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We employ a positron annihilation technique, the spin-polarized two-dimensional angular correlation of annihilation radiation (2D-ACAR), to measure the spin-difference spectra of ferromagnetic nickel. The experimental data are compared with the theoretical results obtained within a combination of the local spin density approximation (LSDA) and the many-body dynamical mean-field theory (DMFT). We find that the self-energy defining the electronic correlations in Ni leads to anisotropic contributions to the momentum distribution. By direct comparison of the theoretical and experimental results we determine the strength of the local electronic interaction U in ferromagnetic Ni as 2.0 ± 0.1 eV.

We determined the bulk electronic structure of the prototypical Heusler compound Cu(2)MnAl by measuring the angular correlation of annihilation radiation using spin-polarized positrons. To this end, a new algorithm for reconstructing 3D densities from projections is introduced that allows us to corroborate the excellent agreement between our electronic structure calculations and the experimental data. The contribution of each individual Fermi surface sheet to the magnetization was identified, and summed to a total spin magnetic moment of 3.6±0.5 μ(B)/f.u..

We present experiments on glucose-gelatin compounds using positron annihilation lifetime spectroscopy (PALS) in order to study the behavior of the free volume dependent on H2O loading, drying, and uniaxial pressure. A semiempirical quantum mechanical model was applied in order to correlate the lifetime of orthopositronium in nanoscaled voids to the void size. This allowed us to determine the absolute value of the mean void radius in the biopolymer samples. In addition, the variation of the total free volume of the differently treated samples is quantified and illustrated by a log-normal distribution function. Most interesting results have been obtained after saturation loading with H2O that leads to the formation of voids with a mean size of 84.3(1.9) Å(3) and to an increase of the total free volume by a factor of 2.5. This observation in the swelled sample is explained by the entropy elastic regime well above the glass transition temperature that greatly facilitates the formation of free volume. Differential scanning calorimetry (DSC) measurements were performed in order to determine the glass transition temperature and to support the interpretation of the results obtained by PALS.

Angular correlation of annihilation radiation (ACAR) is a well established technique for the investigation of the electronic structure. A major limitation of ACAR studies is the available positron flux at a small spot on the sample. For this reason, the focus of this work is put on the discussion of a newly developed source-sample stage of the new 2D-ACAR spectrometer at Technische Universität München which uses an optimized static magnetic field configuration to guide the positrons onto the sample. The achieved spot diameter is d(FWHM) = 5.4 mm, with a high efficiency over the whole energy spectrum of the (22)Na positron source. The implications of the performance of the source-sample stage are discussed with regard to 2D-ACAR measurements of single crystalline α-quartz, which serves as a model system for the determination of the total resolution. A value of (1.53 × 1.64) mrad(2) FWHM was achieved at room temperature.