26 results on '"Carter S. Haines"'
Search Results
2. Unipolar stroke, electroosmotic pump carbon nanotube yarn muscles
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Ray H. Baughman, Seon Jeong Kim, Zhong Wang, Jiyoung Oh, Si Qin, Jong Woo Park, Jianning Ding, Jiang Xu, Sameh Tawfick, Javad Foroughi, Kevin A. Alberto, Kyeongjae Cho, Jinsong Leng, Shaoli Fang, Steven O. Nielsen, Jiuke Mu, Xinghao Hu, Joselito M. Razal, Carter S. Haines, Na Li, Xiaoshuang Zhou, Hetao Chu, Patrick Conlin, Geoffrey M. Spinks, Ningyi Yuan, Hyungjun Kim, and Maenghyo Cho
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Horizontal scan rate ,Multidisciplinary ,Materials science ,Nanotubes, Carbon ,Muscles ,Work (physics) ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,medicine.disease ,01 natural sciences ,0104 chemical sciences ,Electroosmotic pump ,medicine ,Energy transformation ,Artificial muscle ,Artificial Organs ,medicine.symptom ,0210 nano-technology ,Carbon nanotube yarn ,Stroke ,Muscle Contraction ,Biomedical engineering ,Muscle contraction - Abstract
Pump it up Carbon nanotube yarns can be used as electrochemical actuators because infiltration with ions causes a contraction in length and an expansion in diameter. Either positive or negative ions can cause this effect. Chu et al. constructed an all-solid-state muscle that eliminated the need for an electrolyte bath, which may expand the potential for its use in applications. By infiltrating the yarns with charged polymers, the fibers start partially swollen, so the length can increase through the loss of ions. It is thus possible to increase the overall stroke of the muscle. Further, these composite materials show a surprising increase in stroke with scan rate. Science , this issue p. 494
- Published
- 2021
3. Unipolar-stroke, electroosmotic-pump carbon nanotube yarn muscles
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Ray H. Baughman, Hetao Chu, Zhong Wang, Jiuke Mu, Na Li, Xiaoshuang Zhou, Shaoli Fang, Carter S. Haines, Jong W. Park, Si Qin, Ningyi Yuan, Jiang Xu, Sameh Tawfick, Hyungjun Kim, Patrick Conlin, Maenghyo Cho, Kyeongjae Cho, Jiyoung Oh, Steven Nielson, Kelvin Alberto, Joselito M. Razal, Javad Foroughi, Geoffrey M. Spinks, Seon Jeong Kim, Jianning Ding, and Jinsong Leng
- Published
- 2022
4. Enhancing the Work Capacity of Electrochemical Artificial Muscles by Coiling Plies of Twist-Released Carbon Nanotube Yarns
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Hyunsoo Kim, Seon Jeong Kim, Carter S. Haines, Na Li, Jae Sang Hyeon, Tae Jin Mun, Keon Jung Kim, and Ray H. Baughman
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Work (thermodynamics) ,Materials science ,02 engineering and technology ,Carbon nanotube ,Electrolyte ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Capacitance ,0104 chemical sciences ,law.invention ,law ,Ultimate tensile strength ,General Materials Science ,Artificial muscle ,Composite material ,0210 nano-technology ,Energy harvesting ,Mechanical energy - Abstract
Twisted-yarn-based artificial muscles can potentially be used in diverse applications, such as valves in microfluidic devices, smart textiles, air vehicles, and exoskeletons, because of their high torsional and tensile strokes, high work capacities, and long cycle life. Here, we demonstrate electrochemically powered, hierarchically twisted carbon nanotube yarn artificial muscles that have a contractile work capacity of 3.78 kJ/kg, which is 95 times the work capacity of mammalian skeletal muscles. This record work capacity and a tensile stroke of 15.1% were obtained by maximizing yarn capacitance by optimizing the degree of inserted twist in component yarns that are plied until fully coiled. These electrochemically driven artificial muscles can be operated in reverse as mechanical energy harvesters that need no externally applied bias. In aqueous sodium chloride electrolyte, a peak electrical output power of 0.65 W/kg of energy harvester was generated by 1 Hz sinusoidal elongation.
