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The Late Pliensbachian Event (LPE), in the Early Jurassic, is associated with a perturbation in the global carbon cycle (positive carbon isotope excursion (CIE) of ∼2 ‰), cooling of ∼5 ∘C, and the deposition of widespread regressive facies. Cooling during the late Pliensbachian has been linked to enhanced organic matter burial and/or disruption of thermohaline ocean circulation due to a sea level lowstand of at least regional extent. Orbital forcing had a strong influence on the Pliensbachian environments and recent studies show that the terrestrial realm and the marine realm in and around the Cardigan Bay Basin, UK, were strongly influenced by orbital climate forcing. In the present study we build on the previously published data for long eccentricity cycle E459 ± 1 and extend the palaeoenvironmental record to include E458 ± 1. We explore the environmental and depositional changes on orbital timescales for the Llanbedr (Mochras Farm) core during the onset of the LPE. Clay mineralogy, X-ray fluorescence (XRF) elemental analysis, isotope ratio mass spectrometry, and palynology are combined to resolve systematic changes in erosion, weathering, fire, grain size, and riverine influx. Our results indicate distinctively different environments before and after the onset of the LPE positive CIE and show increased physical erosion relative to chemical weathering. We also identify five swings in the climate, in tandem with the 405 kyr eccentricity minima and maxima. Eccentricity maxima are linked to precessionally repeated occurrences of a semi-arid monsoonal climate with high fire activity and relatively coarser sediment from terrestrial runoff. In contrast, 405 kyr minima in the Mochras core are linked to a more persistent, annually wet climate, low fire activity, and relatively finer-grained deposits across multiple precession cycles. The onset of the LPE positive CIE did not impact the expression of the 405 kyr cycle in the proxy records; however, during the second pulse of heavier carbon (13C) enrichment, the clay minerals record a change from dominant chemical weathering to dominant physical erosion.

The Late Pliensbachian Event (LPE), in the Early Jurassic, is associated with a perturbation in the global carbon cycle (positive carbon isotope excursion (CIE) of ~ 2 ‰), cooling of ~5 °C, and the deposition of widespread regressive facies. Cooling during the Late Pliensbachian has been linked to enhanced organic matter burial and/or disruption of thermohaline ocean circulation due to North Sea doming. Orbital forcing had a strong influence on the Pliensbachian environments and recent studies show that the terrestrial realm and the marine realm in and around the Cardigan Bay Basin were strongly influenced by orbital climate forcing. In the present study we build on the previously published data for long eccentricity cycle E459 ± 1 and extend the palaeoenvironmental record to include E458 ± 1. We explore the environmental and depositional changes on orbital time scales for the Mochras core during the onset of the LPE. Clay mineralogy, XRF elemental analysis, isotope ratio mass spectrometry, and palynology are combined to resolve systematic changes in erosion, weathering, fire, grain size and riverine influx. Our results indicate distinctively different environments before and after the onset of the LPE positive CIE, and show increased physical erosion relative to chemical weathering. We also identify 5 swings in the climate, in tandem with the 405 kyr eccentricity minima and maxima. Eccentricity maxima are linked to precessionally repeated occurrences of a semi-arid, monsoonal climate with high fire activity and relatively coarser fraction of terrestrial runoff. In contrast, 405 kyr minima in the Mochras core are linked to a more persistent, annually wet climate, low fire activity, and relatively finer grained deposits across multiple precession cycles. The onset of the LPE +ve CIE did not impact the expression of the 405 kyr in the proxy records, however, during the second pulse of lighter carbon (12C) enrichment, the clay minerals record a change from dominant chemical weathering to dominant physical erosion.

[Background]: ‘Megafire’ is an emerging concept commonly used to describe fires that are extreme in terms of size, behaviour, and/or impacts, but the term’s meaning remains ambiguous. [Approach]: We sought to resolve ambiguity surrounding the meaning of ‘megafire’ by conducting a structured review of the use and definition of the term in several languages in the peer-reviewed scientific literature. We collated definitions and descriptions of megafire and identified criteria frequently invoked to define megafire. We recorded the size and location of megafires and mapped them to reveal global variation in the size of fires described as megafires. [Results]: We identified 109 studies that define the term ‘megafire’ or identify a megafire, with the term first appearing in the peer-reviewed literature in 2005. Seventy-one (~65%) of these studies attempted to describe or define the term. There was considerable variability in the criteria used to define megafire, although definitions of megafire based on fire size were most common. Megafire size thresholds varied geographically from > 100–100,000 ha, with fires > 10,000 ha the most common size threshold (41%, 18/44 studies). Definitions of megafire were most common from studies led by authors from North America (52%, 37/71). We recorded 137 instances from 84 studies where fires were reported as megafires, the vast majority (94%, 129/137) of which exceed 10,000 ha in size. Megafires occurred in a range of biomes, but were most frequently described in forested biomes (112/137, 82%), and usually described single ignition fires (59% 81/137). [Conclusion]: As Earth’s climate and ecosystems change, it is important that scientists can communicate trends in the occurrence of larger and more extreme fires with clarity. To overcome ambiguity, we suggest a definition of megafire as fires > 10,000 ha arising from single or multiple related ignition events. We introduce two additional terms – gigafire (> 100,000 ha) and terafire (> 1,000,000 ha) – for fires of an even larger scale than megafires., Threatened Species Recovery Hub; NSW Bushfire Risk Management Research Hub; Australian Wildlife Society; World Wildlife Fund

Currently, our ability to link wildland fire behaviour to fire effects is through the lens of fire severity assessments, because there are no ground-based post-fire metrics that are able to quantitively capture aspects of heat transfer to plants. This presents a particular challenge when considering tree mortality linked to cambial damage, which can occur in both low-intensity surface fires through to high-intensity crown fires. Recent research suggests that measuring the amount of light reflected from charcoals produced by wildland fires will provide information about the energy flux that created the char. We created an experimental forest fire in which we had instrumented individual trees to record the energy delivered to the bark close to the base of the trees. We then assessed the bark charcoal reflectance of the same trees. We found that bark charcoal reflectance showed a strong positive correlation (r2 > 0.86, P = 0.0031) with increasing duration of heating and the total energy delivered to the bark. We suggest that this may provide useful quantitative data that can be included in models or post-fire surveys to estimate tree mortality due to cambial kill.

