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A near-minimal instance of optical cooling is experimentally presented wherein the internal-state entropy of a single atom is reduced more than twofold by illuminating it with broadband, incoherent light. Since the rate of optical pumping by a thermal state increases monotonically with its temperature, the cooling power in this scenario increases with higher thermal occupation, an example of a phenomenon known as cooling by heating. In contrast to optical pumping by coherent, narrow-band laser light, here we perform the same task with fiber-coupled, broadband sunlight, the brightest laboratory-accessible source of continuous blackbody radiation., Comment: 4 pages

Gas-phase molecules capable of repeatable, narrow-band spontaneous photon scattering are prized for direct laser cooling and quantum state detection. Recently, large molecules incorporating phenyl rings have been shown to exhibit similar vibrational closure to the small molecules demonstrated so far, and it is not yet known if the high vibrational-mode density of even larger species will eventually compromise optical cycling. Here, we systematically increase the size of hydrocarbon ligands attached to single alkaline-earth-phenoxides from (-H) to -C$_{14}$H$_{19}$ while measuring the vibrational branching fractions of the optical transition. We find that varying the ligand size from 1 to more than 30 atoms does not systematically reduce the cycle closure, which remains around 90%. Theoretical extensions to larger diamondoids and bulk diamond surface suggest that alkaline earth phenoxides may maintain the desirable scattering behavior as the system size grows further, with no indication of an upper limit., Comment: 9 pages, 5 figures, SI(34 pages)

Kidney cancer is a global health concern, and accurate assessment of patient frailty is crucial for optimizing surgical outcomes. This paper introduces AI Age Discrepancy, a novel metric derived from machine learning analysis of preoperative abdominal CT scans, as a potential indicator of frailty and postoperative risk in kidney cancer patients. This retrospective study of 599 patients from the 2023 Kidney Tumor Segmentation (KiTS) challenge dataset found that a higher AI Age Discrepancy is significantly associated with longer hospital stays and lower overall survival rates, independent of established factors. This suggests that AI Age Discrepancy may provide valuable insights into patient frailty and could thus inform clinical decision-making in kidney cancer treatment., Comment: 10 pages, 3 figures, 2 tables

Modern communication, navigation, and radar systems rely on low noise and frequency-agile microwave sources. In this application space, photonic systems provide an attractive alternative to conventional microwave synthesis by leveraging high spectral purity lasers and optical frequency combs to generate microwaves with exceedingly low phase noise. However, these photonic techniques suffer from a lack of frequency tunability, and also have substantial size, weight, and power requirements that largely limit their use to laboratory settings. In this work, we address these shortcomings with a hybrid opto-electronic approach that combines simplified optical frequency division with direct digital synthesis to produce tunable low-phase-noise microwaves across the entire X-band. This results in exceptional phase noise at 10 GHz of -156 dBc/Hz at 10 kHz offset and fractional frequency instability of 1x10^-13 at 0.1 s. Spot tuning away from 10 GHz by 500 MHz, 1 GHz, and 2 GHz, yields phase noise at 10 kHz offset of -150 dBc/Hz, -146 dBc/Hz, and -140 dBc/Hz, respectively. The synthesizer architecture is fully compatible with integrated photonic implementations that will enable a versatile microwave source in a chip-scale package. Together, these advances illustrate an impactful and practical synthesis technique that shares the combined benefits of low timing noise provided by photonics and the frequency agility of established digital synthesis.