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- 2019
5. Torsional refrigeration by twisted, coiled, and supercoiled fibers
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Douglas S. Galvao, Carter S. Haines, Yicheng Xiao, Enlai Gao, Linlin Mou, Xuemin Wang, Na Li, Run Wang, Xiang Zhou, Sitong Li, Alexandre F. Fonseca, Zunfeng Liu, Shaoli Fang, Zhongsheng Liu, Wenqian He, Zhong Wang, Ali E. Aliev, Yanan Shen, Jiuke Mu, Mengmeng Chen, Wubin Zhao, Baigang An, Dong Qian, Marcio Dias Lima, Hongbing Lu, Kaiqing Yu, Shougen Yin, Yaowang Li, Ray H. Baughman, and Nan Jiang
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Materials science ,FOS: Physical sciences ,02 engineering and technology ,Applied Physics (physics.app-ph) ,010402 general chemistry ,01 natural sciences ,Fishing line ,chemistry.chemical_compound ,Natural rubber ,Composite material ,Twist ,Quantitative Biology::Biomolecules ,Condensed Matter - Materials Science ,Multidisciplinary ,Refrigeration ,Materials Science (cond-mat.mtrl-sci) ,Physics - Applied Physics ,Polyethylene ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,chemistry ,visual_art ,visual_art.visual_art_medium ,Lower cost ,Cooling energy ,0210 nano-technology - Abstract
Twisting is cool Rubber bands that are stretched and held in an extended shape for a while will extract heat from their surroundings as they are allowed to relax, owing to a reversal of stress-induced crystallization, which is an exothermic process. Wang et al. examine the potential for solid-state cooling of twisted fibers, along with configurations such as supercoiling, for materials including natural rubber, polyethylene, and nickel-titanium fibers. The cooling is related to the change in entropy of the material as it is mechanically deformed. Science , this issue p. 216
- Published
- 2019
6. New twist on artificial muscles
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Ali E. Aliev, Carter S. Haines, Ray H. Baughman, Na Li, Geoffrey M. Spinks, and Jiangtao Di
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Engineering ,Multidisciplinary ,business.industry ,Work (physics) ,Mechanical engineering ,Nanotechnology ,Robotics ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,medicine ,Energy transformation ,Paddle ,Artificial muscle ,Fiber ,Artificial intelligence ,medicine.symptom ,0210 nano-technology ,business ,Spinning ,Muscle contraction - Abstract
Lightweight artificial muscle fibers that can match the large tensile stroke of natural muscles have been elusive. In particular, low stroke, limited cycle life, and inefficient energy conversion have combined with high cost and hysteretic performance to restrict practical use. In recent years, a new class of artificial muscles, based on highly twisted fibers, has emerged that can deliver more than 2,000 J/kg of specific work during muscle contraction, compared with just 40 J/kg for natural muscle. Thermally actuated muscles made from ordinary polymer fibers can deliver long-life, hysteresis-free tensile strokes of more than 30% and torsional actuation capable of spinning a paddle at speeds of more than 100,000 rpm. In this perspective, we explore the mechanisms and potential applications of present twisted fiber muscles and the future opportunities and challenges for developing twisted muscles having improved cycle rates, efficiencies, and functionality. We also demonstrate artificial muscle sewing threads and textiles and coiled structures that exhibit nearly unlimited actuation strokes. In addition to robotics and prosthetics, future applications include smart textiles that change breathability in response to temperature and moisture and window shutters that automatically open and close to conserve energy.
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- 2016
7. High-Performance Biscrolled MXene/Carbon Nanotube Yarn Supercapacitors
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Shayan Seyedin, Ray H. Baughman, Si Qin, Carter S. Haines, Joselito M. Razal, Raquel Ovalle-Robles, Jizhen Zhang, Na Li, Jiangting Wang, Ariana Levitt, Weiwei Lei, Zhiyu Wang, and Yury Gogotsi
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Supercapacitor ,Flexibility (engineering) ,Materials science ,Nanotechnology ,02 engineering and technology ,General Chemistry ,Carbon nanotube ,Yarn ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Capacitance ,Energy storage ,0104 chemical sciences ,law.invention ,Biomaterials ,Form factor (design) ,law ,visual_art ,visual_art.visual_art_medium ,General Materials Science ,Electronics ,0210 nano-technology ,Biotechnology - Abstract
Yarn-shaped supercapacitors (YSCs) once integrated into fabrics provide promising energy storage solutions to the increasing demand of wearable and portable electronics. In such device format, however, it is a challenge to achieve outstanding electrochemical performance without compromising flexibility. Here, MXene-based YSCs that exhibit both flexibility and superior energy storage performance by employing a biscrolling approach to create flexible yarns from highly delaminated and pseudocapacitive MXene sheets that are trapped within helical yarn corridors are reported. With specific capacitance and energy and power densities values exceeding those reported for any YSCs, this work illustrates that biscrolled MXene yarns can potentially provide the conformal energy solution for powering electronics beyond just the form factor of flexible YSCs.
