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1. Feasibility of using thin crystalline silicon films epitaxially grown at 165 °C in solar cells: A computer simulation study

Author

Roca i Cabarrocas P., Labrune M., Cariou R., Chakraborty S., and Chatterjee P.

Subjects
Renewable energy sources, TJ807-830
Abstract

We have previously reported on the successful deposition of heterojunction solar cells whose thin intrinsic crystalline absorber layer is grown using the standard radio frequency plasma enhanced chemical vapour deposition process at 165 °C on highly doped P-type (100) crystalline silicon substrates. The structure had an N-doped hydrogenated amorphous silicon emitter deposited on top of the intrinsic epitaxial silicon layer. However to form the basis of a solar cell, the epitaxial silicon film must be chiefly responsible for the photo-generated current of the structure and not the underlying crystalline silicon substrate. In this article we use detailed electrical-optical modelling to calculate the minimum thickness of the epitaxial silicon layer for this to happen. We have also investigated by modelling the influence of the a-Si:H/epitaxial-Si and epitaxial-Si/c-Si interface defects, the thickness of the epitaxial silicon layer and its volume defect density on cell performance. Finally by varying the input parameters and considering various light-trapping schemes, we show that it is possible to attain a conversion efficiency in excess of 13% using only a 5 micron thick epitaxial silicon layer.

Published
2013
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8. Non-targeted analysis of lipidic extracts by high-resolution mass spectrometry to characterise the chemical exposome: Comparison of four clean-up strategies applied to egg

Author

Padioleau, A., Cariou, R., Guiffard, I., Le Bizec, B., Escher, Beate, Antignac, J.-P., Dervilly, G., Padioleau, A., Cariou, R., Guiffard, I., Le Bizec, B., Escher, Beate, Antignac, J.-P., and Dervilly, G.

Abstract

Biota samples are used to monitor chemical stressors and their impact on the ecosystem and to describe dietary chemical exposure. These complex matrices require an extraction step followed by clean-up to avoid damaging sensitive analytical instruments based on chromatography coupled to mass spectrometry. While interest for non-targeted analysis (NTA) is increasing, there is no versatile or generic sample preparation for a wide range of contaminants suitable for a diversity of biotic matrices. Among the contaminants’ variety, persistent contaminants are mostly hydrophobic (mid- to non-polar) and bio-magnify through the lipidic fraction. During their extraction, lipids are generally co-extracted, which may cause matrix effect during the analysis such as hindering the acquired signal. The aim of this study was to evaluate the efficacy of four clean-up methods to selectively remove lipids from extracts prior to NTA. We evaluated (i) gel permeation chromatography (GPC), (ii) Captiva EMR-lipid cartridge (EMR), (iii) sulphuric acid degradation (H2SO4) and (iv) polydimethyl siloxane (PDMS) for their efficiency to remove lipids from hen egg extracts. Gas and liquid chromatography coupled with high-resolution mass spectrometry fitted with either electron ionisation or electrospray ionisation sources operating in positive and negative modes were used to determine the performances of the clean-up methods. A set of 102 chemicals with a wide range of physico-chemical properties that covers the chemical space of mid- to non-polar contaminants, was used to assess and compare recoveries and matrix effects. Matrix effects, that could hinder the mass spectrometer signal, were lower for extracts cleaned-up with H2SO4 than for the ones cleaned-up with PDMS, EMR and GPC. The recoveries were satisfactory for both GPC and EMR while those determined for PDMS and H2SO4 were low due to poor partitioning and degradation/dissociation of the compounds, respectively. The choice of the clean-up me

Published
2023

12. P15-08 PANORAMIX: Providing risk assessments of complex real-life mixtures for the protection of Europe’s citizens and the environment

Author

Vinggaard, A.M., primary, Lamoree, M., additional, Escher, B.I., additional, Antignac, J.-P., additional, Scholze, M., additional, Jensen, T.K., additional, Herzler, M., additional, Audebert, M., additional, Hamers, T., additional, Kortenkamp, A., additional, Busquet, F., additional, Piumatti, M., additional, Dervilly, G., additional, Valente, M.J., additional, Cariou, R., additional, Moteau, S., additional, Oelgeschläger, M., additional, Renko, K., additional, Schmeisser, S., additional, Maier, D., additional, and Laursen, L.L., additional

Published
2022
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13. Mixture risk assessment of complex real-life mixtures—The PANORAMIX project

