal assignment. It is argued that the luminosity variations are certainly the result of g-mode pulsations. Although the amplitudes of some of the peaks exhibit significant variations on the time scales of a year or so, the underlying frequency structure of the pulsations is stable over much longer intervals. The existing linear theory is invoked to determine, or strongly constrain, many of the fundamental physical parameters describing this star. Its mass is found to be 0.586 solar mass, is rotation period 1.38 days, its magnetic field less than 6000 G, its pulsation and rotation axes to be aligned, and its outer layers to be compositionally stratified.
- Published
- 1991
- Full Text
- View/download PDF
35. Recyclable supported Pd-NHC catalytic systems for the copper-free Sonogashira cross-coupling in flow
- Author
-
Peñafiel, I., primary, Martínez-Lombardia, A., additional, Godard, C., additional, Claver, C., additional, and Lapkin, A., additional
- Published
- 2018
- Full Text
- View/download PDF
36. Whole earth telescope observations of the white dwarf G29-38 - Phase variations of the 615 second period
- Author
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Winget, D. E, Nather, R. E, Clemens, J. C, Provencal, J, Kleinman, S. J, Bradley, P. A, Wood, M. A, Claver, C. F, Robinson, E. L, and Hine, B. P
- Subjects
Astrophysics - Abstract
An extensive set of high-speed photometric observations obtained with the Whole Earth Telescope network is used to show that the complex light curve of the ZZ Zeti (DAV) star G29-38 is dominated by a single, constant amplitude period of 615 s during the time span of these observations. The pulse arrival times for this period exhibit a systematic variation in phase readily explained by light-travel time effects produced by reflex orbital motion about an unseen companion. The best-fit model to the observations indicates a highly eccentric orbit, a period of 109 + or - 13 days and a minimum mass of 0.5 solar mass for the companion.
- Published
- 1990
- Full Text
- View/download PDF
37. Synthesis, reactivity and catalytic properties of rhodium complexes of ( R,R)-1-benzyl-3,4-dithioetherpyrrolidines
- Author
-
Diéguez, M, Ruiz, A, Claver, C, Pereira, M.M, Flor, M.T, Bayón, J.C, Serra, M.E.S, and Rocha Gonsalves, A.M.d’A
- Published
- 1999
- Full Text
- View/download PDF
38. Core-substituted naphthalenediimides anchored on BiVO4 for visible light-driven water splitting
- Author
-
Organometàl.lics i Catàlisi Homogènia, Química Quàntica, Síntesis Orgànica Estereoselectiva, Química Física i Inorgànica, Química Analítica i Química Orgànica, Universitat Rovira i Virgili, Carbó, J. ; Hernández, S. ; Ottone, C. ; Proto, S.; Tolod, K.; Díaz de los Bernardos, M. ; Solé-Daura, A. ; Godard, C.; Castillón, S. ; Russo, N. ; Saracco, G. ; Claver, C., Organometàl.lics i Catàlisi Homogènia, Química Quàntica, Síntesis Orgànica Estereoselectiva, Química Física i Inorgànica, Química Analítica i Química Orgànica, Universitat Rovira i Virgili, and Carbó, J. ; Hernández, S. ; Ottone, C. ; Proto, S.; Tolod, K.; Díaz de los Bernardos, M. ; Solé-Daura, A. ; Godard, C.; Castillón, S. ; Russo, N. ; Saracco, G. ; Claver, C.