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- 2018
8. Hierarchically buckled sheath-core fibers for superelastic electronics, sensors, and muscles
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Márcio D. Lima, Raquel Ovalle-Robles, Dong Qian, Shougen Yin, D. W. Lee, Douglas S. Galvao, Q. Yin, Xavier Lepró, Xiaodong Wang, Zunfeng Liu, Jianning Ding, Mei Zhang, Hongbing Lu, Hongyan Wang, C. Dong, Ray H. Baughman, Run Wang, F. A. Moura, Nan Jiang, Carter S. Haines, Jiangtao Di, Y. T. Chong, Shaoli Fang, Ningyi Yuan, Wei Lv, Rui Zhang, Mengmeng Chen, and R. C. Zhang
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Multidisciplinary ,Fabrication ,Materials science ,Nanotechnology ,Carbon nanotube ,Capacitance ,law.invention ,Core (optical fiber) ,Buckling ,Natural rubber ,law ,visual_art ,visual_art.visual_art_medium ,Electronics ,Fiber ,Composite material - Abstract
Composite stretchable conducting wires Think how useful a stretchable electronic “skin” could be. For example you could place it over an aircraft fuselage or a body to create a network of sensors, processors, energy stores, or artificial muscles. But it is difficult to make electronic interconnects and strain sensors that can stretch over such surfaces. Liu et al. created superelastic conducting fibers by depositing carbon nanotube sheets onto a prestretched rubber core (see the Perspective by Ghosh). The nanotubes buckled on relaxation of the core, but continued to coat it fully and could stretch enormously, with relatively little change in resistance. Science , this issue p. 400 ; see also p. 382
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- 2015
9. Harvesting temperature fluctuations as electrical energy using torsional and tensile polymer muscles
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Hyeon Jun Sim, Xuemin Wang, Shazed Aziz, Ray H. Baughman, Seon Jeong Kim, Mikhail E. Kozlov, Shi Hyeong Kim, John D. W. Madden, Geoffrey M. Spinks, Márcio D. Lima, Carter S. Haines, Changsoon Choi, Hongbing Lu, and Dong Qian
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Renewable Energy, Sustainability and the Environment ,business.industry ,Electric potential energy ,Rotational speed ,Polyethylene ,Pollution ,chemistry.chemical_compound ,Nuclear Energy and Engineering ,chemistry ,Waste heat ,Ultimate tensile strength ,Electronic engineering ,Environmental Chemistry ,Artificial muscle ,Electric power ,Composite material ,business ,Thermal energy - Abstract
Diverse means have been deployed for harvesting electrical energy from mechanical actuation produced by low-grade waste heat, but cycle rate, energy-per-cycle, device size and weight, or cost have limited applications. We report the electromagnetic harvesting of thermal energy as electrical energy using thermally powered torsional and tensile artificial muscles made from inexpensive polymer fibers used for fishing line and sewing thread. We show that a coiled 27 μm-diameter nylon muscle fiber can be driven by 16.7 °C air temperature fluctuations to spin a magnetic rotor to a peak torsional rotation speed of 70 000 rpm for over 300 000 heating–cooling cycles without performance degradation. By employing resonant fluctuations in air temperature of 19.6 °C, an average output electrical power of 124 W per kg of muscle was realized. Using tensile actuation of polyethylene-based coiled muscles and alternating flows of hot and cold water, up to 1.4 J of electrical energy was produced per cycle. The corresponding per cycle electric energy and peak power output, per muscle weight, were 77 J kg−1 and 28 W kg−1, respectively.
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- 2015
10. Polar-Electrode-Bridged Electroluminescent Displays: 2D Sensors Remotely Communicating Optically
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Dan Hu, Yueh-Lin Loo, Wei Huang, Carter S. Haines, Na Li, Clifton Shen, Lin Yuan, Lijia Yan, Shaoli Fang, Xiuru Xu, Hong Meng, Anvar A. Zakhidov, and Ray H. Baughman
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Materials science ,business.industry ,Mechanical Engineering ,02 engineering and technology ,Electroluminescence ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,law.invention ,Electroluminescent display ,Optics ,Mechanics of Materials ,law ,Electrode ,Optoelectronics ,Polar ,General Materials Science ,New device ,Light emission ,Graphite ,0210 nano-technology ,business ,Alternating current - Abstract
A novel geometry for electroluminescent devices, which does not require transparent electrodes for electrical input, is demonstrated, theoretically analyzed, and experimentally characterized. Instead of emitting light through a conventional electrode, light emission occurs through a polar liquid or solid and input electrical electrodes are coplanar, rather than stacked in a sandwich configuration. This new device concept is scalable and easily deployed for a range of modular alternating-current-powered electroluminescent light sources and light-emitting sensing devices. The polar-electrode-bridged electroluminescent displays can be used as remotely readable, spatially responsive sensors that emit light in response to the accumulation and distribution of materials on the device surface. Using this device structure, various types of alternating current devices are demonstrated. These include an umbrella that automatically lights up when it rains, a display that emits light from regions touched by human fingers (or painted upon using a mixture of oil and water), and a sensor that lights up differently in different areas to indicate the presence of water and its freezing. This study extends the dual-stack, coplanar-electrode device geometry to provide displays that emit light from a figure drawn on an electroluminescent panel using a graphite pencil.