Diatomic molecular codes [arXiv:1911.00099] are designed to encode quantum information in the orientation of a diatomic molecule, allowing error correction from small torques and changes in angular momentum. Here, we directly study noise native to atomic and molecular platforms -- spontaneous emission, stray electromagnetic fields, and Raman scattering -- and show that diatomic molecular codes fail against this noise. We derive simple necessary and sufficient conditions for codes to protect against such noise. We also identify existing and develop new absorption-emission (\AE) codes that are more practical than molecular codes, require lower average momentum, can directly protect against photonic processes up to arbitrary order, and are applicable to a broader set of atomic and molecular systems., Comment: 5+5 pages, 3 figures. Added appendix about non-locality of spontaneous decay

Polyatomic molecules equipped with optical cycling centers (OCCs), enabling continuous photon scattering during optical excitation, are exciting candidates for advancing quantum information science. However, as these molecules grow in size and complexity the interplay of complex vibronic couplings on optical cycling becomes a critical, but relatively unexplored consideration. Here, we present an extensive exploration of Fermi resonances in large OCC-containing molecules, surpassing the constraints of harmonic approximation. High-resolution dispersed laser-induced fluorescence and excitation spectroscopy reveal Fermi resonances in calcium and strontium phenoxides and their derivatives. This resonance manifests as vibrational coupling leading to intensity borrowing by combination bands near optically active harmonic bands. The resulting additional vibration-changing decays require more repumping lasers for effective optical cycling. To mitigate these effects, we explore altering vibrational energy level spacing through substitutions on the phenyl ring or changes in the OCC itself. While the complete elimination of vibrational coupling in complex molecules remains challenging, our findings underscore the potential for significant mitigation, opening new avenues for optimizing optical cycling in large polyatomic molecules., Comment: 8 pages, 4 figures, 1 table, SI (15 pages)

The $\textit{omg}$ protocol is a promising paradigm that uses multiple, application-specific qubit subspaces within the Hilbert space of each single atom during quantum information processing. A key assumption for $\textit{omg}$ operation is that a subspace can be accessed independently without deleterious effects on information stored in other subspaces. We find that intensity noise during laser-based quantum gates in one subspace can cause decoherence in other subspaces, potentially complicating $\textit{omg}$ operation. We show, however, that a magnetic-field-induced vector light shift can be used to eliminate this source of decoherence. As this technique requires simply choosing a certain, magnetic field dependent, polarization for the gate lasers it is straightforward to implement and potentially helpful for $\textit{omg}$ based quantum technology., Comment: 5 + 3 pages, 3 + 2 figures

We perform entanglement of spin and motional degrees of freedom of a single, ground-state trapped ion through the application of a $16$ ps laser pulse. The duration of the interaction is significantly shorter than both the motional timescale ($30$ $\mu$s) and spin precession timescale ($1$ ns) , demonstrating that neither sets a fundamental speed limit on this operation for quantum information processing. Entanglement is demonstrated through the collapse and revival of spin coherence as the spin components of the wavefunction separate and recombine in phase space. We infer the fidelity of these single qubit operations to be $(97^{+3}_{-4})\%$., Comment: 5 pages, 4 figures

Numerous modern technologies are reliant on the low-phase noise and exquisite timing stability of microwave signals. Substantial progress has been made in the field of microwave photonics, whereby low noise microwave signals are generated by the down-conversion of ultra-stable optical references using a frequency comb. Such systems, however, are constructed with bulk or fiber optics and are difficult to further reduce in size and power consumption. Our work addresses this challenge by leveraging advances in integrated photonics to demonstrate low-noise microwave generation via two-point optical frequency division. Narrow linewidth self-injection locked integrated lasers are stabilized to a miniature Fabry-P\'{e}rot cavity, and the frequency gap between the lasers is divided with an efficient dark-soliton frequency comb. The stabilized output of the microcomb is photodetected to produce a microwave signal at 20 GHz with phase noise of -96 dBc/Hz at 100 Hz offset frequency that decreases to -135 dBc/Hz at 10 kHz offset--values which are unprecedented for an integrated photonic system. All photonic components can be heterogeneously integrated on a single chip, providing a significant advance for the application of photonics to high-precision navigation, communication and timing systems.