Author

Escher, Beate, Lamoree, M., Antignac, J.-P., Scholze, M., Herzler, M., Hamers, T., Jensen, T.K., Audebert, M., Busquet, F., Maier, D., Oelgeschläger, M., Valente, M.J., Boye, H., Schmeisser, S., Dervilly, G., Piumatti, M., Motteau, S., König, Maria, Renko, K., Margalef, M., Cariou, R., Ma, Y., Treschow, A.F., Kortenkamp, A., Vinggaard, A.M., Escher, Beate, Lamoree, M., Antignac, J.-P., Scholze, M., Herzler, M., Hamers, T., Jensen, T.K., Audebert, M., Busquet, F., Maier, D., Oelgeschläger, M., Valente, M.J., Boye, H., Schmeisser, S., Dervilly, G., Piumatti, M., Motteau, S., König, Maria, Renko, K., Margalef, M., Cariou, R., Ma, Y., Treschow, A.F., Kortenkamp, A., and Vinggaard, A.M.

Abstract

Humans are involuntarily exposed to hundreds of chemicals that either contaminate our environment and food or are added intentionally to our daily products. These complex mixtures of chemicals may pose a risk to human health. One of the goals of the European Union’s Green Deal and zero-pollution ambition for a toxic-free environment is to tackle the existent gaps in chemical mixture risk assessment by providing scientific grounds that support the implementation of adequate regulatory measures within the EU. We suggest dealing with this challenge by: (1) characterising ‘real-life’ chemical mixtures and determining to what extent they are transferred from the environment to humans via food and water, and from the mother to the foetus; (2) establishing a high-throughput whole-mixture-based in vitro strategy for screening of real-life complex mixtures of organic chemicals extracted from humans using integrated chemical profiling (suspect screening) together with effect-directed analysis; (3) evaluating which human blood levels of chemical mixtures might be of concern for children’s development; and (4) developing a web-based, ready-to-use interface that integrates hazard and exposure data to enable component-based mixture risk estimation. These concepts form the basis of the Green Deal project PANORAMIX, whose ultimate goal is to progress mixture risk assessment of chemicals.

Published
2022

14. PANORAMIX: Providing risk assessments of complex real-life mixtures for the protection of Europe’s citizens and the environment

Author

Vinggaard, A.M., Lamoree, M., Escher, Beate, Antignac, J.-P., Scholze, M., Jensen, T.K., Herzler, M., Audebert, M., Hamers, T., Kortenkamp, A., Busquet, F., Piumatti, M., Dervilly, G., Valente, M.J., Cariou, R., Moteau, S., Oelgeschläger, M., Renko, K., Schmeisser, S., Maier, D., Laursen, L.L., Vinggaard, A.M., Lamoree, M., Escher, Beate, Antignac, J.-P., Scholze, M., Jensen, T.K., Herzler, M., Audebert, M., Hamers, T., Kortenkamp, A., Busquet, F., Piumatti, M., Dervilly, G., Valente, M.J., Cariou, R., Moteau, S., Oelgeschläger, M., Renko, K., Schmeisser, S., Maier, D., and Laursen, L.L.

Abstract

no abstract

Published
2022

17. Large Size Flexible and Laminated Space Photovoltaic Arrays

Author

Guerin, T., Jamin, C., Voarino, P., Vergnet, D., Zevenbergen, P., and Cariou, R.

Subjects
Concentrators, PV for Space Applications, and TPV, PV Systems – Modelling, Design, Operation and Performance
Abstract

38th European Photovoltaic Solar Energy Conference and Exhibition; 1324-1328, Space industry is facing a wave of important changes. The booming of space activities comes along with greater PV power requirements for geostationary orbit. With solar electrical propulsion and high throughput satellites, it becomes necessary to increase arrays’ specific power (W/kg) and power density (W/m3). Moving away from standard rigid panels towards foldable / flexible solar arrays is a promising way to meet this mass and volume challenges and thus address this high-power demand. The ALFAMA project [1], [2] - Advanced Lightweight and Flexible Array with Mechanical Architecture – brings innovative solutions by developing thin and foldable solar arrays with low cost fabrication processes such as lamination and printed electronics.

Published
2021
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18. ALFAMA Project: Development of a Flexible and Laminated Space Photovoltaic Array

Author

Guerin, T., Cariou, R., Noël, S., Khorenko, V., Jamin, C., Roujol, Y., Voarino, P., and Chabuel, F.