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- 2017
11. Flexible, Ultralight, Porous Superconducting Yarns Containing Shell-Core Magnesium Diboride-Carbon Nanotube Nanofibers
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Márcio D. Lima, Carter S. Haines, Julia Bykova, Anvar A. Zakhidov, M. B. Salamon, Ray H. Baughman, and Derrick Tolly
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Superconductivity ,Materials science ,Mechanical Engineering ,Nanowire ,chemistry.chemical_element ,Aerogel ,Carbon nanotube ,law.invention ,chemistry.chemical_compound ,chemistry ,Mechanics of Materials ,law ,Nanofiber ,Magnesium diboride ,General Materials Science ,Composite material ,Boron ,Critical field - Abstract
Magnesium-diboride-coated carbon nanotube arrays are synthesized by templating carbon-nanotube aerogel sheets with boron and then converting the boron to MgB2. The resultant MgB2-CNT sheets are twisted into flexible, light-weight yarns that have a superconducting transition around 37.8 K and critical current and critical field comparable with those of existing MgB2 wires, but have about 20 times lower density than bulk MgB2.
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- 2014
12. Intelligently Actuating Liquid Crystal Elastomer‐Carbon Nanotube Composites
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Ha Beom Lee, Shi Hyeong Kim, Vinay V. Naik, Ali E. Aliev, Cedric P. Ambulo, Hyun Kim, Taylor H. Ware, Jae Ah Lee, Carter S. Haines, Ray H. Baughman, and Raquel Ovalle-Robles
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Biomaterials ,Materials science ,law ,Electrochemistry ,Liquid crystal elastomer ,Carbon nanotube ,Composite material ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,law.invention - Published
- 2019
13. Oriented Graphene Nanoribbon Yarn and Sheet from Aligned Multi-Walled Carbon Nanotube Sheets
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Anvar Zhakidov, Marcio Dias-Lima, Justin Sovich, Elizabeth Castillo-Martínez, Yves J. Chabal, Mikhail Kozlov, Javier Carretero-González, Carter S. Haines, Ray H. Baughman, Duncan M. Rogers, Muge Acik, and Xavier Lepró
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Nanotube ,Materials science ,Nanotubes, Carbon ,Graphene ,Mechanical Engineering ,Graphene foam ,Electric Conductivity ,Nanotechnology ,Electrochemical Techniques ,Yarn ,Carbon nanotube ,Electrochemistry ,law.invention ,Mechanics of Materials ,law ,visual_art ,visual_art.visual_art_medium ,Graphite ,General Materials Science ,Polytetrafluoroethylene ,Graphene nanoribbons ,Graphene oxide paper - Abstract
Highly oriented graphene nanoribbons sheets and yarns are produced by chemical unzipping of self-standing multiwalled carbon nanotube (MWNT) sheets. The as-produced yarns - after being chemically and thermally reduced - exhibit a good mechanical, electrical, and electrochemical performance.
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- 2012
14. MXene Yarn Supercapacitors: High-Performance Biscrolled MXene/Carbon Nanotube Yarn Supercapacitors (Small 37/2018)
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Zhiyu Wang, Carter S. Haines, Jizhen Zhang, Ray H. Baughman, Na Li, Si Qin, Ariana Levitt, Raquel Ovalle-Robles, Shayan Seyedin, Yury Gogotsi, Jiangting Wang, Joselito M. Razal, and Weiwei Lei
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Supercapacitor ,Materials science ,General Chemistry ,Yarn ,Carbon nanotube ,law.invention ,Biomaterials ,law ,visual_art ,visual_art.visual_art_medium ,General Materials Science ,Composite material ,Carbon nanotube yarn ,Biotechnology - Published
- 2018
15. Nylon-muscle-actuated robotic finger
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Yonas Tadesse, Ray H. Baughman, Carter S. Haines, Mônica Jung de Andrade, Lianjun Wu, Richard S. Rome, and Márcio D. Lima
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Finger movement ,Materials science ,Robotic finger ,technology, industry, and agriculture ,Robotic hand ,Artificial muscle ,Spring (mathematics) ,Muscle fibre ,Silicone tube ,Simulation ,Humanoid robot ,Biomedical engineering - Abstract
This paper describes the design and experimental analysis of novel artificial muscles, made of twisted and coiled nylon fibers, for powering a biomimetic robotic hand. The design is based on circulating hot and cold water to actuate the artificial muscles and obtain fast finger movements. The actuation system consists of a spring and a coiled muscle within a compliant silicone tube. The silicone tube provides a watertight, expansible compartment within which the coiled muscle contracts when heated and expands when cooled. The fabrication and characterization of the actuating system are discussed in detail. The performance of the coiled muscle fiber in embedded conditions and the related characteristics of the actuated robotic finger are described.