Variations in wildfire are a hot topic due to concerns linked to the current climate crisis. Although an increasing number of studies focus on how the coupled climate and anthropogenic forcings influence fire frequency and behaviour in highly fire-prone regions, there has been less research in more temperate ecosystems.Analyzing charcoal records yields insights into the fire regimes in a given area, including the fire frequency, type, and intensity. Recent research suggests that measuring the amount of light reflected from charcoals can provide information about the energy flux during the pyrolysis of plant material, which can be further translated into a proxy for fire intensity. To assess the use of reflectance as a post-fire tool for palaeofire intensity reconstructions, we used annually laminated (varved) sediment record from Lake Żabińskie, north-eastern Poland.We provide both quantitative macrocharcoal, and charcoal reflectance measurements of individual charcoal particles as well as semi-quantitative morphotypes analysis. These data were compared with palynological analysis of the vegetation shifts and evidence for the impact of humans in the lake area. Our preliminary research indicates that lower reflectance measurements (mean value around 1%) most likely relate to the litter fires as the charcoals show features of biodegradation before the fire. Higher values (mean 1-3%) represent surface understory fires (undergrowth burning) while the highest reflectance values (mean >3%) can be related to the crown fires. Our measurements are the first of this kind in this part of the world.

Quantifying sedimentary charcoal content by estimation of volume from two-dimensional images is a relatively new and little-used method, but has the potential to improve the accuracy of fire histories. It requires a power transformation of area data, and multiplication by a coefficient to account for particle shape. The latter step has been routinely overlooked, or considered unnecessary, with volume estimates made simply by power transformation of the area data. Some researchers have used the method on the basis of the power transformation only, and others have rejected it as unnecessary on the same basis. However, the assumption that the shape coefficient can be ignored is likely to introduce very large errors, resulting in overestimation of charcoal volume. The magnitude of the error is indicated by a limited amount of empirical data obtained from volumetric measurement of individual charcoal particles, and accurate use of the method would require considerable further work to extend this data set. In a sedimentary sequence where particle morphology varies with depth, the errors identified could seriously distort the fire history produced. However, as such variation is easily identified, the method can still improve charcoal quantification where morphology is stationary.

North Africa features some of the most frequently burnt biomes on Earth, including the semi-arid grasslands of the Sahel and wetter savannas immediately to the south. Natural fires are fuelled by rapid biomass production during the wet season, its desiccation during the dry season and ignition by frequent dry lightning strikes. Today, fire activity decreases markedly both to the north of the Sahel, where rainfall is extremely low, almost eliminating biomass over the Sahara, and to the south where forest biomes are too wet to burn. Over the last glacial cycle, rainfall and vegetation cover over northern Africa varied dramatically in response to gradual astronomically-forced insolation change, changes in atmospheric carbon dioxide levels, and abrupt cooling events over the North Atlantic Ocean associated with the reorganisation of Meridional Overturning Circulation (MOC). Here we report the results of a study into the impact of these climate changes on fire activity in northern African over the last 50,000 years (50 kyr). Our reconstructions come from marine sediments with strong age control that provide an uninterrupted record of charcoal particles exported from the African continent. We studied three sites on a latitudinal transect along the northwest African margin between 21 and 9°N. Our sites exhibit a distinct latitudinal relationship between past changes in rainfall and fire activity. At the southernmost site (GeoB9528-3, 9°N), fire activity decreased during intervals of increasing humidity, while our northernmost site (ODP Site 658, 21°N) clearly demonstrates the opposite relationship. The site in the middle of our transect, offshore of the present day southern Sahel today (GeoB9508-5, 15°N), exhibits a “Goldilocks” relationship between fire activity and hydroclimate, wherein charcoal fluxes peak under intermediate rainfall climate conditions and are supressed by transition to more arid or more humid conditions. Our results are remarkably consistent with the predictions of the intermediate fire-productivity hypothesis developed in conceptual macroecological models and supported by empirical evidence of modern day fire activity. Feedback processes operating between fire, climate and vegetation are undoubtedly complex but temperature is suggested to be the main driver of temporal change in fire activity globally, with the precipitation-evaporation balance perhaps a secondary influence in the Holocene tropics. However, there is only sparse coverage of Africa in the composite records upon which those interpretations are based. We conclude that hydroclimate (not temperature) exerted the dominant control on burning in the tropics of northern Africa well before the Holocene (from at least 50 ka). publishedVersion

The Triassic-Jurassic boundary marks the third largest mass extinction event in the Phanerozoic, characterized by a rise in CO

Fire regimes are changing due to both anthropogenic climatic drivers and vegetation management challenges, making it difficult to determine how climate alone might influence wildfire activity. Earth has been subject to natural-background climate variability throughout its past due to variations in Earth’s orbital parameters (Milkankovitch cycles), which provides an opportunity to assess climate-only driven variations in wildfire. Here we present a 350,000 yr long record of fossil charcoal from mid-latitude (~35°N) Jurassic sedimentary rocks. These results are coupled to estimates of variations in the hydrological cycle using clay mineral, palynofacies and elemental analyses, and lithological and biogeochemical signatures. We show that fire activity strongly increased during extreme seasonal contrast (monsoonal climate), which has been linked to maximal precessional forcing (boreal summer in perihelion) (21,000 yr cycles), and we hypothesize that long eccentricity modulation further enhances precession-forced fire activity. Increased fire activity in the Early Jurassic is related to changes in the hydrological cycle driven by enhanced seasonality due to orbital forcing, according to a mid-latitude sedimentary charcoal record spanning 350,000 years.

