Search

(Abridged) Molecular lines are commonly detected towards protostellar sources. However, to get a better understanding of the chemistry of these sources we need unbiased molecular surveys over a wide frequency range for as many sources as possible to shed light on the origin of this chemistry, particularly any influence from the external environment. We present results from the PILS-Cygnus survey of ten intermediate- to high-mass protostellar sources in the nearby Cygnus-X complex, through high angular resolution interferometric observations over a wide frequency range. Using the Submillimeter Array (SMA), a spectral line survey of ten sources was performed in the frequency range 329-361 GHz, with an angular resolution of $\sim$1\farcs5, ($\sim$2000 AU, source distance of 1.3 kpc). Spectral modelling was performed to identify molecular emission and determine column densities and excitation temperatures for each source. We detect CH$_3$OH towards nine of the ten sources, CH$_3$OCH$_3$ and CH$_3$OCHO towards three sources, and CH$_3$CN towards four sources. Towards five sources the chemistry is spatially differentiated (different species peak at different positions and are offset from the peak continuum emission). The chemical properties of each source do not correlate with their position in the Cygnus-X complex, nor do the distance or direction to the nearest OB associations. However, the five sources located in the DR21 filament do appear to show less line emission compared to the five sources outside the filament. This work shows how important wide frequency coverage observations are combined with high angular resolution observations for studying the protostellar environment. Based on the ten sources observed here, the external environment appears to only play a minor role in setting the chemical environment on these small scales ($<$ 2000 AU)., Comment: 19 pages, 77 pages appendices

(Abridged) Complex organic molecules (COMs) are commonly detected in and near star-forming regions. However, the dominant process in the release of these COMs from the icy grains - where they predominately form - to the gas phase is still an open question. We investigate the origin of COM emission in a protostellar source, CygX-N30, through high-angular-resolution interferometric observations over a continuous broad frequency range. We used 32 GHz Submillimeter Array observations with continuous frequency coverage from 329 to 361 GHz at an angular resolution of ~1" to do a line survey and obtain a chemical inventory of the source. The line emission was used to determine column densities and excitation temperatures for the COMs. We mapped out the intensity distribution of the different species and identified approximately 400 lines that can be attributed to 29 different molecular species and their isotopologues. We find that the molecular peak emission is along a linear gradient, coinciding with the axis of red- and blueshifted H2CO and CS emission. Chemical differentiation is detected along this gradient, with the O-bearing molecular species peaking towards one component of the system and the N- and S-bearing species peaking towards the other. The inferred column densities and excitation temperatures are compared to other sources where COMs are abundant. The origin of the observed COM emission is probably a combination of the young stellar sources along with accretion of infalling material onto a disc-like structure surrounding a young protostar. The low D/H ratio observed (<0.1%) likely reflects a pre-stellar phase where COMs formed on the ices at warm temperatures (~ 30 K), with inefficient deuterium fractionation. The observations and results presented here demonstrate the importance of good frequency coverage and high angular resolution when disentangling the origin of COM emission., Comment: 61 pages, 60 figures. To be published in Astronomy & Astrophysics

Complex organic molecules with three carbon atoms are found in the earliest stages of star formation. In particular, propenal (C$_2$H$_3$CHO) is a species of interest due to its implication in the formation of more complex species and even biotic molecules. This study aims to search for the presence of C$_2$H$_3$CHO and other three-carbon species such as propylene (C$_3$H$_6$) in the hot corino region of the low-mass protostellar binary IRAS 16293--2422 to understand their formation pathways. We use ALMA observations in Band 6 and 7 from various surveys to search for the presence of C$_3$H$_6$ and C$_2$H$_3$CHO towards the protostar IRAS 16293--2422 B (IRAS 16293B). We report the detection of both C$_3$H$_6$ and C$_2$H$_3$CHO towards IRAS 16293B, however, no unblended lines were found towards the other component of the binary system, IRAS 16293A. We derive column density upper limits for C$_3$H$_8$, HCCCHO, n-C$_3$H$_7$OH, i-C$_3$H$_7$OH, C$_3$O, and cis-HC(O)CHO towards IRAS 16293B. We then use a three-phase chemical model to simulate the formation of these species in a typical prestellar environment followed by its hydrodynamical collapse until the birth of the central protostar. Different formation paths, such as successive hydrogenation and radical-radical additions on grain surfaces, are tested and compared to the observational results. The simulations reproduce the abundances within one order of magnitude from those observed towards IRAS 16293B, with the best agreement found for a rate of $10^{-12}$ cm$^3$ s$^{-1}$ for the gas-phase reaction C$_3$ + O $\rightarrow$ C$_2$ + CO. Successive hydrogenations of C$_3$, HC(O)CHO, and CH$_3$OCHO on grain surfaces are a major and crucial formation route of complex organics molecules, whereas both successive hydrogenation pathways and radical-radical addition reactions contribute to the formation of C$_2$H$_5$CHO., Comment: Accepted for publication in A&A. 24 pages, 17 figures

