13 results on '"Clémentine Fellah"'
Search Results
2. Incorporation of Manganese Complexes within Hybrid Resol-Silica and Carbon-Silica Nanoparticles
- Author
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François-Xavier Turquet, Montserrat Corbella, Clémentine Fellah, Gilles Montagnac, Bruno Reynard, Laurent Bonneviot, Kun Zhang, and Belén Albela
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hybrid materials ,manganese complexes ,mesoporous silica ,nanoparticles ,resol ,carbon ,Chemistry ,QD1-999 - Abstract
The incorporation of a luminescent probe into a nano-vector is one of the approaches used to design chemosensors and nanocargos for drug delivery and theranostics. The location of the nano-vector can be followed using fluorescence spectroscopy together with the change of environment that affects the fluorescence properties. The ligand 9-anthracene carboxylate is proposed in this study as a luminescent probe to locate two types of manganese complexes inside three series of porous nanoparticles of different composition: resol-silica, carbon-silica and pure silica. The manganese complexes are a tetranuclear MnIII cluster [MnIII4(μ-O)2(μ-AntCO2)6(bpy)2(ClO4)2] with a butterfly core, and a MnII dinuclear complex [{MnII(bpy)(AntCO2)}2(μ-AntCO2)2(μ-OH2)]. The magnetic measurements indicate that both complexes are present as dinuclear entities when incorporated inside the particles. Both the Mn complexes and the nanoparticles are luminescent. However, when the metal complexes are introduced into the nanoparticles, the luminescent properties of both are altered. The study of the fluorescence of the nanoparticles’ suspensions and of the supernatants shows that MnII compounds seem to be more retained inside the particles than MnIII compounds. The resol-silica nanoparticles with MnII complexes inside is the material that presents the lowest complex leaching in ethanol.
- Published
- 2021
- Full Text
- View/download PDF
3. Morphological Characterization of Graphene Plans Stacking.
- Author
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Albane Borocco, Clémentine Fellah, James Braun, Marie-Hélène Berger, and Petr Dokládal
- Published
- 2017
- Full Text
- View/download PDF
4. Fast exhumation rate during late orogenic extension: The new timing of the Pilat detachment fault (French Massif Central, Variscan belt)
- Author
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Patrick Monié, Benoit Bevillard, Clémentine Fellah, Gweltaz Mahéo, Véronique Gardien, Anne-Sabine Grosjean, Philippe Hervé Leloup, Michel Faure, Cyril Chelle-Michou, Jean-Louis Paquette, Jean-Emmanuel Martelat, Pascal Allemand, Laboratoire Magmas et Volcans (LMV), Institut national des sciences de l'Univers (INSU - CNRS)-Institut de Recherche pour le Développement et la société-Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA)-Observatoire de Physique du Globe de Clermont-Ferrand (OPGC), and Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA)
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geography ,geography.geographical_feature_category ,Metamorphic core complex ,Geology ,Crust ,Massif ,Fault (geology) ,Detachment fault ,Leucogranite ,Sill ,[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry ,Shear zone ,Petrology - Abstract
International audience; A leucogranite sill in the footwall of the extensional Pilat shear zone (PSZ) Eastern French Massif Central was emplaced and sheared in a short time interval, between 301.8–3.1 and 303.0–1.6 Ma (zircon U–Pb and mica 40 Ar/ 39 Ar ages, respectively). Extension ended at 298.5–1.5 Ma ( 40Ar/ 39 Ar on mica) as shown by a non deformed dike cross cutting the sheared zone. On the hanging wall of the fault, the opening of the St. Etienne Basin filled by coarse clastic sedimentation confirms the existence of a relief south of the PSZ. U-Pb dating of a lithic-rich ignimbrite at the bottom of the basin and of a volcanic layer at the top delivred ages of 310.5–3.4 Ma and 299.3–1.3 Ma, respectively. Close U-Pb and 40 Ar/ 39 Ar ages from syn- to post-tectonic granites indicate very fast cooling (150°C/Myr) and exhumation rate (6 mm/yr) corresponding to the emplacement of granites in the middle crust immediately followed by their fast tectonic exhumation and cooling into the upper crust. The development of the Pilat fault in the thermally softened crust is responsible for the rapid exhumation of the Velay dome, a Metamorphic Core Complex localized in the footwall of the sheared zone. Here we propose that its rapid exhumation was due to localized sub crustal lithospheric mantle dripping. These new data show that there was only one extensional phase in the PSZ coeval with the opening of the St. Etienne coal Basin. Finally, the new chronology obtained in this study is challenging previous ages suggesting 20 Ma activity for the Pilat shear zone.