Cretaceous oceanic anoxic event 2 (OAE2) is thought to have been contemporary with extensive volcanism and the release of large quantities of volcanic CO2 capable of triggering marine anoxia through a series of biogeochemical feedbacks. High-resolution reconstructions of atmospheric CO2 concentrations across the initiation of OAE2 suggest that there were also two distinct pulses of CO2 drawdown coeval with increased organic carbon burial. These fluctuations in CO2 likely led to significant climatic changes, including fluctuations in temperatures and the hydrological cycle. Paleofire proxy records suggest that wildfire was a common occurrence throughout the Cretaceous Period, likely fueled by the estimated high atmospheric O2 concentrations at this time. However, over geological time scales, the likelihood and behavior of fire are also controlled by other factors such as climate, implying that CO2-driven climate changes should also be observable in the fossil charcoal record. We tested this hypothesis and present a high-resolution study of fire history through the use of fossil charcoal abundances across the OAE2 onset, and we compared our records to the estimated CO2 fluctuations published from the same study sites. Our study illustrates that inferred wildfire activity appears to relate to changes in CO2 occurring across the onset of OAE2, where periods of CO2 drawdown may have enabled an increase in fire activity through suppression of the hydrological cycle. Our study provides further insight into the relationships between rapid changes in the carbon cycle, climate, and wildfire activity, illustrating that CO2 and climate changes related to inferred wildfire activity can be detected despite the estimated high Cretaceous atmospheric O2 concentrations.

The physical and chemical properties of black carbon (BC) and organic aerosols are important for predicting their radiative forcing in the atmosphere. During the Soot Aerodynamic Size Selection for Optical properties (SASSO) project and a EUROCHAMP-2020 transnational access project, different types of light absorbing carbon were studied, including BC from catalytically stripped diesel exhaust, a flame burner, a colloidal graphite standard (Aquadag), and from controlled flaming wood combustion. Brown carbon (BrC) was also investigated in the form of organic aerosol emissions from wood burning (pyrolysis and smouldering) and from the nitration of secondary organic aerosol (SOA) proxies produced in a photochemical reaction chamber. Here we present insights into the physical and chemical properties of the aerosols, with optical properties being presented in subsequent publications. The dynamic shape factor (χ) of BC particles and material density (ρm) of organic aerosols were investigated by coupling a charging-free Aerodynamic Aerosol Classifier (AAC) with a Centrifugal Particle Mass Analyzer (CPMA) and Scanning Mobility Particle Sizer (SMPS). The morphology of BC particles was captured by transmission electron microscopy (TEM). For BC particles from the diesel engine and flame burner emissions, the primary spherule sizes were similar, around 20 nm. With increasing particle size, BC particles adopted more collapsed/compacted morphologies for the former source but tended to show more aggregated morphologies for the latter source. For particles emitted from the combustion of dry wood samples, the χ of BC particles and the ρm of organic aerosols were observed in the ranges 1.8–2.17 and 1.22–1.32 g/cm3, respectively. Similarly, for wet wood samples, the χ and ρm ranges were 1.2–1.85 and 1.44–1.60 g/cm3, respectively. Aerosol mass spectrometry measurements show no clear difference in mass spectra of the organic aerosols in individual burn phases (pyrolysis or smouldering phase) with the moisture content of the wood samples. This implies that the effect moisture has on the organic chemical profile of wood burning emissions is through changing the durations of the different phases of the burn cycle, not through the chemical modification of the individual phases. In this study, the incandescence signal of a Single Particle Soot Photometer (SP2) was calibrated with three different types of BC particles and compared with that from an Aquadag standard that is commonly used to calibrate SP2 incandescence to a BC mass. A correction factor is defined as the ratio of the incandescence signal from an alternative BC source to that from the Aquadag standard, and took values of 0.82 (or 0.79), 0.88 and 0.84–0.91 for the BC particles emitted from the diesel engine running under hot (or cold idle) conditions, the flame burner and wood combustion, respectively. These correction factors account for differences in instrument response to BC from different sources compared to the standardised Aquadag calibration and are more appropriate than the common value of 0.75 recommended by Laborde et al. (2012b) when deriving the mass concentration of BC emitted from diesel engines. Quantifying the correction factor for many types of BC particles found commonly in the atmosphere may enable better constraints to be placed on this factor depending on the BC source being sampled, and thus improve the accuracy of future SP2 measurements of BC mass concentrations.

