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We review and refine the geological setting of an area located nearby the Tyrrhenian seacoast, in the inner zone of the Northern Apennines (southern Tuscany), where a Neogene monzogranite body (estimated in about 3 km long, 1.5 km wide, and 0.7 km thick) emplaced during early Pliocene. This magmatic intrusion, known as the Gavorrano pluton, is partially exposed in a ridge bounded by regional faults delimiting broad structural depressions. A widespread circulation of geothermal fluids accompanied the cooling of the magmatic body and gave rise to an extensive Fe-ore deposit (mainly pyrite) exploited during the past century. The tectonic setting which favoured the emplacement and exhumation of the Gavorrano pluton is strongly debated with fallouts on the comprehension of the Neogene evolution of this sector of the inner Northern Apennines. Data from a new fieldwork dataset, integrated with information from the mining activity, have been integrated to refine the geological setting of the whole crustal sector where the Gavorrano monzogranite was emplaced and exhumed. Our review, implemented by new palynological, petrological and structural data pointed out that: (i) the age of the Palaeozoic phyllite (hosting rocks) is middle-late Permian, thus resulting younger than previously described (i.e., pre-Carboniferous), (ii) the conditions at which the metamorphic aureole developed are estimated at a temperature of c. 660 °C and at a depth lower than c. 6 km, (iii) the tectonic evolution which determined the emplacement and exhumation of the monzogranite is constrained in a transfer zone, in the frame of the extensional tectonics affecting the area continuously since Miocene.

The record of metamorphic conditions is commonly highly heterogeneous in spatially close rocks of different composition and rheology. The well-studied Cima di Gagnone area in the Central Alps represents such an example, as relatively small, 1– to 100 s-meter scale, ultrahigh–pressure and high–temperature ultramafic lenses are enveloped within amphibolite–facies metasediments. We present new field observations, microstructural and petrological analyses, and thermodynamic modelling results on these metasediments, showing that these rocks generally experienced medium pressure and medium temperature conditions of 1.0–1.2 GPa and 640–700 °C, followed by a retrograde stage around 0.6–0.8 GPa and 600–675 °C. However, a few samples from the immediate proximity of the ultramafic lenses record significantly higher P–T conditions of 1.3–1.7 GPa and 750–850 °C, approaching the high pressure and high temperature conditions of the ultramafic bodies (1.5–3.1 GPa, 650–850 °C). Mineral/bulk chemistry changes during growth of new mineral phases hint to local melt/fluid interaction (i.e., metasomatism) between metasediments and ultramafics during the high temperature deformation. Preliminary U-Pb LA–ICP–MS dating suggests that zircon grains from the metasomatic reaction zone have been fully re–equilibrated during the early stage of Alpine exhumation (~36 Ma), while the large part of the metasediments records only pre–Alpine ages. We finally recast these new data into the regional P–T–t–D paths and discuss the consequences of these findings for understanding the exhumation processes of HP rocks. We found different local equilibria (ΔP up to 2 GPa; ΔT up to 160 °C) that cannot be explained simply by retrograde metamorphism or by tectonic amalgamation. Rather, our work suggests a significant role of deformation in producing variable pressure and temperature record within the rocks.