Measuring polarization from thermal dust emission can provide constraints on the magnetic field structure around embedded protostars. However, interpreting the observations is challenging without models that consistently account for both the complexity of the protostellar birth environment and polarization mechanisms. We aim to provide a better understanding with a focus on bridge-like structures such as that observed towards the protostellar multiple IRAS 16293--2422 by comparing synthetic polarization maps of thermal reemission with observations. We analyze the magnetic field properties associated with the formation of a protostellar multiple based on ideal MHD 3D zoom-in simulations carried out with the RAMSES code. To compare with observations, we post-process a snapshot of a bridge-like structure that is associated with a forming triple star system with the radiative transfer code POLARIS and produce multi-wavelength dust polarization maps. In the most prominent bridge of our sample, the typical density is about 10^(-16) g cm^(-3), and the magnetic field strength is about 1 to 2 mG. The magnetic field structure has an elongated toroidal morphology and the dust polarization maps trace the complex morphology. In contrast, the magnetic field strength associated with the launching of asymmetric bipolar outflows is significantly more magnetized (~100 mG). At {\lambda}=1.3 mm, the orientation of grains in the bridge is similar for the case accounting for radiative alignment torques (RATs) compared to perfect alignment with magnetic field lines. However, the polarization fraction in the bridge is three times smaller for the RAT scenario compared to assuming perfect alignment. At shorter wavelengths ({\lambda} < 200 {\mu}m), dust polarization does not trace the magnetic field because other effects such as self-scattering and dichroic extinction dominate the orientation of the polarization., Comment: 18 pages, 12 figures plus 3 figures in the appendix, accepted for publication in A&A

The collapse of the protostellar envelope results in the growth of the protostar and the development of a protoplanetary disk, playing a critical role during the early stages of star formation. Characterizing the gas infall in the envelope constrains the dynamical models of star formation. We present unambiguous signatures of infall, probed by optically thick molecular lines, toward an isolated embedded protostar, BHR 71 IRS1. The three dimensional radiative transfer calculations indicate that a slowly rotating infalling envelope model following the "inside-out" collapse reproduces the observations of both HCO$^{+}$ $J=4\rightarrow3$ and CS $J=7\rightarrow6$ lines, and the low velocity emission of the HCN $J=4\rightarrow3$ line. The envelope has a model-derived age of 12000$\pm$3000 years after the initial collapse. The envelope model underestimates the high velocity emission at the HCN $J=4\rightarrow3$ and H$^{13}$CN $J=4\rightarrow3$ lines, where outflows or a Keplerian disk may contribute. The ALMA observations serendipitously discover the emission of complex organic molecules (COMs) concentrated within a radius of 100 au, indicating that BHR 71 IRS1 harbors a hot corino. Eight species of COMs are identified, including CH$_{3}$OH and CH$_{3}$OCHO, along with H$_{2}$CS, SO$_{2}$ and HCN $v_{2}=1$. The emission of methyl formate and $^{13}$C-methanol shows a clear velocity gradient within a radius of 50 au, hinting at an unresolved Keplerian rotating disk., Comment: 42 pages, 38 figures, accepted for publication in ApJ

