Search

Highlights There are increasing need for the development of electromagnetic wave‐absorbing materials since the growing concern about electromagnetic interference. However, materials with integrated structure and function are difficult to attain due to the high content of functional fillers. In this paper, carbon nanotubes (CNTs) were formed into a three‐dimensional porous framework, known as Buckypaper (BP), which was subsequently in situ deposited with iron tetraoxide (Fe3O4) through the sol–gel method and incorporated into epoxy resin to create Fe3O4/BP/EP composites by hot pressing. The three‐dimensional porous structure of Fe3O4/BP facilitates the high‐content incorporation and uniform dispersion of CNTs and Fe3O4 nanoparticles. The results indicate that the 33%Fe3O4/BP/EP composite achieved an optimal reflection loss of −38.41 dB and an absorption bandwidth of 3.28 GHz at the optimal matching thickness of 1.5 mm. This performance primarily stems from Fe3O4 adjusting the impedance matching of BP and enhancing the magnetic loss capability of CNTs. Furthermore, the deposition of Fe3O4 on BP improves the mechanical strength of BP/EP, The 17% Fe3O4/BP/EP composite achieves a tensile strength of 35.09 MPa, which is 46.27% higher than that of BP/EP and 92.38% higher than pure EP. Fe3O4/BP was prepared by deposition of Fe3O4 onto surfaces of the CNTs framework. Fe3O4/BP/EP composites with different Fe3O4/BP were fabricated. Fe3O4 adjusts impedance matching of BP, and forms heterogeneous interfaces. Fe3O4/BP/EP composites exhibit excellent wave absorption performance. Fe3O4/BP/EP composites possess improved mechanical properties. [ABSTRACT FROM AUTHOR]

In recent years, the demand for solid, thin, and flexible energy storage devices has surged in modern consumer electronics, which require autonomy and long duration. In this context, hybrid supercapacitors have become strategic, and significant efforts are being made to develop cells with higher energy densities while preserving the power density of conventional supercapacitors. Motivated by these requirements, we report the development of a new high-performance dual-redox-mediator supercapacitor. In this study, cells were constructed using fully moldable buckypapers (BPs), composed of carbon nanotubes and cellulose nanofibers, as electrodes. We evaluated the compatibility of BPs with hydrogel polymer electrolytes, based on 1 mol L−1 H2SO4 and polyvinyl alcohol (PVA), supplemented with different redox species: methylene blue, indigo carmine, and hydroquinone. Solid cells were constructed containing two active redox species to maximize the specific capacity of each electrode. Considering the main results, the dual-redox-mediator supercapacitor exhibits high energy density of 32.0 Wh kg−1 (at 0.8 kW kg−1) and is capable of delivering 25.9 Wh kg−1 at high power demand (4.0 kW kg−1). Stability studies conducted over 10,000 galvanostatic cycles revealed that the PVA polymer matrix benefits the system by inhibiting the crossover of redox species within the cell. [ABSTRACT FROM AUTHOR]

A novel modeling approach is developed for investigating the effectiveness of buckypaper (BP), a porous membrane made of a highly cross-linked network of carbon nanotubes, in improving the electromagnetic interference (EMI) shielding properties of carbon fiber-reinforced polymer (CFRP) composites. The methodology uses quantum tunneling-based equivalent electrical circuits and Monte Carlo simulations to predict the frequency-dependent electrical conductivity and EMI shielding effectiveness (SE) of the hybrid BP/CFRP composites. The study examines a signal frequency range of 50 MHz to 12 GHz that includes the very high and X-band. The results show that at a frequency of 12 GHz, the transverse conductivity increases to approximately 12.67 S/m, while the longitudinal conductivity decreases to about 3300 S/m from an initial value of 40,000 S/m. These results are then integrated into the ANSYS High-Frequency Structure Simulator to predict SE by simulating the propagation of electromagnetic waves through a semi-infinite composite shield element. The numerical simulations illustrate that incorporating BP significantly improves the SE of CFRP composites beyond 2 GHz owing to its high conductivity in that frequency range. For instance, at 12 GHz signal frequency, adding a single BP interleaf enhances the SE of a [90, 0] laminate by up to ~64%. [ABSTRACT FROM AUTHOR]

We describe the creation of a conductive microcavity based on the assembly of two pieces of carbon nanotube buckypaper for the entrapment of two enzymes, horseradish peroxidase (HRP) and glucose oxidase (GOx), as well as a redox mediator: 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid diammonium salt (ABTS). The hollow electrode, employing GOx, HRP, and the mediator, as an electrochemical enzyme cascade model, is utilized for glucose sensing at a potential of 50 mV vs. Ag/AgCl. This bienzyme electrode demonstrates the ability to oxidize glucose by GOx and subsequently convert H2O2 to water via the electrical wiring of HRP by ABTS. Different redox mediators (ABTS, potassium hexacyanoferrate (III), and hydroquinone) are tested for HRP wiring, with ABTS being the best candidate for the electroenzymatic reduction of H2O2. To demonstrate the possibility to optimize the enzyme cascade configuration, the enzyme ratio is studied with 1 mg HRP combined with variable amounts of GOx (1–4 mg) and 2 mg GOx combined with variable amounts of HRP (0.5–2 mg). The bienzyme electrode shows continuous operational stability for over a week and an excellent storage stability in phosphate buffer, with a decay of catalytic current by only 29% for 1 mM glucose after 100 days. [ABSTRACT FROM AUTHOR]