- Abstract
In this work, a novel catalytic system for the sunlight-driven water splitting reaction, which exploits the photocatalytic ability of BiVO4 coupled to a new kind of noble-metal-free organic dye molecules, is proposed. Hence, mono- and di-substituted naphthalenediimides (NDIs) were designed to have different functional groups that provide to them both tunable optical properties and adjustable HOMO/LUMO levels, and were selectively prepared (starting from 1,4,5,8-naphthalenetetracarboxylic acid) achieving yields >69%. Smart anchoring groups (i.e. carboxylates or aromatic amines) were added to the dyes in order to allow them to covalently bond to acidic –OH groups present on the BiVO4 surface. An easy and low-cost room temperature dip-coating technique was used to dye-sensitize both BiVO4 powders and thin films. NMR, MS, FT-IR, TG, FESEM, XRD, XPS and optical analyses confirmed the successful organic synthetic routes and good dyes/BiVO4 linkages. Photochemical and photoelectrochemical water oxidation reaction tests, together with DFT calculations, demonstrated that a proper alignment of the semiconductor/NDI-based dye energy levels is fundamental for enhancing the photocatalyst performance through a Z-scheme mechanism. The ability of the NDI organic molecules to delocalize the electronic charges was also a key factor for minimizing recombination processes and achieving more than a ten-fold increase in the photocurrent density of a 6 cm2 BiVO4 photo-electrode. The here reported results open new perspectives for the utilization of this new series of core-substituted NDIs, which are able to improve the activity of photocatalysts for different sunlight-driven applications, e.g. waste water treatment and organic contaminants’ degradation, other than the production of sola
- Published
- 2017
39. Advances in the preparation of highly selective nanocatalysts for the semi-hydrogenation of alkynes using colloidal approaches
- Author
-
Organometàl.lics i Catàlisi Homogènia, Química Física i Inorgànica, Universitat Rovira i Virgili, Claver, C. ; Delgado, J. ; Benkirane, O. ; Curulla-Ferré, D. ; Godard. C., Organometàl.lics i Catàlisi Homogènia, Química Física i Inorgànica, Universitat Rovira i Virgili, and Claver, C. ; Delgado, J. ; Benkirane, O. ; Curulla-Ferré, D. ; Godard. C.
- Abstract
Filiació URV: SI Review, In the last decade, the semi-hydrogenation of alkynes has experienced significant advances in terms of fine control of alkene selectivity and prevention of the over-hydrogenation reaction. Such advances have been possible to a large extent through the progress in colloidal methods for the preparation of metallic nanoparticles. The present review describes the contributions in the field of the selective hydrogenation of alkynes involving the utilization of colloidal methodologies. These approaches permit the fine modulation of several parameters affecting the catalytic performance of the active phase such as the particle size, the bulk and the surface structure and composition. For the transformation of liquid substrates, the nature of the stabilizers, the reducing agents and the metal precursors employed for the synthesis of the catalysts can be tuned to enhance the alkene selectivity. In contrast, in catalytic transformations of gaseous substrates, the presence of adsorbed species at the metal surface usually gives detrimental results while the interplay between the support and the active phase appears to be a more convincing alternative for catalyst tuning.
- Published
- 2017
40. Facile synthesis of NHC-stabilized Ni nanoparticles and their catalytic application in the Z-selective hydrogenation of alkynes
- Author
-
Organometàl.lics i Catàlisi Homogènia, Química Física i Inorgànica, Universitat Rovira i Virgili, Claver, C. ; Díaz de los Bernardos, M. ; Pérez-Rodríguez, S. ; Gual, A. ; Godard, C., Organometàl.lics i Catàlisi Homogènia, Química Física i Inorgànica, Universitat Rovira i Virgili, and Claver, C. ; Díaz de los Bernardos, M. ; Pérez-Rodríguez, S. ; Gual, A. ; Godard, C.
- Abstract
Well defined Ni nanoparticles (NiNPs) stabilized with N-heterocyclic carbenes (NHCs) have been synthesized through a new methodology involving the decarboxylation of a zwitterionic CO2 adduct. Their catalytic performance was tested in the partial hydrogenation of alkynes into (Z)-alkenes under very mild reaction conditions (50 8C and 5 bar H2 pressure), providing excellent activities and selectivities
- Published
- 2017
41. Effect of the polymeric stabilizer in the Aqueous phase Fischer-Tropsch synthesis catalyzed by colloidal cobalt nanocatalysts
- Author
-
Síntesis Orgànica Estereoselectiva, Organometàl.lics i Catàlisi Homogènia, Química Física i Inorgànica, Química Analítica i Química Orgànica, Universitat Rovira i Virgili, Claver, C. ; Delgado, J. ; Castillón, S. ; Curulla-Ferré, D.; Godard. C., Síntesis Orgànica Estereoselectiva, Organometàl.lics i Catàlisi Homogènia, Química Física i Inorgànica, Química Analítica i Química Orgànica, Universitat Rovira i Virgili, and Claver, C. ; Delgado, J. ; Castillón, S. ; Curulla-Ferré, D.; Godard. C.
