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The ocean industries are characterized by being export-driven. The exports of ocean industries (hereafter termed ocean exports) caused environmental pollution with amounts of CO2 emissions and thereby affected climate change. There is a need, therefore, for accurate assessments of CO2 emissions embodied in ocean exports--which can help policymakers adopt targeted emissionreduction measures to formulate sustainable ocean policies. However, few studies of ocean-industry emissions considered impacts in sectoral and trade pattern heterogeneity, especially from export perspective. To fill this gap, we measured and evaluated the export-embodied CO2 emissions from China's ocean industries, based on our newly developed high-resolution and comparable time-series environmentally extended input-output database, called EE-DPN-OEIOT. The results showed that China's ocean exports generated 94.3 Mt of embodied CO2 emissions in 2017, with nearly 40% originating from processing ocean exports. Regarding the evolution from 2007 to 2017, the total export-embodied CO2 emissions from ocean industries decreased by 7.3%, while the embodied CO2 emissions in processing ocean exports increased by 50.1%. From 2007 to 2017, the decrease in carbon emission intensity was the major driving factor of the downturn in export-embodied CO2 emissions across the total ocean economy and for seven ocean subsectors (60%), while the export-scale effect primarily drove the increases in CO2 emissions. Moreover, there were disparities in the driving factors behind changes in embodied CO2 emissions between processing and non-processing ocean exports. Based on our findings, we proposed three recommendations from a trade perspective to facilitate low-carbon sustainable transition of China's ocean economy, thus better fulfilling Sustainable Development Goal 14. [ABSTRACT FROM AUTHOR]

To reduce the C footprint of human activities, there is a growing need for alternative energy sources including the production of bioenergy feedstocks. Miscanthus × giganteus is a high yielding grass with low environmental impact and high potential for feedstock use. Studying the composition of the aboveground tissues of Miscanthus is important for understanding feedstock quality for biofuel conversion and how crop residue quality may affect soil input management. Data on Miscanthus leaf and stem chemistry including carbon (C), nitrogen (N), macronutrient concentrations, and the optical characteristics of the water extractable organic matter (WEOM) was analyzed to identify differences in composition between aboveground tissues and modeled to identify soil variables that may be correlated with tissue chemistry. Leaves and stems were dominated by N, potassium (K), calcium (Ca), phosphorus (P), and magnesium (Mg), but overall, the leaves contained higher nutrient concentrations compared to the stems. The leaves displayed elevated Si:K (0.0935) and Ca:K (0.445) ratios and lower C:N (36) and C:P (323) ratios compared to the stems (0.0560, 0.145, 150, and 645, respectively). Leaf WEOM contained large, aromatic, and complex structures, while the stem WEOM was dominated by small, recently produced structures. Varying relationships were found between tissue C and the mobile C pool in surface (0–15 cm) and deep (45–60 cm) soils. Overall, Miscanthus leaves had a chemical composition indicative of reduced biofuel quality compared to the stems. The relationships with soil mobile C suggest a dynamic linkage between Miscanthus physiology and this active soil C pool. These results have implications for crop nutrient allocation and nutrient management practices. [ABSTRACT FROM AUTHOR]

Poor access to adequate, clean, and safe water is one of the greatest world problems people encounter. There has been considerable attention in recent times toward the use of natural coagulants for water treatment. This study seeks to promote this by investigating the potential of Elephantorrhiza goetzei (E. goetzei) seed extract as natural coagulants for water treatment. This included the determination of key ingredients responsible for the coagulation process and optimal dosages for the removal of turbidity, fluoride, manganese, and iron. The residual content of organic matter in the treated water and the quality of sludge produced were also investigated. The methodology consisted of a proximate analysis procedure to investigate the active ingredient(s) responsible for coagulation and standard jar tests. Standard methods were used for the analyses. Coagulant dosages ranging from 0 to 300 mg/L at a rapid mixing speed of 120 rpm for 1 min, a slow mixing speed of 30 rpm for 15 min, and a settling time of 15 min were used for the jar test. The analysis of variance (ANOVA) using IBM SPSS Version 20 was conducted, and regression models were developed to determine the effect of coagulant dosage on turbidity, pH, total dissolved solids, fluoride, iron, manganese, chemical oxygen demand (COD), nitrogen, and phosphorus. The results obtained from the proximate analysis of E. goetzei seed extract show that values of 5.25%, 21.40%, 8.23%, 32.99%, 2.20%, and 29.93% were obtained for moisture, crude protein, crude fiber, fat, ash, and carbohydrate content, respectively. Moreover, seed extract of E. goetzei achieved removal efficiencies up to 94.8%, 50.1%, 90.0%, and 53.9% for turbidity, fluoride, iron, and manganese in water, respectively. The coagulant has the potential to achieve the desired World Health Organization (WHO) drinking water standards for turbidity, fluoride, iron, and manganese. The COD increased from 55.3 to 419.3 mg/L as the coagulant dosage increased from 0 to 100 mg/L. This could cause an unwanted rise in microbial activities, affecting the microbiological quality of the treated water. The total nitrogen and phosphorus concentrations obtained in the sludge at 100 mg/L were 0.343 and 0.194 µg/kg, respectively, and this compromises its attractiveness for agricultural reuse purposes. [ABSTRACT FROM AUTHOR]

Background: Dissolved organic matter (DOM) plays a significant role in the biogeochemical cycle of crucial elements in aquatic ecosystem. However, it is still not clear on the spectral characteristics of water DOM in different types of alpine wetlands, which have less anthropogenic influences and intensive ultraviolet radiation. Here, we collected 107 water samples from marsh, lake, and river wetlands in the Zoige plateau, China, and analyzed the chemical characteristics, compositions, and potential sources of chromophoric DOM by combining UV–vis spectroscopy and excitation–emission matrix fluorescence spectroscopy coupled with parallel factor analysis (EEMs-PARAFAC). Results: UVC and UVA fulvic-like substances were the prevailing fluorescence components in water DOM, which accounted for 23.74–71.59% and 16.76–30.01% of the total fluorescence intensity, respectively. Compared with the lake and river wetlands, fluoresce intensities of UVC and UVA fulvic-like substances in DOM were higher in marsh wetland. Marsh wetlands possessed the highest SUVA254, E2/E3, E2/E4, and E4/E6 of DOM, suggesting higher humification degree, higher relative molecular nominal size, and higher aromaticity. And the E2/E4 ratios in most water samples were higher than 12, indicating water DOM was mainly derived from autochthonous sources in alpine wetlands. Conclusions: Wetland types strongly affected the spectral characteristics of water DOM in Zoige plateau. These findings may be beneficial for sustainable management of alpine wetlands. [ABSTRACT FROM AUTHOR]

On Arctic shelves, benthic food-webs are tightly linked to overlying primary production. In the seasonal ice zone, sympagic (ice-associated) primary production can be a major source of carbon for the benthos on productive inflow shelves. However, the role of sympagic organic matter is less well-understood in food webs of heavily ice-covered, less- productive outflow shelves, such as the northeast Greenland shelf. Highly branched isoprenoid biomarkers (HBIs) were used to track the relative distribution of sympagic and pelagic organic matter in the water column, sediments, and benthic fauna of the northeast Greenland shelf and fjords. Low pelagic HBI presence throughout the study area indicated a generally low production by pelagic diatoms (at the time of sampling). This was reflected in the benthos, as ~90% of their assimilated carbon was estimated to come from sympagic sources, indicating a benthic food-web highly reliant on sympagic production. This reliance was higher in coastal areas than on the open shelf, where the potentially higher pelagic productivity and shallower water on banks likely increased contributions of pelagic organic matter. As declining ice cover and reduced production of fast-sinking ice algae projected for Arctic shelves will likely result in weaker coupling between ice algae and the benthos, with possible consequences for future benthic-community structure and function. [ABSTRACT FROM AUTHOR]

Aims: Long-term application of organic materials has been shown to significantly enhance the content of soil organic matter (SOM), underscoring the critical need to examine the components of soil organic carbon for a deeper understanding of SOM functionalities. Thus, the structural changes and microbial driving mechanisms of water extractable organic matter (WEOM), fulvic acid (FA) and humic acid (HA) were investigated in black soil by a long-term fertilization experiment. Methods: This 33-year experiment comprises five treatments: no fertilizer (CK), chemical fertilizer (NPK), chemical fertilizer with low-rate straw (NPKJ1), chemical fertilizer with high-rate straw (NPKJ2), and chemical fertilizer with organic manure (NPKM). We also conducted a detailed study of WEOM, FA, HA, and the microbial community structure in both the 0–20 cm and 20–40 cm soil layers. Results: Our findings indicate that organic material application primarily sourced WEOM, FA, and HA from microbial metabolism and plant-derived origins, exhibiting humus and aromatization characteristics with high molecular weight. WEOM was rich in fulvic acid-like and humic acid-like compounds, while FA and HA contained more protein-like components. Organic material use altered WEOM, FA, and HA structures by impacting soil microbial biomass carbon (MBC) and fungal/bacterial biomass. In 0–20 cm soil layer, SOM content was mainly influenced by humus, especially the HA fraction, whereas in 20–40 cm soil layer, it was predominantly affected by WEOM. Conclusions: The present study emphasizes that the application of organic materials can influence the structure of microbial communities, thereby affecting the composition of WEOM, FA, and HA, consequently influencing the organic matter content in different soil layers. [ABSTRACT FROM AUTHOR]