Subjects
Concentrators and PV for Space Applications, PV Systems and Storage – Modelling, Design, Operation and Performance
Abstract

37th European Photovoltaic Solar Energy Conference and Exhibition; 1261-1263, The ALFAMA project - Advanced Lightweight and Flexible Array with Mechanical Architecture - focuses on the development of a flexible solar array for high power space missions. Nowadays, the booming of space activities comes along with a greater power demand. A reduction of solar array stowage volume (W/m3) and an increased power/mass ratio (W/kg) are needed, and moving away from standard rigid panels towards flexible solar arrays is promising to meet this high-power demand. Material selection, layer stack design, as well as interconnector technology are key drivers to build a robust flexible array. The work presented here focuses on the development of a flexible solar array coupons.

Published
2020
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19. Do farming conditions influence brominated flame retardant levels in pig and poultry products?

Author

Huneau-Salaün, A., primary, Cariou, R., additional, Royer, E., additional, Jondreville, C., additional, Balaine, L., additional, Souchet, C., additional, Coton, J., additional, Vénisseau, A., additional, Thomas, R., additional, Rousselière, Y., additional, Charpiot, A., additional, Marchand, P., additional, Dervilly-Pinel, G., additional, Marcon, M., additional, Le Bizec, B., additional, Travel, A., additional, and Le Bouquin, S., additional

Published
2020
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20. Accumulation of an emergent contaminant, α-hexabromocyclododecane ( -HBCDD), in tissues of pigs

Author

Royer, E., Cariou, R, Baéza, Elisabeth, Travel, Angélique, Jondreville, Catherine, Institut du Porc (IFIP), Ecole Nationale Vétérinaire, Agroalimentaire et de l'alimentation Nantes-Atlantique (ONIRIS), Biologie des Oiseaux et Aviculture (BOA), Institut National de la Recherche Agronomique (INRA)-Université de Tours (UT), ITAVI, Unité de Recherches Animal et Fonctionnalités des Produits Animaux (URAFPA), Université de Lorraine (UL)-Institut National de la Recherche Agronomique (INRA), Institut National de la Recherche Agronomique (INRA)-Université de Tours, and Institut National de la Recherche Agronomique (INRA)-Université de Lorraine (UL)

Subjects
[SDV.GEN]Life Sciences [q-bio]/Genetics, [SDV.GEN.GA]Life Sciences [q-bio]/Genetics/Animal genetics, [SDV]Life Sciences [q-bio], [INFO]Computer Science [cs], ComputingMilieux_MISCELLANEOUS
Abstract

International audience

Published
2018

21. Author Correction: III-V-on-silicon solar cells reaching 33% photoconversion efficiency in two-terminal configuration (Nature Energy (2018) DOI: 10.1038/s41560-018-0125-0)

Author

Cariou, R., Benick, J., Feldmann, F., Höhn, O., Hauser, H., Beutel, P., Razek, N., Wimplinger, M., Bläsi, B., Lackner, D., Hermle, M., Siefer, G., Glunz, S.W., Bett, A.W., Dimroth, F., and Publica

Abstract

In the version of this Article originally published, in the 'Rear-side light trapping' paragraph of the Methods section, the values of depth and fill factor were incorrectly given as 350 nm and 50%, respectively; instead, the values should have read 250 nm and 60%. This has now been corrected.

Published
2018

22. Occurrence of Dechlorane Plus and related compounds in catfish (Silurus spp.) from rivers in France

Author

Abdel Malak, I., Cariou, R., Venisseau, A., Dervilly Pinel, G., Jaber, F., Babut, M., Le Bizec, B., Laboratoire d'étude des Résidus et Contaminants dans les Aliments (LABERCA), Institut National de la Recherche Agronomique (INRA)-Ecole Nationale Vétérinaire, Agroalimentaire et de l'alimentation Nantes-Atlantique (ONIRIS), Université Libanaise, RiverLy (UR Riverly), Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA), French General Directorate for Food, and Lebanese Association for Scientific Research

Subjects
fish, contamination, TOXICITE, COURS D'EAU, [SDE]Environmental Sciences, toxicity, muscles, MUSCLE, [CHIM.OTHE]Chemical Sciences/Other, SILURIDAE, rivers, POISSON
Abstract

International audience; Dechlorane related compounds (DRCs), including Dechlorane Plus (syn-DP and anti-DP), Dechlorane-601,-602, -603 and Chlordene Plus (CP), constitute a group of polychlorinated flame retardants (FRs) that are still of industrial use. In particular, DRCs have been detected in various nvironmental matrices and in different aquatic and terrestrial biota, thus exhibiting bioaccumulation and biomagnification potentials. The present study aimed at producing first occurrence data of a range of DRCs in Silurus spp. samples from different rivers located in France. Determination was carried out by gas chromatography high-resolution mass spectrometry after a sample clean-up based on a multilayer silica column and gel permeation chromatography. The concentration of monitored SDRCs ranged from 1.58 to 408 pg.g-1 wet weight (54 - 11100 pg.g-1 lipid weight). The fractional abundance of syn- and anti-DP stereoisomers was similar to that reported by other studies with an average equal to 0.60. Dec-601 was not detected in any sample. Detection frequencies ranged between 34 and 100% for other DRCs. Investigated correlations between DRCs and polychlorobiphenyls (PCBs) suggest a link with lipid content but independent contamination sources.