Carbon fiber/polyether ether ketone thermoplastic composites formed by automated fiber placement are susceptible to delamination damage. The interlaminar mechanical performance of carbon fiber/polyether ether ketone laminates can be enhanced in situ by doping carbon nanotubes in the plies. In this paper, the interfacial bonding energy between polyether ether ketone and buckypaper is analyzed by molecular dynamics. A novel method for preparing buckypaper/polyether ether ketone reinforcement materials and buckypaper/carbon fiber/polyether ether ketone multi-scale thermoplastic composites is proposed. The microstructure, crystallinity, and mechanical properties are analyzed. The results show that the polyether ether ketone resin fully penetrate the buckypaper interior and have a good interfacial bonding property. The buckypaper/polyether ether ketone composite films have a dense structure and are well-doped into the plies of carbon fiber/polyether ether ketone laminates. Compared with carbon fiber/polyether ether ketone laminates, the crystallinity, interlaminar shear strength, Model-I fracture toughness, and Model-II fracture toughness of buckypaper/carbon fiber/polyether ether ketone laminates are increased by 22.3%, 22.2%, 20%, and 9.5%, respectively. [ABSTRACT FROM AUTHOR]

AbstractStructural health monitoring (SHM) of brittle structures will require versatile sensing instrumentation that can transmitting transient loadings into rapid electrical responses. This research investigated the sensing performance of CNT Buckypaper (CNT-BP) thin-films on stressed fiber-reinforced composites, which are integral materials to various industries of the infrastructure. Three-point bending experiments revealed an extraordinary gauge factor (∼40) and impressive response linearity. Electrical responses were instantaneous; moreover, low force impacts were detectable, the sensors provided clear indications of spatial recognition. Most importantly, the manufacturing methods are scalable and cost effective compared to commercialized strain gauges. This study examined micro-strain measurements (

In recent years, the demand for solid, thin, and flexible energy storage devices has surged in modern consumer electronics, which require autonomy and long duration. In this context, hybrid supercapacitors have become strategic, and significant efforts are being made to develop cells with higher energy densities while preserving the power density of conventional supercapacitors. Motivated by these requirements, we report the development of a new high-performance dual-redox-mediator supercapacitor. In this study, cells were constructed using fully moldable buckypapers (BPs), composed of carbon nanotubes and cellulose nanofibers, as electrodes. We evaluated the compatibility of BPs with hydrogel polymer electrolytes, based on 1 mol L−1 H2SO4 and polyvinyl alcohol (PVA), supplemented with different redox species: methylene blue, indigo carmine, and hydroquinone. Solid cells were constructed containing two active redox species to maximize the specific capacity of each electrode. Considering the main results, the dual-redox-mediator supercapacitor exhibits high energy density of 32.0 Wh kg−1 (at 0.8 kW kg−1) and is capable of delivering 25.9 Wh kg−1 at high power demand (4.0 kW kg−1). Stability studies conducted over 10,000 galvanostatic cycles revealed that the PVA polymer matrix benefits the system by inhibiting the crossover of redox species within the cell.

A novel modeling approach is developed for investigating the effectiveness of buckypaper (BP), a porous membrane made of a highly cross-linked network of carbon nanotubes, in improving the electromagnetic interference (EMI) shielding properties of carbon fiber-reinforced polymer (CFRP) composites. The methodology uses quantum tunneling-based equivalent electrical circuits and Monte Carlo simulations to predict the frequency-dependent electrical conductivity and EMI shielding effectiveness (SE) of the hybrid BP/CFRP composites. The study examines a signal frequency range of 50 MHz to 12 GHz that includes the very high and X-band. The results show that at a frequency of 12 GHz, the transverse conductivity increases to approximately 12.67 S/m, while the longitudinal conductivity decreases to about 3300 S/m from an initial value of 40,000 S/m. These results are then integrated into the ANSYS High-Frequency Structure Simulator to predict SE by simulating the propagation of electromagnetic waves through a semi-infinite composite shield element. The numerical simulations illustrate that incorporating BP significantly improves the SE of CFRP composites beyond 2 GHz owing to its high conductivity in that frequency range. For instance, at 12 GHz signal frequency, adding a single BP interleaf enhances the SE of a [90, 0] laminate by up to ~64%.

Structural health monitoring (SHM) of brittle structures will require versatile sensing instrumentation that can transmitting transient loadings into rapid electrical responses. This research investigated the sensing performance of CNT Buckypaper (CNT-BP) thin-films on stressed fiber-reinforced composites, which are integral materials to various industries of the infrastructure. Three-point bending experiments revealed an extraordinary gauge factor (∼40) and impressive response linearity. Electrical responses were instantaneous; moreover, low force impacts were detectable, the sensors provided clear indications of spatial recognition. Most importantly, the manufacturing methods are scalable and cost effective compared to commercialized strain gauges. This study examined micro-strain measurements (<1%) of carbon fiber composites, in which bending strain of 0.002% could be detected. In addition, damage progressions of glass fiber composites were recorded in response to low-impact energies. Less than 20 J of impact energy was detectable by the sensor, and the severity could be assessed from drastic changes in the sensing behavior. [ABSTRACT FROM AUTHOR]

This study aims to exploit the distinctive properties of carbon nanotube materials, which are particularly pronounced at the microscopic scale, by deploying fabrication techniques that allow their features to be observed macroscopically. Specifically, we aim to create a semiconductor device that exhibits flexibility and the ability to modulate its electromagnetic wave absorption frequency by means of biasing. Initially, we fabricate a sheet of carbon nanotubes through a vacuum filtration process. Subsequently, phosphorus and boron elements are separately doped into the nanotube sheet, enabling it to embody the characteristics of a PN diode. Measurements indicate that, in addition to the fundamental diode's current–voltage relationship, the device also demonstrates intriguing transmission properties under the TEM mode of electromagnetic waves. It exhibits a frequency shift of approximately 2.3125 GHz for each volt of bias change. The final result is a lightweight and flexible carbon-based semiconductor microwave filter, which can conform to curved surfaces. This feat underscores the potential of such materials for innovative and effective electromagnetic wave manipulation. [ABSTRACT FROM AUTHOR]