Foodborne pathogens pose a persistent threat in broiler chicken production, particularly during the slaughter process, where contamination with zoonotic pathogens remains a concern. This study focuses on the potential of organic acids, such as formic and lactic acid, and the oxidizing agent peracetic acid, to decontaminate scalding water and enhance the hygiene of chicken carcasses. We conducted suspension tests introducing various organic loads to mirror the conditions of practical scalding water. Additionally, the surface tests were performed on chicken skin. Both methods were further tested in an experimental slaughtering facility. In suspension tests, the organic acids achieved impressive decontamination, with a 5‐log10 reduction of the test organisms Enterococcus hirae, Salmonella Typhimurium and Campylobacter jejuni at minimal concentrations (between 0.04% and 2% for formic acid; between 0.1% and 4.5% for lactic acid). Peracetic acid also effectively sanitized model water and chicken skin, even when used in low concentrations (between 0.001% and 0.1%), both in the laboratory‐based testing and in the experimental slaughtering facility. These results suggest that the tested disinfectants can effectively sanitize process water, even under conditions mimicking practical scalding water with organic matter. Peracetic acid, in particular, proved highly effective in improving chicken skin hygiene even at low concentrations. [ABSTRACT FROM AUTHOR]

Compared with 454 sequencing technology, short-read sequencing (e.g., Illumina) technology generates sequences of high accuracy, but limited length (<500 bp). Such a limitation can prove that studying a target gene using a large amplicon (>500 bp) is challenging. The ammonia monooxygenase subunit A (amoA) gene of ammonia-oxidizing archaea (AOA), which plays a crucial part in the nitrification process, is such a gene. By providing a full overview of the community of a functional microbial guild, 16S ribosomal ribonucleic acid (rRNA) gene sequencing could overcome this problem. However, it remains unclear how 16S rRNA primer selection influences the quantification of relative abundance and the identification of community composition of nitrifiers, especially AOA. In the present study, a comparison was made between the performance of primer pairs 338F-806R, 515F-806R, and 515F-907R to a shotgun metagenome approach. The structure of nitrifier communities subjected to different long-term organic matter amendment and water management protocols was assessed. Overall, we observed higher Chao1 richness diversity of soil total bacteria by using 515F-806R compared to 338F-806R and 515F-907R, while higher Pielou's evenness diversity was observed by using 515F-806R and 515F-907R compared to 338F-806R. The studied primer pairs revealed different performances on the relative abundance of Thaumarchaeota, AOB, and NOB. The Thaumarchaeota 16S rRNA sequence was rarely detected using 338F-806R, while the relative abundances of Thaumarchaeota detected using 515F-806R were higher than those detected by using 515F-907R. AOB showed higher proportions in the 338F-806R and 515F-907R data, than in 515F-806R data. Different primers pairs showed significant change in relative proportion of NOB. Nonetheless, we found consistent patterns of the phylotype distribution of nitrifiers in different treatments. Nitrosopumilales (NP) and Nitrososphaerales (NS) clades were the dominant members of the AOA community in soils subject to controlled irrigation, whereas Ca. Nitrosotaleales (NT) and NS clades dominated the AOA community in soils subject to flooding irrigation. Nitrospira lineage II was the dominant NOB phylotype in all samples. Overall, ideal 16S rRNA primer pairs were identified for the analysis of nitrifier communities. Moreover, NP and NT clades of AOA might have distinct environmental adaptation strategies under different irrigation treatments. [ABSTRACT FROM AUTHOR]

The application of low-pressure nanofiltration (NF) was investigated for three different applications: water reuse from acid mine drainage (AMD), surface water containing natural organic matter (NOM) and agricultural reuse of microfiltered biologically treated sewage effluent (MF-BTSE). AMD contains many valuable rare earth elements (REEs) and copper (Cu) that can be recovered with fresh water. The NF90 membrane was investigated for recovery of fresh water from synthetic AMD. A steady permeate flux of 15.5 ± 0.2 L/m2h was achieved for pretreated AMD with over 98% solute rejection. NF90 achieved a high dissolved organic carbon (DOC) rejection of 95% from surface water containing NOM where 80% of the organic fraction was hydrophilic, mainly humics. The NF process maintained a high permeate flux of 52 LMH at 4 bars. The MF-BTSE was treated by NTR-729HF for agricultural reuse. NTR-729HF membranes were capable of rejecting DOC and inorganics such as sulfates and divalent ions (SO42−, Ca2+ and Mg2+) from MF-BTSE, with less than 20% rejection of monovalent (Na+ and Cl−) ions. The sodium adsorption ratio (SAR) was significantly reduced from 39 to 14 after treatment through NTR-729HF at 4 bar. The resulting water was found to be suitable to irrigate salt-sensitive crops. [ABSTRACT FROM AUTHOR]

With the gradual depletion of conventional petroleum resources, oil shale, as an important unconventional oil and gas resource, is of great significance to alleviate the global energy crisis and optimize the energy structure. In this study, we comprehensively assessed the organic matter abundance, type, maturity, and trace element characteristics of oil shale by collecting and analyzing oil shale samples from the Lower Permian region in the western part of the southern margin of the Junggar Basin, and by applying pyrolysis analysis and rock pyrolysis analysis. The study showed that the average value of total organic carbon (TOC) of the oil shale in the study area was 10.26%, of which 41.67% was medium-grade oil shale and 58.33% was low-grade oil shale, reflecting the overall abundance of medium-low organic matter. The average value of hydrocarbon potential was 40.83 mg/g. The hydrogen index of the oil shale samples ranged from 77 to 861.06 mg/g, with an average value of 405.56 mg/g. The organic matter type was mainly of the II1 type (humic-sapropelic type), which accounted for 75% of the total, and the analysis of the highest pyrolysis peak temperature showed that 83.33% of the samples were in the low maturity-mature stage. Trace element analyses revealed that the oil shales in the study area were formed in a terrestrialweakly reduced depositional environment. Especially, the analysis of Sr/Ba, Th/U and B/Ga ratios indicated that the oil shale was mainly formed in freshwater-semi-saline environment. In addition, the analysis of V/(V+Ni) and U/Th ratios supports the reduced environment in which the oil shale was formed. The shale in the Dalongkou area has greater salinity values and higher organic matter productivity in the water body at the time of formation compared to the oil shale in the Cangfanggou area. The results of this study are important for understanding the geochemical properties and mineralization potential of the Lower Permian oil shales in the western part of the southern margin of the Junggar Basin. [ABSTRACT FROM AUTHOR]

Background and aims: Nitrogen (N) mineralization and immobilization are two important N biogeochemical processes in estuarine and coastal sediments. However, the changes of those two processes in sediment following Spartina alterniflora (S. alterniflora) invasions into mangrove wetlands under aerobic and anaerobic conditions remain limited. Methods: We used a 15N stable isotope dilution technique to investigate sediment gross N mineralization (GNM) and NH4+ immobilization (GAI) under aerobic and anaerobic conditions in mangrove communities, mangrove communities mixed with S. alterniflora, and pure S. alterniflora communities in the Zhangjiang Estuary, China. Results: GNM and GAI rates varied spatially and seasonally. Summer N mineralization and immobilization rates under aerobic and anaerobic conditions were both significantly higher than those in winter, and the high rates were observed mainly in mangrove sediments and decreased with S. alterniflora invasion. GNM rates in aerobic conditions were significantly higher than those in anaerobic conditions, while GAI rates in aerobic conditions were less than those in anaerobic conditions. GNM and GAI rates were related closely to temperature, water content and organic matter. S. alterniflora invasion can weaken GNM and GAI rates by reducing organic matter accumulation, and S. alterniflora invasion could have reduced sediment N mineralization (2.10 × 103 t N yr−1) and immobilization (1.46 × 103 t N yr−1) in mangrove wetlands of China from 1980 to 2020. Conclusions: Our results highlight the importance of S. alterniflora invasion and hydrological conditions in controlling N mineralization and immobilization processes in mangrove sediments and are essential for the evaluation of N-balance in this N-limited ecosystem. [ABSTRACT FROM AUTHOR]

