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Water vapor produces a series of diagnostic emission lines in the near infrared between 2.60 and 2.75 microns. The Visual and Infrared Mapping Spectrometer (VIMS) onboard the Cassini spacecraft detected this emission signal from Enceladus' plume, and so VIMS observations provide information about the variability of the plume's water vapor content. Using a data set of 249 spectral cubes with relatively high signal-to-noise ratios, we confirmed the strength of this water-vapor emission feature corresponds to a line-of-sight column density of order 10^20 molecules/m^2, which is consistent with previous measurements from Cassini's Ultraviolet Imaging Spectrograph (UVIS). Comparing observations made at different times indicates that the water-vapor flux is unlikely to vary systematically with Enceladus' orbital phase, unlike the particle flux, which does vary with orbital phase. However, variations in the column density on longer and shorter timescales cannot be ruled out and merit further investigation., Comment: 16 pages, 11 figures, 1 supplemental table (ascii format)

The nucleus of comet 67P/Churyumov-Gerasimenko exhibits a broad spectral reflectance feature around 3.2 $\mu$m, which is omnipresent in all spectra of the surface, and whose attribution has remained elusive since its discovery. Based on laboratory experiments, we have shown that most of this absorption feature is due to ammonium (NH4+) salts mixed with the dark surface material. The depth of the band is compatible with semi-volatile ammonium salts being a major reservoir of nitrogen in the comet, which could dominate over refractory organic matter and volatile species. These salts may thus represent the long-sought reservoir of nitrogen in comets, possibly bringing their nitrogen-to-carbon ratio in agreement with the solar value. Moreover, the reflectance spectra of several asteroids are compatible with the presence of NH4+ salts at their surfaces. The presence of such salts, and other NH4+-bearing compounds on asteroids, comets, and possibly in proto-stellar environments, suggests that NH4+ may be a tracer of the incorporation and transformation of nitrogen in ices, minerals and organics, at different phases of the formation of the Solar System.

The Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) suite of instruments operated throughout the over two years of the Rosetta mission operations in the vicinity of comet 67P/Churyumov-Gerasimenko. It measured gas densities and composition throughout the comet's atmosphere, or coma. Here we present two-years' worth of measurements of the relative densities of the four major volatile species in the coma of the comet, H2O. CO2, CO and O2, by one of the ROSINA sub-systems called the Double Focusing Mass Spectrometer (DFMS). The absolute total gas densities were provided by the Comet Pressure Sensor (COPS), another ROSINA sub-system. DFMS is a very high mass resolution and high sensitivity mass spectrometer able to resolve at a tiny fraction of an atomic mass unit. We have analyzed the combined DFMS and COPS measurements using an inversion scheme based on spherical harmonics that solves for the distribution of potential surface activity of each species as the comet rotates, changing solar illumination, over short intervals and as the comet changes distance from the sun and orientation of its spin axis over long time intervals. We also use the surface boundary conditions derived from the inversion scheme to simulate the whole coma with our fully kinetic Direct Simulation Monte Carlo model and calculate the production rates of the four major species throughout the mission. We compare the derived production rates with revised remote sensing observations by the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) as well as with published observations from the Microwave Instrument for the Rosetta Orbiter (MIRO). Finally we use the variation of the surface production of the major species to calculate the total mass loss over the mission and, for different estimates of the dust/gas ratio, calculate the variation of surface loss over the nucleus., Comment: 144 pages, 9 figures, 8 tables, 1 supplemental table

The goal of Project GAUSS is to return samples from the dwarf planet Ceres. Ceres is the most accessible ocean world candidate and the largest reservoir of water in the inner solar system. It shows active cryovolcanism and hydrothermal activities in recent history that resulted in minerals not found in any other planets to date except for Earth's upper crust. The possible occurrence of recent subsurface ocean on Ceres and the complex geochemistry suggest possible past habitability and even the potential for ongoing habitability. Aiming to answer a broad spectrum of questions about the origin and evolution of Ceres and its potential habitability, GAUSS will return samples from this possible ocean world for the first time. The project will address the following top-level scientific questions: 1) What is the origin of Ceres and the origin and transfer of water and other volatiles in the inner solar system? 2) What are the physical properties and internal structure of Ceres? What do they tell us about the evolutionary and aqueous alteration history of icy dwarf planets? 3) What are the astrobiological implications of Ceres? Was it habitable in the past and is it still today? 4) What are the mineralogical connections between Ceres and our current collections of primitive meteorites? GAUSS will first perform a high-resolution global remote sensing investigation, characterizing the geophysical and geochemical properties of Ceres. Candidate sampling sites will then be identified, and observation campaigns will be run for an in-depth assessment of the candidate sites. Once the sampling site is selected, a lander will be deployed on the surface to collect samples and return them to Earth in cryogenic conditions that preserves the volatile and organic composition as well as the original physical status as much as possible., Comment: Section 3.4 revised; List of team members updated; Typos corrected

Laboratory spectral measurements of relevant analogue materials were performed in the framework of the Rosetta mission in order to explain the surface spectral properties of comet 67P. Fine powders of coal, iron sulphides, silicates and their mixtures were prepared and their spectra measured in the Vis-IR range. These spectra are compared to a reference spectrum of 67P nucleus obtained with the VIRTIS/Rosetta instrument up to 2.7 {\mu}m, excluding the organics band centred at 3.2 {\mu}m. The species used are known to be chemical analogues for cometary materials which could be present at the surface of 67P. Grain sizes of the powders range from tens of nanometres to hundreds of micrometres. Some of the mixtures studied here actually reach the very low reflectance level observed by VIRTIS on 67P. The best match is provided by a mixture of sub-micron coal, pyrrhotite, and silicates. Grain sizes are in agreement with the sizes of the dust particles detected by the GIADA, MIDAS and COSIMA instruments on board Rosetta. The coal used in the experiment is responsible for the spectral slope in the visible and infrared ranges. Pyrrhotite, which is strongly absorbing, is responsible for the low albedo observed in the NIR. The darkest components dominate the spectra, especially within intimate mixtures. Depending on sample preparation, pyrrhotite can coat the coal and silicate aggregates. Such coating effects can affect the spectra as much as particle size. In contrast, silicates seem to play a minor role., Comment: 12 pages, 11 figures, 2 tables

