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We report on inelastic neutron scattering (INS) measurements on the molecular spin ring CsFe$_8$, in which eight spin-5/2 Fe(III) ions are coupled by nearest-neighbor antiferromagnetic Heisenberg interaction. We have recorded INS data on a non-deuterated powder sample up to high energies at the time-of-flight spectrometers FOCUS at PSI and MARI at ISIS, which clearly show the excitation of spin waves in the ring. Due to the small number of spin sites, the spin-wave dispersion relation is not continuous but quantized. Furthermore, the system exhibits a gap between the ground state and the first excited state. We have modeled our data using exact diagonalization of a Heisenberg-exchange Hamiltonian together with a small single-ion anisotropy term. Due to the molecule's symmetry, only two parameters $J$ and $D$ are needed to obtain excellent agreement with the data. The results can be well described within the framework of the rotational-band model as well as antiferromagnetic spin-wave theories., Comment: 10 pages, 9 figures, REVTEX 4

The antiferromagnetic molecular finite chain Cr6 was studied by inelastic neutron scattering. The observed magnetic excitations at 2.6 and 4.3 meV correspond, due to the open boundaries of a finite chain, to standing spin waves. The determined energy spectrum revealed an essentially classical spin structure. Hence, various spin-wave theories were investigated in order to assess their potential for describing the elementary excitations of finite spin systems., Comment: 6 pages, 6 figures, accepted for publication in Europhysics Letters

The Q dependence of the inelastic neutron scattering (INS) intensity of transitions within the ground-state spin multiplet of single-molecule magnets (SMMs) is considered. For these transitions, the Q dependence is related to the spin density map in the ground state, which in turn is governed by the Heisenberg exchange interactions in the cluster. This provides the possibility to infer the exchange-coupling constants from the Q dependence of the INS transitions within the spin ground state. The potential of this strategy is explored for the M = +-10 -> +- 9 transition within the S = 10 multiplet of the molecule Mn12 as an example. The Q dependence is calculated for powder as well as single-crystal Mn12 samples for various exchange-coupling situations discussed in the literature. The results are compared to literature data on a powder sample of Mn12 and to measurements on an oriented array of about 500 single-crystals of Mn12. The calculated Q dependence exhibits significant variation with the exchange-coupling constants, in particular for a single-crystal sample, but the experimental findings did not permit an unambiguous determination. However, although challenging, suitable experiments are within the reach of today's instruments., Comment: 11 pages, 6 figures, REVTEX4, to appear in PRB

The low-lying magnetic excitations in the dimer of single-molecule magnets (Mn4)2 are studied by inelastic neutron scattering as a function of hydrostatic pressure. The anisotropy parameters D and B04, which describe each Mn4 subunit, are essentially pressure independent, while the antiferromagnetic exchange coupling J between the two Mn4 subunits strongly depends on pressure, with an increase of 42% at 17 kbar. Additional pressure dependent powder X-ray measurements allow a structural interpretation of the findings., Comment: 4 pages, 4 figures, REVTEX4, to be published in PRB

Time-resolved inelastic neutron scattering measurements on an array of single-crystals of the single-molecule magnet Mn12ac are presented. The data facilitate a spectroscopic investigation of the slow relaxation of the magnetization in this compound in the time domain., Comment: 3 pages, 4 figures, REVTEX4, to appear in Appl. Phys. Lett., for an animation see also http://www.dcb.unibe.ch/groups/guedel/members/ow2/trins.htm

It has been shown that sunlit snow and ice plays an important role in processing atmospheric species. Photochemical production of a variety of chemicals has recently been reported to occur in snow/ice and the release of these photochemically generated species may significantly impact the chemistry of the overlying atmosphere. Nitrogen oxide and oxidant precursor fluxes have been measured in a number of snow covered environments, where in some cases the emissions significantly impact the overlying boundary layer. For example, photochemical ozone production (such as that occurring in polluted mid-latitudes) of 3-4 ppbv/day has been observed at South Pole, due to high OH and NO levels present in a relatively small boundary layer. Field and laboratory experiments have determined that the origin of the observed NOx flux is the photochemistry of nitrate within the snowpack, however some details of the mechanism have not yet been elucidated. A variety of low molecular weight organic compounds have been shown to be emitted from sunlit snowpacks, the source of which has been proposed to be either direct or indirect photo-oxidation of natural organic materials present in the snow. Although myriad studies have observed active processing of species within irradiated snowpacks, the fundamental chemistry occurring remains poorly understood. Here we consider the nature of snow at a fundamental, physical level; photochemical processes within snow and the caveats needed for comparison to atmospheric photochemistry; our current understanding of nitrogen, oxidant, halogen and organic photochemistry within snow; the current limitations faced by the field and implications for the future.

The Kodiak Islands are located approximately 130 to 250 km from the Alaska-Aleutian Trench where the Pacific plate is underthrusting the North American plate at a rate of about 57 mm/yr. The southern extent of the 1964 Prince William Sound (${M-w}$ = 9.2) earthquake rupture occurred offshore and beneath the eastern portion of the Kodiak Islands. Here we report GPS results (1993-2001) from northern Kodiak Island that span the transition between the 1964 uplift region along the eastern coast and the region of coseismic subsidence further inland. The horizontal velocity vectors range from 22.9 $\pm$ 2.2 mm/yr at N26.3$\deg$W $\pm$ 2.5$\deg$, about 150 km from the trench, to 5.9 $\pm$ 1.3 mm/yr at N65.9$\deg$W $\pm$ 6.6$\deg$, about 190 km from the trench. Near the northeastern coast of Kodiak the velocity vector above the shallow, locked main thrust zone is between the orientation of PCFC-NOAM plate motion (N22$/deg$W) and the trench-normal (N3O$\deg$W). Further west, our geodetic results suggest the accumulation of shear strain that will be released eventually as left-lateral motion on upper plate faults such as the Kodiak Island fault. These results are consistent with the hypothesis that the difference between the Pacific-North American plate motion and the orientation of the down going slab would lead to 4-8 mm/yr of left-lateral slip. Short-term geodetic uplift rates range from 2 - 14 mm/yr, with the maximum uplift located near the axis of maximum subsidence during the 1964 earthquake. We evaluated alternate interseismic models for Kodiak to test the importance of various mechanisms responsible for crustal deformation rates. These models are based on the plate interface slip history inferred from earlier modeling of coseismic and post-seismic geodetic results. The horizontal (trench perpendicular) and vertical deformation rates across Kodiak are consistent with a model that includes the viscoelastic response to : (1) a downgoing Pacific plate interface that is locked at shallow depths,(2) coseismic slip in the 1964 and (3) interseismic creep below the seismogenic zone. The change in orientation of the horizontal velocity vector occurs down-dip from the locked main thrust zone. In southern Kodiak, the coseismic slip in the 1964 earthquake was smaller than in the northern Kodiak region; yet, the horizontal, interseismic velocities as a function of distance from the trench are comparable to those in northern Kodiak. Based on the earthquake history prior to, and following the 1964 earthquake, we hypothesize that the plate interface in southern Kodiak slips in more frequent large earthquakes than in northern Kodiak.