Published
2018

25. Fate of a brominated flame retardant (HBCD) in chickens and pigs: a generic modelling approach

Author

Cariou, R., Baéza, Elisabeth, Dominguez-Romero, Elena, Omer, E., Souchet, Christophe, Vénisseau, A., Marchand, P., Dervilly-Pinel, G., Le Bizec, Bruno, Travel, A., Jondreville, Catherine, Laboratoire d'étude des Résidus et Contaminants dans les Aliments (LABERCA), Institut National de la Recherche Agronomique (INRA)-Ecole Nationale Vétérinaire, Agroalimentaire et de l'alimentation Nantes-Atlantique (ONIRIS), Unité de Recherches Avicoles (URA), Institut National de la Recherche Agronomique (INRA), ITAVI, Unité de Recherches Animal et Fonctionnalités des Produits Animaux (URAFPA), Institut National de la Recherche Agronomique (INRA)-Université de Lorraine (UL), and CASDAR Braviporc

Subjects
[SDV.GEN]Life Sciences [q-bio]/Genetics, [SDV.GEN.GA]Life Sciences [q-bio]/Genetics/Animal genetics, [SDV]Life Sciences [q-bio], [INFO]Computer Science [cs], ComputingMilieux_MISCELLANEOUS
Abstract

International audience

Published
2016

26. Enantiomer-specific accumulation and depuration of α-hexabromocyclododecane (α-HBCDD) in broiler chicken (Gallus domesticus) as a tool to identify contamination sources

Author

Omer, E., Cariou, R., Baéza, Elisabeth, Dominguez-Romero, Elena, Souchet, C., Vénisseau, A., Marchand, P., Dervilly-Pinel, G., Le Bizec, Bruno, Travel, A., Jondreville, Catherine, Laboratoire d'étude des Résidus et Contaminants dans les Aliments (LABERCA), Institut National de la Recherche Agronomique (INRA)-Ecole Nationale Vétérinaire, Agroalimentaire et de l'alimentation Nantes-Atlantique (ONIRIS), Unité de Recherches Avicoles (URA), Institut National de la Recherche Agronomique (INRA), ITAVI, Unité de Recherches Animal et Fonctionnalités des Produits Animaux (URAFPA), Institut National de la Recherche Agronomique (INRA)-Université de Lorraine (UL), and CASDAR Braviporc

Subjects
[SDV.GEN]Life Sciences [q-bio]/Genetics, [SDV.GEN.GA]Life Sciences [q-bio]/Genetics/Animal genetics, [SDV]Life Sciences [q-bio], [INFO]Computer Science [cs], ComputingMilieux_MISCELLANEOUS
Abstract

International audience

Published
2016

30. Hexabromocyclododecane in poultry and pork: a comprehensive study of exposure and transfer into products

Author

Cariou, R., Huneau-Salaün, A., Elena Dominguez-Romero, Omer, E., Amand, G., Souchet, C., Balaine, L., Charpiot, A., Vénisseau, A., Marchand, P., Marcon, M., Jérémy Ratel, Le Bouquin, S., Royer, E., Gaud Dervilly, Erwan Engel, Elisabeth Baéza, Le Bizec, B., Travel, A., Catherine Jondreville, LUNAM Université [Nantes Angers Le Mans], Agence nationale de sécurité sanitaire de l'alimentation, de l'environnement et du travail (ANSES), Unité de Recherches Avicoles (URA), Institut National de la Recherche Agronomique (INRA), Unité de Recherches Animal et Fonctionnalités des Produits Animaux (URAFPA), Université de Lorraine (UL)-Institut National de la Recherche Agronomique (INRA), ITAVI, Institut du Porc (IFIP), Qualité des Produits Animaux (QuaPA), CASDAR Braviporc, and ProdInra, Migration

Subjects
[SDV] Life Sciences [q-bio], [SPI.GPROC] Engineering Sciences [physics]/Chemical and Process Engineering, [SDV]Life Sciences [q-bio], [SDV.IDA]Life Sciences [q-bio]/Food engineering, [INFO]Computer Science [cs], [SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering, [INFO] Computer Science [cs], [SDV.IDA] Life Sciences [q-bio]/Food engineering, ComputingMilieux_MISCELLANEOUS
Abstract

International audience

Published
2015

31. Kelvin Probe Force Microscopy Study of Electric Field Homogeneity in Epitaxial Silicon Solar Cells Cross-Section

Author

Narchi, P., Picardi, G., Cariou, R., Foldyna, M., Prod'homme, P., and Roca I Cabarrocas, P.

