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The Cassini spacecraft orbiting Saturn carries the composite infrared spectrometer (CIRS) designed to study thermal emission from Saturn and its rings and moons. CIRS, a Fourier transform spectrometer, is an indispensable part of the payload providing unique measurements and important synergies with the other instruments. It takes full advantage of Cassini's 13-year-long mission and surpasses the capabilities of previous spectrometers on Voyager 1 and 2. The instrument, consisting of two interferometers sharing a telescope and a scan mechanism, covers over a factor of 100 in wavelength in the mid and far infrared. It is used to study temperature, composition, structure, and dynamics of the atmospheres of Jupiter, Saturn, and Titan, the rings of Saturn, and surfaces of the icy moons. CIRS has returned a large volume of scientific results, the culmination of over 30 years of instrument development, operation, data calibration, and analysis. As Cassini and CIRS reach the end of their mission in 2017, we expect that archived spectra will be used by scientists for many years to come.

A condensate cloud on Titan identified by its 220 cm−1 far-infrared signature continues to undergo seasonal changes at both the north and south poles. In the north, the cloud, which extends from 55 N to the pole, has been gradually decreasing in emission intensity since the beginning of the Cassini mission with a half-life of 3.8 years. The cloud in the south did not appear until 2012 but its intensity has increased rapidly, doubling every year. The shape of the cloud at the south pole is very different from that in the north. Mapping in 2013 December showed that the condensate emission was confined to a ring with a maximum at 80 S. The ring was centered 4deg from Titanʼs pole. The pattern of emission from stratospheric trace gases like nitriles and complex hydrocarbons (mapped in 2014 January) was also offset by 4deg, but had a central peak at the pole and a secondary maximum in a ring at about 70 S with a minimum at 80 S. The shape of the gas emission distribution can be explained by abundances that are high at the atmospheric pole and diminish toward the equator, combined with correspondingly increasing temperatures. We discuss possible causes for the condensate ring. The present rapid build up of the condensate cloud at the south pole is likely to transition to a gradual decline from 2015 to 2016. Key words: molecular processes - planets and satellites: atmospheres - planets and satellites: composition - planets and satellites: individual (Titan) - radiation mechanisms: thermal

Since the Voyager 1 (V1) flyby in 1980, Titans exploration from space and the ground has been ongoing for more than a full revolution of Saturn around the Sun (one Titan year or 29.5 Earth years was completed in May 2010). In this study we search for temporal variations affecting Titans atmospheric thermal and chemical structure within that year. We process Cassini CIRS data taken during the Titan flybys from 2006-2013 and compare them to the 1980 V1IRIS spectra (re-analyzed here). We also consider data from Earth-based and -orbiting observatories (such as from the ISO, re-visited). When we compare the CIRS 2010 and the IRIS data we find limited inter-annual variations, below the 25 or35 levels for the lower and middle, or the high latitudes, respectively. A return to the 1980 stratospheric temperatures and abundances is generally achieved from 50degN to 50degS, indicative of the solar radiation being the dominating energy source at 10 AU, as for the Earth, as predicted by GCM and photochemical models. However, some exceptions exist among the most complex hydrocarbons (C4H2 and C3H4), especially in the North. In the Southern latitudes, since 2012, we see a trend for an increase of several trace gases, possibly indicative of a seasonal atmospheric reversal. At the Northern latitudes we found enhanced abundances around the period of the northern spring equinox in mid-2009 (as in Bampasidis et al. 2012), which subsequently decreased (from 2010-2012) returning to values similar to those found in the V1 epoch a Titanian year before.

Seasonal changes in Titan's surface brightness temperatures have been observed by Cassini in the thermal infrared. The Composite Infrared Spectrometer (CIRS) measured surface radiances at 19 micron in two time periods: one in late northern winter (Ls = 335d eg) and another centered on northern spring equinox (Ls = 0 deg). In both periods we constructed pole-to-pole maps of zonally averaged brightness temperatures corrected for effects of the atmosphere. Between late northern winter and northern spring equinox a shift occurred in the temperature distribution, characterized by a warming of approximately 0.5 K in the north and a cooling by about the same amount in the south. At equinox the polar surface temperatures were both near 91 K and the equator was 93.4 K. We measured a seasonal lag of delta Ls approximately 9 in the meridional surface temperature distribution, consistent with the post-equinox results of Voyager 1 as well as with predictions from general circulation modeling. A slightly elevated temperature is observed at 65 deg S in the relatively cloud-free zone between the mid-latitude and southern cloud regions.

The Cassini spacecraft completed its nominal mission at Saturn in 2008 and began its extended mission. Cassini carries the Composite Infrared Spectrometer (CIRS); a Fourier transform spectrometer that measures the composition, thermal structure and dynamics of the atmospheres of Saturn and Titan, and also the temperatures of other moons and the rings.