We describe the creation of a conductive microcavity based on the assembly of two pieces of carbon nanotube buckypaper for the entrapment of two enzymes, horseradish peroxidase (HRP) and glucose oxidase (GOx), as well as a redox mediator: 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid diammonium salt (ABTS). The hollow electrode, employing GOx, HRP, and the mediator, as an electrochemical enzyme cascade model, is utilized for glucose sensing at a potential of 50 mV vs. Ag/AgCl. This bienzyme electrode demonstrates the ability to oxidize glucose by GOx and subsequently convert H2O2 to water via the electrical wiring of HRP by ABTS. Different redox mediators (ABTS, potassium hexacyanoferrate (III), and hydroquinone) are tested for HRP wiring, with ABTS being the best candidate for the electroenzymatic reduction of H2O2. To demonstrate the possibility to optimize the enzyme cascade configuration, the enzyme ratio is studied with 1 mg HRP combined with variable amounts of GOx (1–4 mg) and 2 mg GOx combined with variable amounts of HRP (0.5–2 mg). The bienzyme electrode shows continuous operational stability for over a week and an excellent storage stability in phosphate buffer, with a decay of catalytic current by only 29% for 1 mM glucose after 100 days.

Carbon nanomaterials (CNMs) have some excellent properties that make them ideal candidates as sorbents for solid-phase extraction (SPE). However, practical difficulties related to their handling (dispersion in the atmosphere, bundling phenomena, reduced adsorption capability, sorbent loss in cartridge/column format, etc.) have hindered their direct use for conventional SPE modes. Therefore, researchers working in the field of extraction science have looked for new solutions to avoid the above-mentioned problems. One of these is the design of CNM-based membranes. These devices can be of two different types: membranes that are exclusively composed of CNMs (i.e. buckypaper and graphene oxide paper) and polysaccharide membranes containing dispersed CNMs. A membrane can be used either as a filter, operating under flow-through mode, or as a rotating device, operating under the action of magnetic stirring. In both cases, the main advantages arising from the use of membranes are excellent results in terms of transport rates, adsorption capability, high throughput, and ease of employment. This review covers the preparation/synthesis procedures of such membranes and their potential in SPE applications, highlighting benefits and shortcomings in comparison with conventional SPE materials (especially, microparticles carbonaceous sorbents) and devices. Further challenges and expected improvements are addressed too. [ABSTRACT FROM AUTHOR]

Efforts to fabricate high-conducting and high-strength free-standing graphene/carbon nanotube (CNT) buckypaper through room-temperature functionalization have been frustrated by the defective surface of the graphene and CNTs. In this study, high-quality graphene sheets were prepared via an amino-assisted liquid phase exfoliation method and used to integrate with CNTs to form free-standing flexible graphene/CNTs buckypaper. After that, individual graphene and CNT of the graphene/CNTs buckypaper were linked via diazonium chemistry to generate covalent bonds. By tuning functionalization time, the functionalized graphene/CNTs buckypaper exhibits an electrical conductivity of 87,500 S/m and a Young's modulus of 22.3 GPa, which are 6 and 10 times higher, respectively, than unfunctionalized graphene/CNTs buckypaper. Density functional theory calculations demonstrate that charge transfer rate (K et) of the aryl linker bonded moiety configuration via covalent functionalization is an order faster than without the aryl linker bonded moiety configuration. Unprecedently, the capacitance of the functionalized graphene/CNTs buckypaper is 359.6 mF/cm3 at a scan rate of 1 mV/s with no capacitance change after 10,000 cycles of testing. This work sheds the light of the value of molecular engineering in the design of novel composite for flexible electronics, energy storage and provides important insights into the understanding of basic principles of covalent functionalization of graphene/CNTs. The functionalized graphene/CNTs buckypaper were crosslinked to form covalent bonds between individual material via diazonium chemistry reaction and it achieved an electrical conductivity of 875 S/cm and Young's modulus of 22.3 GPa, which are 6 and 10 times higher than unfunctionalized graphene/CNTs buckypaper. Besides, charge transfer rate (K et) of the functionalized graphene/CNTs shows ten times faster than unfunctionalized moiety configuration. [Display omitted] [ABSTRACT FROM AUTHOR]

Aircraft is regarded as a collection of modern technologies from throughout all industries. However, it is inevitable to develop defects during its service life. In general, the aircraft has a periodic maintenance period, and is inspected according to a well-established process, for example non-destructive testing. However, the maintenance requires massive time and cost. If an unexpected defect occurs due to external environments before the maintenance cycle returns, it is impossible to prevent subsequent damage. This study proposes a novel real-time fatigue crack prediction method using self-sensing carbon nanotube buckypaper and deep learning algorithm. Carbon nanotube buckypaper was fabricated by the wet method. The physics-informed gated recurrent unit was used to predict real time crack growth. The physics-informed deep learning model accurately predicted the fatigue crack length. The results showed that the proposed method is promising in detecting the real-time fatigue crack growth of aircraft structure. [ABSTRACT FROM AUTHOR]