Lake Batur’s water quality on Bali Island has significantly declined, leading to massive annual fish mortality rates. The suspected reason is the expansion of aquaculture using floating net cages (FNC) beyond their capacity. The study aims to assess the impact of FNC-based aquaculture on water quality and organic matter distribution, specifically total organic matter, TSS, and chlorophyll a. The result states that Lake Batur has exceeded its carrying capacity of 10,047 plots since 2018 and currently holds 18,768 plots as of 2022. Within the last five years (2018-2022), the FNC discharged 5,947 tons of organic waste into Lake Batur, containing 1,779 quintals of nitrogen and 430 quintals of phosphorus. Consequently, each liter of Lake Batur water accrues 7.29 mg of organic waste annually, including 2.18 mg of nitrogen and 0.53 mg of phosphorus. Organic waste in Lake Batur has led to a reduction in water transparency, an increase in total organic matter (TOM), a decrease in dissolved oxygen (DO), and an increase in chlorophyll-a (Chl-a) concentrations. Its changes serve as indicators of eutrophication and degradation of water quality. The distribution of organic matter across the euphotic zone did not correlate with FNC distribution, suggesting that FNC distribution no longer influences organic matter distribution. Environmental factors surrounding the SL have emerged as the primary driver of differences in organic matter distribution. It demonstrates the dissemination of organic matter in the euphotic zone of Lake Batur due to the constant discharge of effluent by the long-standing FNC, which has surpassed its maximum capacity. [ABSTRACT FROM AUTHOR]

This study analyzes the molecular composition of dissolved organic matter (DOM) in Prydz Bay by Fourier Transform Ion Cyclotron Resonance mass spectrometry to probe the carbon sequestration capacity in the continental shelf system. Concentrations of particulate organic carbon (POC), particulate nitrogen and dissolved organic carbon (DOC) with water depth show that POC could be mainly decomposed into DOC and/or microbially degraded. Highly labile DOC is further degraded and remineralized by microorganisms within the upper 200 m, as evidenced by a downward enrichment of 13CPOC and increases in the average molecular weight, oxygen atom number (O) and double bond equivalents of DOM molecules, indicating that biodegradation is the main driver for particulate organic matter and DOM evolution with water depth. Semi‐quantitative calculation demonstrates that ∼83% of POC was transformed to DOC as well as dissolved inorganic carbon (DIC), and ∼30% of DOC further to DIC via microbial degradation within the upper 200 m in summer, resulting in a relatively low total organic carbon content in sediments of Prydz Bay. The newly transformed DIC and residue DOC can be preserved in the deep layer due to the formation of well stratified and stable water body in summer of Prydz Bay, ultimately entering the regional circulation system instead of being released back into the atmosphere. This could be one of the most important processes determining the atmosphere CO2 uptake in the continental shelf system of Southern Ocean. Plain Language Summary: The continental shelf system in the Southern Ocean, especially with the development of polynyas, plays a critical role in the global carbon cycle and disproportionally accounts for almost half of the anthropogenic CO2 uptake by the biological pump, with ensuing deep‐sea sequestration by the form of particulate and dissolved organic carbon, and even CO2 due to microbial degradation of primary productivity. However, complex interactions between physical, chemical and biological processes significantly affect the fate of organic carbon through the water column, resulting in an uncertainty of vertical carbon export. In this study, we conduct an investigation on the dissolved organic matter sources and evolution with water depth in summer of Prydz Bay, a typical polynya‐developed continental shelf system in the East Antarctica. The results clearly show that biodegradation is the main factor controlling organic carbon mineralization and mainly occurs within the upper 200 m of water column, with a transformation into dissolved organic carbon (DOC) and dissolved inorganic carbon (DIC). Integrated with regional circulation system and hydrological characteristics, our study further indicates that newly formed DIC and DOC can be preserved in the deep layer of Prydz Bay, then into the regional circulation system rather back to the atmosphere. Key Points: Novel evidence at molecular level shows the vital role of biodegradation during carbon sink in Prydz BayThe conversion of POC into DOC/DIC mainly occurs within the upper 200 m of water columnHighlighting regional circulation's contribution to carbon transport and sequestration in the Southern Ocean [ABSTRACT FROM AUTHOR]

The East China Sea (ECS) is one of the largest marginal seas in the world with high primary productivity and a large area of low dissolved oxygen. This study observed the low‐oxygen bottom water on the outer‐edge shelf of ECS in summer seasons of 2018–2020. The contributions of various water masses to low‐oxygen waters were quantified, and the interaction between low‐oxygen water and Kuroshio water was validated by a mixing model using heavy rare earth elements (HREEs) together with potential temperature, and salinity. For further reliability verification, tracers such as δ34S and 226Ra were additionally utilized to avoid the non‐conservative processes on the shelf area. The low‐oxygen water on the shelf was clarified to be linked to the inner/middle shelf water, and dominated by Kuroshio Subsurface Water (KSSW, 81% ± 3%) and influenced by a non‐negligible extent of pore water (3.0% ± 0.5%). Our findings revealed the transport of low‐oxygen water from the outer‐shelf edge to the Kuroshio area, whose dissolved inorganic nitrogen and dissolved inorganic phosphorus contributions to Kuroshio were 34%–82% and 35%–83%, respectively. The nutrients of low‐oxygen water were regulated primarily by the origins of water and secondarily by organic matter remineralization (DIN: ∼17% and DIP: ∼24%). As control factors, the tide, especially spring tide largely enhanced the water contribution of pore water to low‐oxygen water by 67%, and the El Niño‐Southern Oscillation potentially affected the contributions of KSSW and mid‐shelf water to low‐oxygen water. Plain Language Summary: The significant expansion of low‐oxygen area is a growing concern in the East China Sea (ECS). In the summer of 2018–2020, we identified and quantified the origins of low‐oxygen bottom water on the outer‐edge shelf of ECS. Using multi‐chemical tracer approaches, we found that Kuroshio Subsurface Water (KSSW) was the primary contributor, while mid‐shelf water, and pore water were found to have a non‐negligible contribution to low‐oxygen bottom water. Additionally, the transport of low‐oxygen water to the Kuroshio was confirmed. The contribution of pore water was revealed to increase significantly during spring tide, and the contributions of major water sources (KSSW and mid‐shelf water) had an enhanced variability under El Niño‐Southern Oscillation (ENSO) events. These results suggested that the effects from tide and ENSO events on low‐oxygen water should get more attention. Low‐oxygen phenomena are being intensified by global warming and strong stratification in other shelf seas/coastal seas. Our approaches and findings could provide additional and fresh ideas for future related studies in term of low‐oxygen water. Key Points: Low‐oxygen water on outer‐edge shelf of East China Sea was estimated using multiple chemical tracers with 9% ± 2% mid‐shelf water contributionPore water was first revealed to supply nutrients (∼10%) to low‐oxygen water, with an amplified water contribution (67%) under spring tideEl Niño‐Southern Oscillation possibly influenced the interannual variability in contributions of low‐oxygen water's main water masses (Kuroshio Subsurface Water and mid‐shelf water) [ABSTRACT FROM AUTHOR]

Introduction: Arbuscular mycorrhizal fungi (AMF) are vital in terrestrial ecosystems. However, the community structure characteristics and influencing factors of AMF in the forest ecosystems of arid desert grassland areas require further investigation. Methods: Therefore, we employed high-throughput sequencing technology to analyze the soil AMF community characteristics at different elevations in the Helan mountains. Results: The results revealed that significant differences (P < 0.05) were observed in the soil physicochemical properties among different elevations, and these properties exhibited distinct trends with increasing elevation. Through highthroughput sequencing, we identified 986 operational taxonomic units (OTUs) belonging to 1 phylum, 4 classes, 6 orders, 12 families, 14 genera, and 114 species. The dominant genus was Glomus. Furthermore, significant differences (P < 0.05) were observed in the a-diversity of the soil AMF community across different elevations. Person correlation analysis, redundancy analysis (RDA), and Monte Carlo tests demonstrated significant correlations between the diversity and abundance of AMF communities with soil organic matter (OM) (P < 0.01) and soil water content (WC) (P < 0.05). Discussion: This study provides insights into the structural characteristics of soil AMF communities at various altitudes on the eastern slope of Helan mountain and their relationships with soil physicochemical properties. The findings contribute to our understanding of the distribution pattern of soil AMF and its associations with environmental factors in the Helan mountains, as well as the stability of forest ecosystems in arid desert grassland areas. [ABSTRACT FROM AUTHOR]

