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Photoexcited organic chromophores appended to molecular qubits can serve as a source of spin initialization or multi-level qudit generation for quantum information applications. So far, this approach has been primarily investigated in chromophore/stable radical systems. Here, we extend this concept to a meso-meso linked oxovanadium(IV) porphyrin - free base porphyrin dimer. Femtosecond transient absorption experiments reveal that photoexcitation of the free base porphyrin leads to picosecond triplet state formation via enhanced intersystem crossing. Time-resolved electron paramagnetic resonance (TREPR) experiments carried out at both 85 K and room temperature reveal the formation of a long-lived spin-polarized quartet state through triplet-doublet spin mixing. Notably, a distinct hyperfine structure arising from the interaction between the electron spin quartet state and the vanadyl nucleus (51V, I=7/2) is evident, with the quartet state exhibiting long-lived spin polarization even at room temperature. Theoretical simulations of the TREPR spectra confirm the photogenerated quartet state and provide insights into the non-Boltzmann spin populations. Exploit-ing this phenomenon affords the possibility of using photoinduced triplet states in porphyrins for quantum information as a resource to polarize and magnetically couple molecular electronic or nuclear spin qubits and qudits.

We present the first microscopic model for chirality-induced spin selectivity effect in electron-transfer, in which the internal degrees of freedom of the chiral bridge are explicitly included. By exactly solving this model on short chiral chains we demonstrate that a sizable polarization on the acceptor arises from the interplay of coherent and incoherent dynamics, with strong electron-electron correlations yielding many-body states on the bridge as crucial ingredients. Moreover, we include the coherent and incoherent interactions with vibrational modes and show that they can play an important role in determining the long-time polarized state probed in experiments.

Multiple populations (MPs) in globular clusters (GCs) are stars distinct by their abundances of light elements. The MPs can be directly separated by measuring abundances of C, N, O, Na, Al, Mg with spectroscopy or indirectly from photometric sequences created by the impact of different chemistry on band passes of particular filters, such as the HST pseudo-colours in the ultraviolet. An attempt to link HST pseudo-colours maps (PCMs) and spectroscopy was done by Marino et al. (2019), using abundances mostly from our FLAMES survey. However, we uncovered that an incomplete census of stars in common was used in their population tagging. We correct the situation by building our own PCMs and matching them with our abundances in 20 GCs, plus two GCs from other sources, doubling the sample with spectroscopic abundances available. We found that the pseudo-colour (magF275W-2*magF336W+magF438W) does not have a monotonic trend with Na abundances, enhanced by proton-capture reactions in MPs. Moreover, on average about 16% of stars with spectroscopic Na abundances show a discrepant tagging of MPs with respect to the HST photometry. Stars with chemistry of second generation (SG) are mistaken for first generation (FG) objects according to HST photometry and vice versa. In general, photometric indices tend to overestimate the fraction of FG stars, in particular in low mass GCs. We offer a simple explanation for these findings. Finally, we publish all our PCMs, with more than 31,800 stars in 22 GCs, with star ID and coordinates, for easy check and reproduction, as it should be in science papers., Comment: 24 pages, 19 figures, 2 on-line tables plus 23 pages with 21 figures of Appendix; accepted for publication on Astronomy and Astrophysics

Many problems intractable on classical devices could be solved by algorithms explicitly based on quantum mechanical laws, i.e. exploiting quantum information processing. As a result, increasing efforts from different fields are nowadays directed to the actual realization of quantum devices. Here we provide an introduction to Quantum Information Processing, focusing on a promising setup for its implementation, represented by molecular spin clusters known as Molecular Nanomagnets. We introduce the basic tools to understand and design quantum algorithms, always referring to their actual realization on a molecular spin architecture. We then examine the most important sources of noise in this class of systems and then one of their most peculiar features, i.e. the possibility to exploit many (more than two) available states to encode information and to self-correct it from errors via proper design of quantum error correction codes. Finally, we present some examples of quantum algorithms proposed and implemented on a molecular spin qudit hardware., Comment: After publication, added the sentence: "This is an original manuscript of an article published by Taylor & Francis in Contemporary Physics on 20th of August 2024, available online: https://doi.org/10.1080/00107514.2024.2381952."