Macroscale carbon nanotube layers, also known as buckypapers (BP), were produced and inserted between glass fiber/epoxy prepregs to evaluate the electromagnetic interference shielding effectiveness (EMI SE) in the X band range. The number of BP layers (S) and the wave-transmitting layer thickness (d) diverged so that five sandwich configurations were proposed in this work. The optimized architecture (S = 4 and d = 1.0 mm) led to a high shielding performance, revealing an EMI SE up to ~ 60 dB with a dominant absorption mechanism and an imposing Fabry-Pérot resonance peak. The fabrication of BP composites is uncomplicated and highly straightforward for large-scale manufacturing of promising EMI shielding materials with broad applications in electronics. [ABSTRACT FROM AUTHOR]

Icing hazards often cause severe mobility concerns, safety risks, and even accidents in modern industries. Various ice mitigation strategies have been employed. Electro-thermal heating approach is a popular measure for ice protection, in which heat is generated electrically by internal components and then transferred to the outer surface for anti-icing and de-icing operation. Given the increasing usage of composites in aircraft structures, self-heating fibre reinforced polymer composite has been studied as an ice protection solution for the new generation aircraft. The present work focuses on improving electrical characteristics of carbon nanotube (CNT) based buckypaper (via surface functionalization) and the heating performance with an ice-phobic resin. The results indicated that surface functionalization of multi-wall carbon nanotubes (MWCNTs) was effective in obtaining MWCNT buckypaper (CNP) with improved electrical conductivity. The de-icing test confirmed the electro-thermal heating performance of the CNP based composite in a climate chamber at −20°C. The utilisation of surface modified MWCNTs in self-heating composites could be a promising strategy for maintaining lightweight and efficiency for electro-thermal systems to mitigate icing hazards. [ABSTRACT FROM AUTHOR]

A simple approach to mitigate the use of high voltages on thin bipolar electrodes is described here for the first time. The method involves stacking the desired thin conductor onto a thicker one, thereby creating a pseudo‐single electrode whose width is the sum of the two. Placing the target material on the positive or negative face of the combined bipolar electrode selects which reaction it will be involved in. This method is used to graft sheets of carbon paper, cloth, and buckypaper with an aminophenyl layer that subsequently binds polypyrrole in a simple two stage reaction to create a one‐sided deposit of a supercapacitive material. By itself the necessary driving potential for these reactions exceed 90 V, while with the stack it drops to 9 V. The resulting supercapacitor electrodes display good performance, with specific capacitances up to 210 mF/cm2 and lasting 2500 charge/discharge cycles. [ABSTRACT FROM AUTHOR]

A composite electrode consisting of graphite felt and buckypaper (GF-BP) was developed. GF-BP is used for fabricating a zero-gap structure for all-vanadium redox flow battery (VRFB), which minimizes the distance between two electrodes. With this zero-gap structure, performance of VRFBs is improved, while its flexible design becomes possible. GF and BP are used as base and reinforced materials to combine the proper porous structure of GF and the excellent redox reactivity of vanadium ions promoted by BP. The properties of GF-BP electrode and its applicability to VRFB were evaluated electrochemically and spectroscopically. As a result, its total pore volume and double layer capacitance (0.200 cm3 g−1, 1,547.95 mF g−1) are higher than those of pristine GF electrode (0.040 cm3 g−1, 94.59 mF g−1). When the optimized GF-BP electrode and zero-gap structure are adopted, performance of the zero-gap VRFB using the optimized GF-BP electrode is excellent with energy efficiency (EE) of 60% and discharge capacity of 14.6 Ah L−1 at 160 mA cm−2, while the EE (67.8%) is 20% better than that using pristine GF electrode (72.4%) at 120 mA cm−2. The significant increase in actual active sites of the optimized GF-BP electrode is the main reason for the performance enhancement of the zero-gap VRFB using this. [ABSTRACT FROM AUTHOR]

[Display omitted] • Carbon nanotubes buckypapers as electrocatalysts for the electrochemical reduction of carbon dioxide. • Metal nature and surface chemistry of the buckypapers play a pivotal role in the CO 2 RR efficiency and selectivity. • Syngas is the main product from CO2RR using FePc, CoPc and NiPc as electrocatalysts. • H 2 /CO ratios between 0.17 and 1.28 are obtained with good stability during electrolysis. In the search of versatile electrocatalysts for the electrochemical reduction of carbon dioxide (CO 2 RR), different transition metal phthalocyanines (MPc, where M=Fe, Co, Ni and Cu) have been immobilized by an easy and scalable wet impregnation on carbon nanotubes (CNTs) in the form of buckypaper (BP). Both the nature of the metal and the surface chemistry of the carbon support were found to play a pivotal role in determining their CO 2 RR efficiency and selectivity. We disclose here a potentiodynamic strategy for the controlled surface modification of BP with N- and P-containing polymeric species as a simple heterogenization strategy for molecular catalysts, enabling to easily tune their electrocatalytic performance. Syngas (mixture of H 2 and CO) was obtained as the main product from CO 2 RR using FePc, CoPc and NiPc as electrocatalysts on functionalized (BP f) or non-modified BP. In contrast, CuPc was found to mainly catalyze the hydrogen evolution reaction (HER), with small amounts of formate as the only CO 2 RR product. It is possible to modulate the H 2 /CO ratio in the final product through the appropriate selection of the metal in MPc, the modification of the coordination environment by the controlled functionalization of the carbon support and the adjustment of the operating conditions. In particular, H 2 /CO ratios in a range between 0.17 and 1.28 have been obtained with good stability during electrolysis. Among all the MPc studied, CoPc surfaced as the most promising candidate for the reduction of CO 2 to CO and H 2 production, a finding substantiated by computational studies highlighting the positive impact of phosphate ligands on CoPc. This strategy outlines the starting line of a potential route toward the controlled generation of CO 2 RR-related products. [ABSTRACT FROM AUTHOR]