This article is about the diversity of diatoms in the benthos of the upper sublittoral near Kazantip Cape, located on the shore of the Sea of Azov in the northeastern part of Crimea. The study was conducted in 2022 and 2023 at a depth of 0.1 to 1 m at temperatures from 3.7 °C to 29 °C and salinity from 13.6 to 15.6 psu on the following 11 species of macroalgae: Phaeophyta of Ericaria crinita, Gongolaria barbata, and Cladosiphon mediterraneus; Chlorophyta—Bryopsis hypnoides, Cladophora liniformis, Ulva intestinalis, and Ulva linza; and Rhodophyta—Callithamnion corymbosum, Ceramium arborescens, Polysiphonia denudata, and Pyropia leucosticta. A total of 97 taxa of Bacillariophyta belonging to 3 classes, 21 orders, 30 families, and 45 genera were found. The highest number of diatom species was found on U. linza (61 species), P. denudata (45), E. crinita (40), the lowest number was recorded on thalli P. leucosticta (9). On macroalgae were found of 80% benthic diatoms, 50% marine species, 36% brackish-marine, 9% freshwater, 5% brackish, and 36% cosmopolites. The maximum abundance of the diatom community was 243.4 × 103 cells/cm2 (P. denudata in September at 23.9 °C and 15.0 psu) with dominance by the diatom of Licmophora abbreviata, and the minimum was 3.8 × 103 cells/cm2 (P. leucosticta in January at 3.7 °C and 15.0 psu). The presence in the epiphyton of diatoms—indicators of moderate organic water pollution (32 species), which developed in masse in late summer—indicate a constant inflow of organic matter into the coastal waters of the Kazantip Cape. The bioindicator and statistical studies indicate the effectiveness of the conservation regime, especially at stations within the IUCN reserve, despite relatively high saprobity rates at stations exposed to recreational pressure and poorly treated domestic wastewater. [ABSTRACT FROM AUTHOR]

The vegetation surrounding aquatic ecosystems contributes allochthonous sources of organic matter to the water bodies. In Andean-Patagonian catchments, several non-native species grow among native ones. Different sources of dissolved organic matter (DOM) may vary in their contribution, potentially affecting aquatic functioning. This study evaluates differences in DOM contributions from native and non-native plants, analyzing DOM reactivity through its optical properties. An outdoor experiment was conducted with DOM leaf leachates from two native (Maytenus boaria and Nothofagus dombeyi) and two invasive trees (Salix fragilis and Pinus contorta). We characterized DOM concentration and quality optically by UV–Visible and fluorescence spectroscopy and found differences in both quantity and quality between the different leaf leachates. The exotic S. fragilis presented up to 7 times higher dissolved organic carbon (DOC) values than the other species. We found that leachates response to light exposure depended on its DOM composition. Decreasing patterns of DOC absorbance and fluorescence were observed in all leachates over time. We detected a gradient in leaf leachate photoreactivity due to solar exposure: (S. fragilis > P. contorta > M. boaria = N. dombeyi). Overall, our work shows that the invasive plants studied produce larger amounts of degradable DOM than some local native species. [ABSTRACT FROM AUTHOR]

This study was conducted to evaluate surface water quality using pollution indices including the organic pollution index (OPI), comprehensive pollution index (CPI), and water quality index (WQI), cluster analysis (CA), with the support of one-way analysis of variance (One-way ANOVA), and principal component analysis (PCA). Water quality data at 42 locations, with 22 water quality parameters including temperature, pH, turbidity, salinity, chloride, total dissolved solids, electrical conductivity, sulfate, dissolved oxygen, total suspended solids, biological oxygen demand, chemical oxygen demand, nitrite, nitrate, ammonium, orthophosphate, coliform, E. coli, arsenic, cadmium, lead, and copper, were used for the evaluation. The results showed that all the pollution indices fluctuated spatially and temporally. The OPI index ranged from slight organic pollution to heavy organic pollution, and the OPI values in February and April were higher than those in other months. OPI values were classified as moderate with 54.76% of the locations and heavily polluted with 45.24%. Assessment based on the CPI revealed that 16.7% and 83.3% of locations were classified as moderately contaminated and heavily contaminated, respectively. The WQI classified 45% of the locations as poor and 55% of the locations as having average water quality. In particular, the water quality in August, October, and December was better than that in other months. PCA results showed that eight polluting sources were responsible for 77.1% of the water quality variation. The main surface water polluting sources could be natural sources (riverbank erosion, rainwater runoff), wastewater (domestic, agricultural, and industrial), water discharge from the national park, and livestock areas. Local environmental management agencies need to have appropriate solutions to improve water quality. Future research should focus on the contribution sources to surface water degradation. [ABSTRACT FROM AUTHOR]

Data on the presence of hydrochemical anomalies in river water in Murmansk region are presented, contrast hydrochemical anomalies are identified, and hydrochemical series are formed. The least number of anomalous values was recorded in the concentrations of magnesium, calcium, and organic matter in river water, and the largest number, for metal compounds. Most of the identified hydrochemical anomalies are positive and low-contrast. Contrast anomalies are most often in manganese compounds. Most of the identified anomalies in terms of manganese compounds in river water are of mixed genesis (in the Pechenga River basin). Hydrochemical anomalies in the water of ecologically safe reaches of the Lotta and Ura rivers are of natural origin and are caused by geochemical features of the catchments. [ABSTRACT FROM AUTHOR]

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This study investigates the environmental impacts caused by the scaling up of the photocatalytic purification of drinking water using ultraviolet light-emitting diode technology. The life cycle assessment methodology was utilised to estimate the environmental impacts of two different reactor setups commonly used in lab-scale studies: an immobilised and a suspended TiO2 catalytic system. The functional unit adopted was the treatment of 1 L of water with an initial 7.8 mg/L concentration of natural organic matter, achieving a final 1 mg/L concentration. The use of a suspended photocatalyst was found to have an environmental footprint that was 87% lower than that of the immobilised one. From the sensitivity analysis, the environmental hotspots of the treatment process were the electricity usage and immobilised catalyst production. Therefore, alternative scenarios investigating the use of a renewable electricity mix and recyclable materials were explored to enhance the environmental performance of the photocatalytic treatment process. Using a renewable electricity mix, a decrease of 55% and 15% for the suspended and immobilised catalyst, respectively, was observed. Additionally, the process of recycling the glass used to support the immobilised catalyst achieved a maximum reduction of 22% in the environmental impact from the original scenario, with 100 glass reuses appearing to provide diminishing returns on the environmental impact savings. [ABSTRACT FROM AUTHOR]

River organic matter transformations impact the cycling of energy, carbon, and nutrients. The delivery of distinct dissolved organic matter (DOM) sources can alter aquatic DOM cycling and associated biogeochemical processes. Yet DOM source and reactivity are not well‐defined for many river systems, including in western Canada. Here, we explore DOM cycling in the mainstem of the Oldman River (stream order 6–7), a heavily regulated river network in southern Alberta (Canada). We compared seasonal river DOM content, composition, and bioavailability with nine endmember leachates from the river valley using optical properties and incubations to estimate biodegradable dissolved organic carbon (BDOC). River DOM composition was most similar to terrestrial soil leachates, followed by autochthonous DOM leachates. River DOM bioavailability was low (BDOC = 0%–16.6%, mean of 7.1%). Endmember leachate bioavailability increased from soils (BDOC = 23.9%–53.7%), to autochthonous sources (fish excretion, macrophytes, biofilm; BDOC = 49.9%–80.0%), to terrestrial vegetation (leaves, shrubs, grass; BDOC > 80%), scaling positively with protein‐like DOM content and amount of leachable dissolved organic carbon (DOC), and negatively with aromaticity. Seasonally, DOC concentrations changed little despite >15‐fold increases in discharge during spring. River DOM composition shifted modestly toward soil‐like endmembers in spring and more bioavailable autochthonous end members in autumn and winter. Low DOM bioavailability in the river mainstem and low DOC yields shown in previous work point to limited internal processing of DOM and limited bioavailable DOM delivery to downstream habitats, possibly due to upstream flow regulation. Our observations provide important insights into the functioning of western Canadian aquatic networks. Plain Language Summary: Rivers are among the most heavily disturbed ecosystems worldwide. In agricultural regions of western Canada, human impacts on river ecosystem structure and functioning are not well defined. The study of organic matter chemistry provides important insights into aquatic ecosystem properties and biogeochemical processes. Here, we explore the seasonal trends in composition and content of dissolved organic matter in one of Canada's most heavily regulated rivers (the Oldman River, Alberta). While land use impacts on river organic matter cycling are documented elsewhere, we provide unique insights by tracking changes in river organic matter composition and microbial consumption across a complete annual cycle that includes winter. The composition and content of river organic matter changed little among seasons. Compared to potential organic matter sources from the river valley (soils, plants, aquatic organisms, and biofilm), river water had organic matter that mostly resembled soil sources, and secondarily river sources. Compared to all potential sources, river organic matter was less bioavailable to microbes and on the low end of bioavailability relative to other global aquatic systems. We hypothesize that human alterations to the flow regime upstream (including damming and irrigation) may dampen seasonal changes in river organic matter composition and cycling. Key Points: Bioavailability of end member leachates increased from soils to river sources (fish, then macrophytes and biofilm), to terrestrial plantsDissolved organic matter (DOM) composition and bioavailability were modestly responsive to elevated discharge during the spring freshetWeakly bioavailable soil DOM dominated the downstream river pool, possibly showing the mainstem is not a hotspot for DOM transformation [ABSTRACT FROM AUTHOR]

