1. The crystal structure of a new calcium aluminate phase containing formate
- Author
-
Dalconi, M, Artioli, G, Masciocchi, N, Giacobbe, C, Castiglioni, F, Ferrari, G, Dalconi M. C., Artioli G., Masciocchi N., Giacobbe C., Castiglioni F., Ferrari G., Dalconi, M, Artioli, G, Masciocchi, N, Giacobbe, C, Castiglioni, F, Ferrari, G, Dalconi M. C., Artioli G., Masciocchi N., Giacobbe C., Castiglioni F., and Ferrari G.
- Abstract
A new calcium aluminate phase containing formate ions was synthesized and its crystal structure determined. This new phase is indicated as M-phase and was firstly observed in Portland cement pastes hydrated in presence of Ca-formate and in excess of water. The crystal structure of the M-phase was successfully solved in the R-3 space group of the trigonal system on the basis of synchrotron X-ray single crystal diffraction data. The structural model was confirmed by Rietveld refinement of the powder diffraction data acquired on the synthesized pure sample. The crystal structure of the M-phase is similar to that of ettringite, being characterized by columns of AlO6 octahedra alternating with groups of three edge-sharing CaO7 polyhedra. The formate ions (HCOO)(-) share two oxygens with Ca polyhedra and are located in the interspace between the columns. The crystal structure of the M-phase testifies the strong interaction occurring between small organic molecules as formate and the calcium aluminate components of Portland cement.
- Published
- 2021