Localizing oneself during endoscopic procedures can be problematic due to the lack of distinguishable textures and landmarks, as well as difficulties due to the endoscopic device such as a limited field of view and challenging lighting conditions. Expert knowledge shaped by years of experience is required for localization within the human body during endoscopic procedures. In this work, we present a deep learning method based on anatomy recognition, that constructs a surgical path in an unsupervised manner from surgical videos, modelling relative location and variations due to different viewing angles. At inference time, the model can map an unseen video's frames on the path and estimate the viewing angle, aiming to provide guidance, for instance, to reach a particular destination. We test the method on a dataset consisting of surgical videos of transsphenoidal adenomectomies, as well as on a synthetic dataset. An online tool that lets researchers upload their surgical videos to obtain anatomy detections and the weights of the trained YOLOv7 model are available at: https://surgicalvision.bmic.ethz.ch., Comment: Early Accept at MICCAI 2024

Context. Globular clusters are considered key objects for understanding the formation and evolution of the Milky Way. In this sense, their characterisation in terms of their chemical and orbital parameters can provide constraints to the chemical evolution models of the Galaxy. Aims. We use the heavy element abundances of globular clusters to trace their overall behaviour in the Galaxy, aiming to analyse potential relations between the hot H-burning and s-process elements. Methods. We measured the content of Cu I and s- and r-process elements (Y II, Ba II, La II, and Eu II) in a sample of 210 giant stars in 18 Galactic Globular Clusters from high-quality UVES spectra. The clusters span a large metallicity range, and the sample is the largest uniformly analysed for what concerns heavy elements in Globular Clusters. Results. Cu abundances did not show considerable spread in the sample nor correlation with Na, meaning that the Na nucleosynthesis process does not affect the Cu abundance. Most GCs closely follow the Cu, Y, Ba, La, and Eu field stars' distribution, revealing a similar chemical evolution. The Y abundances in mid-metallicity regime GCs (-1.10 dex <[Fe/H]<-1.80 dex) display a mildly significant correlation with the Na abundance, which should be further investigated. Finally, we did not find any significant difference between the n-capture abundances among GCs with Galactic and extragalactic origin., Comment: 23pages and 20 figures

M 39 is a nearby young open cluster hardly studied in the last decades. No giant is known among its members and its chemical composition has never been studied. In order to investigate it we performed high-resolution spectroscopy of 20 expected cluster members with the HARPS and FIES spectrographs. By combining our observations with archival photometry and $Gaia$-DR3 data we searched for evolved members and studied cluster properties such as the radial velocity, extinction and age. For the first time, we provide stellar parameters and chemical abundances for 21 species with atomic numbers up to 56. We have not found any new giant as likely member and notice a negligible reddening along the cluster field, that we place at 300 pc. We obtain a mean radial velocity for M 39 of -5.5$\pm$0.5 km s$^{-1}$ and an isochrone-fitting age of 430$\pm$110 Ma, which corresponds to a MSTO mass of around 2.8 Msol. This value is consistent with the Li content and chromospheric activity shown by its members. Based on main-sequence stars the cluster exhibits a solar composition, [Fe/H]=+0.04$\pm$0.08 dex, compatible with its Galactocentric location. However, it has a slightly subsolar abundance of Na and an enriched content of neutron-capture elements, specially Ba. In any case, the chemical composition of M 39 is fully compatible with that shown by other open clusters that populate the Galactic thin disc, Comment: 16 pages, 16 figures, 11 tables; accepted for publication in Astronomy & Astrophysics

The role of chirality in determining the spin dynamics of photoinduced electron transfer in donor-acceptor molecules remains an open question. Although chirality-induced spin selectivity (CISS) has been demonstrated in molecules bound to substrates, experimental information about whether this process influences spin dynamics in the molecules themselves is lacking. Here we use time-resolved electron paramagnetic resonance spectroscopy to show that CISS strongly influences the spin dynamics of isolated covalent donor-chiral bridge-acceptor (D-B$\chi$-A) molecules in which selective photoexcitation of D is followed by two rapid, sequential electron transfer events to yield D$^+$-B$\chi$-A$^-$. Exploiting this phenomenon affords the possibility of using chiral molecular building blocks to control electron spin states in quantum information applications.