Hill fires have the potential to influence dissolved organic matter (DOM) in water bodies, yet fewer studies have investigated the effects of hill fires on DOM within watersheds in karst areas. In this study, we employed the three-dimensional fluorescence-parallel factor analysis (EEM-PARAFAC) method to analyze the DOM fluorescence peaks, component compositions, fluorescence indices, and sources within the water body of the Yuanteng River sub-basin, which was impacted by the hill fire, serving as our primary research focus. The results indicate the presence of three primary fluorescent fractions in the water body of the Yuanteng River: C1, resembling humic acid (fulvic acid); C2, consisting of biopolymers and microbial by-products; and C3, containing proteins such as tyrosine and tryptophan. The Yuanteng River exhibited elevated levels of humus-like substances, diminished concentrations of protein-like substances, and demonstrated higher biogenic, freshness, and humification indices compared to unaffected water samples, reflecting the impact of the hill fire. Elevated levels of exogenous humic acid-like inputs into the waters of the Yuanteng River, along with exogenous inputs of DOM, were primarily influenced by stable, high-molecular-weight organic matter. Additionally, agricultural effluent, domestic sewage, and anthropogenic activities contributed to these inputs to a lesser degree. The impacts of endogenous inputs are mainly related to the restoration of ecosystems. The occurrence of hill fires has significantly influenced the composition of dissolved organic matter in the waters of the Yuanteng River. A comprehensive analysis of the impacts of hill fires on dissolved organic matter in water bodies can serve as a valuable reference for characterizing DOM in the water bodies of the Yuanteng River. Furthermore, it can inform strategies for environmental protection, facilitate the traceability of pollutants in water bodies, and contribute to environmental and ecological restoration efforts following hill fires in the region. [ABSTRACT FROM AUTHOR]

Size exclusion chromatography with total organic carbon detection (HPSEC-TOC) is a widely employed technique for characterizing aquatic natural organic matter (NOM) into high, medium, and low molecular weight fractions. This study validates the suitability of HPSEC-TOC for a simplified yet efficient routine analysis of freshwater and its application within drinking water treatment plants. The investigation highlights key procedural considerations for optimal results and shows the importance of sample preservation by refrigeration with a maximum storage duration of two weeks. Prior to analysis, the removal of inorganic carbon is essential, which is achieved without altering the NOM composition through sample acidification to pH 6 and subsequent N2-purging. The chromatographic separation employs a preparative TSK HW-50S column to achieve a limit of detection of 19.0 µgC dm−3 with an injection volume of 1350 mm−3. The method demonstrates linearity up to 10,000 µgC dm−3. Precision, trueness and recovery assessments are conducted using certified reference materials, model compounds, and real water samples. The relative measurement uncertainty in routine analysis ranges from 3.22% to 5.17%, while the measurement uncertainty on the bias is 8.73%. Overall, the HPSEC-TOC represents a reliable tool for NOM fractions analysis in both treated and untreated ground and surface water. [ABSTRACT FROM AUTHOR]

Terrestrial organic matter subsidizes aquatic food webs and plays an important role in carbon cycling in lake ecosystems, where it is decomposed mainly by microbes. However, the contribution of terrestrial and aquatic microbiomes on terrestrial carbon cycling and their effects on the biochemical fate of carbon has remained understudied. Therefore, we explored the microbial carbon utilization of three chemically differing leaf species in lake water in microcosms and quantified the biochemical endpoints of leaf carbon in CO2, CH4, and microbial biomass. Additionally, we identified microbial taxa responsible for leaf carbon recycling and studied the role of epiphytic and endophytic leaf microbiomes in microbial community succession in lake water. Microbially utilized leaf carbon was mainly respired (82.7 ± 1.4%), whereas a small proportion (17.1 ± 1.4%) was assimilated into biomass. Carbon from nitrogen‐rich alder leaves was taken up at the fastest rate, whereas birch leaf addition produced the highest concentrations of CH4, suggesting that leaf chemistry affects the decomposition rate and biochemical fate of carbon. In particular, terrestrial bacteria shaped the succession of aquatic bacterial communities. The addition of leaves resulted in the equal contribution of epiphytic and endophytic bacteria in the lake water, whereas epiphytic fungi dominated the fungal community structure. Our results suggest that terrestrial bacteria originating from terrestrial leaves influence the microbiome succession in lake ecosystems and play a key role in linking terrestrial carbon to an aquatic food web and determining the quality of carbon emissions that are released into the atmosphere. [ABSTRACT FROM AUTHOR]

The composition of dissolved organic matter of cloud water has been investigated through non-targeted high-resolution mass spectrometry on only a few samples that were mostly collected in the Northern Hemisphere in the USA, Europe and China. There remains, therefore, a lack of measurements for clouds located in the Southern Hemisphere, under tropical conditions and influenced by forest emissions. As a matter of fact, the comparison of the composition of clouds collected in different locations is challenging since the methodology for the analysis and data treatment is not standardized. In this work, the chemical composition of three samples collected at Réunion Island (REU) during the BIO-MAÏDO field campaign, in the Indian Ocean, with influences from marine, anthropogenic and biogenic (tropical) emissions, is investigated and compared to the chemical composition of samples collected at the Puy de Dôme (PUY) observatory in France. The same methodology of analysis and data treatment was employed, producing a unique dataset for the investigation of the molecular composition of organic matter in cloud water. Besides the analysis of elemental composition, we investigated the carbon oxidation state (OSC) of dissolved organic matter, finding that overall samples collected at PUY are more oxidized than those collected at REU. Molecular formulas were also classified based on stoichiometric elemental ratios, showing the high frequency and abundance of reduced organic compounds, classified as lipids (LipidC), in this matrix, which led to a search for terpene oxidation products in cloud water samples. To better discriminate between samples collected at PUY and REU, statistical analysis (principal component analysis and agglomerative hierarchical clustering) was performed on the ensemble of molecular formulas and their intensities. Samples collected at REU have a different composition from samples collected at PUY, which is mainly linked to different primary sources, the processing of organic matter in cloud water and the influence of different primary emissions at the two locations. [ABSTRACT FROM AUTHOR]

Simple Summary: The foliage of the tree Brosimum alicastrum is widely employed by small farmers in Latin America to supplement cattle, sheep and goats during the dry season. Foliage is manually cut, and the branches are chopped and fed directly, being highly palatable to ruminant species. The foliage remains green throughout the year, and the tree can be defoliated twice per year. Cattle can also directly browse the foliage from the tree, but it is mostly used in cut and carry systems and transported in carts to farms. The experiment hereby described showed that the crude protein fraction of the foliage of B. alicastrum is highly fermentable in the rumen, supplying nitrogen for growth of the microbial population. As the percent of foliage of B. alicastrum in the ration was increased, dry matter intake by sheep was concomitantly increased, as was the rate of the passage of digesta through the rumen and the supply of microbial nitrogen to the small intestine. The foliage of B. alicastrum is a valuable feedstuff for ruminants in the tropics and can be used as a cheap source of protein during the critical periods of the year to improve weight gain and milk yield in a sustainable way. An experiment was carried out to assess the effect of the incorporation of sun-dried foliage of Brosimum alicastrum into rations based on hay of Megathyrsus maximus on intake, rumen fermentation, kinetics of passage, microbial nitrogen supply to the small intestine, apparent digestibility in Pelibuey hair sheep. Four rations were randomly allotted to four rumen-cannulated lambs (BW = 37.4 ± 4.9 kg) using a 4 × 4 Latin square design to assess the effect of increasing levels (0, 15, 30 and 45% DM basis) of foliage of Brosimum alicastrum on a basal ration of M. maximus. Organic matter intake and water consumption increased linearly (p < 0.01) with increasing levels of B. alicastrum in the ration. The rate and potential extent of rumen fermentation of OM and CP of B. alicastrum were 10.6%/h and 86.6% and 11.4%/h and 95.2%, respectively, but no effect (p > 0.05) was found on the potential rumen degradation of DM (40.2%) or on the rate of degradation of DM (0.033%/h) of M. maximus, although a positive effect was found in the rumen degradation rate of NDF (p < 0.05). VFA and ammonia concentration in the rumen and the rate of passage of solids and liquids through the rumen (k1) increased linearly (p < 0.01) with increasing levels of B. alicastrum. Rumen pH was not affected by the incorporation of B. alicastrum (p > 0.05). Microbial nitrogen supply to the small intestine (p < 0.001), apparent digestibility of dry matter (p < 0.01) and NDF (p < 0.05) of the rations were also significantly increased as a result of the incorporation of B. alicastrum foliage. Results from this experiment suggest that the foliage of Brosimum alicastrum can be readily incorporated at around 30% of the ration of dry matter in hair sheep with beneficial effects on feed intake, rate of passage and microbial N supply to the lower tract. [ABSTRACT FROM AUTHOR]