Complex organic molecules (COM) are detected in many sources in the warm inner regions of envelopes surrounding deeply embedded protostars. Exactly how these COM form remains an open question. This study aims to constrain the formation of complex organic molecules through comparisons of their abundances towards the Class 0 protostellar binary IRAS 16293-2422 (IRAS16293). We utilised observations from the ALMA Protostellar Interferometric Line Survey of IRAS16293. The species identification and the rotational temperature and column density estimation were derived by fitting the extracted spectra towards IRAS16293 A and IRAS16293 B with synthetic spectra. The majority of the work in this paper pertains to the analysis of IRAS16293 A for a comparison with the results from the other binary component, which have already been published. We detect 15 different COM, as well as 16 isotopologues towards the most luminous companion protostar IRAS16293 A. Tentative detections of an additional 11 isotopologues are reported. We also searched for and report on the first detections of CH3OCH2OH and t-C2H5OCH3 towards IRAS16293 B and the follow-up detection of CH2DCHO and CH3CDO. Twenty-four lines of CHD2OH are also identified. The comparison between the two protostars of the binary system shows significant differences in abundance for some of the species, which are partially correlated to their spatial distribution. The spatial distribution is consistent with the sublimation temperature of the species; those with higher expected sublimation temperatures are located in the most compact region of the hot corino towards IRAS16293 A. This spatial differentiation is not resolved in IRAS16293 B and will require observations at a higher angular resolution. In parallel, the list of identified CHD2OH lines shows the need of accurate spectroscopic data including their line strength., Comment: Accepted for publication in A&A. 31 pages, 17 figures

Context. Propyne (CH$_3$CCH) has been detected in a variety of environments, from Galactic star-forming regions to extragalactic sources. Such molecules are excellent tracers of the physical conditions in star-forming regions. Aims. This study explores the emission of CH$_3$CCH in the low-mass protostellar binary, IRAS 16293$-$2422, examining the spatial scales traced by this molecule, as well as its formation and destruction pathways. Methods. ALMA observations from the Protostellar Interferometric Line Survey (PILS) are used to determine the abundances and excitation temperatures of CH$_3$CCH towards both protostars, exploring spatial scales from 70 to 2400 au. The three-phase chemical kinetics model MAGICKAL is also used, to explore the chemical reactions of this molecule. Results. CH$_3$CCH is detected towards both IRAS 16293A and IRAS 16293B and is found to trace the hot corino component around each source in the PILS dataset. Eighteen transitions above 3$\sigma$ are detected, enabling robust excitation temperatures and column densities to be determined in each source. In IRAS 16293A, an excitation temperature of 90 K and a column density of 7.8$\times$10$^{15}$ cm$^{-2}$ best fits the spectra. In IRAS 16293B, an excitation temperature of 100 K and 6.8$\times$10$^{15}$ cm$^{-2}$ best fits the spectra. The chemical modelling finds that in order to reproduce the observed abundances, both gas-phase and grain-surface reactions are needed. Conclusions. CH$_3$CCH is a molecule whose brightness and abundance in many different regions can be utilised to provide a benchmark of molecular variation with the physical properties of star-forming regions. It is essential when making such comparisons, that the abundances are determined with a good understanding of the spatial scale of the emitting region, to ensure that accurate abundances are derived., Comment: Accepted for publication in Astronomy & Astrophysics

[Abridged] The majority of stars form in binary or higher order systems. The Class 0 protostellar system IRAS16293-2422 contains two protostars, 'A' and 'B', separated by ~600 au and embedded in a single, 10^4 au scale envelope. Their relative evolutionary stages have been debated. We aim to study the relation and interplay between the two protostars A and B at spatial scales of 60 to ~1000 au. We selected molecular gas line transitions of CO, H2CO, HCN, CS, SiO, and CCH from the ALMA-PILS spectral imaging survey (329-363 GHz) and used them as tracers of kinematics, density, and temperature in the IRAS16293-2422 system. The angular resolution of the PILS data set allows us to study these quantities at a resolution of 0.5 arcsec (60 au [..]). Line-of-sight velocity maps of both optically thick and optically thin molecular lines reveal: (i) new manifestations of previously known outflows emanating from protostar A; (ii) a kinematically quiescent bridge of dust and gas spanning between the two protostars, with an inferred density between 4 10^4 and 3 10^7 cm^-3; and (iii) a separate, straight filament seemingly connected to protostar B seen only in CCH, with a flat kinematic signature. Signs of various outflows, all emanating from source A, are evidence of high-density and warmer gas; none of them coincide spatially and kinematically with the bridge. We hypothesize that the bridge arc is a remnant of filamentary substructure in the protostellar envelope material from which protostellar sources A and B have formed. One particular morphological structure appears to be due to outflowing gas impacting the quiescent bridge material. The continuing lack of clear outflow signatures unambiguously associated to protostar B and the vertically extended shape derived for its disk-like structure lead us to conclude that source B may be in an earlier evolutionary stage than source A., Comment: Accepted for publication in A&A. 27 pages, 24 figures

