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Zhuxi W-Cu deposit in northern Jiangxi Province is a recently found super large skarn W deposit. The formation of this deposit is closely related to granitic intrusions. The mining area is located in the central Jiangxi Taqian-Fuchun ore belt in Qin(zhou)-Hang(zhou) joint zone. The discovery of this deposit is further evidence for the model of the Southern tungsten North expansion. However, due to the lack of systematic geochemistry and geochronology of ore-related intrusions, the knowledge of this model is limited. Ore-related fine-grained muscovite granite was chosen as the research object for the study reported on in this paper. LA-ICP-MS zircon U-Pb dating of granite yielded a 206Pb/238U weighted average age of 146.90±0.97 Ma (MSWD=0.55). These granitic rocks have high silicon, alkali and potassium, and are strongly peraluminous, which belongs to the typical S-type granite. This study has indicated that ore-related magmatism occurred at the late Jurassic in Jiangnan uplift and provides new evidence for the genesis of Zhuxi W-Cu deposit and metallogenic regularity of the Taqian-Fuchun metallogenic belt.

The Zhuxi ultra-large type copper-tungsten deposit in the Northeast Jiangxi province located in Taqian -Fuchun metallogenic belt which belongs to Jiangnan ancient island-arc, the discovery of the deposit has verified Southern Tungsten North Expansion perspective and challenge the viewpoint that Tungsten located in the south but the copper located in the north of Jiangxi provience, but the previous lack of accurate chronology study related to Zhuxi copper-tungsten mineralization of granite not enough, resulting in the geodynamic background of understanding. In this study, on the basis of detailed field investigation, core logging and petrology studies on the granodioritic porphyries which had intruded into the Middle Proterozoic Shuangqiaoshan group and with copper mineralization alteration, using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U-Pb dating, we obtained the granodioritic porphyries zircon 206Pb/238U weighted mean age of 847.2±9.4Ma (MSWD=0.111), which can represent the granodiorite porphyry magma emplacement and crystallization age, belonging to the neoproterozoic. The results reveal that the granodioritic porphyries of Zhuxi copper-tungsten mine is a product of the early Neoproterozoic Southern China ancient oceanic crust subduction and Yangtze and Cathaysian continental blocks collisional magmatism, the magmatic activity provides the basis for the metallogenic Qinzhou-Hangzhou metallogenic belt, and the magma event is close related to the Taqian-Fuchun ore belt mineralization, it also provides new evidence for the study of Zhuxi ultra-large type copper-tungsten deposit.

A new tungsten-copper deposit with large-super mineralization potential was recently discovered in the Zhuxi area, Jingdezhen city of Jiangxi Province. The primary halo research plays a very important guiding role in further exploration work. By using Polarized Energy Dispersive X-ray Fluorescence Spectrometry, Inductively Coupled Plasma-Mass Spectrometry/Atomic Emission Spectrometry, large amounts of sample analyses have been conducted. According to the contents of elements W, Sn, Bi, Mo, Pb, Zn, Cu, As, Sb and Ag, these are served as the indicators of the primary halo. The primary halo of Zhuxi tungsten-copper deposit shows that Cu, Zn, Ag and Pb have good correlation as well as W, Bi, Sn and Mo. W is also correlated with Cu. The ore-forming elements have some characteristics in space. In the same section, high temperature elements such as W are more enriched at the northwest, whereas in the plane, this performance appeared at the southwest. Overall, W-oriented high-temperature elements are more enriched at lower depths. By comparison, Cu-oriented middle-temperature elements are shallower than W. This study indicates that the Cu deposit is distributed in the medium deep part (-1400--1500 m), W deposit in the deep part (-1400--1900 m) and Ag, As, Sb at the surface (-1100--1200 m). This study provides a theoretical basis for mineralization forecast and further exploration.

Accompanied by the crucial breakthrough of prospecting for skarn-type Cu-W deposit in Zhuxi of Jiangxi Province, the previously established model of ore distribution was incorrect in that the W and Cu deposits distribution was in the south and north regions respectively. A new model is presented, indicating that the south W deposit might occur in the north region. To verify the new hypothesis, the crystallizing ages and tectonic attributes of ore-related igneous rocks become a critical issue. Furthermore, there are several lamprophyre veins in the study area that might have some temporal and spatial relationships to the Cu-W deposit. Consequently, after extensive field surveying, core logging recording and thin section observation, the veins were dated accurately by zircon U-Pb isotopic method of LA-ICP-MS. Two groups of 206Pb/238U weighted ages of crystallization were yielded, one being (856 ± 10) Ma (MSWD=0.22), and the other is (160.3 ± 2.1) Ma (MSWD=0.17). Considering overall proofs, it is suggested here that the former group of age might represents a magmatism event during the period of subduction for South China ancient oceanic crust in early Neoproterozoic and of collision between the Yangtze and the Cathaysia continental blocks, while the latter one might indicate a magma intrusion event in the early period of Late Jurassic, which produced re-melting of previous rocks triggered by subduction from the Pacific to the Eura-asia plates in Early Jurassic, in accordance with the metallogenic age of the Taqian-Fuchun metallogenic belt in Zhuxi area. The lamprophyre geochronological study in the paper provides a sound theory basis for the metallogenesis of Zhuxi Cu-W deposits.

