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The Martian climate is governed by an annual cycle, that results in the condensation of CO$_{2}$ ice during winter, up to a meter thick at the pole and thousands of kilometers in extension. Water and dust may be trapped during the condensation and freed during the sublimation. In addition, ice may be translucent or granular depending on the deposition process (snow vs direct condensation), annealing efficiency, and dust sinking process. The determination of ice translucency is of particular interest to confirm or reject the cold jet model (also known as Kieffer model). This work is focused on the dune field of Richardson Crater in which strong interactions between the water, dust and CO$_{2}$ cycles are observed. We analyzed CRISM hyperspectral images in the near IR using radiative transfer model inversion. We demonstrate that among the states of CO$_{2}$ ice, the translucent state is observed most frequently. The monitoring of surface characteristics shows a decrease in the thickness of the ice during the spring consistently with climate models simulations. We estimate a very low dust content of a few ppmv into the CO$_{2}$ ice, consistent with the formation scenario of cold jets. The water impurities is around 0.1\%v, almost stable during the spring, suggesting a water escape from the surface of subliming CO$_{2}$ ice layer. The water ice grain size varies in a range 1 to 50 microns. From these results, we propose the following new mechanism of small water ice grain suspension: as a cold jet occurs, water ice grains of various sizes are lifted from the surface. These jets happen during daytime, when the general upward gas flux from the subliming CO$_{2}$ ice layer is strong enough to carry the smaller grains, while the bigger fall back on the CO$_{2}$ ice layer. The smaller water grains are carried away and integrated to the general atmospheric circulation., Comment: Preprind accepted in Icarus (19/06/2018)

The origin of the martian methane is still poorly understood. A plausible explanation is that methane could have been produced either by hydrothermal alteration of basaltic crust or by serpentinization of ultramafic rocks producing hydrogen and reducing crustal carbon into methane. Once formed, methane storage on Mars is commonly associated with the presence of hidden clathrate reservoirs. Here, we alternatively suggest that chabazite and clinoptilolite, which belong to the family of zeolites, may form a plausible storage reservoir of methane in the martian subsurface. Because of the existence of many volcanic terrains, zeolites are expected to be widespread on Mars and their Global Equivalent Layer may range up to more than $\sim$1 km, according to the most optimistic estimates. If the martian methane present in chabazite and clinoptilolite is directly sourced from an abiotic source in the subsurface, the destabilization of a localized layer of a few millimeters per year may be sufficient to explain the current observations. The sporadic release of methane from these zeolites requires that they also remained isolated from the atmosphere during its evolution. The methane release over the ages could be due to several mechanisms such as impacts, seismic activity or erosion. If the methane outgassing from excavated chabazite and/or clinoptilolite prevails on Mars, then the presence of these zeolites around Gale Crater could explain the variation of methane level observed by Mars Science Laboratory., Comment: Accepted for publication in Icarus

We review the reservoirs of methane clathrates that may exist in the different bodies of the Solar System. Methane was formed in the interstellar medium prior to having been embedded in the protosolar nebula gas phase. This molecule was subsequently trapped in clathrates that formed from crystalline water ice during the cooling of the disk and incorporated in this form in the building blocks of comets, icy bodies, and giant planets. Methane clathrates may play an important role in the evolution of planetary atmospheres. On Earth, the production of methane in clathrates is essentially biological, and these compounds are mostly found in permafrost regions or in the sediments of continental shelves. On Mars, methane would more likely derive from hydrothermal reactions with olivine-rich material. If they do exist, martian methane clathrates would be stable only at depth in the cryosphere and sporadically release some methane into the atmosphere via mechanisms that remain to be determined.

Motivated by the possibility of comparing theoretical predictions of Lake Vostok's composition with future in situ measurements, we investigate the composition of clathrates that are expected to form in this environment from the air supplied to the lake by melting ice. In order to establish the best possible correlation between the lake water composition with that of air clathrates formed in situ, we use a statistical thermodynamic model based on the description of the guest-clathrate interaction by a spherically averaged Kihara potential with a nominal set of potential parameters. We determine the fugacities of the different volatiles present in the lake by defining a "pseudo" pure substance dissolved in water owning the average properties of the mixture and by using the Redlich-Kwong equation of state to mimic its thermodynamic behavior. Irrespective of the clathrate structure considered in our model, we find that xenon and krypton are strongly impoverished in the lake water (a ratio in the 0.04--0.1 range for xenon and a ratio in the $\sim$0.15--0.3 range for krypton), compared to their atmospheric abundances. Argon and methane are also found depleted in the Lake Vostok water by factors in the 0.5--0.95 and 0.3--0.5 ranges respectively, compared to their atmospheric abundances. On the other hand, the carbone dioxide abundance is found substantially enriched in the lake water compared to its atmospheric abundance (by a factor in the 1.6--5 range at 200 residence times). The comparison of our predictions of the CO$_2$ and CH$_4$ mole fractions in Lake Vostok with future in situ measurements will allow disentangling between the possible supply sources., Comment: Accepted for publication in Astrobiology