- Published
- 2022
5. Iron oxidation state in serpentines and magnesian chlorites of subduction-related rocks
- Author
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Bruno Reynard, Clémentine Fellah, Catherine McCammon, Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement (LGL-TPE), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Université Jean Monnet - Saint-Étienne (UJM)-Centre National de la Recherche Scientifique (CNRS), and CNRS-INSU through 'Programme National de Planétologie
- Subjects
[SDU]Sciences of the Universe [physics] - Abstract
The ferric iron content in hydrothermally altered ultrabasic rocks and their major minerals, serpentines and Mg-chlorites, is important for establishing the oxidation state budget from oceanic ridges to subduction zones, in carbonaceous chondrites, and for modeling phase equilibria. A compilation of literature Mössbauer spectroscopic data on serpentines and magnesian chlorites from high-pressure ophiolites yields much lower ferric-to-total-iron ratios (Fe3+ / Fetotal) than those obtained on similar samples by X-ray absorption near-edge spectroscopy (XANES), leading to contradictory estimates of the ferric iron budget of subduction zones. New Mössbauer analysis of antigorite and Mg-chlorite samples from suites of high-pressure ophiolitic terrains of various Phanerozoic ages confirms the low and homogeneous values previously obtained by this technique, while lizardite inherited from oceanic hydrothermal alteration is ferric iron rich. We argue that XANES values may be biased by photo-oxidation when samples have a high Mg content, which is the case for serpentines and chlorites from subduction zones. Photo-oxidation is less important in Fe-poor phyllosilicates of the mica and talc families and does not affect the Fe-rich serpentines (greenalite, cronstedtite) of meteorites or Fe-rich terrestrial phyllosilicates. Mössbauer Fe3+ / Fetotal ratios of serpentine confirm the occurrence of a major redox change at the lizardite–antigorite transition near 300–400 ∘C rather than at the dehydration of antigorite at 500–650 ∘C in serpentinites from high-pressure ophiolites.
- Published
- 2022
6. Study of Molecular-Level Dispersion of Pristine Graphene in Aqueous Media via Polyvinyl Alcohol Coil Physisorption
- Author
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Ying Huo, Yun Long, Sheng Yuan, Bérangère Toury, Bernard Normand, Clémentine Fellah, Lucian Roiban, and Stéphane Benayoun
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Electrochemistry ,General Materials Science ,Surfaces and Interfaces ,Condensed Matter Physics ,Spectroscopy - Abstract
Graphene has been widely used as a nanofiller in advanced electronic devices and nanocomposite materials to achieve enhanced electronic, mechanical, and barrier properties. Adequate polymers play the role of the composite matrix and can assist in the liquid-phase exfoliation of pristine graphene without any heavy chemical modification and the detriment of the properties of graphene. This stabilization mechanism is generally attributed to the steric forces formed between the polymer-adsorbed adsorbent. However, the key influence of the polymer concentration on the maximum graphene content in the colloidal solutions is still unclear. In this study, three different molar weights of water-soluble polyvinyl alcohol (PVA) were used for graphene dispersion. The influence of the PVA concentration on the graphene dispersion was systematically studied. Based on Flory's theory, we first proposed a model to describe the polymer adsorption process in the graphene/PVA/water ternary system in the "dilute" regime and simulated the adsorption-free energy changes during this transformation. This model is in good agreement with the experimental results and explains the critical polymer concentration
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- 2022
7. Proposal for a complete 3D surface reconstruction using images from a scanning electron microscope (SEM)
- Author
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Mayra Yucely Beb, Sounkalo Dembélé, Akkiz Bekel, Isabelle Jouffroy-Bapicot, Sébastien Thibaud, Nadine Piat, Olivier Lehmann, Jean-Yves Rauch, Patrick Rougeot, Louis-Marie Lebas, Cyril Langlois, Lucian Roiban, Clémentine Fellah, Gilles Cuny, and Karine Masenelli-Varlot
- Abstract
A three-dimensional model enables the development of accurate solutions to have more information about the thickness, texture, and characteristics of small-size samples for education and metrology applications. This project proposes an idea to obtain a complete 3D surface reconstruction using the application of Pollen 3D for the scanning electron microscope (SEM) images with high magnification. The main objective is to have a set of images of the complete 360° rotation of the sample with a robot inside the chamber of the SEM. Simulation SEM images with Blender (open source application) are proposed for results validation.