Subjects
Silicon-based Thin Film and Silicon-Heterojunction Solar Cells and Modules, THIN FILM SOLAR CELLS AND MODULES
Abstract

31st European Photovoltaic Solar Energy Conference and Exhibition; 1026-1029, Using Kelvin probe force microscopy, cross-section measurements along the PIN junction of an epitaxial silicon solar cell were performed under operating conditions (illumination, voltage bias). Surface potential profiles show coherent behaviors with theoretical expectations when the device is under increasing illumination intensity, increasing voltage bias, or under illumination at different wavelengths. Using measurements under voltage bias, we propose a methodology to investigate the electric field homogeneity along the PIN junction. It is shown that the electric field is not homogeneous for the cell measured and it is suggested that this might be due either to preparation steps or to inhomogeneous defective layer along the PIN junction.

Published
2015
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32. Photonic nanostructures for advanced light trapping in thin crystalline silicon solar cells

Author

Trompoukis , C., ABDO , I., Cariou , R., COSNIER , T., Cosme , I., Chen , W., Depauw , V., Deparis , O., Dmitriev , A., Drouard , Emmanuel, Foldyna , M., Garcia-Caurel , E., Gordon , I., Heidari , B., HERMAN , A., Lalouat , Loïc, Lee , K., Liu , Jia, LODEWIJKS , K., Mandorlo , Fabien, IMEC ( IMEC ), Catholic University of Leuven ( KU Leuven ), Departement Elektrotechniek - ESAT [leuven], Katholieke Universiteit Leuven ( KU Leuven ), Laboratoire de physique des interfaces et des couches minces [Palaiseau] ( LPICM ), École polytechnique ( X ) -Centre National de la Recherche Scientifique ( CNRS ), Alcatel-Thalès III-V lab ( III-V Lab ), THALES-ALCATEL, Service d'Optique et Acoustique, Université Libre de Bruxelles [Bruxelles] ( ULB ), INL - Nanophotonique ( INL - Photonique ), Institut des Nanotechnologies de Lyon ( INL ), École Centrale de Lyon ( ECL ), Université de Lyon-Université de Lyon-Université Claude Bernard Lyon 1 ( UCBL ), Université de Lyon-École supérieure de Chimie Physique Electronique de Lyon ( CPE ) -Institut National des Sciences Appliquées de Lyon ( INSA Lyon ), Université de Lyon-Institut National des Sciences Appliquées ( INSA ) -Institut National des Sciences Appliquées ( INSA ) -Centre National de la Recherche Scientifique ( CNRS ) -École Centrale de Lyon ( ECL ), Université de Lyon-Institut National des Sciences Appliquées ( INSA ) -Institut National des Sciences Appliquées ( INSA ) -Centre National de la Recherche Scientifique ( CNRS ), Laboratoire Interdisciplinaire Carnot de Bourgogne ( LICB ), Université de Bourgogne ( UB ) -Centre National de la Recherche Scientifique ( CNRS ), Key Laboratory of Electromagnetic Processing of Materials (Ministry of Education), Northeastern University [Shenyang], and INL - Photovoltaïque ( INL - PV )

Subjects
[ SPI.MAT ] Engineering Sciences [physics]/Materials, [ SPI ] Engineering Sciences [physics], [ SPI.NANO ] Engineering Sciences [physics]/Micro and nanotechnologies/Microelectronics, [ SPI.OPTI ] Engineering Sciences [physics]/Optics / Photonic, ComputingMilieux_MISCELLANEOUS
Abstract

International audience; no abstract

Published
2015

33. Epitaxial Growth of Silicon Thin Films by Low Temperature RF-PECVD from SiF4/H2/Ar

Author

Léal, R., Dornstetter, J.-C., Haddad, F., Bruneau, B., Cariou, R., Chen, W., Cosme Bolanos, I., Poulain, G., Maurice, J.-L., and Roca I Cabarrocas, P.