The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft has obtained spectra of Titan during most of the 44 flybys of the Cassini prime mission. Water vapor on Titan was first detected using whole-disk observations from the Infrared Space Observatory (Coustenis et al 1998, Astron. Astrophys. 336, L85-L89). CIRS data permlt the retrieval of the latitudinal variation of water on Titan and some limited information on its vertical profile. Emission lines of H2O on Titan are very weak in the CIRS data. Thus, large spectral averages as well as improvements in calibration are necessary to detect water vapor. Water abundances were retrieved in nadir spectra at 55 South, the Equator, and at 19 North. Limb spectra of the Equator were also modeled to constrain the vertical distribution of water. Stratospheric temperatures in the 0.5 - 4.0 mbar range were obtained by inverting spectra of CH4 in the v4 band centered at 1304/cm. The temperature in the lower stratosphere (4 - 20 mbar) was derived from fitting pure rotation lines of CH4 between 80 and 160/cm. The origin of H2O and CO2 is believed to be from the ablation of micrometeorites containing water ice, followed by photochemistry. This external source of water originates either within the Saturn system or from the interplanetary medium. Recently, Horst et al (J. Geophys. Res. 2008, in press) developed a photochemical model of Titan in which there are two external sources of oxygen. Oxygen ions (probably from Enceladus) precipitate into Titan's atmosphere to form CO at very high altitudes (1100 km). Water ice ablation at lower altitudes (700 km) forms H2O and subsequent chemistry produces CO2. CIRS measurements of CO, CO2, and now of H2O will provide valuable constraints to these photochemical models and - improve our understanding of oxygen chemistry on Titan.

The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft has obtained numerous spectra of Saturn at varying spectral and spatial resolutions since Saturn Orbit Insertion in 2004. Emission lines due to water vapor in Saturn's stratosphere were first detected using whole-disk observations from the Infrared Space Observatory (Feuchtgruber et al 1997) and subsequently confirmed by the Submillimeter Wave Astronomy Satellite (Rergin et al 2000). CIRS has detected water and the data permit the retrieval of the latitudinal variation of water on Saturn. Emission lines of H2O on Saturn are very weak in the CIRS data. Thus. large spectral averages as well as improvements in calibration are necessary to detect water vapor. Zonally averaged nadir spectra were produced every 10 degrees of latitude. Stratospheric temperatures in the 0.5 - 5.0 mbar range were obtained by inverting spectra of CH4 in the v4 band centered at 1304 cm(exp -1). The origin of water vapor is believed to be from the ablation of micrometeorites containing water ice, followed by photochemistry. This external source of oxygen originates either from the Saturn system (from the rings or perhaps from Enceladus) or from the interplanetary medium. Connerney (1986) proposed a mechanism to transport water from the inner edge of the B-ring along magnetic field lines to specific latitudes (50N and 44S) on Saturn. Prange et al (2006) interpreted a minimum in the abundance of acetylene from ultraviolet spectra near 41S on Saturn as possibly due to an enhanced influx of water. Existing CIRS far-IR spectra are at relatively low spatial resolution, but observations at closer range planned for the extended mission will be able to test the "ring rain" mechanism by searching for localized water vapor enhancement at midlatitudes.

The atmosphere of Titan has a spectral window of low opacity around 530/cm in the thermal infrared where radiation from the surface can be detected from space. The Composite Infrared spectrometer1 (CIRS) uses this window to measure the surface brightness temperature of Titan. By combining all observations from the Cassini tour it is possible to go beyond previous Voyager IRIS studies in latitude mapping of surface temperature. CIRS finds an average equatorial surface brightness temperature of 93.7+/-0.6 K, which is close to the 93.65+/-0.25 K value measured at the surface by Huygens HASi. The temperature decreases toward the poles, reaching 91.6+/-0.7 K at 90 S and 90.0+/-1.0 K at 87 N. The temperature distribution is centered in latitude at approximately 12 S, consistent with Titan's season of late northern winter. Near the equator the temperature varies with longitude and is higher in the trailing hemisphere, where the lower albedo may lead to relatively greater surface heating5. Modeling of radiances at 590/cm constrains the atmospheric H2 mole fraction to 0.12+/-0.06 %, in agreement with results from Voyager iris.

A large fraction of 19-micron thermal radiation from the surface of Titan reaches space through a spectral window of low atmospheric opacity. The emergent radiance, after removing the effect of the atmosphere, gives the brightness temperature of the surface. This atmospheric window is covered by the far-infrared channel of the Composite Infrared spectrometer1 (CIRS) on Cassini. In mapping Titan surface temperatures, CIRS is able to improve upon results of Voyager IRIS, by taking advantage of improved latitude coverage and a much larger dataset. Observations are from a wide range of emission angles and thereby provide constraints on the atmospheric opacity and radiance that are used to derive the surface temperature. CIRS finds an average equatorial surface brightness temperature of 93.7+/-0.6 K, virtually identical to the HASI temperature at the Huygens landing site. Mapping in latitude shows that the surface temperature decreases toward the poles by about 2 K in the south and 3 K in the north. This surface temperature distribution is consistent with the formation of lakes seen at high latitudes on Titan.