Fire regimes are changing due to anthropogenic climatic drivers and fuel management challenges in all regions of Earth. However, the planet is also subject to natural background variability due to Earth’s orbital parameters (Milkankovitch cycles). To date no studies have assessed a sedimentary record that is sufficiently long or has a resolution that is high enough to assess both long eccentricity and precessional forcings on fire. Here we present a ~350,000 yr record of wildfire activity, using fossil charcoal from Jurassic sediments.The studied interval is part of the astronomically constrained Upper Pliensbachian of the Mochras borehole, Cardigan Bay Basin. The site was located within the Laurasian Seaway, south of the Viking Corridor that linked the north-western Tethys Ocean to the Boreal Sea, at a palaeolatitude of ~35°N. Clear lithological couplets of carbonate-rich and TOC-enhanced beds are observed, which show an orbital control on deposition. High resolution macrocharcoal (>125 um) and microcharcoal (10-125 um) abundance data have been obtained at a ~2 ky resolution over the studied interval. Charcoal data are coupled to estimates of variations in the hydrological cycle using clay mineral analyses, along with palynofacies and elemental analyses, and lithological and biogeochemical signatures.We show that fire activity was strongly increased during (1) a period of maximum eccentricity (405,000 yr cycle) and (2) inferred maximum in seasonal contrast due to precession (20,000 yr cycles). In these periods with a strong seasonality, charcoal abundance indicates enhanced wildfire activity. This is coupled to a more seasonal pattern of rainfall as indicated by the relative abundance of smectite versus kaolinite. We argue that the shift to a more seasonal climate would have led to the increase in dry-adapted conifer forests. Conifers have biochemical and morphological traits that make them particularly flammable whether dry or live.This climate induced change in vegetation contributed to increased wildfire activity in the seasonal dry periods.Increase in wildfire activity on an orbital time scale indicates that currently wildfires should be suppressed as Earth is close to an eccentricity minimum, such that man may have counteracted a relatively fire limited period.

The source of oxygen to Earth’s atmosphere is organic carbon burial, whilst the main sink is oxidative weathering of fossil carbon. However, this sink is to insensitive to counteract oxygen rising above its current level of about 21%. Biogeochemical models suggest that wildfires provide an additional regulatory feedback mechanism. However, none have considered how the evolution of different plant groups through time have interacted with this feedback. The Cretaceous Period saw not only super-ambient levels of atmospheric oxygen but also the evolution of the angiosperms, that then rose to dominate Earth’s ecosystems. Here we show, using the COPSE biogeochemical model, that angiosperm-driven alteration of fire feedbacks likely lowered atmospheric oxygen levels from ~30% to 25% by the end of the Cretaceous. This likely set the stage for the emergence of closed-canopy angiosperm tropical rainforests that we suggest would not have been possible without angiosperm enhancement of fire feedbacks., Global oxygen regulation over Earth history has largely depended on variations in organic carbon burial, which includes the suppression of land vegetation due to fires. Here, the authors show that major evolutionary changes in plant ecosystems could have influenced fire regimes and thus affected atmospheric O2.

Wildfires in temperate regions like the UK can cause major impacts for ecosystems, society and human health and wellbeing. Under changing climate and land use patterns it is therefore important to better understand how we can assess the danger posed by fires in the landscape. Major wildfire events in the UK over recent years have highlighted the risk posed by wildfires, and has led to recognition of wildfire as an environmental hazard in the UK National Risk Register.Fire Danger Rating Systems (FDRS) are designed to assess the fuel and weather to provide estimates of flammability and likely fire behaviour under those conditions. These danger ratings can inform management decisions for land managers, direct resourcing plans for FRS teams, and feed into strategic planning for local and national governments. However, the UK does not yet have a fit-for-purpose FDRS and we lack the fundamental scientific and end-user understanding to predict effectively the likelihood, behaviour and impact of wildfire incidents in the UK at present and under future climate and land use scenarios.This poster will present the outline and structure of a new NERC-funded, multi-institution, 4-year project that will develop the underpinning knowledge and tools to develop a UK FDRS. We are very keen to hear from the wildfire community about ways in which this work could help you with your activities and to link up with other projects.

At present Earth’s climate is warming and the frequency of large wildfires appears to be increasing (Westerling and Bryant, 2008). Long term trends in climate and the effect on wildfire are understudied and examining the geological record can aid current understanding of natural variability of wildfire over longer time scales. The Early Jurassic is a period of overall global warmth, and therefore serves as a suitable modern-day analogue to understand changes in the Earth System. The Early Jurassic was characterized by major climatic and environmental perturbations which can be seen preserved at high resolution on orbital timescales. Recent research has indicated from Quaternary deposits that wildfires respond to orbital forcings (Daniau et al., 2013). This study tests whether wildfire activity corresponds to changes over Milankovitch timescales in the deep past. A high-resolution astrochronology exists for the Upper Pliensbachian in the Llanbedr (Mochras Farm) borehole (NW Wales). Ruhl et al. (2016) show that elemental concentration recorded by hand-held X-ray fluorescence (XRF), changes mainly at periodicities of ~21,000 year, ~100,000 year and ~400,000 year, and which can be related to visually described sedimentary bundles. We have quantified the abundance of fossil charcoal at a high resolution (10-15 cm) to test the hypothesis that these well-preserved climatic cycles influenced fire activity throughout this globally warm period. Our results suggest that variations in charcoal abundance are coupled to Milankovitch forcings over periods of ~21,000 and ~400,000 years. Supplementary to the charcoal record, a high-resolution clay minerology dataset has been generated, which indicates the presence of the 400ky cycle. Decreased hydrology on land, corresponds to increased charcoal production. We suggest that these changes in fire relate to changes in seasonality and monsoonal activity that drove changes in vegetation that are linked to variations in the orbital forcing.