Cooling of systems to sub-kelvin temperatures is usually done using either a cold bath of particles or spontaneous photon scattering from a laser field; in either case, cooling is driven by interaction with a well-ordered, cold (i.e. low entropy) system. However, there have recently been several schemes proposed for ``cooling by heating,'' in which raising the temperature of some mode drives the cooling of the desired system faster. We discuss how to cool a trapped ion to its motional ground state using unfiltered sunlight at $5800\,\mathrm{K}$ to drive the cooling. We show how to treat the statistics of thermal light in a single-mode fiber for delivery to the ion, and show experimentally how the black-body spectrum is strongly modified by being embedded in quasi-one-dimension. Quantitative estimates for the achievable cooling rate with our measured fiber-coupled, low-dimensional sunlight show promise for demonstrating this implementation of cooling by heating., Comment: 9 pages

${}^{133}\mathrm{Ba}^+$ is illuminated by a laser that is far-detuned from optical transitions, and the resulting spontaneous Raman scattering rate is measured. The observed scattering rate is lower than previous theoretical estimates. The majority of the discrepancy is explained by a more accurate treatment of the scattered photon density of states. This work establishes that, contrary to previous models, there is no fundamental limit to laser-driven quantum gates from laser-induced spontaneous Raman scattering., Comment: 4 + 2 pages, 4 + 1 figures

We study photon scattering errors in stimulated Raman driven quantum logic gates. For certain parameter regimes, we find that previous, simplified models of the process significantly overestimate the gate error rate due to photon scattering. This overestimate is shown to be due to previous models neglecting the detuning dependence of the scattered photon frequency and Lamb-Dicke parameter, a second scattering process, interference effects on scattering rates to metastable manifolds, and the counter-rotating contribution to the Raman transition rate. The resulting improved model shows that there is no fundamental limit on gate error due to photon scattering for electronic ground state qubits in commonly-used trapped-ion species when the Raman laser beams are red detuned from the main optical transition. Additionally, photon scattering errors are studied for qubits encoded in metastable $D_{5/2}$ manifold, showing that gate errors below $10^{-4}$ are achievable for all commonly-used trapped ions., Comment: 24 pages, 8 figures, to be submitted to Phys. Rev. A. In this version, we changed the two-qubit gate under consideration. Originally, we considered a gate driven by two perpendicular pairs of Raman beams. In this version, we consider a gate driven by a pair of Raman beams counterpropagating against a third Raman beam

We describe the encoding of multiple qubits per atom in trapped atom quantum processors and methods for performing both intra- and inter-atomic gates on participant qubits without disturbing the spectator qubits stored in the same atoms. We also introduce techniques for selective state preparation and measurement of individual qubits that leave the information encoded in the other qubits intact, a capability required for qubit quantum error correction. The additional internal states needed for polyqubit processing are already present in atomic processors, suggesting that the resource cost associated with this multiplicative increase in qubit number could be a good bargain in the short to medium term., Comment: 9 pages, 4 figures

Erasures, or errors with known locations, are a more favorable type of error for quantum error-correcting codes than Pauli errors. Converting physical noise into erasures can significantly improve the performance of quantum error correction. Here we apply the idea of performing erasure conversion by encoding qubits into metastable atomic states, proposed by Wu, Kolkowitz, Puri, and Thompson [Nat. Comm. 13, 4657 (2022)], to trapped ions. We suggest an erasure-conversion scheme for metastable trapped-ion qubits and develop a detailed model of various types of errors. We then compare the logical performance of ground and metastable qubits on the surface code under various physical constraints, and conclude that metastable qubits may outperform ground qubits when the achievable laser power is higher for metastable qubits., Comment: 20 pages, 8 figures