This study aims to exploit the distinctive properties of carbon nanotube materials, which are particularly pronounced at the microscopic scale, by deploying fabrication techniques that allow their features to be observed macroscopically. Specifically, we aim to create a semiconductor device that exhibits flexibility and the ability to modulate its electromagnetic wave absorption frequency by means of biasing. Initially, we fabricate a sheet of carbon nanotubes through a vacuum filtration process. Subsequently, phosphorus and boron elements are separately doped into the nanotube sheet, enabling it to embody the characteristics of a PN diode. Measurements indicate that, in addition to the fundamental diode’s current–voltage relationship, the device also demonstrates intriguing transmission properties under the TEM mode of electromagnetic waves. It exhibits a frequency shift of approximately 2.3125 GHz for each volt of bias change. The final result is a lightweight and flexible carbon-based semiconductor microwave filter, which can conform to curved surfaces. This feat underscores the potential of such materials for innovative and effective electromagnetic wave manipulation.

Lithium-ion batteries (LIBs) have been used in many fields, such as consumer electronics and automotive and grid storage, and its applications continue to expand. Several studies have attempted to improve the performance of LIBs. In particular, the use of high-capacity silicon and tin as anodes has been widely studied. Although anodes composed of silicone and tin have high theoretical capacities, poor electrical conductivity and considerable volume expansion of such anodes deteriorate the LIB performance. Thus, Li4Ti5O12 (LTO), a zero-strain material, has attracted much attention with high cycle stability and rate capability through improved electrical conductivity. However, LTO has the disadvantages of a low electrical conductivity (10−8 to 10−13 S cm−1) and moderate Li+ ion diffusion coefficient (10−9 to 10−16 cm2 s−1). In this study, the flexible and free-standing composite films were fabricated using only LTO and multi-walled carbon nanotube(CNT) with high electrical conductivity and ion diffusivity. The prepared LTO/CNT films showed a higher charge/discharge capacity than the theoretical capacity of the LTO electrode. [ABSTRACT FROM AUTHOR]

Pharmaceutical products such as antibiotics, analgesics, steroids, and non-steroidal anti-inflammatory drugs (NSAIDs) are new emerging pollutants, often present in wastewater, potentially able to contaminate drinking water resources. Adsorption is considered the cheapest and most effective technique for the removal of pollutants from water, and, recently, membranes obtained by wet filtration method of SWCNT aqueous solutions (SWCNT buckypapers, SWCNT BPs) have been proposed as self-standing porous adsorbents. In this paper, the ability of graphene oxide/single-walled carbon nanotube composite membranes (GO-SWCNT BPs) to remove some important NSAIDs, namely Diclofenac, Ketoprofen, and Naproxen, was investigated at different pH conditions (pH 4, 6, and 8), graphene oxide amount (0, 20, 40, 60, and 75 wt.%), and initial NSAIDs concentration (1, 10, and 50 ppm). For the same experimental conditions, the adsorption capacities were found to strongly depend on the graphene oxide content. The best results were obtained for 75 wt.% graphene oxide with an adsorption capacity of 118 ± 2 mg g−1 for Diclofenac, 116 ± 2 mg g−1 for Ketoprofen, and 126 ± 3 mg g−1 for Naproxen at pH 4. Overall, the reported data suggest that GO-SWCNT BPs can represent a promising tool for a cheap and fast removal of NSAIDs from drinking water resources, with easy recovery and reusability features. [ABSTRACT FROM AUTHOR]

Abstract In this paper, carbon nanotube (CNT) buckypapers (BPs) were produced by vacuum filtration of CNT water suspensions prepared by sonication using 0.5 wt % of Triton X-100 dispersing agent. The as-produced BPs were efficiently dispersed and presented very low optical reflectance, with an average reflectance of 1.30% in the visible range and hydrophilic/oleophilic properties, readily absorbing water or oil liquid drops through their network of pores. Plasma treatment with 1, 1, 1, 2 tetrafluoroethane (C2H2F4) turned the BPs superhydrophobic with water contact angles (CA) greater than 140°, while still maintaining their oleophilic properties unchanged. This effect is attributed to the combination of the decrease of surface energy and modification of the surface structure with micro/nanopores due to the coating with a fluorocarbon film. After only 1 minute plasma treatment, the BPs presented high hydrophobicity (CA = 145°) while keeping their oleophilicity and the very low optical reflectance essentially unaffected. These results indicate that a good combination of low reflectance and a superhydrophobic/oleophilic behavior can be achieved which is of importance for technological applications that require super black surfaces and prevent water from being absorbed, improving the handling of optical signals and increasing the useful life of materials.

A new concept of hollow electrode based on the assembly of two buckypapers creating a microcavity which contains a biocatalyst is described. To illustrate this innovative concept, hollow bioelectrodes containing 0.16–4 mg bilirubin oxidase in a microcavity were fabricated and applied to electroenzymatic reduction of O2 in aqueous solution. For hemin-modified buckypaper, the bioelectrode shows a direct electron transfer between multi-walled carbon nanotubes and bilirubin oxidase with an onset potential of 0.77 V vs. RHE. The hollow bioelectrodes showed good storage stability in solution with an electroenzymatic activity of 30 and 11% of its initial activity after 3 and 6 months, respectively. The co-entrapment of bilirubin oxidase and 2,2-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) in the microcavity leads to a bioelectrode exhibiting mediated electron transfer. After 23 h of intermittent operation, 5.66 × 10−4 mol of O2 were electroreduced (turnover number of 19,245), the loss of catalytic current being only 54% after 7 days. [ABSTRACT FROM AUTHOR]