The use of $d$-level qudits instead of two-level qubits can largely increase the power of quantum logic for many applications, ranging from quantum simulations to quantum error correction. Molecular Nanomagnets are ideal spin systems to realize these large-dimensional qudits. Indeed, their Hamiltonian can be engineered to an unparalleled extent and can yield a spectrum with many low-energy states. In particular, in the last decade intense theoretical, experimental and synthesis efforts have been devoted to develop quantum simulators based on Molecular Nanomagnets. However, this remarkable potential is practically unexpressed, because no quantum simulation has ever been experimentally demonstrated with these systems. Here we show the first prototype quantum simulator based on an ensemble of molecular qudits and a radiofrequency broadband spectrometer. To demonstrate the operativity of the device, we have simulated quantum tunneling of the magnetization and the transverse-field Ising model, representative of two different classes of problems. These results represent an important step towards the actual use of molecular spin qudits in quantum technologies.

The topotactic intercalation of transition-metal dichalcogenides with atomic or molecular ions acts as an efficient knob to tune the electronic ground state of the host compound. A representative material in this sense is 1$T$-TiSe$_{2}$, where the electric-field-controlled intercalations of lithium or hydrogen trigger superconductivity coexisting with the charge-density wave phase. Here, we use the nuclear magnetic moments of the intercalants in hydrogen-intercalated 1$T$-TiSe$_{2}$ as local probes for nuclear magnetic resonance experiments. We argue that fluctuating mesoscopic-sized domains nucleate already at temperatures higher than the bulk critical temperature to the charge-density wave phase and display cluster-glass-like dynamics in the MHz range tracked by the $^{1}$H nuclear moments. Additionally, we observe a well-defined independent dynamical process at lower temperatures that we associate with the intrinsic properties of the charge-density wave state. In particular, we ascribe the low-temperature phenomenology to the collective phason-like motion of the charge-density wave being hindered by structural defects and chemical impurities and resulting in a localized oscillating motion., Comment: 9 pages, 4 figures

We discuss stabilizer quantum-error correction codes implemented in a single multi-level qudit to avoid resource escalation typical of multi-qubit codes. These codes can be customized to the specific physical errors on the qudit, effectively suppressing them. We demonstrate a Fault-Tolerant implementation on molecular spin qudits, showcasing nearly exponential error suppression with only linear qudit size growth. Notably, this outperforms qubit codes using thousands of units. We also outline the required properties for a generic physical system to Fault-Tolerantly implement these embedded codes.

We present the homogeneous abundance analysis for a combined sample of 185 giants in the bulge globular cluster (GC) NGC 6388. Our results are used to describe the multiple stellar populations and differences or analogies with bulge field stars. Proton-capture elements indicate that a single class of first-generation polluters is sufficient to reproduce both the extreme and intermediate parts of the anti-correlations among light elements O, Na, Mg, and Al, which is at odds with our previous results based on a much smaller sample. The abundance pattern of other species in NGC 6388 closely tracks the trends observed in bulge field stars. In particular, the alpha-elements, including Si, rule out an accreted origin for NGC 6388, confirming our previous results based on iron-peak elements, chemo-dynamical analysis, and the age-metallicity relation. The neutron-capture elements are generally uniform, although the [Zr/Fe] ratio shows an intrinsic scatter, correlated to Na and Al abundances. Instead, we do not find enhancement in neutron-capture elements for stars whose photometric properties would classify NGC 6388 as a type II GC. Together with the homogeneity in [Fe/H] we found in a previous paper, this indicates we need to better understand the criteria to separate classes of GCs, coupling photometry, and spectroscopy. These results are based on abundances of 22 species (O, Na, Mg, Al, Si, Ca, Ti, Sc, V, Cr, Mn, Fe, Co, Ni, Zn, Y, Zr, Ba, La, Ce, Nd, and Eu) from UVES spectra sampling proton-, alpha-, neutron-capture elements, and Fe-peak elements. For 12 species, we also obtain abundances in a large number of giants (up to 150) from GIRAFFE spectra., Comment: 19 pages plus 6 pages of Appendix, 23 figures, 5 tables; accepted for publication on Astronomy and Astrophysics