The Secchi disc depth (Dsd) measurement is widely used to monitor eutrophication and the quality of the aquatic environment. This study aimed to investigate the relationship between Dsd and various factors, including the coefficient of attenuation of photosynthetically active radiation [Kd (PAR)], the depth of the euphotic zone (Deu), PAR at the Secchi disk depth (Esd) and the absorption coefficient of PAR (F) in the Neva Estuary, one of largest estuaries of the Baltic Sea. Environmental variables impacting these indices were identified using data collected from midsummer 2012 to 2020. The Dsd values in the estuary ranged from 0.3 to 4.0 m, with an average value of 1.8 m, while the Deu/Dsd ratio ranged from 1.5 to 6.0 with an average value of 2.8. These values were significantly lower than those observed in the open waters of the Baltic Sea. The highest Deu/Dsd ratio was observed in turbid waters characterized by high Kd(PAR) and low Dsd. Contrary to expectations, Dsd did not exhibit a significant relationship with the concentration of chlorophyll a, raising doubts about the utility of historical Dsd data for reconstructing phytoplankton development in the estuary. Principal component analysis did not identify the primary environmental variables strongly affecting the optical characteristics of water. However, recursive partitioning of the dataset using analysis of variance (CART approach) revealed that the concentration of suspended mineral matter (SMM) was the primary predictor of Deu/Dsd, Kd(PAR), and F. This SMM was associated with the frequent resuspension of bottom sediments during windy weather and construction activities in the estuary. Concentrations of suspended organic matter and the depth of the water area were found to be less significant as environmental variables. Furthermore, the CART approach demonstrated that different combinations of environmental variables in estuarine waters could result in similar optical indicator values. To reliably interpret the data and determine the optical characteristics of water in estuaries from Dsd, more complex models incorporating machine learning and neural connections are required. Additionally, reference determinations of Esd in various regions with specific sets of environmental variables would be valuable for comparative analyses and better understanding of estuarine systems. [ABSTRACT FROM AUTHOR]

A field trial was performed to carry out an enhanced phytoremediation technique for multi-metal contaminated copper tailings by Sudan grass (Sorghum Sudanese), ryegrass (Lolium perenne L.), and Bermuda grass (Cynodon dactylon), using conditioner (TH-LZ01) and straw combination into composite amendments as soil amendments, aimed to obtain the maximum of phytoremediation effect. The results showed that compared with untreated herbaceous plants, the application of conditioner and straw planted with herbaceous plants reduced the pH and conductivity and increased the organic matter and water content of the copper tailings to different degrees. With the addition of conditioner and straw, the DTPA-Cd, DTPA-Cu, DTPA-Pb, and DTPA-Zn contents in the copper tailings showed a decreasing trend compared with the untreated group. The herbaceous plants were promoted to reduce the percentage contents of acid soluble fractions Cd, Cu, Pb, and Zn and to increase the percentage contents of reducible, oxidizable, and residual fractions heavy metals (Cd, Cu, Pb, and Zn) in the copper tailings to different degrees. The contents of Cd, Cu, Pb, and Zn in the underground part of herbaceous plants were higher than those in the aboveground part, and the contents of Cd, Cu, Pb, and Zn in the aboveground part and underground part decreased after adding conditioner and straw, which indicated that the conditioner and straw inhibited the transport of heavy metals in the plant. Furthermore, the principal component analysis showed that the application of conditioner and straw with planting ryegrass had more potential for improving the physicochemical properties of copper tailings and reducing heavy metal toxicity, followed by Bermuda grass and Sudan grass. [ABSTRACT FROM AUTHOR]

Organic matter accumulation in water can cause serious problems such as oxygen depletion and quality deterioration of waters. While calcium carbonate has been used as green and low‐cost adsorbent for water treatment, its efficiency in reducing the chemical oxygen demand (COD) of water, which is a measure of organic pollution, is restrained by the limited specific surface area and chemical activity. Herein, inspired by the high‐magnesium calcite (HMC) found in biological materials, a feasible method to synthesize fluffy dumbbell‐like HMC with large specific surface area is reported. The magnesium inserting increases the chemical activity of the HMC moderately but without lowering its stability too much. Therefore, the crystalline HMC can retain its phase and morphology in aqueous environment for hours, which allows the establishment of adsorption equilibrium between the solution and the adsorbent that retains its initial large specific surface area and improved chemical activity. Consequently, the HMC exhibits notably enhanced capability in reducing the COD of lake water polluted by organics. This work provides a synergistic strategy to rationally design high‐performance adsorbents by simultaneously optimizing the surface area and steering the chemical activity. [ABSTRACT FROM AUTHOR]

This study aimed to determine the role of water hyacinth (Eichhornia crassipes Mart.) organic matter on water retention at pF 2.54 and pF 4.2, available water content, and bulk density (BD). The research method used was a factorial randomized block design. The first factor was the sorghum variety, which consisted of 2 levels, namely, V1 (variety) and V2 (Kawali). The second factor was the dose of water hyacinth organic matter, which consisted of 5 levels, namely P0 (without the application of water hyacinth organic matter), P1 (10 tons.ha-1), P2 (20 tons.ha-1), P3 (30 tons.ha-1), and P4 (40 tons.ha-1). Water retention was measured at pF 2.54 and pF 4.2 using a pressure plate apparatus and pressure membrane apparatus, respectively, and BD was measured using the ring method. The results showed that the treatment of organic matter application and varieties had a significant effect on water retention at pF 2.54, available water content, and BD with the best treatment of 40 tons of organic matter application and Kawali variety, but not affecting water retention at pF 4.2. There was no interaction between water hyacinth organic matter and sorghum varieties to improve water retention and BD. The highest water retention at pF 2.54 was 32.24% (P4), and the highest available water content was 11.67% (P4) but not significantly different from P3 (11.55%); the lowest BD was 1.11 g.cm-3 (P4) but not significantly different from P3 (1.13 g.cm-3). A very strong positive linear and negative linear correlation exists between available water content and BD with plant height, panicle length, and sorghum yield. [ABSTRACT FROM AUTHOR]

The present study determines the environmental quality and carrying capacity for the restoration of the degraded mangroves in Southeast Sulawesi. The physico-chemical conditions of estuarine water and its sediment nutrient contents were determined in both protected and unprotected areas, with no significant difference (p > 0.05) except for nitrogen and inorganic carbon contents of water. The current study found promising environments for the restoration of degraded mangroves in unprotected areas in Southeast Sulawesi. [ABSTRACT FROM AUTHOR]

Comparisons among vegetated and unvegetated intertidal habitats have led to the paradigm that benthic fauna are more abundant and diverse in the former. Mangroves and their associated saltmarshes are the dominant vegetation type in intertidal zones of the Ajuruteua Peninsula, northern Brazil, however until now, there no studies that investigate the benthic fauna among vegetated and unvegetated intertidal habitats. Therefore, the present study compares the macrobenthic fauna among red mangrove (Rhizophora mangle), saltmarsh (Spartina alterniflora) and adjacent unvegetated sediment (mangrove borders and saltmarsh borders) in the Furo Grande tidal channel in the Caeté estuary, northern Brazil. Overall, vegetated habitats have finer sediments, lower salinities and temperatures and higher organic matter and water content than unvegetated habitats. However, the macrofauna structure among the habitats did not fully correspond to this division, perhaps responding instead to differences among the four habitats in detrital production, tidal inundation frequency, leaf litter processing by crabs and rates of predation. Deposit feeding tubificid oligochaetes and capitellid polychaetes were particularly abundant in the mangrove and at mangrove borders probably due to greater availability of suitably processed detritus. [ABSTRACT FROM AUTHOR]