Water decontamination is an important challenge resulting from the incorrect disposal of heavy metal waste into the environment. Among the different available techniques (e.g., filtration, coagulation, precipitation, and ion-exchange), adsorption is considered the cheapest and most effective procedure for the removal of water pollutants. In the last years, several materials have been tested for the removal of heavy metals from water, including metal-organic frameworks (MOFs), single-walled carbon nanotubes (SWCNTs), and graphene oxide (GO). Nevertheless, their powder consistency, which makes the recovery and reuse after adsorption difficult, is the main drawback for these materials. More recently, SWCNT buckypapers (SWCNT BPs) have been proposed as self-standing porous membranes for filtration and adsorption processes. In this paper, the adsorption capacity and selectivity of Pb2+ (both from neat solutions and in the presence of other interferents) by SWCNT BPs were evaluated as a function of the increasing amount of GO used in their preparation (GO-SWCNT buckypapers). The highest adsorption capacity, 479 ± 25 mg g−1, achieved for GO-SWCNT buckypapers with 75 wt.% of graphene oxide confirmed the effective application of such materials for cheap and fast water decontamination from lead. [ABSTRACT FROM AUTHOR]

Enzymatic biofuel cells (EBFCs) are emerged as promising power sources for implantable devices, offering excellent form factor and performance. For these applications, EBFCs require customer tailored structure and more than 10 μW power. In this study, flexible and stretchable EBFCs are suggested, assessing their performance using tube-type artificial blood vessel (TABV) cell kit with sheep blood fuel. To fabricate the EBFCs, buckypaper (BP) is molded to polydimethylsiloxane (PDMS) to fabricate BP@PDMS electrode that shows excellent strain rate (95 %) and durability (1500 cycles) in tensile and fatigue tests. Additionally, electrochemical evaluations are implemented to measure the performance of anode and cathode fabricated with BP@PDMS. In anode including 1,10-phenanthroline-5,6-dione and glucose dehydrogenase, maximum reactivity of glucose oxidation is 1.05 mA/cm2, while in cathode including bilirubin oxidase, that of oxygen reduction is 0.61 mA/cm2. Regarding flexibility, anode and cathode are little affected by current density irrespective of bending angle, proving that the fabricated anode and cathode have good flexibility. To emulate the behavior of EBFCs in actual blood vessel, EBFCs are implanted in TABV cell kit, fueling sheep blood. Observed open circuit voltage of 0.59 V and maximum power of 26 μW reveals that fabricated EBFCs have superior potential to be considered as power sources for implantable devices. [Display omitted] • Performance of flexible/stretchable EBFCs is assessed by in-house tube cell. • EBFCs including sheep blood fuel are well operated. • PDMS molded BP electrode shows excellent strain rate and durability. • Current density of electrodes is little affected by bending angle. • EBFCs shows excellent open circuit voltage (0.59 V) and maximum power (26 μW). [ABSTRACT FROM AUTHOR]

Filtration based processing of nanotube and polymer-nanotube dispersions is used to create polymer and nano-filler hybrid materials. The composite morphology consists of two layers: (1) a region where polymer chains have direct matrix interaction with the nano-fillers and (2) a nano-filler rich region excluded from matrix interactions. The experimental work here demonstrates the processing of this hybrid material using polyacrylonitrile (PAN) and single-wall carbon nanotubes (SWNT) at various PAN/SWNT weight concentrations. Mechanical analyses were performed to evaluate effective contributions from the SWNT in each of the defined layers. The region of high matrix-filler interactions exhibits blending behavior with material properties following suit. As a result, mechanical performance is consistent and begins to exceed theoretical predictions derived from Halpin–Tsai calculations. Tensile strength and modulus reached values as high as 60 MPa and 7.7 GPa, respectively, surpassing the performance of neat nano-filler (36 MPa, 3.9 GPa) and neat polymer matrix (44 MPa, 2.0 GPa) films. Additionally, the measurement of electrical properties shows that the blended polymer-SWNT region exhibits conductivity comparable to the filler. The results of this work suggest that blending polymers and nano-fillers is possible and may facilitate the production of materials with comparatively high mechanical performance and electrical conductivities. [ABSTRACT FROM AUTHOR]

Carbon nanotubes (CNTs) are the building blocks of a variety of meso- and macro-scale assemblies. Buckypaper (BP) is a typical mesoscopic material that can possess tensile strength and modulus of up to three to four orders of magnitude lower than constituent CNTs. Identifying the "ruler" that not only predicts the realistic tensile properties of BP but also enables the scaling up of these characteristics with the aid of key CNT and structural parameters remains an open challenge. Herein, we propose a comprehensive theoretical framework to devise detailed tensile mechanics of the highly complex and fundamentally challenging random network of multi-walled carbon nanotubes (MWCNTs). A shell-based analytical model comprising intertube sliding and stretching as key modes of deformation has been constructed that successfully reduced Young's modulus of MWCNTs from 1 TPa to a few hundred megapascals in BP. Further, the tensile strength of BP has been modeled based upon the intertube sliding of MWCNTs at a stress that is well below their individual failure strength. A good agreement between the theoretical and experimental stress-strain curves of BPs justified that the predictive model is sufficiently robust. The parametric analysis on various metrics obtained from the analytical model has also been performed. [Display omitted] • BPs can possess tensile properties of up to 3–4 orders of magnitude lower than CNTs. • Predicted the tensile properties of BPs using a shell-based analytical model. • Reduced Young's modulus of CNT from 1 TPa to a few hundred megapascals in BPs. • Modeled the tensile strength of BPs well below the failure strength of CNTs. • A good agreement between theory and experiments has been obtained. [ABSTRACT FROM AUTHOR]