For most practical applications, quantum algorithms require large resources in terms of qubit number, much larger than those available with current NISQ processors. With the network and communication functionalities provided by the Quantum Internet, Distributed Quantum Computing (DQC) is considered as a scalable approach for increasing the number of available qubits for computational tasks. For DQC to be effective and efficient, a quantum compiler must find the best partitioning for the quantum algorithm and then perform smart remote operation scheduling to optimize EPR pair consumption. At the same time, the quantum compiler should also find the best local transformation for each partition. In this paper we present a modular quantum compilation framework for DQC that takes into account both network and device constraints and characteristics. We implemented and tested a quantum compiler based on the proposed framework with some circuits of interest, such as the VQE and QFT ones, considering different network topologies, with quantum processors characterized by heavy hexagon coupling maps. We also devised a strategy for remote scheduling that can exploit both TeleGate and TeleData operations and tested the impact of using either only TeleGates or both. The evaluation results show that TeleData operations may have a positive impact on the number of consumed EPR pairs, while choosing a more connected network topology helps reduce the number of layers dedicated to remote operations.

The implementation of a universal quantum processor still poses fundamental issues related to error mitigation and correction, which demand to investigate also platforms and computing schemes alternative to the main stream. A possibility is offered by employing multi-level logical units (qudits), naturally provided by molecular spins. Here we present the blueprint of a Molecular Spin Quantum Processor consisting of single Molecular Nanomagnets, acting as qudits, placed within superconducting resonators adapted to the size and interactions of these molecules to achieve a strong single spin to photon coupling. We show how to implement a universal set of gates in such a platform and to readout the final qudit state. Single-qudit unitaries (potentially embedding multiple qubits) are implemented by fast classical drives, while a novel scheme is introduced to obtain two-qubit gates via resonant photon exchange. The latter is compared to the dispersive approach, finding in general a significant improvement. The performance of the platform is assessed by realistic numerical simulations of gate sequences, such as Deutsch-Josza and quantum simulation algorithms. The very good results demonstrate the feasibility of the molecular route towards a universal quantum processor., Comment: 16 pages, 11 figures. Accepted in Physical Review Applied

Advanced minimally invasive neurosurgery navigation relies mainly on Magnetic Resonance Imaging (MRI) guidance. MRI guidance, however, only provides pre-operative information in the majority of the cases. Once the surgery begins, the value of this guidance diminishes to some extent because of the anatomical changes due to surgery. Guidance with live image feedback coming directly from the surgical device, e.g., endoscope, can complement MRI-based navigation or be an alternative if MRI guidance is not feasible. With this motivation, we present a method for live image-only guidance leveraging a large data set of annotated neurosurgical videos.First, we report the performance of a deep learning-based object detection method, YOLO, on detecting anatomical structures in neurosurgical images. Second, we present a method for generating neurosurgical roadmaps using unsupervised embedding without assuming exact anatomical matches between patients, presence of an extensive anatomical atlas, or the need for simultaneous localization and mapping. A generated roadmap encodes the common anatomical paths taken in surgeries in the training set. At inference, the roadmap can be used to map a surgeon's current location using live image feedback on the path to provide guidance by being able to predict which structures should appear going forward or backward, much like a mapping application. Even though the embedding is not supervised by position information, we show that it is correlated to the location inside the brain and on the surgical path. We trained and evaluated the proposed method with a data set of 166 transsphenoidal adenomectomy procedures.

Gate-based quantum computers typically encode and process information in two-dimensional units called qubits. Using $d$-dimensional qudits instead may offer intrinsic advantages, including more efficient circuit synthesis, problem-tailored encodings and embedded error correction. In this work, we design a superconducting qudit-based quantum processor wherein the logical space of transmon qubits is extended to higher-excited levels. We propose a universal gate set featuring a two-qudit cross-resonance entangling gate, for which we predict fidelities beyond $99\%$ in the $d=4$ case of ququarts with realistic experimental parameters. Furthermore, we present a decomposition routine that compiles general qudit unitaries into these elementary gates, requiring fewer entangling gates than qubit alternatives. As proof-of-concept applications, we numerically demonstrate the synthesis of ${\rm SU}(16)$ gates for noisy quantum hardware and an embedded error correction sequence that encodes a qubit memory in a transmon ququart to protect against pure dephasing noise. We conclude that universal qudit control -- a valuable extension to the operational toolbox of superconducting quantum information processing -- is within reach of current transmon-based architectures and has applications to near-term and long-term hardware., Comment: 10+6 pages, 9+3 figures, revised version published in PRX Quantum