Copyright of Jurnal Ilmu dan Teknologi Kelautan Tropis is the property of IPB University and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Assessing the profitability of river restoration requires knowledge of the importance of individual ecosystem elements for the value of specific ecosystem services. The aim of this study was to experimentally estimate the effect of the presence of bed load on the processes of water self-purification from suspended solids, organic matter and microplastic fibres. The experiment was carried out in channels with and without bed load, simulating conditions in a lowland river. The system was supplemented with artificial sewage containing FPOM and polypropylene fibres. Changes in the amount of suspended solids in the water, as well as organic matter and microplastics in the water and sediment, were recorded over the course of a week. The presence of a bed load increased the rate of suspension removal from the river water many times over. The decomposition rate of organic matter in the sediment was much higher than in the water, reaching 1 g of organic carbon per week. Bed load favoured the immobilisation of large microplastic fibres, facilitating their incorporation into bottom biofilms. The fibres formed a 'skeleton' that led to the formation of larger bed load biofilms. The study suggests that, even without restoring the connection between river water and groundwater, the supply of bed load to the river significantly increases the efficiency of natural processes in the river ecosystem, including self-purification. [ABSTRACT FROM AUTHOR]

This study investigated potential relationships between land-use structure in the catchments of six southern Baltic coastal lakes that differ in the level of hydrological connection with the sea and the lakes' trophic states. Our results indicate that three types of catchments can be distinguished, each of which has a high contribution of agricultural areas, plus: (i) considerable contributions of wetlands and water bodies (C1); (ii) a large contribution of wooded and seminatural habitats (C2); or (iii) a considerable contribution of artificial surfaces (C3). Correlations were analysed between land-use types and single-parameter Carlson's trophic state indices of lakes (TSI Chl , TSI TP , TSI SD , TSI TOC). Type C2 clearly differed from the others and was linked with the lowest trophic state index values. The other two catchment types were similarly related to the fertility of the coastal lakes. The results show that the analysed lakes' levels of connection with the sea do not affect the trophic state of their waters. Catchment structure, analysed using CORINE Land Cover data, is significantly linked with TP and TOC values, but it does not relate to Secchi depth or chlorophyll content of water in the lakes. Wetlands (especially peat bogs) in the catchment area most strongly reduced the phosphorus and organic carbon content of lake water. Furthermore, comparable contributions of natural vs. anthropogenic components (∼1:1) are associated with a lower trophic state of water. The presented results may be important for shaping the proper management of various catchment types in the future, especially when implementing climate change mitigation strategies. [ABSTRACT FROM AUTHOR]

Sattal Lake is one of the important lake of Nainital regions in Uttarakhand state. Physico-chemical characteristics study in the Sattal Lake has been studied. Chemical examination of the water samples collected from the sampling stations of Sattal lake were done for the tests like Total Solids (TS), pH of water, acidity of water, alkalinity of water, hardness of water, sulfate in water, Chlorides in water, Fluorides in water, Dissolved Oxygen in water, biochemical Oxygen Demand in water, chemical oxygen demand in water, total organic carbon / organic matter in water, nitrogen in water, nitrogen, ammonia, Nitrogen, nitrate, nitrogen, nitrite, nitrogen, organic and Metals in water. The study indicates that Sattal Lake is becoming a oligotrophic lake. The data have been reported in the study or present paper. [ABSTRACT FROM AUTHOR]

The structure of soil is critical for the ecosystem services it provides since it regulates many key soil processes, including water, air and solute movement, root growth and the activity of soil biota. Soil structure is dynamic, driven by external factors such as land management and climate and mediated by a wide range of biological agents and physical processes operating at strongly contrasting time‐scales, from seconds (e.g., tillage) to many decades (e.g., faunal activity and soil aggregation). In this respect, positive feedbacks in the soil–plant system may lead in the longer term to soil physical degradation or to the recovery of structurally poor soils. As far as we are aware, no existing soil‐crop model can account for such processes. In this paper, we describe a new soil‐crop model (USSF, Uppsala model of Soil Structure and Function) that accounts for the effects of soil structure dynamics on water and organic matter cycling at the soil profile scale. Soil structure dynamics are expressed as time‐varying physical (bulk density, porosity) and hydraulic properties (water retention, hydraulic conductivity) responding to the activity of biological agents (i.e., earthworms, plant roots) and physical processes (i.e., tillage, soil swell‐shrink) at seasonal to decadal time‐scales. In this first application of the model, we present the results of 30‐year scenario simulations that illustrate the potential role and importance of soil structure dynamics for the soil water balance, carbon storage in soil, root growth, and winter wheat yields on two soils (loam and clay) in the climate of central Sweden. A sensitivity analysis was also performed for these two scenarios using the Morris method of elementary effects, which revealed that the most sensitive parameters controlling soil structure dynamics in the USSF model are those determining aggregation induced by organic matter turnover and swell/shrink. We suggest that the USSF model is a promising new tool to investigate a wide range of processes and phenomena triggered by land use and climate change. Results from this study show that feedback in the soil‐crop system mediated by the dynamics of soil physical and hydraulic properties are potentially of central importance for long‐term predictions of soil water balance, crop production, and carbon sequestration under global change. [ABSTRACT FROM AUTHOR]

The problem of eutrophication of water objects as a global process is analyzed. The volumes of increasing planetary use of N and P, the dispersion of which together with climate warming leads to an increase in the nutrient content of lakes and rivers, are shown. The results of original studies of remote lakes of the Arctic zone are provided. The tendency toward an increase in the contents of N and P, as well as organic matter in water lakes even in case of the absence of anthropogenic impact, is revealed. It is proved that the climate warming mostly affects the increase in the nutrient content and the trophic status of lakes. [ABSTRACT FROM AUTHOR]

Uranium isotopes in ancient sedimentary rocks have emerged as a powerful proxy for the oxygenation history of Earth surface environments. Proper quantitative interpretation of δ238U data hinges, however, on an understanding of isotopic fractionation associated with uranium removal to sediments under different redox conditions. Whereas oxygenated environments are plentiful in the modern ocean, euxinic settings are scarce today, and persistently ferruginous settings are not a feature in the modern ocean, leaving lakes as our best analogs for iron-rich waters. These challenges to studying δ238U behavior under contemporaneous oxic, euxinic (sulfidic), and ferruginous (iron-rich) marine conditions limit our ability to apply the isotope proxy to ancient oceans. Here, we present δ238U data from five coeval cores through the Lower Mississippian Sunbury Shale of the semi-restricted Appalachian Basin (North America), which were deposited across a strong redox gradient from intermittently oxic conditions proximal to the Catskill Delta, to ferruginous conditions in the central basin axis and euxinic conditions along the basin-bounding Cumberland Sill. Overall, we find that both euxinic and ferruginous environments are capable of imparting high degrees of uranium isotope fractionation and that δ238U values covary more strongly with total organic carbon (TOC) and trace metal abundances than they do with the presence of euxinic versus ferruginous conditions. We suggest uranium sorption or incorporation into sinking organic matter in the water column as a mechanism for generating positive covariation between δ238U and TOC, particularly at lower TOC concentrations. We also compare our δ238U data to broadly coeval carbonates from Nevada, which can be used to estimate Early Mississippian seawater δ238U values. We find that Sunbury Shale cores deposited under stably anoxic conditions (both euxinic and ferruginous) and under consistently brackish salinities away from freshwater sources record an increasing δ238U trend through time that loosely mirrors the record for carbonates (and thus estimates for seawater) with an offset of ∼0.4‰ to 1.1‰, depending on the inferred offset between carbonate and seawater. In contrast, cores deposited close to the Catskill Delta and in a shallow oceanic-restricted basin transition across the Cumberland Sill record a decreasing δ238U trend through time, opposite the inferred seawater trend and suggestive of entirely local controls on δ238U values. Ultimately, these data suggest that highly productive environments with high rates of organic carbon loading can exert a strong control on the global δ238U mass balance regardless of whether euxinic or ferruginous conditions are present. These results necessitate a partial reassessment of the processes controlling δ238U variability in seawater and sedimentary rocks through Earth history. [ABSTRACT FROM AUTHOR]