Subjects
THIN FILM SOLAR CELLS, Silicon-based Thin Film Solar Cells
Abstract

29th European Photovoltaic Solar Energy Conference and Exhibition; 1959-1962, Diffused emitters have shown their limitations in the way to achieve high efficiency solar cells especially as a result of difficulties to make thin and sharp junctions. Epitaxial emitters are a good solution to tackle these drawbacks, but so far no solar cells have even reached diffused emitters solar cells efficiency in spite of better potential. However most of suggested processes used for this application are based on APCVD or LPCVD. These high temperature processes induce thermal stress in the c-Si wafer and as a consequence carriers lifetime strongly decreases. We describe here how to perform low temperature (~200 °C) epitaxy by standard RF-PECVD from SiF4/H2/Ar mixtures. By studying process parameters such as H2 depletion in the plasma and ion bombardment energy, we are able to optimize the process conditions to perform epitaxy. Crystalline thin films have been characterized by in situ and ex situ ellipsometry, then TEM and electron diffraction have been used to assess ellipsometry measurement, revealing an epitaxy with good structural properties. Further work is under way to characterize the electronic properties and to dope these epi-layers.

Published
2014
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34. Optical and Electrical Improvement of Rear Side ITO for Heterojunction Back Contact Solar Cells

Author

Granata, S.N., Tous, L., Bearda, T., Nassar, J., Cariou, R., Trompoukis, C., Van Nieuwenhuysen, K., Abdulraheem, Y., Gordon, I., Szlufcik, J., Roca I Cabarrocas, P., Mertens, R., and Poortmans, J.

Subjects
WAFER-BASED SILICON SOLAR CELLS AND MATERIALS TECHNOLOGY, Silicon Solar Cell Improvements
Abstract

29th European Photovoltaic Solar Energy Conference and Exhibition; 1024-1027, In this paper, the electrical and optical characteristics of the Indium-Doped Tin Oxide (ITO) are tuned in order to design an ITO-based spacer between the a-Si:H and the metal contact suited for Amorphous / Crystalline Heterojunction interdigitated Back Contact Solar Cells (a-Si:H / c-Si HJ i-BC). ITO carrier concentration, mobility, resistivity, extinction coefficient, and work function, as well as the ITO / a-Si:H specific contact resistances are evaluated as a function of O2 relative flow rate during ITO deposition. An ITO having carrier concentration of 4.5x1019 cm-3, mobility of 20.2 cm2/(V.s) and resistivity of 6.24 mΩ.cm is found to be an optimum leading to ITO / a-Si:H(p/i) and ITO / a-Si:H(n/i) specific contact resistances values of 0.6 Ω.cm2 and 0.1 Ω.cm2 respectively and a RS reflectance of 58% at 1200nm when integrated in Silver / ITO / a-Si:H / c-Si(textured) test structures.

Published
2014
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35. Nanophotonics for ultrathin crystalline silicon photovoltaics: When photons (actually) meet electrons

Author

Depauw, V., ABDO, I., Boukhicha, R., Cariou, R., Chen, W., Cosme, I., Deparis, O., Dmitriev, A., Drouard, Emmanuel, El Daif, Ounsi, Foldyna, M., Garcia-Caurel, E., Heidari, B., HERMAN, A., Lalouat, Loic, Seassal, Christian, Liu, Jia, LODEWIJKS, K., Mandorlo, Fabien, Orobtchouk, Regis, IMEC (IMEC), Catholic University of Leuven - Katholieke Universiteit Leuven (KU Leuven), Laboratoire de physique des interfaces et des couches minces [Palaiseau] (LPICM), École polytechnique (X)-Centre National de la Recherche Scientifique (CNRS), Alcatel-Thalès III-V lab (III-V Lab), THALES-ALCATEL, Laboratoire des Sciences de l'Ingénieur Appliquées à la Mécanique et au génie Electrique (SIAME), Université de Pau et des Pays de l'Adour (UPPA), Service d'Optique et Acoustique, Université libre de Bruxelles (ULB), INL - Nanophotonique (INL - Photonique), Institut des Nanotechnologies de Lyon (INL), Centre National de la Recherche Scientifique (CNRS)-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Institut National des Sciences Appliquées (INSA)-Université de Lyon-Institut National des Sciences Appliquées (INSA)-Université de Lyon-École Centrale de Lyon (ECL), Université de Lyon-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-École supérieure de Chimie Physique Electronique de Lyon (CPE)-Centre National de la Recherche Scientifique (CNRS)-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Université de Lyon-École supérieure de Chimie Physique Electronique de Lyon (CPE), INL - Hétéroepitaxie et Nanostructures (INL - H&N), INL - Photovoltaïque (INL - PV), École Centrale de Lyon (ECL), Université de Lyon-Université de Lyon-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-École supérieure de Chimie Physique Electronique de Lyon (CPE)-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-École Centrale de Lyon (ECL), and Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)