Oxygen has varied in its abundance in the atmosphere throughout Earth’s long –term evolutionary history. Laboratory experiments have shown that fire responds rapidly to oxygen changes. Therefore it has been suggested that increases and decreases in atmospheric oxygen levels have influenced fire frequency, fire behaviour and plant evolutionary adaptations to fire.Recent research has indicated that periods with high atmospheric oxygen, such as the Cretaceous period, which also saw the evolution of new plant groups had the coupled effect of altering fire behaviour. Such modelled fire behaviour has been able to estimate that fires during this period would have been more intense and spread more rapidly which likely fed back to changes in ecosystem dominance. However, we are lacking understanding of how oxygen driven changes in fire might feedback to influence the dominance and distribution of land-surface vegetation cover across Earth’s surface throughout Earth history.Here I will present, a series of oxygen-fire-land cover simulations using the LPJ-LMfire Dynamic Global Vegetation Model that considers how oxygen-mediated changes in fire frequency and behaviour lead to changes in dominance of selected plant functional types within Earth’s biomes and influence the total land area covered by forest.Our aim being to explore the coupled influence of oxygen and a climate on vegetation distributions mediated by fire throughout Earth’s past such that we can work towards understanding the balance of natural fire feedbacks to the Earth system versus human interrupted fire feedbacks in our modern day.

Properties of the wildfires are hard to precisely and accurately measure during the event. This limits our ability to estimate effects of the event on the environment (e.g., how quickly will the area be able to recover, and what will be the long-term carbon storage in an ecosystem Hurteau and Brooks, 2011). Currently used methods of estimating of the ‘fire severity’ (the amount of vegetation and carbon loss from an ecosystem following a fire) are either subjective (fire severity scales Ryan and Noste 1985), time consuming (charcoal reflectance Belcher et al. 2019) or expensive (thermocouples with data-loggers). Here we present results of our proof of concept tests of a new approach that may allow ecologists to monitor fire severity and the energy distribution across a burned area by looking at the effects of the fire on litter such as tin cans, bottles and plastic items, that are often revealed following wildfire events. The approach is based on the fact that different types of packages and materials are known to decompose at different temperatures. We will present results from: 1) Field observations of burned litter compared with the charcoal reflectance measurements based on samples collected in the same spot from the 2018 Ferndown, UK. 2) experimental heating of a range of typical litter based elements in the wildFIRE Lab, using it’s state-of-the-art fire testing equipment; 3) results of the field-scale experiments performed during the controlled burns in Dorset in the beginning of 2020.

Impact craters are formed when an asteroid strikes the surface with the hyper-velocity (usually higher than ~1km/s). The kinetic energy of the impactor is released as an explosion, a crater is formed, and target material is deposited outside, forming a proximal and later distal ejecta blanket. This consists of rocks, the surface soil layer and numerous plants remains (Cassidy et al. 1965, Khryanina 1981, Herd et al. 2008), including remains of trees directly killed by the asteroid (Losiak et al. 2016, Losiak et. Al. 2020). We have found a number of charcoals that we suggest are related to the formation of the following confirmed impact craters: Kaali Main, Kaali 2/8 (Estonia, Losiak et al. 2016), Morasko (Poland, Szokaluk et al. 2019), Whitecourt (Canada, Herd et al. 2008) and Ries crater (Buchner and Schmieder 2009). Three of these locations represent small (30-100 m in diameter) impact craters developed primarily in unconsolidated materials such as glacial tills and fluvioglacial sands. Whereas, Ries is a much larger and older crater: it is 24 km in diameter and 14.5 Ma old.Here we present the results from a set of experiments that reproduce the process of formation of charcoals within the proximal ejecta blankets of small impacts. Firstly, charring experiments were achieved using the iCone Calorimeter that recreated a range of heating possibilities that might results from small impact cratering processes. The iCone allows samples to be heated, with or without ignition at a range of radiant heat fluxes for given durations; these heat fluxes can be static or transient, both of which may be relevant to different impact formation mechanisms. Secondly, we buried leaves and fragments of different woods in heated sand over a range of temperatures durations and cooling regimes to assess the potential for relatively cool ejecta to cause transformations of organic material to char in situ. All the chars created in the experiments were analysed via reflectance microscopy and compared with the charcoal that have been produced by modern wildfires. Our aim being to better understand the environmental effects of differently sized impact craters, but also to study the mode of preservation of plants killed during such extraterrestrial impact events.Buchner & Schmieder 2009. MAPS44:1051–1060.Cassidy et al. 1965. Science149:1055-1064.Herd et al. 2008. Geology36:955–958.Hudspith et al. 2010. PPP291:40–51.Khryanina 1981Int. Geology Rev.23:1-10.Losiak et al. 2016. MAPS51:681–695.Losiak et al. 2020. MAPSaccepted.Scott 2010 PPP291:11–39.Sztokaluk et al. MAPS54:1478-1494.

The Triassic-Jurassic Boundary marks one of the largest mass extinction events of the Phanerozoic. Across the boundary, a rise in carbon-dioxide levels and global temperatures are hypothesized to have driven significant environmental changes inducing a major floral turnover, causing vegetation structure, composition and leaf morphology to alter, and inferred wildfire activity to increase.An example of these changes can be observed at the Astartekløft site in East Greenland, where previous work identified a change in flora from broad-leaved conifer dominated to an assemblage dominated by narrow leaved conifers, coeval with a five-fold increase in charcoal abundances.Variations in carbon-dioxide concentrations have been shown to be capable of influencing leaf chemistry. It could therefore be hypothesized that carbon-dioxide-driven climate changes across the Triassic-Jurassic boundary may have been capable of not only inducing changes in leaf morphological fuel properties, but also variations in biochemical properties that are both capable of altering wildfire behaviour.In order to assess this, we selected three plant species that have ancient evolutionary origins and correspond to the dominant leaf morphotypes of litter-forming vegetation observed at the Astartekløft site across the Triassic-Jurassic boundary. We grew these species in current ambient and high carbon-dioxide (Triassic-Jurassic boundary) atmospheric conditions and analysed variations in the chemistry of the leaves, using gas chromatography mass spectrometry, and assessed aspects of their flammability using micro-calorimetry. These data were used to inform a fire behaviour model to produce estimates of variations in fire behaviour, such as surface fire spread, flame length and fireline intensity across the Triassic-Jurassic boundary at Astartekløft.Our results reveal a change in leaf chemistry that is expressed as a suppression of volatile content in the three species grown under elevated carbon-dioxide concentrations, compared to those grown under ambient conditions. By accounting for these variations in a fire behaviour model, we estimate that fire behaviour was more extreme prior to the increase in carbon-dioxide across the boundary, suggesting a switch from a period of infrequent but intense fast-moving surface fires during the Triassic, to a period of frequent but low intensity and slow spreading fires during the earliest Jurassic. Our results indicate that that increases in carbon-dioxide concentrations may have impacted leaf chemistry and thus flammability, and may therefore have played an interesting role in determining fire behaviour characteristics during this marked period of Earth’s past.