Among the multiple stellar populations in globular clusters (GCs) the very high-temperature H-burning regime, able to produce elements up to potassium, is still poorly explored. Here we present the first abundance analysis of K in 42 giants of NGC 6715 (M 54) with homogeneous abundances of light elements previously derived in our FLAMES survey. Owing to the large mass and low metallicity, a large excess of K could be expected in this GC, which is located in the nucleus of the Sagittarius dwarf galaxy. We actually found a spread in [K/Fe] spanning about 1 dex, with [K/Fe] presenting a significant anti-correlation with [O/Fe] ratios, regardless of the metallicity component in M 54. Evidence for a K-Mg anti-correlation also exists, but this is statistically marginal because of the lack of very Mg-poor stars in this GC. We found, however, a strong correlation between K and Ca. These observations clearl y show that the K enhancement in M 54 is probably due to the same network of nuclear reactions generating the phenomenon of multiple stellar populations, at work in a regime of very high temperature. The comparison with recent results in omega Cen is hampered by an unexplained trend with the temperatures for K abundances from optical spectroscopy, and somewhat by a limited sample size for infrared APOGEE data. There are few doubts, however, that the two most massive GCs in the Milky Way host a K-Mg anti-correlation., Comment: 8 pages, 5 figures, 1 table; accepted for publication on Astronomy and Astrophysics

Exploring the Galactic chemical evolution and enrichment scenarios with open clusters allows us to understand the history of the Milky Way disk. High-resolution spectra of OCs are a crucial tool, as they provide precise chemical information, to combine with precise distances and ages. The aim of the Stellar Population Astrophysics project is to derive homogeneous and accurate comprehensive chemical characterization of a number of poorly studied OCs.Using the HARPS-N echelle spectrograph at the Telescopio Nazionale Galileo, we obtained high-resolution spectra of giant stars in 18 OCs, 16 of which are chemically characterized for the first time, and two of which are well studied for comparison. The OCs in this sample have ages from a few tens of Myr to 4 Gyr, with a prevalence of young clusters. We already presented the radial velocities and atmospheric parameters for them in a previous SPA paper. Here, we present results for the alpha-elements O, and the light elements, all determined by the equivalent width method. We also measured Li abundance through the synthesis method.We discuss the behaviors of lithium, sodium and aluminum in the context of stellar evolution. We study the radial, vertical, and age trends for the measured abundance ratios in a sample that combines our results and recent literature for OCs, finding significant gradients only for [Mg/Fe] and [Ca/Fe] in all cases. Finally,we compare O and Mg in the combined sample with chemo-dynamical models, finding a good agreement for intermediate-age and old clusters. There is a sharp increase in the abundance ratios measured among very young clusters, accompanied by a poorer fit with the models for O and Mg, likely related to the inadequacy of traditional model atmospheres and methods in the derivation of atmospheric parameters and abundance ratios for stars of such young ages

Hydrogen (H) plays a key role in the near-to-room temperature superconductivity of hydrides at megabar pressures. This suggests that H doping could have similar effects on the electronic and phononic spectra of materials at ambient pressure as well. Here, we demonstrate the non-volatile control of the electronic ground state of titanium diselenide (1T-TiSe$_2$) via ionic liquid gating-driven H intercalation. This protonation induces a superconducting phase, observed together with a charge-density wave through most of the phase diagram, with nearly doping-independent transition temperatures. The H-induced superconducting phase is possibly gapless-like and multi-band in nature, in contrast with those induced in TiSe$_2$ via copper, lithium, and electrostatic doping. This unique behavior is supported by ab initio calculations showing that high concentrations of H dopants induce a full reconstruction of the bandstructure, although with little coupling between electrons and high-frequency H phonons. Our findings provide a promising approach for engineering the ground state of transition metal dichalcogenides and other layered materials via gate-controlled protonation., Comment: Main text: 13 pages, 5 figures; Supplementary: 12 pages, 12 figures