We report the production and spectroscopic characterization of strontium (I) phenoxide ($\mathrm{SrOC}_6\mathrm{H}_5$, or SrOPh) and variants featuring electron-withdrawing groups designed to suppress vibrational excitation during spontaneous emission from the electronically excited state. Optical cycling closure of these species, which is the decoupling of vibrational state changes from spontaneous optical decay, is found by dispersed laser-induced fluorescence spectroscopy to be high, in accordance with theoretical predictions. A high-resolution, rotationally-resolved laser excitation spectrum is recorded for SrOPh, allowing the estimation of spectroscopic constants and identification of candidate optical cycling transitions for future work. The results confirm the promise of strontium phenoxides for laser cooling and quantum state detection at the single-molecule level., Comment: Erratum for a correction of an incorrect grant number for the NSF Center for Chemical Innovation, Phase I. The correct number should be CHE-2221453

Sustainable Development Goal (SDG) Target 4.b calls to "substantially expand globally the number of scholarships" for enrollment in overseas higher education between 2015 and 2020. To advance knowledge on international scholarships and sustainability, this chapter examines notions of sustainability in literature related to international scholarships for students in the Global South. Based on an exploratory review of literature, ways that sponsored international student mobility -- programs, students, graduates, and networks -- maintain and sustain systems and outcomes are explored. Findings are presented through four frames: (a) programmatic sustainability, (b) organizational development, (c) national sustainable development, and (d) international and global actions. Challenges to sustainability, such as poor coordination between degrees earned and local market conditions, are also discussed. In addition, the findings point to several prominent ways that scholarships could contribute to sustainability that are mostly absent from the literature: transformative education for sustainable development, and international education for environmental sustainability. The chapter closes with a vision of alumni networks -- both within and among programs -- to work together to transform societies and tackle the most pernicious international challenges of our time. [This chapter was published in: "Annual Review of Comparative and International Education 2020," International Perspectives on Education and Society, Vol. 40, Emerald Publishing Limited, 2021, pp. 257-277.]

Molecular design principles provide guidelines for augmenting a molecule with a smaller group of atoms to realize a desired property or function. We demonstrate that these concepts can be used to create an optical cycling center that can be attached to a number of aromatic ligands, allowing the scattering of many photons from the resulting molecules without changing the molecular vibrational states. We provide further design principles that indicate the ability to expand this work. This represents a significant step towards a quantum functional group, which may serve as a generic qubit moiety that can be attached to a wide range of molecular structures and surfaces., Comment: 6 pages, 3 figures

Rapid and repeated photon cycling has enabled precision metrology and the development of quantum information systems using a variety of atoms and simple molecules. Extending optical cycling to structurally complex molecules would provide new capabilities in these areas, as well as in ultracold chemistry. Increased molecular complexity, however, makes realizing closed optical transitions more difficult. Building on the already established strong optical cycling of diatomic, linear triatomic, and symmetric top molecules, recent theoretical and experimental work has indicated that cycling will be extendable to phenol containing molecules, as well as other asymmetric species. The paradigm for these systems is the use of an optical cycling center bonded to a molecular ligand. Theory has suggested that cycling may be extended to even larger ligands, like naphthalene, pyrene and coronene. Here, we study the optical excitation and vibrational branching of the molecules CaO-2-naphthyl, SrO-2-naphthyl and CaO-1-naphthyl and find only weak decay to excited vibrational states, indicating a promising path to full quantum control and laser cooling of large arene-based molecules., Comment: 9 pages, 3 figures, 2 tables

Over the last 20 years, there has been an explosion of genomic data collected for disease association, functional analyses, and other large-scale discoveries. At the same time, there have been revolutions in cloud computing that enable computational and data science research, while making data accessible to anyone with a web browser and an internet connection. However, students at institutions with limited resources have received relatively little exposure to curricula or professional development opportunities that lead to careers in genomic data science. To broaden participation in genomics research, the scientific community needs to support students, faculty, and administrators at Underserved Institutions (UIs) including Community Colleges, Historically Black Colleges and Universities, Hispanic-Serving Institutions, and Tribal Colleges and Universities in taking advantage of these tools in local educational and research programs. We have formed the Genomic Data Science Community Network (http://www.gdscn.org/) to identify opportunities and support broadening access to cloud-enabled genomic data science. Here, we provide a summary of the priorities for faculty members at UIs, as well as administrators, funders, and R1 researchers to consider as we create a more diverse genomic data science community., Comment: 42 pages, 3 figures