Global warming will likely perturb carbon storage and cycling throughout many components of the exogenic carbon cycle, but its net impact on the long-term fate of organic carbon stabilized in soils is unclear. Abrupt warming during the Paleocene-Eocene Thermal Maximum (PETM) profoundly altered vegetation and hydrologic patterns globally. To assess the consequences for soil carbon in a mid-latitude region we measured total organic carbon (%TOC), polycyclic aromatic hydrocarbons (PAHs), charcoal, and sporomorphs (pollen and spores) at two paleo-floodplain depositional sites in the Bighorn Basin, Wyoming, USA. At both sites %TOC, PAHs, charcoal, and sporomorphs declined during the PETM. The decline in pyrogenic carbon, which is more severe than the decline in %TOC, is consistent with isotopic and fossil evidence for degradation of labile organic compounds and preservation of highly refractory allochthonous organic carbon. The severe loss of less-labile contemporaneous PETM (autochthonous) soil carbon, illustrated by the fate of pyrogenic carbon, indicates intensified rates of organic matter decay during the PETM. Because of the highly degraded signature of organic matter in these PETM sections, it is difficult to discern if less pyrogenic carbon is in part a consequence of less fire occurrence during the PETM. We propose that in this mid-latitude region of the western USA increased soil carbon oxidation hindered soil carbon sequestration during this period of hotter climate with more seasonal precipitation.

Charcoal morphometry is increasingly employed in the analysis of Quaternary sediments, but has not been applied in studies of earlier sediments. We present findings relating to charcoal morphometry and morphotypes in a Toarcian sequence, which contains a preponderance of highly elongate forms, and morphometric values well outside expected ranges. SEM imaging reveals elongate particles of two distinct kinds. One originates in conifer xylem, and may be associated with formation at high levels of heating. It is proposed that the other may derive from tree ferns, or from plants with similar growth forms. Our results show the importance of recognizing the wide morphological variation that exists in sedimentary charcoal. Failing to do so may result in serious errors in its identification, interpretation and quantification.

All of our current understanding of fossil charcoal structure comes from observations of modern wood charcoal produced in furnaces. These charcoals consistently show cell wall homogenization after prolonged heating (>325°C) and this is therefore considered to be a key identifying feature of fossil charcoal. Yet furnaces are unable to replicate the full combustion processes that occur during a wildfire. Here, for the first time, we have studied the microscopic structural evolution of charcoal produced using calorimetry, wherein the wood is ignited under controlled conditions and the heat release rate and other parameters measured, and the resulting charcoal studied using reflected light microscopy. We show that homogenization of cell walls is actually only a short-lived phase of charcoal formation that occurs during the early heating stages as the pyrolysis front traverses through the wood. Cell wall homogenization is then rapidly overprinted by the thinning, distortion and breakdown of cell walls, and a notable visual increase in reflectance. Our preliminary study therefore suggests that we need to first improve our understanding of charcoal formation in order to better understand the fossil record of wildfires.

This paper stemmed from discussions at a workshop held in Cornwall, UK, for which we thank the Biotechnology and Biosciences Research Council (BBSRC) through a GCRF‐IAA grant to the University of Exeter, and Borneo Nature Foundation (BNF) for funding. M.E.H.'s drafting of this paper was supported financially by BNF and A.H.'s research was funded through a doctoral scholarship by DAAD (German Academic Exchange Service). Tropical forests and peatlands provide important ecological, climate and socio‐economic benefits from the local to the global scale. However, these ecosystems and their associated benefits are threatened by anthropogenic activities, including agricultural conversion, timber harvesting, peatland drainage and associated fire. Here, we identify key challenges, and provide potential solutions and future directions to meet forest and peatland conservation and restoration goals in Indonesia, with a particular focus on Kalimantan.Through a round‐table, dual‐language workshop discussion and literature evaluation, we recognized 59 political, economic, legal, social, logistical and research challenges, for which five key underlying factors were identified. These challenges relate to the 3Rs adopted by the Indonesian Peatland Restoration Agency (Rewetting, Revegetation and Revitalization), plus a fourth R that we suggest is essential to incorporate into (peatland) conservation planning: Reducing Fires.Our analysis suggests that (a) all challenges have potential for impact on activities under all 4Rs, and many are inter‐dependent and mutually reinforcing, implying that narrowly focused solutions are likely to carry a higher risk of failure; (b) addressing challenges relating to Rewetting and Reducing Fire is critical for achieving goals in all 4Rs, as is considering the local socio‐political situation and acquiring local government and community support; and (c) the suite of challenges faced, and thus conservation interventions required to address these, will be unique to each project, depending on its goals and prevailing local environmental, social and political conditions.With this in mind, we propose an eight‐step adaptive management framework, which could support projects in both Indonesia and other tropical areas to identify and overcome their specific conservation and restoration challenges. Publisher PDF