Nitrogen oxides are thought to play a significant role as a nitrogen reservoir and to potentially participate in the formation of more complex species. Until now, only NO, N$_2$O and HNO have been detected in the interstellar medium. We report the first interstellar detection of nitrous acid (HONO). Twelve lines were identified towards component B of the low-mass protostellar binary IRAS~16293--2422 with the Atacama Large Millimeter/submillimeter Array, at the position where NO and N$_2$O have previously been seen. A local thermodynamic equilibrium model was used to derive the column density ($\sim$ 9 $\times$ 10$^{14}$ cm$^{-2}$ in a 0.5'' beam) and excitation temperature ($\sim$ 100 K) of this molecule. HNO, NO$_2$, NO$^+$, and HNO$_3$ were also searched for in the data, but not detected. We simulated the HONO formation using an updated version of the chemical code Nautilus and compared the results with the observations. The chemical model is able to reproduce satisfactorily the HONO, N$_2$O, and NO$_2$ abundances, but not the NO, HNO, and NH$_2$OH abundances. This could be due to some thermal desorption mechanisms being destructive and therefore limiting the amount of HNO and NH$_2$OH present in the gas phase. Other options are UV photodestruction of these species in ices or missing reactions potentially relevant at protostellar temperatures., Comment: Accepted in A&A Letters

Studies of deuterated isotopologues of complex organic molecules can provide important constraints on their origin in regions of star formation. In particular, the abundances of deuterated species are very sensitive to the physical conditions in the environment where they form. Due to the low temperatures in regions of star formation, these isotopologues are enhanced to significant levels, making detections of multiply-deuterated species possible. However, for complex organic species, only the multiply-deuterated variants of methanol and methyl cyanide have been reported so far. The aim of this paper is to initiate the characterisation of multiply-deuterated variants of complex organic species with the first detection of doubly-deuterated methyl formate, CHD2OCHO. We use ALMA observations from the Protostellar Interferometric Line Survey (PILS) of the protostellar binary IRAS 16293-2422, in the spectral range of 329.1 GHz to 362.9 GHz. We report the first detection of doubly-deuterated methyl formate CHD2OCHO in the ISM. The D/H ratio of CHD2OCHO is found to be 2-3 times higher than the D/H ratio of CH2DOCHO for both sources, similar to the results for formaldehyde from the same dataset. The observations are compared to a gas-grain chemical network coupled to a dynamical physical model, tracing the evolution of a molecular cloud until the end of the Class 0 protostellar stage. The overall D/H ratio enhancements found in the observations are of the same order of magnitude as the predictions from the model for the early stages of Class 0 protostars. However, the higher D/H ratio of CHD2OCHO compared to the D/H ratio of CH2DOCHO is still not predicted by the model. This suggests that a mechanism is enhancing the D/H ratio of singly- and doubly-deuterated methyl formate that is not in the model, e.g. mechanisms for H-D substitutions., Comment: Accepted for publication in A&A

This paper presents a systematic survey of the deuterated and 13C isotopologues of a variety of oxygen-bearing complex organic molecules on Solar System scales toward the protostar IRAS 16293-2422B. We use the data from an unbiased molecular line survey between 329 and 363 GHz from the Atacama Large Millimeter/submillimeter Array (ALMA). The observations probe scales of 60 AU where most of the organic molecules have sublimated off dust grains and are present in the gas-phase. The complex organic molecules can be divided into two groups with one group, the simpler species, showing a D/H ratio of approximately 2% and the other, the more complex species, D/H ratios of 4-8%. This division may reflect the formation time of each species in the ices before or during warm-up/infall of material through the protostellar envelope. No significant differences are seen in the deuteration of different functional groups for individual species, possibly a result of the short time-scale for infall through the innermost warm regions where exchange reactions between different species may be taking place. The species show differences in excitation temperatures between 125 K and 300 K. This likely reflects the binding energies/sublimation temperatures of the individual species, in good agreement to what has previously been found for high-mass sources. For dimethyl ether, the 12C/13C ratio is found to be lower by up to a factor of 2 compared to typical ISM values similar to what has previously been inferred for glycolaldehyde. The results point to the importance of ice surface chemistry for the formation of these complex organic molecules at different stages in the evolution of embedded protostars and demonstrate the use of accurate isotope measurements for understanding the history of individual species., Comment: Accepted for publication in A&A. Abstract abridged