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- 2015
16. Three-dimensionally bonded spongy graphene material with super compressive elasticity and near-zero Poisson’s ratio
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Humberto Terrones, Shaoli Fang, Alin Cristian Chipara, Nestor Perea Lopez, Xavier Lepró, Lakshmy Pulickal Rajukumar, Guankui Long, Mauricio Terrones, Ana Laura Elías, Yi Huang, Pulickel M. Ajayan, Ray H. Baughman, Peishuang Xiao, Márcio D. Lima, Ali E. Aliev, Simin Feng, Seon Jeong Kim, Na Li, Huicong Chang, Mikhail E. Kozlov, Fan Zhang, Pengfei Chu, Ningbo Yi, Yongsheng Chen, Jae Ah Lee, Long Zhang, Yingpeng Wu, Carter S. Haines, Jiyoung Oh, Zhong Zhang, Narayanan Tharangattu Narayanan, Tengfei Zhang, and Lu Huang
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Multidisciplinary ,Materials science ,Graphene ,General Physics and Astronomy ,Nanotechnology ,General Chemistry ,Elasticity (physics) ,Poisson distribution ,General Biochemistry, Genetics and Molecular Biology ,Poisson's ratio ,law.invention ,symbols.namesake ,law ,symbols ,Composite material - Abstract
It is a challenge to fabricate graphene bulk materials with properties arising from the nature of individual graphene sheets, and which assemble into monolithic three-dimensional structures. Here we report the scalable self-assembly of randomly oriented graphene sheets into additive-free, essentially homogenous graphene sponge materials that provide a combination of both cork-like and rubber-like properties. These graphene sponges, with densities similar to air, display Poisson's ratios in all directions that are near-zero and largely strain-independent during reversible compression to giant strains. And at the same time, they function as enthalpic rubbers, which can recover up to 98% compression in air and 90% in liquids, and operate between -196 and 900 °C. Furthermore, these sponges provide reversible liquid absorption for hundreds of cycles and then discharge it within seconds, while still providing an effective near-zero Poisson's ratio.
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- 2015
17. Electrochemically Powered, Energy‐Conserving Carbon Nanotube Artificial Muscles
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Jae Ah Lee, Xavier Lepró, Keon Jung Kim, Na Li, Ray H. Baughman, Carter S. Haines, Raquel Ovalle-Robles, and Seon Jeong Kim
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Materials science ,Short cycle ,02 engineering and technology ,Electrolyte ,Carbon nanotube ,010402 general chemistry ,01 natural sciences ,law.invention ,law ,Tensile Strength ,Ultimate tensile strength ,General Materials Science ,Composite material ,Carbon nanotube yarn ,Nanotubes, Carbon ,Muscles ,Mechanical Engineering ,Energy conversion efficiency ,Electrochemical Techniques ,Robotics ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Mechanics of Materials ,Artificial muscle ,0210 nano-technology ,Muscle Contraction - Abstract
While artificial muscle yarns and fibers are potentially important for many applications, the combination of large strokes, high gravimetric work capacities, short cycle times, and high efficiencies are not realized for these fibers. This paper demonstrates here electrochemically powered carbon nanotube yarn muscles that provide tensile contraction as high as 16.5%, which is 12.7 times higher than previously obtained. These electrochemical muscles can deliver a contractile energy conversion efficiency of 5.4%, which is 4.1 times higher than reported for any organic-material-based artificial muscle. All-solid-state parallel muscles and braided muscles, which do not require a liquid electrolyte, provide tensile contractions of 11.6% and 5%, respectively. These artificial muscles might eventually be deployed for a host of applications, from robotics to perhaps even implantable medical devices.
- Published
- 2017
18. Laminar composite structures for high power actuators
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Mkhitar Hobosyan, Patricia M. Martinez, Karen S. Martirosyan, Al. A. Zakhidov, Carter S. Haines, and Ray H. Baughman
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Work (thermodynamics) ,Materials science ,Physics and Astronomy (miscellaneous) ,Composite number ,Laminar flow ,02 engineering and technology ,Carbon nanotube ,Yarn ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Combustion ,01 natural sciences ,0104 chemical sciences ,law.invention ,Stress (mechanics) ,law ,visual_art ,visual_art.visual_art_medium ,Composite material ,0210 nano-technology ,Actuator - Abstract
Twisted laminar composite structures for high power and large-stroke actuators based on coiled Multi Wall Carbon Nanotube (MWNT) composite yarns were crafted by integrating high-density Nanoenergetic Gas Generators (NGGs) into carbon nanotube sheets. The linear actuation force, resulting from the pneumatic force caused by expanding gases confined within the pores of laminar structures and twisted carbon nanotube yarns, can be further amplified by increasing NGG loading and yarns twist density, as well as selecting NGG compositions with high energy density and large-volume gas generation. Moreover, the actuation force and power can be tuned by the surrounding environment, such as to increase the actuation by combustion in ambient air. A single 300-μm-diameter integrated MWNT/NGG coiled yarn produced 0.7 MPa stress and a contractile specific work power of up to 4.7 kW/kg, while combustion front propagated along the yarn at a velocity up to 10 m/s. Such powerful yarn actuators can also be operated in a vacuu...