- Published
- 2022
8. Incorporation of Manganese Complexes within Hybrid Resol-Silica and Carbon-Silica Nanoparticles
- Author
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Kun Zhang, Clémentine Fellah, Belén Albela, Gilles Montagnac, Montserrat Corbella, Laurent Bonneviot, Bruno Reynard, and François-Xavier Turquet
- Subjects
General Chemical Engineering ,chemistry.chemical_element ,Nanoparticle ,Manganese ,manganese complexes ,luminescent properties ,Fluorescence spectroscopy ,Article ,lcsh:Chemistry ,Metal ,chemistry.chemical_compound ,Sílice ,Polymer chemistry ,hybrid materials ,Manganès ,General Materials Science ,Carboxylate ,mesoporous silica ,Nanociència ,Nanopartícules ,Ligand ,carbon ,Silica ,Mesoporous silica ,resol ,Nanoscience ,lcsh:QD1-999 ,chemistry ,anthracene carboxylate ,visual_art ,visual_art.visual_art_medium ,Nanoparticles ,nanoparticles ,Hybrid material - Abstract
The incorporation of a luminescent probe into a nano-vector is one of the approaches used to design chemosensors and nanocargos for drug delivery and theranostics. The location of the nano-vector can be followed using fluorescence spectroscopy together with the change of environment that affects the fluorescence properties. The ligand 9-anthracene carboxylate is proposed in this study as a luminescent probe to locate two types of manganese complexes inside three series of porous nanoparticles of different composition: resol-silica, carbon-silica and pure silica. The manganese complexes are a tetranuclear MnIII cluster [MnIII4(μ-O)2(μ-AntCO2)6(bpy)2(ClO4)2] with a butterfly core, and a MnII dinuclear complex [{MnII(bpy)(AntCO2)}2(μ-AntCO2)2(μ-OH2)]. The magnetic measurements indicate that both complexes are present as dinuclear entities when incorporated inside the particles. Both the Mn complexes and the nanoparticles are luminescent. However, when the metal complexes are introduced into the nanoparticles, the luminescent properties of both are altered. The study of the fluorescence of the nanoparticles’ suspensions and of the supernatants shows that MnII compounds seem to be more retained inside the particles than MnIII compounds. The resol-silica nanoparticles with MnII complexes inside is the material that presents the lowest complex leaching in ethanol.
- Published
- 2021
9. Manganese oxidation states repartition in a channel‑like mesoporous zirconium oxide
- Author
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Nelly Couzon, Clémentine Fellah, Leostan Cristian, Fernand Chassagneux, Rodica Chiriac, Francois Toche, Brioude, A., Ioan-Ovidiu Ersen, Khrouz, L., Lucian Roiban, Bois, L., Laboratoire des Multimatériaux et Interfaces (LMI), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Centre National de la Recherche Scientifique (CNRS), École normale supérieure - Lyon (ENS Lyon), National Institute for Research and Development of Isotopic and Molecular Technologies (INCDTIM), Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), Université de Strasbourg (UNISTRA)-Matériaux et nanosciences d'Alsace, Centre National de la Recherche Scientifique (CNRS)-Institut National de la Santé et de la Recherche Médicale (INSERM)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Université de Strasbourg (UNISTRA)-Centre National de la Recherche Scientifique (CNRS)-Institut National de la Santé et de la Recherche Médicale (INSERM)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Université de Strasbourg (UNISTRA)-Centre National de la Recherche Scientifique (CNRS)-Réseau nanophotonique et optique, Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA), Matériaux, ingénierie et science [Villeurbanne] (MATEIS), Université de Lyon-Université de Lyon-Centre National de la Recherche Scientifique (CNRS)-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA), Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon, Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Université de Strasbourg (UNISTRA), Université de Lyon-Université de Lyon-Institut National des Sciences Appliquées de Lyon (INSA Lyon), and Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)
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[CHIM.MATE]Chemical Sciences/Material chemistry - Abstract
International audience; Here, we present a mesoporous mixed manganese zirconium oxide (MnZr) synthesized by evaporation induced self-assembly (EISA) method involving a block copolymer self-assembly method. The MnZr oxide has been fully characterized by X-ray diffraction, transmission electronic microscopy, analytical electronic tomography, nitrogen adsorption/desorption isotherms, thermogravimetric analysis, X-ray photoelectron spectroscopy and electronic paramagnetic resonance. Electronic tomography analysis reveals that a mesoporous solid solution MnZr was successfully obtained by this way, with a homogeneous dispersion of Mn. X-ray diffraction, X-ray photoelectron spectroscopy, thermal analysis and electronic paramagnetic resonance inform about the manganese oxidation states present (II, III and IV) and their location within the sample.