Hydroxylamine (NH$_{2}$OH) and methylamine (CH$_{3}$NH$_{2}$) have both been suggested as precursors to the formation of amino acids and are therefore of interest to prebiotic chemistry. Their presence in interstellar space and formation mechanisms, however, are not well established. We aim to detect both amines and their potential precursor molecules NO, N$_{2}$O and CH$_{2}$NH towards the low-mass protostellar binary IRAS 16293--2422, in order to investigate their presence and constrain their interstellar formation mechanisms around a young Sun-like protostar. ALMA observations from the unbiased, high angular resolution and sensitivity Protostellar Interferometric Line Survey (PILS) are used. Spectral transitions of the molecules under investigation are searched for with the CASSIS line analysis software. CH$_2$NH and N$_{2}$O are detected for the first time towards a low-mass source, the latter molecule through confirmation with the single-dish TIMASSS survey. NO is also detected. CH$_{3}$NH$_{2}$ and NH$_{2}$OH are not detected and stringent upper limit column densities are determined. The non-detection of CH$_{3}$NH$_{2}$ and NH$_{2}$OH limits the importance of formation routes to amino acids involving these species. The detection of CH$_{2}$NH makes amino acid formation routes starting from this molecule plausible. The low abundances of CH$_2$NH and CH$_{3}$NH$_{2}$ compared to Sgr B2 indicate that different physical conditions influence their formation in low- and high-mass sources., Comment: Accepted for publication in A&A

Methyl isocyanide (CH$_3$NC) is the isocyanide with the largest number of atoms confirmed in the interstellar medium (ISM), but it is not an abundant molecule, having only been detected towards a handful of objects. Conversely, its isomer, methyl cyanide (CH$_3$CN), is one of the most abundant complex organic molecules detected in the ISM, with detections in a variety of low- and high-mass sources. We use ALMA observations from the Protostellar Interferometric Line Survey (PILS) to search for methyl isocyanide and compare its abundance with that of its isomer methyl cyanide. We use a new line catalogue from the Cologne Database for Molecular Spectroscopy (CDMS) to identify methyl isocyanide lines. We also model the chemistry with an updated version of the three-phase chemical kinetics model {\em MAGICKAL}, presenting the first chemical modelling of methyl isocyanide to date. We detect methyl isocyanide for the first time in a solar-type protostar, IRAS 16293$-$2422 B, and present upper limits for its companion protostar, IRAS 16293$-$2422 A. Methyl isocyanide is found to be at least 20 times more abundant in source B compared to source A, with a CH$_3$CN/CH$_3$NC abundance ratio of 200 in IRAS 16293--2422 B and >5517 in IRAS 16293$-$2422 A. We also present the results of a chemical model of methyl isocyanide chemistry in both sources, and discuss the implications on methyl isocyanide formation mechanisms and the relative evolutionary stages of both sources., Comment: Accepted to A&A on 5th July 2018

Complex organic molecules are readily detected in the inner regions of the gaseous envelopes of forming protostars. In particular, molecules that contain nitrogen are interesting due to the role nitrogen plays in the development of life and the compact scales such molecules have been found to trace around forming protostars. The goal of this work is to determine the inventory of one family of nitrogen-bearing organic molecules, complex nitriles (molecules with a $-$CN functional group) towards two hot corino sources in the low-mass protostellar binary IRAS 16293$-$2422. This work explores the abundance differences between the two sources, the isotopic ratios, and the spatial extent derived from molecules containing the nitrile functional group. Using data from the Protostellar Interferometric Line Survey (PILS) obtained with ALMA we determine abundances and excitation temperatures for the detected nitriles. We also present a new method for determining the spatial structure of sources with high line density and large velocity gradients $-$ Velocity-corrected INtegrated emission (VINE) maps. We detect methyl cyanide (CH$_3$CN) as well as 5 of its isotopologues, including the detection of CHD$_2$CN which is the first detection in the ISM. We also detect ethyl cyanide (C$_2$H$_5$CN), vinyl cyanide (C$_2$H$_3$CN), and cyanoacetylene (HC$_3$N). We find that abundances are similar between IRAS 16293A and IRAS 16293B on small scales except for vinyl cyanide which is only detected towards the latter source. This suggests an important difference between the sources either in their evolutionary stage or warm-up timescales. We also detect a spatially double-peaked emission for the first time in molecular emission in the A source, suggesting that this source is showing structure related to a rotating toroid of material., Comment: A&A accepted 24th April 2018