It is well assessed that the charge transport through a chiral potential barrier can result in spin-polarized charges. The possibility of driving this process through visible photons holds tremendous potential for several aspects of quantum information science, e.g., the optical control and readout of qubits. In this context, the direct observation of this phenomenon via spin-sensitive spectroscopies is of utmost importance to establish future guidelines to control photo-driven spin selectivity in chiral structures. Here, we provide direct proof that time-resolved electron paramagnetic resonance (EPR) can be used to detect long-lived spin polarization generated by photoinduced charge transfer through a chiral bridge. We propose a system comprising CdSe QDs, as a donor, and C60, as an acceptor, covalently linked through a saturated oligopeptide helical bridge (\c{hi}) with a rigid structure of ~ 10{\AA}. Time-resolved EPR spectroscopy shows that the charge transfer in our system results in a C60 radical anion, whose spin polarization maximum is observed at longer times with respect to that of the photogenerated C60 triplet state. Notably, the theoretical modeling of the EPR spectra reveals that the observed features may be compatible with chirality-induced spin selectivity and identifies which parameters need optimization for unambiguous detection of the phenomenon. This work lays the basis for the optical generation and direct manipulation of spin polarization induced by chirality., Comment: 45 pages, 5 main-text figures, 1 main-text table

Context: Open clusters are ideal laboratories to investigate a variety of astrophysical topics, from the properties of the Galactic disc to stellar evolution models. For this purpose, we need to know their chemical composition in detail. Unfortunately, the number of systems with chemical abundances determined from high resolution spectroscopy remains small. Aims: Our aim is to increase the number of open clusters with radial velocities and chemical abundances determined from high resolution spectroscopy by sampling a few stars in clusters not studied previously. Methods: We obtained high resolution spectra with the FIES spectrograph at NOT for 41 stars belonging to 20 open clusters. These stars have high astrometric membership probabilities, determined from the Gaia second data release. Results: We derived radial velocities for all the observed stars, which were used to confirm their membership to the corresponding clusters. For Gulliver\,37 we cannot be sure the observed star is a real member. We derived atmospheric parameters for the 32 stars considered real cluster members. We discarded five stars because they have very low gravity or atmospheric parameters were not properly constrained due to low signal-to-noise ratio spectra. Therefore, detailed chemical abundances were determined for 28 stars belonging to 17 clusters. For most of them, this is the first chemical analysis available in the literature. Finally, we compared the clusters in our sample to a large population of well studied clusters. The studied systems follow the trends, both chemical and kinematical, described by the majority of open clusters. Worth noticing that the three most metal-poor studied clusters (NGC\,1027, NGC\,1750 and Trumpler 2) are enhanced in Si but not in the other alpha-elements studied (Mg, Ca and Ti)., Comment: 19 pages Accepted for publication on A&A

Chemical tagging of globular clusters (GCs) is often done using abundances of alpha-elements. The iron-peak elements Sc, V, and in particular Zn were proposed as an alternative to alpha-elements to tag accreted GCs in the metal-rich regime, where the dwarf galaxy Sagittarius and its GCs show peculiarly marked under-abundances of these heavier species with respect to Milky Way stars. A handful of stars in NGC 6388 was used to suggest an accreted origin for this GC, contradicting the results from dynamics. We tested the efficiency of the iron-peak method by using large samples of stars in NGC 6388, compared to thousands of field stars in the disc and the bulge of the Milky Way. Our abundance ratios of Sc (185 stars) and V (35 stars) for NGC 6388 are within about 1.5 sigma from the average for the field stars with a similar metallicity, and they are in perfect agreement for Zn (31 stars), claimed to be the most sensitive element concerning the accretion pattern. Moreover, the chemo-dynamical plots, coupled to the bifurcated age-metallicity relation of GCs in the Galaxy, clearly rule out any association of NGC 6388 to the groups of accreted GCs. Using a large set of GC abundances from the literature, we also show that the new method with Sc, V, and Zn seems to be efficient in picking up GCs related to the Sagittarius dwarf galaxy. Whether this is also generally true for accreted GCs seems to be less evident, and it should be verified with larger and homogeneous samples of stars both in the field and in GCs., Comment: 12 pages, 4 figures plus 7 figures in Appendix; accepted for publication as a Letter in Astronomy and Astrophysics