- Published
- 2020
10. Identification of inorganic particles resulting from degradation of ESSURE® implants: Study of 10 cases
- Author
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Mickaël Catinon, Vincent Balter, Elisabeth Roux, Aline Auroux, Michel Vincent, Clémentine Fellah, Gilles Sournies, Ana-Maria Trunfio-Sfarghiu, Laboratoire de Mécanique des Contacts et des Structures [Villeurbanne] (LaMCoS), Institut National des Sciences Appliquées de Lyon (INSA Lyon), and Université de Lyon-Institut National des Sciences Appliquées (INSA)-Université de Lyon-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)
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myalgia ,Adult ,medicine.medical_specialty ,Sterilization, Tubal ,medicine.medical_treatment ,[SDV]Life Sciences [q-bio] ,Hysteroscopy ,ESSURE Hysteroscopic sterilization Fallopian tube biopsy Tin particles Electron microscopy ,Hysterectomy ,03 medical and health sciences ,Salpingectomy ,0302 clinical medicine ,Pregnancy ,medicine ,Humans ,030212 general & internal medicine ,Adverse effect ,MESH: ESSURE Hysteroscopic sterilization Fallopian tube biopsy Tin particles Electron microscopy ,Fallopian Tubes ,030219 obstetrics & reproductive medicine ,business.industry ,Obstetrics and Gynecology ,Uterine horns ,Middle Aged ,equipment and supplies ,3. Good health ,Surgery ,medicine.anatomical_structure ,Reproductive Medicine ,Essure ,Female ,Implant ,medicine.symptom ,business ,Fallopian tube - Abstract
Objective Approximately 750,000 women worldwide have undergone ESSURE hysteroscopic sterilization since 2002. In 2015, an increase in adverse effects was noted, with gynaecological and systemic symptoms reported. Scanning electron microscopy (SEM) analysis of fallopian tube and uterine horn tissues and implants, after hysterectomy or salpingectomy, revealed the presence of inorganic particles resulting from implant degradation. Study design Ten patients (age 42–53 years) were included in this study. Of these, eight patients had undergone hysterectomy and two patients had undergone salpingectomy. Mean exposure time was 85.5 months (standard deviation 26.8 months, range 34–105 months). Mineralogical analyses were performed on 13 tissue biopsies and four implants by SEM coupled with energy dispersive x-ray spectrometry. Results In five of the 10 patients, tin particles were observed in fallopian tube or uterine horn tissues with inflammatory cell reactions. In the other five cases, iron, chromium, nickel or platinum particles were observed. For implants, major deterioration of the weld zone was observed with either destroyed appearance or the presence of an organic coating containing numerous particles. Discussion and conclusion Analysis of the preclinical studies performed by the manufacturer suggests that degradation of the tin weld plays a major role in these adverse events, with increasing leaching and corrosion between 3 and 6 months for an intratubal insert that si designed to remain in an woman’s body for her entire life. For patients with gynaecological symptoms (e.g. pain, metrorragies) needing explantation, these findings raise the question of a causal relationship between tin particles from implant degradation and the inflammatory tissue response. For patients with systemic symptoms (e.g. blurred vision, headache, asthenia, myalgia), the hypothesis that these symptoms may be related to the formation of organotin (chemical compounds based on tin with hydrocarbon substituents) in the body has yet to be proven. Tin levels in blood have to be measured before and after explantation. To the authors’ knowledge, this is the first study to report significant degradation of the ESSURE implant weld, evidenced by the detection of tin particles in the uterine tissue of patients and comparison of the welding zone between unused and used implants.