The Early Jurassic was characterized by major climatic and environmental perturbations which can be seen preserved at high resolution on orbital timescales. The Early Jurassic is a period of overall global warmth, and therefore serves as a suitable modern-day analogue to understand changes in the Earth System. Presently, Earth’s climate is warming and the frequency of large wildfires appears to be increasing. Recent research has indicated that Quaternary deposits reveal that wildfires respond to orbital forcings; however, to date no study has been able to test whether wildfire activity corresponds to changes over Milankovitch timescales in the deep past. A high-resolution astrochronology exists for the Upper Pliensbachian in the Llanbedr (Mochras Farm) borehole (NW Wales). Ruhl et al. (2016) show that elemental concentration recorded by hand-held X-ray fluorescence (XRF), changes mainly at periodicities of ~21,000 year, ~100,000 year and ~400,000 year, and which can be related to visually described sedimentary bundles. We have quantified the abundance of fossil charcoal at a high resolution (10-15 cm) to test the hypothesis that these well-preserved climatic cycles influenced fire activity throughout this globally warm period. Preliminary results suggest that variations in charcoal abundance are coupled to Milankovitch forcings over periods of ~21,000 and ~100,000 years. We suggest that these changes in fire relate to changes in seasonality and monsoonal activity that drove changes in vegetation that are linked to variations in the orbital forcing. Supplementary to the charcoal record, a high-resolution clay mineralogy dataset has been generated to further explain the climatic cyclicity observed in the wildfire record regarding the hydrology on land.

Changes in atmospheric oxygen concentration over Earth history are commonly related to the evolution of animals and plants. But there is no direct geochemical proxy for O2 levels, meaning that estimations rely heavily on modeling approaches. The results of such studies differ greatly, to the extent that today's atmospheric mixing ratio of 21% might be either the highest or lowest level during the past 200 m.y. Long-term oxygen sources, such as the burial in sediments of reduced carbon and sulfur species, are calculated in models by representation of nutrient cycling and estimation of productivity, or by isotope mass balance (IMB)—a technique in which burial rates are inferred in order to match known isotope records. Studies utilizing these different techniques produce conflicting estimates for paleoatmospheric O2, with nutrient-weathering models estimating concentrations close to, or above, that of the present day, and IMB models estimating low O2, especially during the Mesozoic. Here we re-assess the IMB technique using the COPSE biogeochemical model. IMB modelling is confirmed to be highly sensitive to assumed carbonate δ13C, and when this input is defined following recent compilations, predicted O2 is significantly higher and in reasonable agreement with that of non-IMB techniques. We conclude that there is no model-based support for low atmospheric oxygen concentrations during the past 200 m.y. High Mesozoic O2 is consistent with wildfire records and the development of plant fire adaptions, but links between O2 and mammal evolution appear more tenuous.

Charcoal has an exceptional ability to reflect light when viewed using reflectance microscopy. The amount of light reflected is variable depending on the differential ordering of graphite-like phases within the charcoal itself. It has been suggested that this relates to the temperature of formation, whereby higher formation temperatures result in high charcoal reflectance. However, this explanation is derived from oven-based chars that do not well represent the natural combustion process. Here, we have experimentally created charcoals using a cone calorimeter, in order to explore the development of charcoal reflectance during pre-ignition heating and peak heat-release rate, through to the end of flaming and the transition to char oxidation. We find that maximum charcoal reflectance is reached at the transition between pyrolysis and char oxidation, before its conversion to mineral ash, and indicates that our existing understanding of reflectance is in error. We suggest that charcoal reflectance warrants additional study as it may provide a useful quantitative addition to ground-based fire severity surveys, because it may allow exploration of surface heating after the main fire front has passed and the fire transitions to smouldering phases.

Summary Current phylogenetic evidence shows that fire began shaping the evolution of land plants 125 Ma, although the fossil charcoal record indicates that fire has a much longer history (>350 Ma). Serotiny (on-plant seed storage) is generally accepted as an adaptation to fire among woody plants. We developed a conceptual model of the requirements for the evolution of serotiny, and propose that serotiny is only expressed in the presence of a woody rachis as supporting structure, compact scales covering seeds as protective structure, seed wing as dispersal structure, and crown fire as the agent of selection and mechanism for seed release. This model is strongly supported by empirical data for modern ecosystems. We reconstructed the evolutionary history of intrinsic structural states required for the expression of serotiny in conifers, and show that these were diagnostic for early (‘transitional’) conifers from 332 Ma (late-Carboniferous). We assessed the likely flammable characteristics of early conifers and found that scale-leaved conifers burn rapidly and with high intensity, supporting the idea that crown fire regimes may have dominated early conifer ecosystems. Synthesis. Coupled with strong evidence for frequent fire throughout the Permian-Carboniferous and fossil evidence for other fire-related traits, we conclude that many early conifers were serotinous in response to intense crown fires, indicating that fire may have had a major impact on the evolution of plant traits as far back as 350 Ma.

Sedimentary charcoal is a widely used tool for reconstructing past fire histories. These fossil charcoals are normally quantified as the number or area of particles present in a sediment sample, but it is not known how well either measure is correlated with their volume. Areal measurements are often treated as the true measure of quantity, which may introduce bias to fire histories. The relationship of measured area to volume is a function of shape, and if this relationship can be understood, areal measurements may be adjusted to better reflect volume. We show that particle elongation may be particularly important when making such adjustments. We also establish a high degree of correlation between volume and area in a mid-Holocene mesocharcoal assemblage, which indicates that the bias may be small in similar cases.

