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Here we study characteristic length scales in an aqueous suspension of symmetric oppositely charged colloid subject to a uniform electric field by Brownian Dynamics simulations. We consider a sufficiently strong electric field where the like charges in the system form macroscopic lanes. We construct spatial correlation functions characterizing structural order and that of particles of different mobilities in-plane transverse to the electric field at a given time. We call these functions as equal time density correlation function (ETDCF). The ETDCF between particles of different charges, irrespective of mobilities, are called structural ETDCFs, while those between particles of different mobilities are called the dynamic ETDCF. We extract the characteristic length of correlation by fitting the envelopes of the ETDCFs to exponential dependence. We find that structural ETDCF and the dynamical-ETDCFs of the slow particles increase with time. This suggests that the slow particles undergo microphase separation in the background of the fast particles which drive the structural pattern in the plane transverse to the lanes. The ETDCFs can be measured for colloidal systems directly following particle motion by video-microscopy and may be useful to understand patterns out of equilibrium.

We study the temperature dependence of static and dynamic responses of Coulomb interacting particles in two-dimensional traps across the thermal crossover from an amorphous solid- to liquid-like behaviors. While static correlations, that investigate the translational and bond orientational order in the confinements, show the footprints of hexatic-like phase at low temperature, dynamics of the particles slow down considerably in this state -- reminiscent of a supercooled liquid. Using density correlations, we probe intriguing signatures of long-lived inhomogeneities due to the interplay of the irregularity in the confinement and long-range Coulomb interactions. The relaxation at multiple time scales show stretched-exponential decay of spatial correlations in irregular traps. Temperature dependence of characteristic time scales, depicting the structural relaxation of the system, show striking similarities with those observed for the glassy systems indicating that, some of the key signatures of supercooled liquids emerge in confinements with lower spatial symmetries., Comment: 12 pages + 6 pages supplementary materials, 10 main figures, 8 supplemenatry figures

The interplay between structure and dynamics in non-equilibrium steady-state is far from understood. We address this interplay by tracking Brownian Dynamics trajectories of particles in a binary colloid of opposite charges in an external electric field, undergoing cross-over from homogeneous to lane state, a prototype of heterogeneous structure formation in non-equilibrium systems. We show that the length scale of structural correlations controls heterogeneity in diffusion and consequent anomalous dynamic responses, like the exponential tail in probability distributions of particle displacements and stretched exponential structural relaxation. We generalise our observations using equations for steady state density which may aid to understand microscopic basis of heterogeneous diffusion in condensed matter systems.

We calculate analytically the forces between two solvophobic solutes, considering a model system. We show that the effective interaction forces between two solvophobic solutes, mediated by the solvent, is attractive for short ranges, which decreases linearly with surface-to-surface separation s between the solutes and repulsive in the long range falling off as 1 / s 4 . The attraction originates from the unbalanced Laplace force at the liquid-gas interface, generated by the repulsive interaction with the solvent particles, around the solutes at small s. The long range part arises due to unbalanced osmotic pressure. We illustrate the calculations for the Lennard-Jones solvent. We discuss the general implication of our results in the context of hydrophobic collapse.

The dynamical response of Coulomb-interacting particles in nano-clusters are analyzed at different temperatures characterizing their solid- and liquid-like behavior. Depending on the trap-symmetry, both the spatial and temporal correlations undergo slow, stretched exponential relaxations at long times, arising from spatially correlated motion in string-like paths. Our results indicate that the distinction between the `solid' and `liquid' is soft: While particles in a `solid' flow producing dynamic heterogeneities, motion in `liquid' yields unusually long tail in the distribution of particle-displacements. A phenomenological model captures much of the subtleties of our numerical simulations., Comment: 5 pages, 4 figures, includes supplementary materials

From the crystal structure data and using the concept of equilbrium statistical mechanics we show how to calculate the thermodynamics of protein/DNA complexes. We apply the method to the TATA-box binding protein (TBP)/TATA sequence complex. We have estimated the change in free energy and entropy for each of the base pair (bp). The local rigidity of the DNA is estimated from the curvature of the free energy. We also estimate the free energy gain of the protein due to bond formation with a particular bp. We thus figure out the bps responsible for specific binding., Comment: 4 pages, 3 figures and 1 table

We incorporate the effects of fluctuations in a density functional analysis of the freezing of a colloidal liquid in the presence of an external potential generated by interfering laser beams. A mean field treatment, using a density functional theory, predicts that with the increase in the strength of the modulating potential, the freezing transition changes from a first order to a continuous one via a tricritical point for a suitable choice of the modulating wavevectors. We demonstrate here that the continuous nature of the freezing transition at large values of the external potential $V_{e}$ survives the presence of fluctuations. We also show that fluctuations tend to stabilize the liquid phase in the large $V_{e}$ regime., Comment: published

Recently it has been shown that a strongly interacting colloidal mixture consisting of oppositely driven particles, undergoes a nonequilibrium transition towards lane formation provided the driving strength exceeds a threshold value. We predict here a reentrance effect in lane formation: for fixed high driving force and increasing particle densities, there is first a transition towards lane formation which is followed by another transition back to a state with no lanes. Our result is obtained both by Brownian dynamics computer simulations and by a phenomenological dynamical density functional theory., Comment: 4 pages, 2 figures

The codons, sixtyfour in number, are distributed over the coding parts of DNA sequences. The distribution function is the plot of frequency-versus-rank of the codons. These distributions are characterised by parameters that are almost universal, i.e., gene independent. There is but a small part that depends on the gene. We present the theory to calculate the universal (gene-independent) part. The part that is gene-specific, however, has undetermined overlaps and fluctuations., Comment: 31 pages, 5 figures