It is a fatal challenge to the traditional cognition, which the W and Cu deposits distribute in the south and north regions of Jiangxi Province respectively, when the super Cu-W deposit in Zhuxi area was discovered recently, which attracts domestic researchers' attention and their interests in restudying geology of Taqian-Fuchun metallogenic belt in Zhuxi area that provides pivotal proofs for phenomenon of the south W deposit extends to the north region of the area. The recent discovery of the super Cu-W deposit in the Zhuxi area of northeast Jiangxi has challenged the belief that W and Cu deposits are distributed in the south and north regions of the province respectively and has led to a renewed interest in analyzing these areas again. The metallogenesis types in the Taqian-Fuchun metallogenic belt are complicated with multiple ores. For instance, Cu, W, Mo and Au are related to various igneous rocks, with some diagenesis. To address geological issues, such as the tectonic evolutional setting and ore material origins, which need to be solved urgently, the zircon U-Pb isotopic method of LA-ICP-MS was utilized and is reported in this paper in order to date the ore-related magmatic rocks. The results show that there were at least three periods of magmatism and two stages of metallogenesis in the belt. The three periods of magmatism include 850 Ma and 160 Ma granodiorites and for the lamprophyre veins, 146 Ma granites. Two stages of metallogenesis are the Taqian skarn-type W-Mo deposit and the Yuexing skarn-type Cu polymetallic deposit related to the 160 Ma granites, and the Zhuxi skarn-type Cu-W deposit related to the 146 Ma granites. Thus, considering previous regional data, the hypothesis from this study is that the ore-related magmas of Neoproterozoic and Jurassic in the belt were derived from the same magma chamber and the latter was inherited from the former. The porphyry granite and aplite veins formed in 145 Ma are the indicators of Cu-W deposit.

The Zhuxi deposit is a new discovery of copper-tungsten dominated large-super-large ore deposit with great mineralization potential situated in the Zhuxi Area, Jingdezhen City, Jiangxi Province. However, present research is somewhat limited for some of the geological characteristics. Further study on genetic types and geochemical characteristics for this deposit is necessary. A bench-top type Polarized Energy Dispersive X-Ray Fluorescence Spectrometer, coupled with directly pressed powder samples has been used to analyze drill core samples of the Cu-W ore body. The instrument used in the experiments has a high detection ability for measuring major elements (SiO2, CaO and MgO) and trace elements (Cu, W, Zn and Ag), compositions with low detection limit, small error, good stability and other characteristics. The experimental results show that the major elements of SiO2, CaO and MgO have strong metasomatism characteristics. The SiO2 and CaO have a negative correlation. Trace elements Cu, W, Zn and Ag also exhibit symbiotic features, and Cu, W contents are high in the middle and low on both sides spatially. All evidence explains the metasomatism characteristics controlled by structures. The element variations and related mineral compositions also indicate that ore-forming materials were derived from granodiorite, porphyry, granite porphyry and diorite. These results provide a theoretical basis for mineralization forecast and further exploration goals.

A series of new systems of the SrCe1-xTixO3 and SrCe1−xZrxO3 (SCTx and SCZx, x = 0.0–0.1) ceramics have been prepared by the traditional solid-phase methods. The XRD patterns results show that an ABO3-type perovskite structure of the SrCeO3 ceramic can be obtained as x = 0.0. With the increase in Ti4+- and Zr4+-ions-doping content of x = 0.02–0.1, the SCTx and SCZx ceramics basically belong to the perovskite phase with the orthorhombic structure of the space group Pmcn (62), and the results of EDS analysis on the proportion of each element can also verify the correctness of the XRD analytical results. In addition, all the microstructures are dense for the SCTx and SCZx (x = 0.0–0.1) samples. The fitting results of complex plane impedance verified that the temperature stability of SCTx solid solution ceramics is more suitable for adjusting to the practical application range. Especially, the SCTx (x = 0.03) ceramics sintered at 1270 °C for 4 h can obtain the relatively excellent dielectric properties of εr = 50.16, Q × f = 8,940 GHz (at 5.91 GHz), and τf = + 0.08 ppm/°C. [ABSTRACT FROM AUTHOR]