Searches for the prebiotically-relevant cyanamide (NH$_2$CN) towards solar-type protostars have not been reported in the literature. We here present the first detection of this species in the warm gas surrounding two solar-type protostars, using data from the Atacama Large Millimeter/Submillimeter Array Protostellar Interferometric Line Survey (PILS) of IRAS 16293-2422 B and observations from the IRAM Plateau de Bure Interferometer of NGC1333 IRAS2A. We furthermore detect the deuterated and $^{13}$C isotopologues of NH$_2$CN towards IRAS 16293-2422 B. This is the first detection of NHDCN in the interstellar medium. Based on a local thermodynamic equilibrium analysis, we find that the deuteration of cyanamide ($\sim$ 1.7%) is similar to that of formamide (NH$_2$CHO), which may suggest that these two molecules share NH$_2$ as a common precursor. The NH$_2$CN/NH$_2$CHO abundance ratio is about 0.2 for IRAS 16293-2422 B and 0.02 for IRAS2A, which is comparable to the range of values found for Sgr B2. We explored the possible formation of NH$_2$CN on grains through the NH$_2$ + CN reaction using the chemical model MAGICKAL. Grain-surface chemistry appears capable of reproducing the gas-phase abundance of NH$_2$CN with the correct choice of physical parameters., Comment: Accepted in A&A

Context. The Class 0 protostellar binary IRAS 16293-2422 is an interesting target for (sub)millimeter observations due to, both, the rich chemistry toward the two main components of the binary and its complex morphology. Its proximity to Earth allows the study of its physical and chemical structure on solar system scales using high angular resolution observations. Such data reveal a complex morphology that cannot be accounted for in traditional, spherical 1D models of the envelope. Aims. The purpose of this paper is to study the environment of the two components of the binary through 3D radiative transfer modeling and to compare with data from the Atacama Large Millimeter/submillimeter Array. Such comparisons can be used to constrain the protoplanetary disk structures, the luminosities of the two components of the binary and the chemistry of simple species. Methods. We present 13CO, C17O and C18O J=3-2 observations from the ALMA Protostellar Interferometric Line Survey (PILS), together with a qualitative study of the dust and gas density distribution of IRAS 16293-2422. A 3D dust and gas model including disks and a dust filament between the two protostars is constructed which qualitatively reproduces the dust continuum and gas line emission. Results and conclusions. Radiative transfer modeling of source A and B, with the density solution of an infalling, rotating collapse or a protoplanetary disk model, can match the constraints for the disk-like emission around source A and B from the observed dust continuum and CO isotopologue gas emission. If a protoplanetary disk model is used around source B, it has to have an unusually high scale-height in order to reach the dust continuum peak emission value, while fulfilling the other observational constraints. Our 3D model requires source A to be much more luminous than source B; LA ~ 18 $L_\odot$ and LB ~ 3 $L_\odot$., Comment: Accepted for publication in Astronomy and Astrophysics, 20 pages, 12 figures

[abridged] The enhanced degrees of deuterium fractionation observed in envelopes around protostars demonstrate the importance of chemistry at low temperatures, relevant in pre- and protostellar cores. formaldehyde is an important species in the formation of methanol and more complex molecules. Here, we present the first study of formaldehyde deuteration on small scales around the prototypical low-mass protostar IRAS 16293-2422 using high spatial and spectral resolution Atacama Large Millimeter/submillimeter Array (ALMA) observations. Numerous isotopologues of formaldehyde are detected, among them H$_2$C$^{17}$O, and D$_2^{13}$CO for the first time in the ISM. The large range of upper energy levels covered by the HDCO lines help constrain the excitation temperature to 106$\pm$13 K. Using the derived column densities, formaldehyde shows a deuterium fractionation of HDCO/H$_2$CO=6.5$\pm$1%, D$_2$CO/HDCO=12.8$^{+3.3}_{-4.1}$%, and D$_2$CO/H$_2$CO=0.6(4)$\pm$0.1%. The isotopic ratios derived are $^{16}$O/$^{18}$O=805, $^{18}$O/$^{17}$O=3.2 and $^{12}$C/$^{13}$C=56. The HDCO/H$_2$CO ratio is lower than found in previous studies, highlighting the uncertainties involved in interpreting single dish observations of the inner warm regions. The D$_2$CO/HDCO ratio is only slightly larger than the HDCO/H$_2$CO ratio. This is consistent with formaldehyde forming in the ice as soon as CO has frozen onto the grains, with most of the deuteration happening towards the end of the prestellar core phase. A comparison with available time-dependent chemical models indicates that the source is in the early Class 0 stage., Comment: Accepted for publication in Astronomy and Astrophysics, 14 pages, 10 figures

