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In large format additive manufacturing (LFAM), a keener understanding of the relationship between the manufacture method and material temperature dependency is needed for the production of large polymer parts. Statistical analyses supported by material properties and a meso-structural understanding of LFAM are applied to elucidate tensile data trends. The data from LFAM polyethylene terephthalate glycol with 30% carbon fiber (CF) (PETG CF30%) panels (diagonal, horizontal, and vertical in the x-y print plane) and injection-molded specimens tensile tested at six different testing temperatures (room temperature, 40 °C, 50 °C, 60 °C, 70 °C, and 80 °C) were used for statistical analyses. A standard deviation, a coefficient of variation, and a two-way and one-way analyses of variance (ANOVA) were conducted. The manufacturing method (44.2%) and temperature (47.4%) have a strong effect on the ultimate tensile strength, in which temperature (82.6%) dominates Young's modulus. To explain the difference between the ultimate tensile strength of vertical, diagonal, and horizontal specimens at room temperature, a visual inspection of the specimen failure was conducted and the maximum stress at the crack tip was calculated analytically. The decreased strength in the diagonal specimens resulted from the reliance on interlaminar adhesion strength. Future work will consider the effect of the void space variation on tensile strength variance. [ABSTRACT FROM AUTHOR]

In this investigation, composite poly(lactic acid) (PLA) systems of hollow glass microspheres (MS) and carbonyl iron particles (CIP) were processed and characterized to investigate the effects of using conductive and insulating particles as additives in a polymer system. PLA-MS and PLA-CIP were set at the two levels of 3.94 and 7.77 vol.% for each particle type to study the effects of the particle material type and loading on neat PLA's thermal properties. It was observed during the twin-screw extrusion that the addition of CIP greatly decreased the viscosity of the PLA melt during processing. Correlations determined using thermogravimetric analysis, differential scanning calorimetry, thermal conductivity, and shear rheology provided insights into how thermal stability was affected. The incorporation of MS and CIP altered thermal properties such as the glass transition temperature (Tg), melting temperature (Tm), and cold crystallization temperature (Tcc). The metal CIP-filled systems had large increases in their thermal conductivity values and viscoelastic transitions compared to those with PLA that were correlated with the observed overheating during extrusion. [ABSTRACT FROM AUTHOR]

This study presents the application of an analytical model to describe the rheological behavior of cement pastes containing silica fume at replacement rates of up to 30% by mass. The analytical model hypothesizes how water interacts with particles in a cementitious system. The coating thickness of water surrounding each particle in the system is estimated. This coating thickness is shown to correlate strongly with measured rheological properties when fit to the Herschel-Bulkley model. To calculate coating thickness, it is necessary to account for the water absorbed by nonhydraulic components in the system, whether aggregate, supplementary cementitious materials, or mineral. The results suggest that silica fume particles may be absorptive, and this absorption capacity, although small, must be considered when designing water-starved cementitious materials. The experimental investigation involved the rheological testing of three water-binder ratios (0.20, 0.30, 0.45), three silica fume replacement levels (10%, 20%, 30%), and eight different silica fume products. [ABSTRACT FROM AUTHOR]