- Abstract
Open Access, A series of small and well defined cobalt nanoparticles were synthesized by the chemical reduction of cobalt salts in water using NaBH4 as a reducing agent and using various polymeric stabilizers. The obtained nanocatalysts of similar mean diameters (ca. 2.6 nm) were fully characterized and tested in the aqueous phase Fischer-Tropsch Synthesis (AFTS). Interestingly, the nature and structure of the stabilizers used during the synthesis of the CoNPs affected the reduction degree of cobalt and the B-doping of these NPs and consequently, influenced the performance of these nanocatalysts in AFTS
- Published
- 2017
42. NHC-stabilised Rh nanoparticles: Surface study and application in the catalytic hydrogenation of aromatic substrates
- Author
-
Síntesis Orgànica Estereoselectiva, Organometàl.lics i Catàlisi Homogènia, Grup de Quimiometria, Qualimetria i Nanosensors, Química Física i Inorgànica, Química Analítica i Química Orgànica, Universitat Rovira i Virgili, Blondeau, P.; Martinez-Espinar, F. ; Nolis, P. ; Chaudret, B. ; Claver, C. ; Castillón, S. ; Godard, C., Síntesis Orgànica Estereoselectiva, Organometàl.lics i Catàlisi Homogènia, Grup de Quimiometria, Qualimetria i Nanosensors, Química Física i Inorgànica, Química Analítica i Química Orgànica, Universitat Rovira i Virgili, and Blondeau, P.; Martinez-Espinar, F. ; Nolis, P. ; Chaudret, B. ; Claver, C. ; Castillón, S. ; Godard, C.
- Abstract
New Rh-NPs stabilised by N-Heterocyclic Carbenes (NHC) were synthesized by decomposition of [Rh(g3-C3H5)3] under H2 atmosphere and fully characterized. Surface studies by FT-IR and NMR spectroscopy employing isotopically labelled ligands were also performed. The Rh0.2 NPs are active catalysts in the reduction of various aromatic substrates. In the reduction of phenol, high selectivities to cyclohexanone or cyclohexanol were obtained depending on the reaction conditions. However, this catalytic system exhibited much lower activity in the hydrogenation of substituted phenols. Pyridine was easily hydrogenated under mild conditions and interestingly, the hydrogenation of 4-methyl and 4- trifluoromethylpyridine resulted slower than that of 2-methylpyridine. The hydrogenation of 1- (pyridin-2-yl)propan-2-one provided the b-enaminone 13a in high yield as a consequence of the partial reduction of the pyridine ring followed by isomerization. Quinoline could be either partially hydrogenated to 1,2,3,4-tetrahydroquinoline or fully reduced to decahydroquinoline by adjusting the reaction conditions.
- Published
- 2017
43. Facile synthesis of NHC-stabilized Ni nanoparticles and their catalytic application in the Z-selective hydrogenation of alkynes
- Author
-
Universitat Rovira i Virgili, de Los Bernardos MD, Pérez-Rodríguez S, Gual A, Claver C, Godard C., Universitat Rovira i Virgili, and de Los Bernardos MD, Pérez-Rodríguez S, Gual A, Claver C, Godard C.
- Abstract
Well defined Ni nanoparticles (NiNPs) stabilized with N-heterocyclic carbenes (NHCs) have been synthesized through a new methodology involving the decarboxylation of a zwitterionic CO2 adduct. Their catalytic performance was tested in the partial hydrogenation of alkynes into (Z)-alkenes under very mild reaction conditions (50 8C and 5 bar H2 pressure), providing excellent activities and selectivities.