Some III-V digital alloy avalanche photodiodes exhibit low excess noise. These alloys have low hole ionization coefficients due to presence of small 'minigaps', enhanced effective mass and large separation between light-hole and split-off bands in the valence band. In this letter, an explanation for the formation of the minigaps using a tight binding picture is provided. Furthermore, we demonstrate that decreasing substrate lattice constant can increase the minigap size and mass in the transport direction. This leads to reduced quantum tunneling and phonon scattering of the holes. Finally, we illustrate the band structure modification with substrate lattice constant for other III-V digital alloys.

The electronic, laser-induced fluorescence spectrum of the $B^2\Sigma^+\leftarrow X^2\Sigma^+$ transition in $^{28}$Si$^{16}$O$^+$ and $^{29}$Si$^{16}$O$^+$ has been recorded in a cryogenic buffer gas cell at $\approx$ 100 K. Molecular constants are extracted for both $^{28}$Si$^{16}$O$^+$ and $^{29}$Si$^{16}$O$^+$, including the Fermi contact hyperfine constant for both the $B$ and $X$ states of $^{29}$Si$^{16}$O$^+$, and used in a discussion of the suitability of SiO$^+$ in future quantum information experiments., Comment: 14 pages, 7 figures

Laser cooling of translational motion of small molecules is performed by addressing transitions that ensure spontaneous emission cannot cause net rotational excitation. This will not be possible once the rotational splitting becomes comparable to the operational excitation linewidth, as will occur for large molecules or wide bandwidth lasers. We show theoretically that in this regime, angular momentum transfer from red-detuned Doppler cooling light can also exert a damping torque on linear molecules, cooling rotation to the same Doppler limit (typically $\approx$ 500 $\mu$K for molecules with $\approx$ 10 ns excited-state lifetimes). This cooling process is derived from photon spin, and indicates that standard optical molasses can also cool molecular rotation with no additional experimental resources.

A series of III-V ternary and quarternary digital alloy avalanche photodiodes (APDs) have recently been seen to exhibit very low excess noise. Using band inversion of an environment-dependent atomistic tight binding description of short period superlattices, we argue that a combination of increased effective mass, minigaps and band split-off are primarily responsible for the observed superior performance. These properties significantly limit the ionization rate of one carrier type, either holes or electrons, making the avalanche multiplication process unipolar in nature. The unipolar behavior in turn reduces the stochasticity of the multiplication gain. The effects of band folding on carrier transport are studied using the Non-Equilibrium Green's Function Method that accounts for quantum tunneling, and Boltzmann Transport Equation model for scattering. It is shown here that carrier transport by intraband tunneling and optical phonon scattering are reduced in materials with low excess noise. Based on our calculations, we propose five simple inequalities that can be used to approximately evaluate the suitability of digital alloys for designing low noise photodetectors. We evaluate the performance of multiple digital alloys using these criteria and demonstrate their validity., Comment: 13 pages, 13 figures and 4 tables

Quantum computers, much like their classical counterparts, will likely benefit from flexible qubit encodings that can be matched to different tasks. For trapped ion quantum processors, a common way to access multiple encodings is to use multiple, co-trapped atomic species. Here, we outline an alternative approach that allows flexible encoding capabilities in single-species systems through the use of long-lived metastable states as an effective, programmable second species. We describe the set of additional trapped ion primitives needed to enable this protocol and show that they are compatible with large-scale systems that are already in operation.