Subjects
[SPI]Engineering Sciences [physics], [SPI.OPTI]Engineering Sciences [physics]/Optics / Photonic, [SPI.NANO]Engineering Sciences [physics]/Micro and nanotechnologies/Microelectronics, [SPI.MAT]Engineering Sciences [physics]/Materials
Abstract

22-26 sept; International audience; no abstract

Published
2014

36. Analysis of Perfluorinated Compounds: comparison between Liquid Chromatography coupled to Tandem Mass Spectrometry and High Resolution Mass Spectrometry

Author

Veyrand B., Durand S., Duigou A., Monteau F., Cariou R., Marchand P., Le Bizec B., STICCA, PATRIZIA, PAGLIUCA, GIAMPIERO, Veyrand B., Sticca P., Pagliuca G., Durand S., Duigou A., Monteau F., Cariou R., Marchand P., and Le Bizec B.

Subjects
HIGH RESOLUTION MASS SPECTROMETRY, PERFLUORINATD COMPOUNDS, TANDEM MASS SPECTROMETRY, food and beverages
Abstract

Perfluorinated compounds, described by some scientist as the “PCBs of the twenty-first century”, are a group of contaminants which present bioaccumulative and persistent properties. Significant amounts of these compounds were detected in human blood and in the liver of many species, and it appears that a potential risk could exist for developmental and other adverse effects associated with exposure in humans. Due to the high affinity of these compounds with the proteins, milk appears to be a highly exposed matrix. Contamination could be present naturally (transfer from cow to milk) or during the processing of milk. The potential toxicity of this matrix is of high concern, considering the large amounts of milk consumed by children. A sensitive and specific method has to be used in order to quantify accurately these compounds in cow milk. Extraction and purification processes present major problems due to the high complexity of the matrix, and they have been optimized using different protocols. A detection method by liquid chromatography coupled to tandem mass spectrometry has been developed, which enables the quantification of 15 perfluorinated compounds, especially PFOS and PFOA. The advantages of using a high resolution system are described in terms of sensitivity and specificity.

Published
2007

38. Low Temperature Epitaxial Growth of Si and SiGe and Their Transfer to Foreign Substrate

Author

Cariou, R., Massiot, I., Ruggeri, R., Ramay, N., Tang, J., Cattoni, A., Collin, S., Nassar, J., and Roca I Cabarrocas, P.

Subjects
THIN FILM SOLAR CELLS, Silicon-based Thin Film Solar Cells
Abstract

28th European Photovoltaic Solar Energy Conference and Exhibition; 2225-2227, Using a standard RF-PECVD reactor, silicon layers are epitaxially grown at 175°C. Few μm thick layers can be efficiently used as an absorber in the wafer equivalent approach: p++c-Si(wafer) / epi-Si(~μm) / n+aSi:H(12nm) has excellent diodes characteristics with FF of 80.5 % and 8,8% efficiency. By dilution of GeH4 in SiH4/H2 plasma, we show for the first time epitaxial SiGe alloys, with variable Ge fraction, grown at such low temperature. Structural and electronic properties of these materials has well has solar cells parameters are investigated using spectroscopic ellipsometry, Raman, TEM, J(V) characteristics and EQE. Using stress induced lift off technique ultra-thin Si layers of few cm2 are transferred on inexpensive substrates. Material quality is kept constant during the transfer process as shown by Raman FWHM of 5.3 cm-1, and ultra-thin heterojunctions solar cells are processed on foreign substrates. Preliminary results suggest lifetimes in higher than 67 μs for passivated 3,2μm thick transferred epitaxial PECVD grown layers.

Published
2013
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42. Les Retardateurs de Flamme Bromés : Exposition humaine, métabolisme et considérations toxicologiques

Author

Zalko, Daniel, Cariou, R, MARCHAND, Philipp, Boulahtouf, A, Le Maire, A, Grimaldi, A, Hillenweck, Anne, Bourguet, W, BALAGUER, P, Le Bizec, Bruno, Antignac, Jean-Philippe, Métabolisme et Xénobiotiques (ToxAlim-MeX), ToxAlim (ToxAlim), Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Ecole Nationale Vétérinaire de Toulouse (ENVT), Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Ecole d'Ingénieurs de Purpan (INPT - EI Purpan), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut National de la Recherche Agronomique (INRA)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut National de la Recherche Agronomique (INRA), Unité de recherche Virologie et Immunologie Moléculaires (VIM (UR 0892)), Institut National de la Recherche Agronomique (INRA), Laboratoire d'étude des Résidus et Contaminants dans les Aliments (LABERCA), Institut National de la Recherche Agronomique (INRA)-Ecole Nationale Vétérinaire, Agroalimentaire et de l'alimentation Nantes-Atlantique (ONIRIS), Saisissez le nom du laboratoire, du service ou du département., Ville service., and ProdInra, Migration