- Published
- 2017
44. A new approach for the preparation of well-defined Rh and Pt nanoparticles stabilized by phosphine-functionalized silica for selective hydrogenation reactions
- Author
-
Universitat Rovira i Virgili, Llop Castelbou J; Szeto KC; Barakat W; Merle N; Godard C; Taoufik M; Claver C, Universitat Rovira i Virgili, and Llop Castelbou J; Szeto KC; Barakat W; Merle N; Godard C; Taoufik M; Claver C
- Abstract
© The Royal Society of Chemistry. In this work, a new methodology for the synthesis of well-defined metallic nanoparticles supported on silica is described. This methodology is based on the surface control provided by SOMC. The nanoparticles are formed via the organometallic approach and are catalytically active in the hydrogenation of p-xylene, 3-hexyne, 4-phenyl-2 butanone, benzaldehyde, and furfural.
- Published
- 2017
45. Advances in the preparation of highly selective nanocatalysts for the semi-hydrogenation of alkynes using colloidal approaches
- Author
-
Universitat Rovira i Virgili, Delgado JA, Benkirane O, Claver C, Curulla-Ferré D, Godard C., Universitat Rovira i Virgili, and Delgado JA, Benkirane O, Claver C, Curulla-Ferré D, Godard C.
- Abstract
In the last decade, the semi-hydrogenation of alkynes has experienced significant advances in terms of fine control of alkene selectivity and prevention of the over-hydrogenation reaction. Such advances have been possible to a large extent through the progress in colloidal methods for the preparation of metallic nanoparticles. The present review describes the contributions in the field of the selective hydrogenation of alkynes involving the utilization of colloidal methodologies. These approaches permit the fine modulation of several parameters affecting the catalytic performance of the active phase such as the particle size, the bulk and the surface structure and composition. For the transformation of liquid substrates, the nature of the stabilizers, the reducing agents and the metal precursors employed for the synthesis of the catalysts can be tuned to enhance the alkene selectivity. In contrast, in catalytic transformations of gaseous substrates, the presence of adsorbed species at the metal surface usually gives detrimental results while the interplay between the support and the active phase appears to be a more convincing alternative for catalyst tuning.
- Published
- 2017
46. Salcy-Naphthalene Cobalt Complexes as Catalysts for the Synthesis of High Molecular Weight Polycarbonates
- Author
-
Universitat Rovira i Virgili, Viciano M; Muñoz B; Godard C; Castillón S; Reyes M; García-Ruiz M; Claver C, Universitat Rovira i Virgili, and Viciano M; Muñoz B; Godard C; Castillón S; Reyes M; García-Ruiz M; Claver C
- Abstract
High molecular weight polypropylene carbonates were prepared by CO2/propylene oxide copolymerization catalyzed by salcy-naphthalene cobalt complexes. The introduction of methyl groups in the ortho position of naphthalene-based salcy ligands and the catalyst loading in the presence of hexane as a co-solvent were crucial to enhance the catalytic performance for the production of polycarbonates of high molecular weight.
- Published
- 2017
47. Core-substituted naphthalenediimides anchored on BiVO4 for visible light-driven water splitting
- Author
-
Universitat Rovira i Virgili, Hernández S; Ottone C; Proto S; Tolod K; Díaz De Los Bernardos M; Solé-Daura A; Carbó J; Godard C; Castillón S; Russo N; Saracco G; Claver C, Universitat Rovira i Virgili, and Hernández S; Ottone C; Proto S; Tolod K; Díaz De Los Bernardos M; Solé-Daura A; Carbó J; Godard C; Castillón S; Russo N; Saracco G; Claver C
- Abstract
In this work, a novel catalytic system for the sunlight-driven water splitting reaction, which exploits the photocatalytic ability of BiVO4 coupled to a new kind of noble-metal-free organic dye molecules, is proposed. Hence, mono- and di-substituted naphthalenediimides (NDIs) were designed to have different functional groups that provide to them both tunable optical properties and adjustable HOMO/LUMO levels, and were selectively prepared (starting from 1,4,5,8-naphthalenetetracarboxylic acid) achieving yields >69%. Smart anchoring groups (i.e. carboxylates or aromatic amines) were added to the dyes in order to allow them to covalently bond to acidic -OH groups present on the BiVO4 surface. An easy and low-cost room temperature dip-coating technique was used to dye-sensitize both BiVO4 powders and thin films. NMR, MS, FT-IR, TG, FESEM, XRD, XPS and optical analyses confirmed the successful organic synthetic routes and good dyes/BiVO4 linkages. Photochemical and photoelectrochemical water oxidation reaction tests, together with DFT calculations, demonstrated that a proper alignment of the semiconductor/NDI-based dye energy levels is fundamental for enhancing the photocatalyst performance through a Z-scheme mechanism. The ability of the NDI organic molecules to delocalize the electronic charges was also a key factor for minimizing recombination processes and achieving more than a ten-fold increase in the photocurrent density of a 6 cm2 BiVO4 photo-electrode. The here reported results open new perspectives for the utilization of this new series of core-substituted NDIs, which are able to improve the activity of photocatalysts for different sunlight-driven applications, e.g. waste water treatment and organic contaminants' degradation, other than the production of solar fuel
- Published
- 2017
48. Effect of the polymeric stabilizer in the Aqueous phase Fischer-Tropsch synthesis catalyzed by colloidal cobalt nanocatalysts
- Author
-
Universitat Rovira i Virgili, Delgado, J. ; Claver, C. ; Castillón, S. ; Curulla-Ferré, D.; Godard. C., Universitat Rovira i Virgili, and Delgado, J. ; Claver, C. ; Castillón, S. ; Curulla-Ferré, D.; Godard. C.