Methyl isocyanate (CH$_{3}$NCO) belongs to a select group of interstellar molecules considered to be relevant precursors in the formation of larger organic compounds, including those with peptide bonds. The molecule has only been detected in a couple of high-mass protostars and potentially on comets. A formation route on icy grains has been postulated for this molecule but experimental evidence is lacking. Here we extend the range of environments where methyl isocyanate is found, and unambiguously identify CH$_{3}$NCO through the detection of 43 unblended transitions in the ALMA Protostellar Interferometric Line Survey (PILS) of the low mass solar-type protostellar binary IRAS 16293-2422. The molecule is detected toward both components of the binary with a ratio HNCO/CH$_3$NCO $\sim$4--12. The isomers CH$_{3}$CNO and CH$_3$OCN are not identified, resulting in upper abundance ratios of CH$_{3}$NCO/CH$_{3}$CNO > 100 and CH$_{3}$NCO/CH$_3$OCN > 10. The resulting abundance ratios compare well with those found for related N-containing species toward high-mass protostars. To constrain its formation, a set of cryogenic UHV experiments is performed. VUV irradiation of CH$_{4}$:HNCO mixtures at 20 K strongly indicate that methyl isocyanate can be formed in the solid-state through CH$_{3}$ and (H)NCO recombinations. Combined with gas-grain models that include this reaction, the solid-state route is found to be a plausible scenario to explain the methyl isocyanate abundances found in IRAS 16293-2422., Comment: Accepted 2017 April 7. Received 2017 March 26; in original form 2017 January 24. 13 pages, 8 figures

One of the open questions in astrochemistry is how complex organic and prebiotic molecules are formed. Aims. Our aim is to start the process of compiling an inventory of oxygen-bearing complex organic molecules toward the solar-type Class 0 protostellar binary IRAS16293-2422 from an unbiased spectral survey with ALMA (PILS). Here we focus on the new detections of ethylene oxide (c-C$_2$H$_4$O), acetone (CH$_3$COCH$_3$), and propanal (C$_2$H$_5$CHO). Methods. With ALMA, we surveyed the spectral range from 329 to 363 GHz at 0.5$"$ (60 AU diameter) resolution. Using a simple model for the molecular emission in LTE, the excitation temperatures and column densities of each species were constrained. Results. We successfully detect propanal (44 lines), ethylene oxide (20 lines) and acetone (186 lines) toward one component of the protostellar binary, IRAS16293B. The high resolution maps demonstrate that the emission for all investigated species originates from the compact central region close to the protostar. This, along with a derived common excitation temperature of $\sim$ 125 K, is consistent with a coexistence of these molecules in the same gas. Conclusions. The observations mark the first detections of acetone, propanal and ethylene oxide toward a low-mass protostar. The relative abundance ratios of the two sets of isomers (CH$_3$COCH$_3$/C$_2$H$_5$CHO $\sim$ 8 and CH$_3$CHO/c-C$_2$H$_4$O $\sim$ 12) are comparable to previous observations toward high-mass protostars. The majority of observed abundance ratios from these results as well as those measured toward high-mass protostars are up to an order of magnitude above the predictions from chemical models. This may reflect either missing reactions or uncertain rates in the chemical networks. The physical conditions, such as temperatures or densities, used in the models, may not be applicable to solar-type protostars either., Comment: Accepted in A&A

