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Recycling of material at subduction zones has fundamental implications for melt composition and mantle rheology. Ocean island basalts sample parts of the mantle from variable depths that have been diversely affected by subduction zone processes and materials, including the subducted slab, metasomatising melts and fluids. Resultant geochemical differences are preserved at a variety of scales from melt inclusions to whole rocks, from individual islands to chains of islands. Here we examine a global dataset of ocean island basalt compositions with a view to understanding the connection between silica-saturation, olivine compositions, and halogens in glass and olivine-hosted melt inclusions to reveal information regarding the mantle sources of intraplate magmatism. We find that minor elements incorporated into olivine, although informative, cannot unambiguously discriminate between different source contributions, but indicate that none of the OIB analysed here are derived solely from dry peridotite melting. Nor can differences in lithospheric thickness explain trace element variability in olivine between different ocean islands. We present new halogen (F, Cl, Br/Cl, I/Cl) data along with incompatible trace element data for the global array and encourage measurement of fluorine along with heavier halogens to obtain better insight into halogen cycling. We suggest that Ti-rich silica-undersaturated melts require a contribution from carbonated lithosphere, either peridotite or eclogite and are an important component sampled by ocean island basalts, together with altered oceanic crust. These results provide new insights into our understanding of mantle-scale geochemical cycles, and also lead to the potential for the mantle transition zone as an underestimated source for observed volatile and trace-element enrichment in ocean island basalts.

The martian meteorite Northwest Africa (NWA) 8114 is a regolith breccia grouped with the NWA 7034 (‘Black Beauty’) stone and others. The meteorite, with its complex rock and mineral load, records over 4.4 billion years of martian geological and atmospheric history. In this work we present new analyses of noble gases in NWA 8114, and consider the constraints they impose on the evolution of the martian atmosphere over the past 4 billion years. We also report a petrographic overview, halogen abundances, and an argon isotope age, which provide context for interpreting the noble gas data. The krypton and xenon elemental signature of NWA 8114 is elementally fractionated with respect to the present-day martian atmosphere as measured in shergottite glasses; there is no requirement for a contribution from the ancient martian atmosphere in our data. The xenon isotopic composition incorporates (i) a component enriched in 129Xe (maximum 129Xe/132Xe = 2.450 ± 0.045 compared with a solar ratio of ∼ 1), which is similar to the present day martian atmosphere, (ii) a cosmic-ray spallation component dominated by production from barium, and (iii) a fission component. We estimate a cosmic ray exposure (CRE) age of 5.7 ± 1.3 Myr from cosmogenic 21Ne and 38Ar. Understanding how the martian atmosphere has changed through the planet’s history is a key part of understanding the planet’s geological history and evolution. We develop a model for the evolution of the martian atmosphere constrained by the amount of spallation-derived xenon in the atmosphere today and the evolution of the 129Xe/132Xe ratio over time. A baseline model in which the early atmosphere collapsed 3.7 Gyr ago (and assuming no further loss) requires a constant degassing of the crustal budget of spallation xenon of 0.034 % Myr−1 to accumulate sufficient spallation-derived xenon in the atmosphere. Combining constraints imposed by the 129Xe/132Xe ratio with the spallation budget requires loss of xenon from the martian atmosphere over the last 3.7 Gyr, with the present day budget being as little as 20 % of that at the start of this period., Geochimica et Cosmochimica Acta, 336, ISSN:0016-7037, ISSN:1872-9533