- Published
- 2020
11. Correction to: Manganese oxidation states repartition in a channel-like mesoporous zirconium oxide
- Author
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Rodica Chiriac, Nelly Couzon, Arnaud Brioude, Fernand Chassagneux, François Toche, Clémentine Fellah, Cristian Leostean, Laurence Bois, Lucian Roiban, Ovidiu Ersen, and Lhoussain Khrouz
- Subjects
Materials science ,Mechanical Engineering ,chemistry.chemical_element ,02 engineering and technology ,Manganese ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Crystallography ,chemistry ,Mechanics of Materials ,Correct name ,Zirconium oxide ,General Materials Science ,Channel (broadcasting) ,0210 nano-technology ,Mesoporous material ,Author name - Abstract
In the original publication the author name ''Cristian Leostean'' has been incorrectly displayed as ''Cristian Loestean". The correct name of the author is ''Cristian Leostean".
- Published
- 2021
12. Morphological Characterization of Graphene Plans Stacking
- Author
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Petr Dokládal, Marie-Hélène Berger, Albane Borocco, Clémentine Fellah, James Braun, Centre de Morphologie Mathématique (CMM), MINES ParisTech - École nationale supérieure des mines de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL), Centre des Matériaux (MAT), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS), Laboratoire des Technologies des Matériaux EXtrêmes (LTMEx), Service des Recherches Métallurgiques Appliquées (SRMA), Département des Matériaux pour le Nucléaire (DMN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Département des Matériaux pour le Nucléaire (DMN), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay, J. Angulo, S. Velasco-Forero, F. Meyer, Mines Paris - PSL (École nationale supérieure des mines de Paris), and Centre des Matériaux (CDM)
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Scale (ratio) ,Orientation space ,Orientation (computer vision) ,Computer science ,Graphene ,Stacking ,Nanotechnology ,02 engineering and technology ,Material Design ,Mathematical morphology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Characterization (materials science) ,law.invention ,[SPI.MAT]Engineering Sciences [physics]/Materials ,Planar ,law ,[MATH.TR-IMG]Mathematics [math]/domain_math.tr-img ,Mathematical Morphology ,0210 nano-technology ,Filtering - Abstract
International audience; The graphene is a material obtained when carbon atoms form large planar molecules. Well organized, large graphene molecules stacked ontop each other convey to graphene particularly interesting properties useful in nuclear industry. Understanding how the organization on the molecular scale influences the mechanical properties of the material is a key element in the material manufacturing process. In this scope, features like local orientation and length have already been largely explored in the literature. This paper brings a new feature evaluating the number of plans stacked ontop each other and the length of this stacking. It allows obtaing other features such as the overall rate of organization or locality and preferential orientation. These informations, synthesized in the form of histograms provides a key information in the processus the material design. Experimental results obtained on images taken by an electronic scanning microscope are presented to illustrate the proposed method.
- Published
- 2017
13. Experimental evidence of condensed carbon formation during serpentinization in formate bearing fluids
- Author
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Samuel Barbier, Muriel Andreani, Vincent Grossi, Gaucher, Eric C., Olivier Sissmann, Isabelle Daniel, Bénédicte Menez, Ingrid Antheaume, Emmanuelle Albalat, Clémentine Fellah, Hervé Cardon, Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement (LGL-TPE), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Université Jean Monnet - Saint-Étienne (UJM)-Centre National de la Recherche Scientifique (CNRS), Centre scientifique et Technique Jean Feger (CSTJF), TOTAL FINA ELF, IFP Energies nouvelles (IFPEN), Laboratoire GéoSciences Réunion (LGSR), Université de La Réunion (UR)-Institut de Physique du Globe de Paris (IPG Paris), and SGF, CNRS, Laboratoire de Géologie de Lyon ou l’étude de la Terre, des planètes et de l’environnement
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experimental serpentinization ,hydrothermal ,carbonaceous materials ,[SDU]Sciences of the Universe [physics] ,ComputingMilieux_MISCELLANEOUS - Abstract
International audience
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