Structural Health Monitoring (SHM) systems are commonly integrated in bonded joints for different applications in order to detect and predict potential fatigue and damages caused by internal and external agents they are subjected to during their operation life. However, each of the current SHM systems presents some drawbacks, as the reduction of structural properties or the difficulty in its implementation. This work deals with the use of a Carbon Nanotube film (Bukypaper) as a sensor in double cantilever beam (DCB) bonded joint specimens for crack growth monitoring purposes. Buckypaper (BP) sheets were manufactured and integrated in adhesive film layers and its integration quality was studied by Scanning Electron Microscopy (SEM). The effect of the integration of different thickness BPs in the mechanical performance of the bonded joints was also assessed performing DCB fracture tests. Also, electro-mechanical tests were conducted using the BP as the sensor, monitoring the output in the electrical resistance during the crack propagation. It was observed the capability of BP to detect and locate the damage during the test with a linear dependence between the electrical resistance measured in the BP and the deduced crack growth, proving the potential of the BP to monitor self-sensing bonded joints. [ABSTRACT FROM AUTHOR]

Abstract Lightweight, flexibility, and low thickness are urgent requirements for next-generation high-performance electromagnetic interference (EMI) shielding materials for catering to the demand for smart and wearable electronic devices. Although several efforts have focused on constructing porous and flexible conductive films or aerogels, few studies have achieved a balance in terms of density, thickness, flexibility, and EMI shielding effectiveness (SE). Herein, an ultrathin, lightweight, and flexible carbon nanotube (CNT) buckypaper enhanced using MXenes (Ti3C2Tx) for high-performance EMI shielding is synthesized through a facile electrophoretic deposition process. The obtained Ti3C2Tx@CNT hybrid buckypaper exhibits an outstanding EMI SE of 60.5 dB in the X-band at 100 μm. The hybrid buckypaper with an MXene content of 49.4 wt% exhibits an EMI SE of 50.4 dB in the X-band with a thickness of only 15 μm, which is 105% higher than that of pristine CNT buckypaper. Furthermore, an average specific SE value of 5.7 × 104 dB cm2 g−1 is exhibited in the 5-μm hybrid buckypaper. Thus, this assembly process proves promising for the construction of ultrathin, flexible, and high-performance EMI shielding films for application in electronic devices and wireless communications.

Carbon nanotube (CNT)‐based membranes combine the promising properties of CNTs with the advantages of membrane separation technologies, offering enhanced membrane performance in terms of permeability and selectivity. This review looks at the existing membrane architectures based on CNTs and their main advantages and disadvantages for water treatment applications. The different types of CNT‐based membranes that are reported in the literature are highlighted, as well as their corresponding fabrication methods. Available methodologies for tailoring the final membrane properties and behavior are thoroughly discussed, making special emphasis in chemical modification of the CNT surface. Finally, the most common applications of CNT‐based membranes in water treatment are reviewed, including seawater or brine desalination, oil–water separation, removal of heavy metals, and organic pollutants. The main limitations and perspectives of CNT‐based membranes are also briefly outlined. [ABSTRACT FROM AUTHOR]

Abstract Lithium–sulfur batteries (LSBs) are considered as the next generation of advanced rechargeable batteries because of their high energy density. In this study, sulfur and CoxS electrocatalyst are deposited on carbon nanotube buckypaper (S/CoxS/BP) by a facile electrodeposition method and are used as a binder-free high-performance cathode for LSBs. Elemental sulfur is deposited on buckypaper by electrooxidation of a polysulfide solution (~ S6 2−). This approach substantially increased the current and time efficiency of sulfur electrochemical deposition on conductive material for LSBs. S/CoxS/BP cathode could deliver an initial discharge capacity as high as 1650 mAh g−1 at 0.1 C, which is close to the theoretical capacity of sulfur. At current rate of 0.5 C, the S/CoxS/BP has a capacity of 1420 mAh g−1 at the first cycle and 715 mAh g−1 after 500 cycles with a fading rate of 0.099% per cycle. The high capacity of S/CoxS/BP is attributed to both the homogeneous dispersion of nanosized sulfur within BP and the presence of CoxS catalyst. The sodium dodecyl sulfate (SDS) pretreatment of BP renders it polarity to bind polysulfides and thus facilitates the good dispersibility of nanosized sulfur within BP. CoxS catalyst accelerates the kinetics of polysulfide conversion and reduces the presence of polysulfide in the cathode, which suppresses the polysulfide diffusion to anode, i.e., the shuttle effect. The mitigation of the active material loss improves not only the capacity but also the cyclability of S/CoxS/BP. Graphic Abstract

Abstract High-purity (99%) carbon nanocoils (CNCs) have been synthesized by using porous α-Fe2O3/SnO2 catalyst. The yield of CNCs reaches 9,098% after a 6 h growth. This value is much higher than the previously reported data, indicating that this method is promising to synthesize high-purity CNCs on a large scale. It is considered that an appropriate proportion of Fe and Sn, proper particle size distribution, and a loose-porous aggregate structure of the catalyst are the key points to the high-purity growth of CNCs. Benefiting from the high-purity preparation, a CNC Buckypaper was successfully prepared and the electrical, mechanical, and electrochemical properties were investigated comprehensively. Furthermore, as one of the practical applications, the CNC Buckypaper was successfully utilized as an efficient adsorbent for the removal of methylene blue dye from wastewater with an adsorption efficiency of 90.9%. This study provides a facile and economical route for preparing high-purity CNCs, which is suitable for large-quantity production. Furthermore, the fabrication of macroscopic CNC Buckypaper provides promising alternative of adsorbent or other practical applications.