- Published
- 2017
19. High Power Density Electrochemical Thermocells for Inexpensively Harvesting Low‐Grade Thermal Energy
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Gordon G. Wallace, Long Zhang, Tae Woo Kim, Joselito M. Razal, Ali Hussain Kazim, Na Li, Carter S. Haines, Douglas R. MacFarlane, Anuncia Gonzalez-Martin, Danah Al-Masri, Sibi Mathew, Mei Zhang, Jennifer M. Pringle, Ray H. Baughman, Shaoli Fang, Yong Hyup Kim, Tae June Kang, Baratunde A. Cola, Jiangtao Di, Jun Chen, and Stephen Beirne
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Materials science ,business.industry ,Mechanical Engineering ,Nanotechnology ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Thermoelectric materials ,7. Clean energy ,01 natural sciences ,0104 chemical sciences ,Power (physics) ,Mechanics of Materials ,Waste heat ,Electrode ,Thermal ,Optoelectronics ,General Materials Science ,0210 nano-technology ,business ,Energy harvesting ,Thermal energy ,Ambient pressure - Abstract
Continuously operating thermo-electrochemical cells (thermocells) are of interest for harvesting low-grade waste thermal energy because of their potentially low cost compared with conventional thermoelectrics. Pt-free thermocells devised here provide an output power of 12 W m-2 for an interelectrode temperature difference (ΔT) of 81 °C, which is sixfold higher power than previously reported for planar thermocells operating at ambient pressure.
- Published
- 2017
20. Carbon-based torsional and tensile artificial muscles driven by thermal expansion (presentation video)
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Seon Jeong Kim, Shaoli Fang, Xiuru Xu, Na Li, Özer Göktepe, Márcio D. Lima, Ray H. Baughman, Mônica Jung de Andrade, Mikhail E. Kozlov, Benjamin J. Swedlove, Javad Foroughi, Fatma Göktepe, Carter S. Haines, John D. W. Madden, Seyed M. Mirvakili, Gordon G. Wallace, Jiyoung Oh, Sina Naficy, Geoffrey M. Spinks, Shi-Hyeong Kim, and Xavier Lepró
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Hysteresis ,Materials science ,chemistry ,Ultimate tensile strength ,chemistry.chemical_element ,Artificial muscle ,Composite material ,Actuator ,Porosity ,Piezoelectricity ,Carbon ,Thermal expansion - Abstract
High-performance artificial muscles have been produced from fibers having highly anisotropic thermal expansion. Inserting twist into these precursor fibers enables thermally-driven torsional actuation and can cause the formation of helical coils. Such coiled structures provide giant-stroke tensile actuation exceeding the 20% in-vivo contraction of natural muscles. This contraction is highly reversible, with over one million cycles demonstrated, and can occur without the hysteresis that plagues competing shape-memory and piezoelectric muscles. Several materials and composites are investigated, including low-cost, commercially-available muscle precursors, potentially facilitating thermally-responsive textiles that change porosity to provide wearer comfort.
- Published
- 2014
21. Mechanism of stroke enhancement by coiling in carbon nanotube hybrid yarn artificial muscles (presentation video)
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Shaoli Fang, Sina Naficy, Xavier Lepró, Xiuru Xu, Na Li, Márcio D. Lima, Jiyoung Oh, Mônica Jung de Andrade, Fatma Göktepe, John D. W. Madden, Seon-Jeong Kim, Geoffrey M. Spinks, Seyed M. Mirvakili, Carter S. Haines, Ray H. Baughman, Javad Foroughi, Özer Göktepe, Gordon G. Wallace, and Mikhail E. Kozlov
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Materials science ,Physics::Medical Physics ,Nanotechnology ,Carbon nanotube ,Yarn ,Spring (mathematics) ,law.invention ,Electromagnetic coil ,law ,visual_art ,Ultimate tensile strength ,visual_art.visual_art_medium ,Artificial muscle ,Fiber ,Composite material ,Order of magnitude - Abstract
Twisted carbon nanotube yarns have been shown to develop useful torsional and tensile actuation. Particularly useful are those hybrid yarns that incorporate a volume-changing guest material into the yarn pore space. Changing guest volume causes concomitant untwisting and shortening of the twisted yarn. Intriguingly, the magnitude of the tensile actuation can be increased by an order of magnitude by inserting such high twist into the fiber as to cause coiling. The mechanism of coil-induced stroke enhancement is investigated using ordinary spring mechanics and it is shown that tensile actuation can be adequately predicted from the coil and yarn geometries.