The heterobimetallic metallacrown (MC), (TMA)$_2${Mn(OAc)$_2$[12-MC$_{Mn(III)Cu(II)N(shi)}$-4](CH$_3$OH)}$\cdot$2.90CH$_3$OH, 1, where TMA$^+$ is tetramethylammonium, $^-$OAc is acetate, and shi$^{3-}$ is salicylhydroximate, consists of a Mn$^{II}$ ion captured in the central cavity and alternating unambiguous and ordered manganese(III) and copper(II) sites about the MC ring, a first for the archetypal MC structure design. DC-magnetometry characterization and subsequent simulation with the Spin Hamiltonian $$H = -J_1(\mathbf{s}_1+\mathbf{s}_3)\cdot\mathbf{s}_5-J_2(\mathbf{s}_2+\mathbf{s}_4)\cdot\mathbf{s}_5-J_3\sum_{i=1}^{4}\mathbf{s}_i\cdot\mathbf{s}_{i+1} + d(s_{z,1}^2 + s_{z,3}^2) + \mu_B\sum_{j=1}^5 g_j\mathbf{s}_j\cdot\mathbf{B}$$ indicates an S = 5/2 ground state and a sizable axial zero-field splitting on Mn$^{III}$. AC-susceptibility measurements reveal that 1 displays slow magnetization relaxation akin to single-molecule magnet (SMM) behavior.

Nuclear spins are candidates to encode qubits or qudits due to their isolation from magnetic noise and potentially long coherence times. However, their weak coupling to external stimuli makes them hard to integrate into circuit-QED architectures, the leading technology for solid-state quantum processors. Here, we study the coupling of $^{173}$Yb(III) nuclear spin states in an [Yb(trensal)] molecule to superconducting cavities. Experiments have been performed on magnetically diluted single crystals placed on the inductors of lumped-element $LC$ superconducting resonators with characteristic frequencies spanning the range of nuclear and electronic spin transitions. We achieve a high cooperative coupling to all electronic and most nuclear [$^{173}$Yb(trensal)] spin transitions. This result is a big leap towards the implementation of qudit protocols with molecular spins using a hybrid architecture., Comment: 8 pages, 5 figures, 66 references, supplemental information (14 pages, 12 figures)

NGC1850 is the nearest Young Massive Cluster of the Local Group with a mass similar to those of Galactic globular clusters. Recent studies have revealed an extended morphology of its MSTO, which can be interpreted as a spread in either age or internal rotation. An accurate spectroscopic determination of its chemical properties is still missing. We analyse spectra obtained with MUSE in adaptive optics mode of 1167 stars in both components of this cluster (NGC1850A and NGC1850B). Thanks to this dataset, we measure an average metallicity of <[M/H]>=-0.31 +/- 0.01, a mean Ba abundance of <[Ba/Fe]>=+0.40 +/- 0.02 and a systemic radial velocity of =251.1 +/- 0.3 km/s. The dispersion of the radial velocities suggests a dynamical mass of log(M/Ms)=4.84 +/- 0.1, while no significant systemic rotation is detected. We detect a significant bimodality in OI line strength among the TO stars of NGC1850A with ~66% of stars with [O/Fe]~-0.16 and the rest with no detectable line. The majority of O-weak stars populate preferentially the red side of the MSTO and show H lines in emission, suggesting that they are Be stars rotating close to their critical velocity. Among normal MSTO stars, red stars have on average broader line profiles than blue ones, suggesting a correlation between colour and rotational velocity. The mean metallicity of this cluster lies at the metal-rich side of the metallicity distribution of the LMC following its age-metallicity relation. The Ba and O abundances agree with those measured in the bar of this galaxy. The observed spread in OI line width among its MS stars can be interpreted as an effect of rotational mixing occurring in the envelopes of O-weak stars. The correlation between line broadening and colour suggests that the observed colour spread among turn-off stars can be due to a wide range in rotational velocity covered by these stars., Comment: 11 pages, 10 figures, acepted for publication by A&A

We present the result of a survey of Monte Carlo simulations of globular clusters hosting two generations of stars including a large (f_b=50%) fraction of primordial binaries in both populations. The dynamical evolution of the two stellar populations is followed for a Hubble time taking into account the effect of the tidal field, two-body relaxation, stellar evolution and three/four-bodies interactions. The fraction of surviving binaries, once accounted for the observational bias and uncertainties, is compared with the available radial velocity time-series performed in real globular clusters, and it is used to constrain the initial spatial concentration of the second generation. The fraction of second generation binaries appears to depend only on the ratio between the total cluster mass and the initial size of the second generation which determines the average velocity dispersion across the extent of this stellar population. In spite of the various uncertainties, we find that the observed fraction can be obtained only assuming a strong initial concentration of the second generation (r_h,S~ 0.1 (M/10^6 M_s) pc). The evolution of the first generation binary fraction is more sensitive to the tidal field strength (with a non negligible effect of the cluster orbital eccentricity) since the tidal field has a direct impact on the first generation structural properties., Comment: 19 pages, 11 figures, accepted for publication by MNRAS