- Abstract
A series of small and well defined cobalt nanoparticles were synthesized by the chemical reduction of cobalt salts in water using NaBH4 as a reducing agent and using various polymeric stabilizers. The obtained nanocatalysts of similar mean diameters (ca. 2.6 nm) were fully characterized and tested in the aqueous phase Fischer-Tropsch Synthesis (AFTS). Interestingly, the nature and structure of the stabilizers used during the synthesis of the CoNPs affected the reduction degree of cobalt and the B-doping of these NPs and consequently, influenced the performance of these nanocatalysts in AFTS
- Published
- 2017
49. Robust zinc complexes bearing pyrrolidine based ligands as recyclable catalysts for the synthesis of cyclic carbonates from CO2 and epoxides
- Author
-
Claver, C., Mercadé, E., Zangrando, E., Godard, C., Organometàl.lics i Catàlisi Homogènia, Química Física i Inorgànica, and Universitat Rovira i Virgili
- Subjects
Chemistry ,1867-3880 ,polycarbonates ,Catalitzadors metàl·lics ,Química - Abstract
12 meses de embargo author can archive pre-print (ie pre-refereeing) postprint: subject to Restrictions below, author can archive post-print (ie final draft post-refereeing) New zinc catalysts bearing the ligands 1-4 containing a pyrrolidine scaffold were synthesized and successfully tested in the coupling of CO2 with terminal and internal epoxides, providing excellent activity and total selectivity to the corresponding cyclic carbonates, even for challenging substrates such as cyclohexene oxide, trans-1,2-epoxybutane and methyl epoxioleate. The Zn-3/TBAI catalytic system revealed as the most active of the series and its robustness was demonstrated through TON values up to 1840 for propylene oxide. The recycling of this catalytic system was also performed up to 5 times without relevant loss of activity using this substrate
- Published
- 2016
- Full Text
- View/download PDF
50. A simple and versatile approach for the fabrication of paper-based nanocatalysts: lost cost, easy handling and catalyst recovery
- Author
-
Andrade, F.J., Montiel, L., Delgado, J.A., Novell, M., Claver, C., Godard, C., Blondeau, P., Organometàl.lics i Catàlisi Homogènia, Grup de Quimiometria, Qualimetria i Nanosensors, Química Analítica i Química Orgànica, Química Física i Inorgànica, and Universitat Rovira i Virgili
- Subjects
Chemistry ,1867-3880 ,Nanotubs de carboni ,Química ,nano catalysis - Abstract
12 meses de embargo author can archive pre-print (ie pre-refereeing) subject to Restrictions below, author can archive post-print (ie final draft post-refereeing) A versatile method for the preparation of efficient and reusable nanocatalysts involving the painting of a commercial filter paper with a Pd@CNT (CNT=carbon nanotubes) ink was herein explored. The resulting paper-based material provided excellent results in the semihydrogenation of alkynes and alkynols and could be recycled at least five times without loss of activity or selectivity.
- Published
- 2016
- Full Text
- View/download PDF
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