Fire is increasingly being recognised as an important evolutionary driver in fire-prone environments. Biochemical traits such as terpene (volatile isoprenoid) concentration are assumed to influence plant flammability but have often been overlooked as fire adaptations. We have measured the leaf-level flammability and terpene content of a selection of Pinus species native to environments with differing fire regimes (crown fire, surface fire and no fire). We demonstrate that this biochemical trait is associated with leaf-level flammability which likely links to fire-proneness and we suggest that this contributes to post-fire seedling survival. We find that surface-fire species have the highest terpene abundance and are intrinsically the most flammable, compared to crown-fire species. We suggest that the biochemical traits of surface fire species may have been under selective pressure to modify the fire environment at the leaf and litter scale to moderate fire spread and intensity. We indicate that litter flammability is driven not only by packing ratios and bulk density, but also by terpene content.

Semifusinite can be an important component of coals and has previously been interpreted to represent partially charred material produced in palaeowildfires. Low reflecting semifusinite is well known for its chemically reactive properties, good burning behaviour, and for its reflectance to increase with coal rank. Yet, when inertinite in coal and sediments is used to interpret palaeowildfire history, the diagenetic history of the basin is rarely considered. Here, we sought to explore whether the low temperature heating that would occur during diagenesis over geological timescales is sufficient to produce semifusinite. Considering the interpretation that semifusinite represents partially charred material, we reheated thermally degraded, but not charred, wood at 100 °C and 200 °C for 24 h. Through prolonged heating at low temperatures, the previously thermally altered but non-charred wood increased in reflectance to such an extent that it would be classified as semifusinite. This finding suggests that not all semifusinite necessarily has a wildfire origin and calls into question its utility in interpreting palaeowildfire activity.

Forest-savanna mosaics are maintained by fire-mediated positive feedbacks; whereby forest is fire suppressive and savanna is fire promoting. Forest-savanna transitions therefore represent the interface of opposing fire regimes. Within the transition there is a threshold point at which tree canopy cover becomes sufficiently dense to shade out grasses and thus suppress fire. Prior to reaching this threshold, changes in fire behaviour may already be occurring within the savanna. Such changes are neither empirically described nor their drivers understood. Fire behaviour is largely driven by fuel flammability. Flammability can vary significantly between grass species and grass species composition can change near forest-savanna transitions. This study measured fire behaviour changes at eighteen forest-savanna transition sites in a vegetation mosaic in Lope National Park in Gabon, central Africa. The extent to which these changes could be attributed to changes in grass flammability was determined using species-specific flammability traits. Results showed simultaneous suppression of fire and grass biomass when tree canopy leaf area index (LAI) reached a value of 3, indicating that a fire suppression threshold existed within the forest-savanna transition. Fires became less intense and less hot prior to reaching this fire suppression threshold. These changes were associated with higher LAI values, which induced a change in the grass community, from one dominated by the highly flammable Anadelphia afzeliana to one dominated by the less flammable Hyparrhenia diplandra. Changes in fire behaviour were not associated with changes in total grass biomass. This study demonstrated not only the presence of a fire suppression threshold but the mechanism of its action. Grass composition mediated fire-behaviour within the savanna prior to reaching the suppression threshold, and grass species composition was mediated by tree canopy cover which was in turn mediated by fire-behaviour. These findings highlight how biotic and abiotic controls interact and amplify each other in this mosaicked landscape to facilitate forest and savanna co-existence.

Here, we explore how charcoal formation under different heating regimes and circumstances leads to chars of different physical properties. In order to do this, we have undertaken (1) carefully controlled laboratory experiments that replicate the different heating regimes that might be experienced during a wildfire and (2) two experimental wildfires where heat variations were monitored across the burn from which resulting charcoal has been studied. The charcoal properties were assessed using charcoal reflectance that measures the light reflected back from the charcoals structure and which links to changes in its structural properties. We find that increased total heat released during combustion positively correlates with increased charcoal reflectance and that this is evidenced from both our laboratory experiments and experimental wildfires. Charcoals that related to lower total heat release were found to have more lignin remaining than those subjected to greater heating indicating that charcoals formed in lower energy regimes are likely to be more susceptible to post-fire degradation. We conclude that charcoal reflectance may make a useful metric with which to determine the distribution of energy delivery across a burned area and that this may be utilized to inform both variations in fire severity and enable the prediction of long-term C budgeting for different types of wildfire.

Global warming events have coincided with turnover of plant species at intervals in Earth history. As mean global temperatures rise, the number, frequency and duration of heat-waves will increase. Ginkgo biloba was grown under controlled climatic conditions at two different day/night temperature regimes (25/20 °C and 35/30 °C) to investigate the impact of heat stress. Photosynthetic CO2-uptake and electron transport were reduced at the higher temperature, while rates of respiration were greater; suggesting that the carbon balance of the leaves was adversely affected. Stomatal conductance and the potential for evaporative cooling of the leaves was reduced at the higher temperature. Furthermore, the capacity of the leaves to dissipate excess energy was also reduced at 35/30 °C, indicating that photo-protective mechanisms were no longer functioning effectively. Leaf economics were adversely affected by heat stress, exhibiting an increase in leaf mass per area and leaf construction costs. This may be consistent with the selective pressures experienced by fossil Ginkgoales during intervals of global warming such as the Triassic – Jurassic boundary or Early Eocene Climatic Optimum. The physiological and morphological responses of the G. biloba leaves were closely interrelated; these relationships may be used to infer the leaf economics and photosynthetic/stress physiology of fossil plants.