We report on the investigation of the magnetic superconductor EuFe$_{2}$(As$_{0.7}$P$_{0.3}$)$_{2}$ based on muon-spin spectroscopy and ac magnetic susceptibility ($\chi$) measurements. The dependence of the internal field at the muon site on temperature is indicative of a ferromagnetic ordering of Eu$^{2+}$ magnetic moments and only the conventional magnon scattering governs the longitudinal relaxation rate at low temperatures. At the same time, we observe a rich phenomenology for the imaginary component of the susceptibility $\chi^{\prime\prime}$ by means of both standard ac susceptibility and a novel technique based on a microwave coplanar waveguide resonator. In particular, we detect activated trends for several features in $\chi^{\prime\prime}$ over frequencies spanning ten orders of magnitude. We interpret our results in terms of the complex dynamics of vortices and antivortices influenced by the underlying structure of magnetic domains., Comment: 8 pages, 7 figures

NGC 6388 is one of the most massive Galactic globular clusters (GC) and it is an old, metal-rich, Galactic bulge cluster. By exploiting previous spectroscopic observations we were able to bypass the uncertainties in membership related to the strong field stars contamination. We present the abundance analysis of 12 new giant stars with UVES spectra and 150 giants with GIRAFFE spectra acquired at the ESO-VLT. We derived radial velocities, atmospheric parameters and iron abundances for all stars. When combined to previous data, we obtain a grand total of 185 stars homogeneously analysed in NGC 6388 from high-resolution spectroscopy. The average radial velocity of the 185 stars is 81.2+/-0.7, rms = 9.4 km/s. We obtain an average metallicity [Fe/H]=-0.480 dex, rms = 0.045 dex (35 stars) and [Fe/H]=-0.488 dex, rms = 0.040 dex (150 stars) from the UVES and GIRAFFE samples, respectively. Comparing these values to internal errors in abundance, we exclude the presence of a significant intrinsic metallicity spread within the cluster. Since about a third of giants in NGC 6388 is claimed to belong to the "anomalous red giants" in the HST pseudo-colour map defining the so-called type-II GCs, we conclude that either enhanced metallicity is not a necessary requisite to explain this classification (as also suggested by the null iron spread for NGC 362) or NGC 6388 is not a type-II globular cluster., Comment: 17 pages, 16 figures, 8 tables; accepted for publication on Astronomy and Astrophysics

Stock 2 is a little-studied open cluster that shows an extended main-sequence turnoff (eMSTO). In order to investigate this phenomenon and characterise the cluster itself we performed high-resolution spectroscopy in the framework of the Stellar Population Astrophysics (SPA) project. We employed the High Accuracy Radial velocity Planet Searcher in North hemisphere spectrograph (HARPS-N) at the Telescopio Nazionale Galileo (TNG). We completed our observations with additional spectra taken with the Catania Astrophysical Observatory Spectrograph (CAOS). In total we observed 46 stars (dwarfs and giants), which represent, by far, the largest sample collected for this cluster to date. We provide the stellar parameters, extinction, radial and projected rotational velocities for most of the stars. Chemical abundances for 21 species with atomic numbers up to 56 have also been derived. We notice a differential reddening in the cluster field whose average value is 0.27 mag. It seems to be the main responsible for the observed eMSTO, since it cannot be explained as the result of different rotational velocities, as found in other clusters. We estimate an age for Stock 2 of 450$\pm$150 Ma which corresponds to a MSTO stellar mass of $\approx$2.8 M$_{\odot}$. The cluster mean radial velocity is around 8.0 km s$^{-1}$. We find a solar-like metallicity for the cluster, [Fe/H]=$-$0.07$\pm$0.06, compatible with its Galactocentric distance. MS stars and giants show chemical abundances compatible within the errors, with the exceptions of Barium and Strontium, which are clearly overabundant in giants, and Cobalt, which is only marginally overabundant. Finally, Stock 2 presents a chemical composition fully compatible with that observed in other open clusters of the Galactic thin disc., Comment: Accepted for publication in Astronomy and Astrophysics; 18 pages, 13 figures, 12 tables