- Published
- 2014
22. Simple and strong: twisted silver painted nylon artificial muscle actuated by Joule heating
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Seyed M. Mirvakili, Carter S. Haines, Na Li, Javad Foroughi, John D. W. Madden, Ray H. Baughman, Ian W. Hunter, Geoffrey M. Spinks, Sina Naficy, and Ali Rafie Ravandi
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Work (thermodynamics) ,Materials science ,Joule ,Carbon nanotube ,engineering.material ,Thermal expansion ,law.invention ,Protein filament ,Coating ,law ,engineering ,Artificial muscle ,Composite material ,Joule heating - Abstract
Highly oriented nylon and polyethylene fibres shrink in length when heated and expand in diameter. By twisting and then coiling monofilaments of these materials to form helical springs, the anisotropic thermal expansion has recently been shown to enable tensile actuation of up to 49% upon heating. Joule heating, by passing a current through a conductive coating on the surface of the filament, is a convenient method of controlling actuation. In previously reported work this has been done using highly flexible carbon nanotube sheets or commercially available silver coated fibres. In this work silver paint is used as the Joule heating element at the surface of the muscle. Up to 29% linear actuation is observed with energy and power densities reaching 840 kJ m-3 (528 J kg-1) and 1.1 kW kg-1 (operating at 0.1 Hz, 4% strain, 1.4 kg load). This simple coating method is readily accessible and can be applied to any polymer filament. Effective use of this technique relies on uniform coating to avoid temperature gradients.
- Published
- 2014
23. Hybrid carbon nanotube yarn artificial muscle inspired by spider dragline silk
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Carter S. Haines, Min Kyoon Shin, Seon Jeong Kim, Márcio D. Lima, Jihwang Park, Cheong Hoon Kwon, Shi Hyeong Kim, Ray H. Baughman, Youn Tae Kim, Geoffrey M. Spinks, and Kyoung Yong Chun
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Nanotube ,Materials science ,Silk ,General Physics and Astronomy ,chemistry.chemical_element ,Carbon nanotube ,General Biochemistry, Genetics and Molecular Biology ,law.invention ,Paraffin wax ,law ,Copolymer ,Animals ,Composite material ,Multidisciplinary ,Nanotubes, Carbon ,Muscles ,Spiders ,General Chemistry ,Yarn ,SILK ,chemistry ,visual_art ,visual_art.visual_art_medium ,Artificial muscle ,Artificial Organs ,Carbon - Abstract
Torsional artificial muscles generating fast, large-angle rotation have been recently demonstrated, which exploit the helical configuration of twist-spun carbon nanotube yarns. These wax-infiltrated, electrothermally powered artificial muscles are torsionally underdamped, thereby experiencing dynamic oscillations that complicate positional control. Here, using the strategy spiders deploy to eliminate uncontrolled spinning at the end of dragline silk, we have developed ultrafast hybrid carbon nanotube yarn muscles that generated a 9,800 r.p.m. rotation without noticeable oscillation. A high-loss viscoelastic material, comprising paraffin wax and polystyrene-poly(ethylene-butylene)-polystyrene copolymer, was used as yarn guest to give an overdamped dynamic response. Using more than 10-fold decrease in mechanical stabilization time, compared with previous nanotube yarn torsional muscles, dynamic mirror positioning that is both fast and accurate is demonstrated. Scalability to provide constant volumetric torsional work capacity is demonstrated over a 10-fold change in yarn cross-sectional area, which is important for upscaled applications.