Highly state-selective, weakly dissipative population transfer is used to irreversibly move the population of one ground state qubit level of an atomic ion to an effectively stable excited manifold with high fidelity. Subsequent laser interrogation accurately distinguishes these electronic manifolds, and we demonstrate a total qubit state preparation and measurement (SPAM) inaccuracy $\epsilon_\mathrm{SPAM} < 1.7 \times 10^{-4}$ ($-38 \mbox{ dB}$), limited by imperfect population transfer between qubit eigenstates. We show experimentally that full transfer would yield an inaccuracy less than $8.0 \times 10^{-5}$ ($-41 \mbox{ dB}$). The high precision of this method revealed a rare ($\approx 10^{-4}$) magnetic dipole decay induced error that we demonstrate can be corrected by driving an additional transition. Since this technique allows fluorescence collection for effectively unlimited periods, high fidelity qubit SPAM is achievable even with limited optical access and low quantum efficiency., Comment: 5 pages, 4 figures

Simple analytical expressions for estimation of second order output intercept point (OIP2) and third order output intercept point (OIP3) of surface normal uni-traveling carrier (UTC) and modified uni-traveling carrier (MUTC) photodiode (PD) are derived. These equations are valuable for estimation of OIP for high power (M)UTC-PDs during the design phase.

Trapped Be+ ions are a leading platform for quantum information science [1], but reactions with background gas species, such as H2 and H2O, result in qubit loss. Our experiment reveals that the BeOH+ ion is the final trapped ion species when both H2 and H2O exist in a vacuum system with cold, trapped Be+. To understand the loss mechanism, low-temperature reactions between sympathetically cooled BeD+ ions and H2O molecules have been investigated using an integrated, laser-cooled Be+ ion trap and high-resolution Time-of-Flight (TOF) mass spectrometer (MS) [2]. Among all the possible products,BeH2O+, H2DO+, BeOD+, and BeOH+, only the BeOH+ molecular ion was observed experimentally, with the assumed co-product of HD. Theoretical analyses based on explicitly correlated restricted coupled cluster singles, doubles, and perturbative triples (RCCSD(T)-F12) method with the augmented correlation-consistent polarized triple zeta (AVTZ) basis set reveal that two intuitive direct abstraction product channels, Be + H2DO+ and D + BeH2O+, are not energetically accessible at the present reaction temperature (~150 K). Instead, a double displacement BeOH+ + HD product channel is accessible due to a large exothermicity of 1.885 eV through a submerged barrier in the reaction pathway. While the BeOD+ + H2 product channel has a similar exothermicity, the reaction pathway is dynamically unfavourable, as suggested by a Sudden Vector Projection analysis. This work sheds light on the origin of the loss and contaminations of the laser-cooled Be+ ions in quantum-information experiments.

Quantum gates are typically vulnerable to imperfections in the classical control fields applied to physical qubits to drive the gates. One approach to reduce this source of error is to break the gate into parts, known as composite pulses (CPs), that typically leverage the constancy of the error over time to mitigate its impact on gate fidelity. Here we extend this technique to suppress secular drifts in Rabi frequency by regarding them as sums of power-law drifts whose first-order effects on over- or under-rotation of the state vector add linearly. Power-law drifts have the form $t^p$ where $t$ is time and the constant $p$ is its power. We show that composite pulses that suppress all power-law drifts with $p \leq n$ are also high-pass filters of filter order $n+1$ arXiv:1410.1624. We present sequences that satisfy our proposed power-law amplitude criteria, $\text{PLA}(n)$, obtained with this technique, and compare their simulated performance under time-dependent amplitude errors to some traditional composite pulse sequences. We find that there is a range of noise frequencies for which the $\text{PLA}(n)$ sequences provide more error suppression than the traditional sequences, but in the low frequency limit, non-linear effects become more important for gate fidelity than frequency roll-off. As a result, the previously known $F_1$ sequence, which is one of the two solutions to the $\text{PLA}(1)$ criteria and furnishes suppression of both linear secular drift and the first order nonlinear effects, is a sharper noise filter than any of the other $\text{PLA}(n)$ sequences in the low frequency limit.