Subjects
[SDV] Life Sciences [q-bio], [SDV]Life Sciences [q-bio], ComputingMilieux_MISCELLANEOUS
Abstract

National audience

Published
2011

46. Simple ruthenium precatalyst for the synthesis of stilbene derivatives and Ring Closing Metathesis in the presence of styrene initiators

Author

Lo, C., Cariou, R., Fischmeister, Cédric, Dixneuf, Pierre H., Institut des Sciences Chimiques de Rennes (ISCR), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)

Subjects
[CHIM.CATA]Chemical Sciences/Catalysis, ComputingMilieux_MISCELLANEOUS
Abstract

International audience

Published
2007

47. Dietary exposure to perfluoroalkyl acids of specific French adult sub-populations: High seafood consumers, high freshwater fish consumers and pregnant women

Author

Yamada, A., primary, Bemrah, N., additional, Veyrand, B., additional, Pollono, C., additional, Merlo, M., additional, Desvignes, V., additional, Sirot, V., additional, Marchand, P., additional, Berrebi, A., additional, Cariou, R., additional, Antignac, J.P., additional, Le Bizec, B., additional, and Leblanc, J.C., additional

Published
2014
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49. Treatment of proximal deep vein thrombosis with a novel synthetic compound (SR90107A/ORG31540) with pure anti-factor Xa activity - A phase II evaluation

Author

Buller, H R, Cariou, R, Gallus, A, Gent, M, Ginsberg, J, Prins, M H, Lensing, A, Levi, M, Nurmohammed, N, Hirsh, J, Roberts, R, ten Cate, J W, Decousus, H, Mismetti, P, Buchmuller, A, Charlet, [No Value], Viallon, A, van der Meer, J, Meinardi, [No Value], Meijer, K, Piovella, F, Barone, M, Beltrametti, C, Serafini, S, Kraaijenhagen, R A, Koopman, M M W, Jagt, H H T, Muller, M B R, Kooy, M V, Nauta, S, Gallus, A S, Coghlan, D, Rich, C, Prandoni, P, Scudeller, A, Scarano, L, Girolami, A, Baker, R, Tan, E, Cooney, J, Eikelboom, J, Ninet, J, Dolmazon, C, Madoux, M H G, Coppere, B, Nenci, G G, Agnelli, G, Falcinelli, F, Morini, M, and d'Angelo, A

Subjects
anticoagulants, PULMONARY-EMBOLISM, ANTITHROMBIN-III, HEPARIN, imaging, PENTASACCHARIDE, HOME, thrombosis
Abstract

Background-Patients with venous thromboembolism require initial treatment with an immediate-acting anticoagulant, low-molecular-weight heparin. We evaluated a novel synthetic factor Xa inhibitor (SR90107a/ORG31540) as an alternative treatment. Methods and Results-A randomized-parallel-group, phase II trial to assess the efficacy and safety of SR90107a/ORG31540 (5, 7.5, or 10 mg once daily) relative to low-molecular-weight heparin (dalteparin, 100 IU/kg twice daily) in symptomatic proximal deep vein thrombosis. The primary outcome measure was the change in thrombus mass, assessed by ultrasonography of the leg veins and perfusion lung scintigraphy, performed at baseline and day 7+/-1. A positive outcome was defined as improvement of the ultrasound and/or perfusion scan result without deterioration of either test. Other outcome measures included symptomatic, recurrent venous thromboembolism and major bleeding for a period of 3 months. All outcomes were interpreted with the observer unaware of treatment allocation. A positive primary outcome was observed in 46 of 100 (46%), 52 of 108 (48%), 48 of 115 (42%), and 56 of 115 (49%), respectively, of the subjects given 5, 7.5, or 10 mg SR90107a/ORG31540 or dalteparin. There were 8 recurrent thromboembolic complications (2.4%) in the 334 patients treated with SR90107a/ORG31540 and 6 (5.0%) in the 119 dalteparin patients, a difference of 2.6% in favor of SR90107a/ORG31540 (95% CI -2.1% to 10.1%). The incidence of bleeding was low and was similar among the groups. Conclusions-The factor Xa inhibitor SR90107a/ORG31540 appears to be an effective and safe treatment for patients with deep vein thrombosis across a wide range of doses. This synthetic compound merits evaluation in phase III studies.

Published
2000

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