The processes that led to the formation of the planetary bodies in the Solar System are still not fully understood. Using the results obtained with the comprehensive suite of instruments on-board ESA's Rosetta mission, we present evidence that comet 67P/Churyumov-Gerasimenko likely formed through the gentle gravitational collapse of a bound clump of mm-sized dust aggregates ("pebbles"), intermixed with microscopic ice particles. This formation scenario leads to a cometary make-up that is simultaneously compatible with the global porosity, homogeneity, tensile strength, thermal inertia, vertical temperature profiles, sizes and porosities of emitted dust, and the steep increase in water-vapour production rate with decreasing heliocentric distance, measured by the instruments on-board the Rosetta spacecraft and the Philae lander. Our findings suggest that the pebbles observed to be abundant in protoplanetary discs around young stars provide the building material for comets and other minor bodies., Comment: accepted by MNRAS

From August to November 2014 the Rosetta orbiter has performed an extensive observation campaign aimed at the characterization of 67P/CG nucleus properties and to the selection of the Philae landing site. The campaign led to the production of a global map of the illuminated portion of 67P/CG nucleus. During this prelanding phase the comet's heliocentric distance decreased from 3.62 to 2.93 AU while Rosetta was orbiting around the nucleus at distances between 100 to 10 km. VIRTIS-M, the Visible and InfraRed Thermal Imaging Spectrometer - Mapping channel (Coradini et al. 2007) onboard the orbiter, has acquired 0.25-5.1 micron hyperspectral data of the entire illuminated surface, e.g. the north hemisphere and the equatorial regions, with spatial resolution between 2.5 and 25 m/pixel. I/F spectra have been corrected for thermal emission removal in the 3.5-5.1 micron range and for surface's photometric response. The resulting reflectance spectra have been used to compute several Cometary Spectral Indicators (CSI): single scattering albedo at 0.55 micron, 0.5-0.8 micron and 1.0-2.5 micron spectral slopes, 3.2 micron organic material and 2.0 micron water ice band parameters (center, depth) with the aim to map their spatial distribution on the surface and to study their temporal variability as the nucleus moved towards the Sun. Indeed, throughout the investigated period, the nucleus surface shows a significant increase of the single scattering albedo along with a decrease of the 0.5-0.8 and 1.0-2.5 micron spectral slopes, indicating a flattening of the reflectance. We attribute the origin of this effect to the partial removal of the dust layer caused by the increased contribution of water sublimation to the gaseous activity as comet crossed the frost-line., Comment: 19 Figures, 5 Tables. Accepted for publication in Icarus journal on 29 February 2016

The spectral position of the 3.6 micron continuum peak measured on Cassini-VIMS I/F spectra is used as a marker to infer the temperature of the regolith particles covering the surfaces of Saturn's icy satellites. This feature is characterizing the crystalline water ice spectrum which is the dominant compositional endmember of the satellites' surfaces. Laboratory measurements indicate that the position of the 3.6 micron peak of pure water ice is temperature-dependent, shifting towards shorter wavelengths when the sample is cooled, from about 3.65 micron at T=123 K to about 3.55 micron at T=88 K. A similar method was already applied to VIMS Saturn's rings mosaics to retrieve ring particles temperature (Filacchione et al., 2014). We report here about the daytime temperature variations observed on the icy satellites as derived from three different VIMS observation types. Temperature maps are built by mining the complete VIMS dataset collected in years 2004-2009 (pre-equinox) and in 2009-2012 (post equinox) by selecting pixels with max 150 km/pixel resolution. VIMS-derived temperature maps allow to identify thermal anomalies across the equatorial lens of Mimas and Tethys., Comment: 42 pages, 15 figures. Accepted for publication in Icarus journal on February 8th 2016

In this work we study the link between the evolution of the internal structure of Vesta and thermal heating due to 26Al and 60Fe and long-lived radionuclides, taking into account the chemical differentiation of the body and the affinity of 26Al with silicates. Differentiation takes place in all scenarios in which Vesta completes its accretion in less than 1.4 Ma after the injection of 26Al into the Solar Nebula. In all those scenarios where Vesta completes its formation in less than 1 Ma from the injection of 26Al, the degree of silicate melting reaches 100 vol. % throughout the whole asteroid. If Vesta completed its formation between 1 and 1.4 Ma after 26Al injection, the degree of silicate melting exceeds 50 vol. % over the whole asteroid but reaches 100 vol. % only in the hottest, outermost part of the mantle in all scenarios where the porosity is lower than 5 vol. %. If the formation of Vesta occurred later than 1.5 Ma after the injection of 26Al, the degree of silicate melting is always lower than 50 vol. % and is limited only to a small region of the asteroid. The radiation at the surface dominates the evolution of the crust which ranges in thickness from 8 to about 30 km after 5 Ma: a layer about 3-20 km thick is composed of primitive unmelted chondritic material while a layer of about 5-10 km is eucritic., Comment: 22 pages, 3 tables, 6 figures. Accepted for publication on Meteoritics and Planetary Science, Special Issue for the Dawn Mission on the composition of Vesta