- Published
- 2013
24. Biscrolling nanotube sheets and functional guests into yarns
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Anvar A. Zakhidov, Márcio D. Lima, Mohammad H. Haque, Neema Rawat, Jiyoung Oh, Ray H. Baughman, Elizabeth Castillo-Martínez, Vaishnavi Aare, Chihye Lewis, Javier Carretero-González, Carter S. Haines, Shaoli Fang, Raquel Ovalle-Robles, Stephanie Stoughton, Mikhail E. Kozlov, and Xavier Lepró
- Subjects
Nanotube ,Multidisciplinary ,Materials science ,Graphene ,Nanotechnology ,Carbon nanotube ,Yarn ,law.invention ,law ,Nanofiber ,visual_art ,Photocatalysis ,visual_art.visual_art_medium ,Weaving ,Spinning - Abstract
Multifunctional applications of textiles have been limited by the inability to spin important materials into yarns. Generically applicable methods are demonstrated for producing weavable yarns comprising up to 95 weight percent of otherwise unspinnable particulate or nanofiber powders that remain highly functional. Scrolled 50-nanometer-thick carbon nanotube sheets confine these powders in the galleries of irregular scroll sacks whose observed complex structures are related to twist-dependent extension of Archimedean spirals, Fermat spirals, or spiral pairs into scrolls. The strength and electronic connectivity of a small weight fraction of scrolled carbon nanotube sheet enables yarn weaving, sewing, knotting, braiding, and charge collection. This technology is used to make yarns of superconductors, lithium-ion battery materials, graphene ribbons, catalytic nanofibers for fuel cells, and titanium dioxide for photocatalysis.
- Published
- 2011
25. Hydrogen-fuel-powered bell segments of biomimetic jellyfish
- Author
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Alex Villanueva, David Novitski, Yonas Tadesse, Shashank Priya, Carter S. Haines, and Ray H. Baughman
- Subjects
Exothermic reaction ,Materials science ,Hydrogen ,chemistry.chemical_element ,Carbon nanotube ,Condensed Matter Physics ,SMA ,Atomic and Molecular Physics, and Optics ,law.invention ,Thermal conductivity ,chemistry ,Mechanics of Materials ,law ,Hydrogen fuel ,Signal Processing ,Heat transfer ,General Materials Science ,Artificial muscle ,Electrical and Electronic Engineering ,Composite material ,Civil and Structural Engineering - Abstract
Artificial muscles powered by a renewable energy source are desired for joint articulation in bio-inspired autonomous systems. In this study, a robotic underwater vehicle, inspired by jellyfish, was designed to be actuated by a chemical fuel source. The fuel-powered muscles presented in this work comprise nano-platinum catalyst-coated multi-wall carbon nanotube (MWCNT) sheets, wrapped on the surface of nickel–titanium (NiTi) shape memory alloy (SMA). As a mixture of oxygen and hydrogen gases makes contact with the platinum, the resulting exothermic reaction activates the nickel–titanium (NiTi)-based SMA. The MWCNT sheets serve as a support for the platinum particles and enhance the heat transfer due to the high thermal conductivity between the composite and the SMA. A hydrogen and oxygen fuel source could potentially provide higher power density than electrical sources. Several vehicle designs were considered and a peripheral SMA configuration under the robotic bell was chosen as the best arrangement. Constitutive equations combined with thermodynamic modeling were developed to understand the influence of system parameters that affect the overall actuation behavior of the fuel-powered SMA. The model is based on the changes in entropy of the hydrogen and oxygen fuel on the composite actuator within a channel. The specific heat capacity is the dominant factor controlling the width of the strain for various pulse widths of fuel delivery. Both theoretical and experimental strains for different diameter (100 and 150 µm) SMA/MWCNT/Pt fuel-powered muscles with dead weight attached at the end exhibited the highest magnitude under 450 ms of fuel delivery within 1.6 mm diameter conduit size. Fuel-powered bell deformation of 13.5% was found to be comparable to that of electrically powered (29%) and natural jellyfish (42%).
- Published
- 2012
26. Sound of carbon nanotube assemblies
- Author
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Shaoli Fang, Márcio D. Lima, Carter S. Haines, Mikhail E. Kozlov, and Jiyoung Oh
- Subjects
Photoacoustic effect ,Nanotube ,Materials science ,Silicon ,General Physics and Astronomy ,chemistry.chemical_element ,Nanotechnology ,Substrate (electronics) ,Carbon nanotube ,Signal ,law.invention ,chemistry ,law ,Composite material ,Alternating current ,Sound pressure - Abstract
Strong thermo- and photoacoustic responses have been detected for aligned arrays of multiwalled carbon nanotube (MWNT) forests and solid drawn MWNT sheets. When heated using alternating current or a near-IR laser modulated in 100–20000Hz range, the nanotube assemblies generated loud, audible sound, with higher sound pressure being detected from the MWNT sheets. An evaluation of nonlinear distortions of the thermoacoustic signal revealed a highly peculiar behavior of the third and fourth harmonics produced from forests grown on silicon wafers. The peculiarities were especially pronounced for short forests and can be associated with the heat transfer from the MWNT layer to the substrate. For both types of nanotube assemblies, the acoustic signal’s amplitude varied with frequency approximately by the power low fp. The power factor p was found to be unexpectedly high for short forests probably due to heat loss to the substrate. The observed peculiarities can be used for the characterization of the prepared MW...
- Published
- 2009
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