Speleothem fluorescence can provide insights into past vegetation dynamics and stalagmite chronology. However, its origin and especially the formation of fluorescent laminations in stalagmites are poorly understood. We conducted a year-long monthly monitoring of drip water fluorescence in La Vallina Cave (northern Iberian Peninsula) and compared the results to drip water chemistry and active speleothems from the same sites. Drip waters were analyzed using fluorescence spectroscopy and parallel factor analysis (PARAFAC). The resulting five-component model indicates contributions from vegetation, microbial activity, and bedrock. Intra-site fluorescence variability is mainly influenced by changes in overlying vegetation, water reservoir time, and respiration rates. Contrary to prevailing views, we find no systematic increase in drip water fluorescence during rainy conditions across drip sites and seasonal variations in drip water fluorescence are absent at a location where present-day speleothem layers form. Our findings challenge the notion of a higher abundance of humic-like fluorescence during the rainy season as the primary cause for layer formation and suggest additional controls on drip water fluorescence, such as bedrock interaction and microbial reprocessing. We also propose that growth rate may control the dilation of the fluorescence signal in stalagmites, indicating other potential mechanisms for fluorescent layer formation. [ABSTRACT FROM AUTHOR]

Improving the removal of micropollutants from wastewater effluent is crucial to protect surface water quality. This can be achieved by applying adsorption to granular activated carbon. However, activated carbon filters used for wastewater treatment have a shorter lifetime than filters used for drinking water production. It was assessed whether this is related exclusively to the higher organic matter concentration in wastewater effluent, compared to drinking water, or also to organic matter characteristics. Influent of activated carbon filters from a drinking water plant and wastewater effluent were used as organic matter sources, and their effect on micropollutant affinity for activated carbon and adsorption rate was compared at the same dissolved organic carbon concentrations. Organic matter characterization (excitation–emission matrices and parallel factor—PARAFAC—analysis) and fractionation methods, based on size and hydrophobicity, were combined to assess the relevance of specific components that affect micropollutant removal. The results show that both organic matter concentration and composition determine their effect on micropollutant affinity for activated carbon and adsorption rate. The affinity of micropollutants for activated carbon is more reduced in the presence of organic matter from wastewater effluent. Adsorption rate is lower in the presence of organic matter originating from drinking water plants at levels around 10 mg/L, compared to wastewater effluent. One PARAFAC component is more abundant in drinking water organic matter and is likely responsible for this effect. This knowledge supports the development of strategies to overcome bottlenecks on the application of activated carbon filters in water treatment. [ABSTRACT FROM AUTHOR]

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The food industry has extensively explored postharvest microbial control, seeking viable technologies to ensure food safety. Although numerous chlorine-based commercial sanitizers serve this purpose, many are plagued by constraints such as instability and diminished disinfectant efficacy. These issues arise from exposure to organic matter in wash water, light, or air. As an innovative and promising alternative, slightly acidic electrolyzed water (SAEW) has emerged, captivating attention for its robust sterilization potential and eco-friendliness in agricultural and food sectors. SAEW generated via electrolysis of a diluted hydrochloric acid (HCl) solution with concentrations ranging from 2 to 6% or aqueous solution of sodium chloride (NaCl) in a nonmembrane electrolytic chamber is reported to possess equivalent antimicrobial properties as strong acidic electrolyzed water (StAEW). In contrast to traditional chlorine sanitizers, SAEW leaves less chlorine residue on sanitized foods such fresh-cut fruit and vegetables, meat, poultry, and aquatic products due to its low available chlorine concentration (ACC). Its near neutral pH of 5 to 6.5 not only renders it environmentally benign but also mitigates the production of chlorine gas, a contrast to low pH conditions seen in StAEW generation. The bactericidal effect of SAEW against various strains of foodborne pathogens is widely believed and accepted to be due to the combined action of high oxidation-reduction-potential (ORP) reactions and undissociated hypochlorite/hypochlorous acid (HOCl). Consequently, a burgeoning interest surrounds the potential of SAEW for sanitation in the food industry, offering an alternative to address shortcomings in sodium hypochlorite solutions and even StAEW. It has been hypothesized from a number of studies that SAEW treatment can increase the quality and nutritional value of harvested fruits, which in turn may enhance their ability to be stored. Therefore, SAEW is not only a promising sanitizer in the food industry but also has the potential to be an efficient strategy for encouraging the accumulation of bioactive chemicals in plants, especially if it is used extensively. This review encapsulates the latest insights concerning SAEW, encompassing its antimicrobial effectiveness, sanitization mechanism, advantages vis-à-vis other sanitizers, and plausible applications across the food industry. [ABSTRACT FROM AUTHOR]

Former coal mines hosted in Upper Carboniferous silt- and sandstones in the Ruhr Basin, NW Germany, are currently examined for post-mining applications (e.g. geothermal energy) and are also important tight-gas reservoir analogs. Core material from well Pelkum-1, comprising Westphalian A (Bashkirian) delta deposits, was studied. The sandstones and siltstones are generally tight (mean porosity 5.5%; mean permeability 0.26 mD). Poor reservoir properties primarily result from pronounced mechanical compaction (mean COPL 38.8%) due to deep burial and high contents of ductile rock fragments. Better reservoir properties in sandstones (>8%; >0.01 mD) are due to (1) lower volumes of ductile grains (<38%) that deform during mechanical compaction and (2) higher volumes in feldspar and unstable rock fragments. During burial these form secondary porosity (>1.5%) resulting from acidic pore water from organic matter maturation. Still, sandstones with enhanced porosities only show a small increase in permeability since authigenic clays (i.e. kaolinite and illite) or late diagenetic carbonates (i.e. siderite and ferroan dolomite/ankerite) clog secondary porosity. Quartz cementation has a minor impact on reservoir properties. Evaluating the Si/Al ratio can be a suitable proxy to assess grain sizes and may be a convenient tool for further exploration. Supplementary material: Lithologs and petrophysical data of well Pelkum-1 are available at https://doi.org/10.6084/m9.figshare.c.7003156 [ABSTRACT FROM AUTHOR]

This study delves into the critical issue of water pollution caused by the presence of metal oxides, synthetic dyes, and dissolved organic matter, shedding light on their potential ramifications for both the environment and human health. Metal oxides, ubiquitous in industrial processes and consumer products, are known to leach into water bodies, posing a significant threat to aquatic ecosystems. Additionally, synthetic dyes, extensively used in various industries, can persist in water systems and exhibit complex chemical behavior. This review provides a comprehensive examination of the toxicity associated with metal oxides, synthetic dyes, and dissolved organic matter in water systems. We delve into the sources and environmental fate of these contaminants, highlighting their prevalence in natural water bodies and wastewater effluents. The study highlights the multifaceted impacts of them on human health and aquatic ecosystems, encompassing effects on microbial communities, aquatic flora and fauna, and the overall ecological balance. The novelty of this review lies in its unique presentation, focusing on the toxicity of metal oxides, dyes, and dissolved organic matter. This approach aims to facilitate the accessibility of results for readers, providing a streamlined and clear understanding of the reported findings. [ABSTRACT FROM AUTHOR]

The excessive accumulation of foam in wastewater treatment plant (WWTP) tanks can impede proper aeration, hindering the effective removal of organic matter from the water. This study proposes a novel technique to monitor in real time the presence of foams in WWTP tanks by using texture segmentation models trained with centralized and federated approaches. These models are designed to segment the foam and quantify the percentage of foam coverage across the entire tank surface. This data provides plant operators with crucial information for identifying the optimal time for foam removal. The proposed methodology is integrated into an image processing pipeline that involves acquiring images using a PTZ camera, ensuring the absence of anomalies in the captured images, and implementing a real-time communication method for event notifications to plant operators. The models exhibit noteworthy performance, achieving an 86% Dice score in foam segmentation, with comparable results obtained through both centralized and federated training. Implemented in a wastewater treatment plant, this integrated pipeline enhances operational efficiency while concurrently reducing costs. [ABSTRACT FROM AUTHOR]

The alpine area has become a sensitive indicator and amplifier of global climate change and human activities because of its unique geographical and climatic conditions. Being an essential part of biochemical cycling, dissolved organic matter (DOM) could effectively help understand the process, structure, and function of alpine aquatic ecosystems. Due to the low content and sampling difficulties, the analysis of DOM in alpine water demands high sensitivity with low sample volume, which has not been comprehensively reviewed. This review summarizes the DOM sampling, pretreatment, and analysis methods involving the characterization of concentration, spectroscopy, and molecular structure. Overall, conventional parameters are the basis of advanced characterization methods. Spectroscopic tests can reveal the optical properties of DOM in response to lights from ultraviolet to infrared wavelengths, to distinguish the chemical composition. Molecular structure characterizations can provide microscopic information such as functional groups, element ratios, and molecular weights. The combination of multiple methods can depict DOM composition from multiple perspectives. In sum, optimized sampling and pretreatment, high-sensitivity molecular characterization, and method integration are crucial for effectively analyzing DOM components in alpine waters. These perspectives help to standardize the DOM characterization process and to understand the correlation between DOM composition and its properties, as well as the migration and transformation of DOM. [ABSTRACT FROM AUTHOR]