The inner regions of the envelopes surrounding young protostars are characterised by a complex chemistry, with prebiotic molecules present on the scales where protoplanetary disks eventually may form. This paper introduces a systematic survey, "Protostellar Interferometric Line Survey (PILS)" of the Class 0 protostellar binary IRAS 16293-2422 using the Atacama Large Millimeter/submillimeter Array (ALMA). The survey covers the full frequency range from 329 to 363 GHz (0.8 mm) with additional targeted observations at 3.0 and 1.3 mm. More than 10,000 features are detected toward one component in the protostellar binary. Glycolaldehyde, its isomers, methyl formate and acetic acid, and its reduced alcohol, ethylene glycol, are clearly detected. For ethylene glycol both lowest state conformers, aGg' and gGg', are detected, the latter for the first time in the ISM. The abundance of glycolaldehyde is comparable to or slightly larger than that of ethylene glycol. In comparison to the Galactic Center, these two species are over-abundant relative to methanol, possibly an indication of formation at low temperatures in CO-rich ices. Both 13C and deuterated isotopologues of glycolaldehyde are detected, also for the first time ever in the ISM. For the deuterated species, a D/H ratio of approximately 5% is found with no differences between the deuteration in the different functional groups of glycolaldehyde. Measurements of the 13C-species lead to a 12C:13C ratio of approximately 30, lower than the typical ISM value. This low ratio may reflect an enhancement of 13CO in the ice due to either ion-molecule reactions in the gas before freeze-out or differences in the temperatures where 12CO and 13CO ices sublimate. The results reinforce the importance of low-temperature grain surface chemistry for the formation of prebiotic molecules seen here in the gas after sublimation of the entire ice mantle., Comment: Accepted for publication in A&A. Abstract abridged

Formamide (NH$_2$CHO) has previously been detected in several star-forming regions and is thought to be a precursor for different prebiotic molecules. Its formation mechanism is still debated, however. Observations of formamide, related species and their isopotologues may provide useful clues to the chemical pathways leading to their formation. The Protostellar Interferometric Line Survey (PILS) represents an unbiased high angular resolution and sensitivity spectral survey of the low-mass protostellar binary IRAS 16293-2422 with the Atacama Large Millimeter/submillimeter Array (ALMA). We detect for the first time the three singly deuterated forms of NH$_2$CHO (NH$_2$CDO, cis- and trans-NHDCHO) as well as DNCO towards the component B of this binary source. The images reveal that the different isotopologues are all present in the same region. Based on observations of the $^{13}$C isotopologues of formamide and a standard $^{12}$C/$^{13}$C ratio, the deuterium fractionation is found to be similar for the three different forms with a value of about 2%. The DNCO/HNCO ratio is also comparable to the D/H ratio of formamide ($\sim$1%). These results are in agreement with the hypothesis that NH$_2$CHO and HNCO are chemically related through grain surface formation., Comment: Accepted in A&A Letters

New laboratory data of CH$_2$CHCN (vinyl cyanide) in its ground and vibrationally excited states at the microwave to THz domain allow searching for these excited state transitions in the Orion-KL line survey. Frequency-modulated spectrometers combined into a single broadband 50-1900 GHz spectrum provided measurements of CH$_2$CHCN covering a spectral range of 18-1893 GHz, whose assignments was confirmed by Stark modulation spectra in the 18-40 GHz region and by ab-initio anharmonic force field calculations. For analyzing the emission lines of CH$_2$CHCN species detected in Orion-KL we used the excitation and radiative transfer code (MADEX) at LTE conditions. The rotational transitions of the ground state of this molecule emerge from four cloud components of hot core nature which trace the physical and chemical conditions of high mass star forming regions in the Orion-KL Nebula. The total column density of CH$_2$CHCN in the ground state is (3.0$\pm$0.9)x10$^{15}$ cm$^{-2}$. We report on the first interstellar detection of transitions in the v10=1/(v11=1,v15=1) dyad in space, and in the v11=2 and v11=3 states in Orion-KL. The lowest energy vibrationally excited states of vinyl cyanide such as v11=1 (at 328.5 K), v15=1 (at 478.6 K), v11=2 (at 657.8 K), the v10=1/(v11=1,v15=1) dyad (at 806.4/809.9 K), and v11=3 (at 987.9 K) are populated under warm and dense conditions, so they probe the hottest parts of the Orion-KL source. Column density and rotational and vibrational temperatures for CH$_2$CHCN in their ground and excited states, as well as for the isotopologues, have been constrained by means of a sample of more than 1000 lines in this survey. Moreover, we present the detection of methyl isocyanide (CH$_3$NC) for the first time in Orion-KL and a tentative detection of vinyl isocyanide (CH$_2$CHNC) and give column density ratios between the cyanide and isocyanide isomers., Comment: 46 pages, 22 figures, 14 tables, 9 online tables