Single-walled carbon nanotube buckypapers (SWCNT-bps) coated with a metal–organic framework ZIF-8 layer were used as supports for the preparation of Pebax® 3533 TFC membranes by both phase inversion and spin coating techniques. Upon proper characterization of the materials by X-ray diffraction, IR spectroscopy, thermogravimetry and electron microscopy, the obtained membranes were tested in gas separation experiments with a 15:85 CO2/N2 mixture. These experiments proved that the ZIF-8 layer prevented from the penetration of the polymer selective film into the SWCNT-bp support, giving rise to a highly permeable selective membrane. The optimum membrane was achieved by the spin-coating method, with better permeation results than that prepared by the phase inversion method, obtaining a CO2 permeance of 566 GPU together with a CO2/N2 selectivity of 20.9.

Lithium-ion batteries (LIBs) have been used in many fields, such as consumer electronics and automotive and grid storage, and its applications continue to expand. Several studies have attempted to improve the performance of LIBs. In particular, the use of high-capacity silicon and tin as anodes has been widely studied. Although anodes composed of silicone and tin have high theoretical capacities, poor electrical conductivity and considerable volume expansion of such anodes deteriorate the LIB performance. Thus, Li4Ti5O12 (LTO), a zero-strain material, has attracted much attention with high cycle stability and rate capability through improved electrical conductivity. However, LTO has the disadvantages of a low electrical conductivity (10−8 to 10−13 S cm−1) and moderate Li+ ion diffusion coefficient (10−9 to 10−16 cm2 s−1). In this study, the flexible and free-standing composite films were fabricated using only LTO and multi-walled carbon nanotube(CNT) with high electrical conductivity and ion diffusivity. The prepared LTO/CNT films showed a higher charge/discharge capacity than the theoretical capacity of the LTO electrode.

Pharmaceutical products such as antibiotics, analgesics, steroids, and non-steroidal anti-inflammatory drugs (NSAIDs) are new emerging pollutants, often present in wastewater, potentially able to contaminate drinking water resources. Adsorption is considered the cheapest and most effective technique for the removal of pollutants from water, and, recently, membranes obtained by wet filtration method of SWCNT aqueous solutions (SWCNT buckypapers, SWCNT BPs) have been proposed as self-standing porous adsorbents. In this paper, the ability of graphene oxide/single-walled carbon nanotube composite membranes (GO-SWCNT BPs) to remove some important NSAIDs, namely Diclofenac, Ketoprofen, and Naproxen, was investigated at different pH conditions (pH 4, 6, and 8), graphene oxide amount (0, 20, 40, 60, and 75 wt.%), and initial NSAIDs concentration (1, 10, and 50 ppm). For the same experimental conditions, the adsorption capacities were found to strongly depend on the graphene oxide content. The best results were obtained for 75 wt.% graphene oxide with an adsorption capacity of 118 ± 2 mg g−1 for Diclofenac, 116 ± 2 mg g−1 for Ketoprofen, and 126 ± 3 mg g−1 for Naproxen at pH 4. Overall, the reported data suggest that GO-SWCNT BPs can represent a promising tool for a cheap and fast removal of NSAIDs from drinking water resources, with easy recovery and reusability features.

In this study, a carbon nanotube (CNT) buckypaper was interleaved in a carbon-fiber-reinforced polymer (CFRP) composite to improve the interlaminar fracture toughness. Interleaving the film of a laminate-type composite poses the risk of deteriorating the in-plane mechanical properties. Therefore, the in-plane shear modulus and shear strength were measured prior to estimating the interlaminar fracture toughness. To evaluate the effect of the buckypaper on the interlaminar fracture toughness of the CFRP, double cantilever beam (DCB) and end notch flexure (ENF) tests were conducted for mode I and mode II delamination, respectively. No significant change was observed for the in-plane shear modulus due to the buckypaper interleaving and the shear strength decreased by 4%. However, the interlaminar fracture toughness of the CFRP increased significantly. Moreover, the mode II interlaminar fracture toughness of the CFRP increased by 45.9%. Optical micrographs of the cross-section of the CFRPs were obtained to compare the microstructures of the specimens with and without buckypaper interleaving. The fracture surfaces obtained after the DCB and ENF tests were examined using a scanning electron microscope to identify the toughening mechanism of the buckypaper-interleaved CFRP. [ABSTRACT FROM AUTHOR]

Enzymatic biofuel cells (EBCs) using non-toxic and naturally derived flavonoid biomediators as anodic catalysts are introduced. In this study, hesperidin, a flavonoid extracted from citrus fruits, served as a biomediator with flavine adenine dinucleotide dependent glucose dehydrogenase (FADGDH). Hesperidin exhibits several advantages, including a low onset potential, a robust catalytic activity, and an excellent stability for glucose oxidation reaction (GOR). This superiority can be attributed to its unique chemical structure and electrochemically activated capability. For its activation, a catechol group was produced on the right side of the phenyl ring of hesperidin, existing in both chemically and physically adsorbed forms. Following activation, a redox reaction occurred at a buckypaper (BP) supported electrode (BP/Activated Hesperidin (A-Hesperidin)) at −0.05 and 0.15 V (vs. Ag/AgCl). When BP/A-Hesperidin/FADGDH was employed, the reactivity of GOR reached 0.61 mA cm−2 at 0.3 V with 10 mmol L−1 glucose. These performances surpass those reported in similar research studies. When the EBC using BP/A-Hesperidin/FADGDH was operated, its maximum power density (MPD) reached 212.84 ± 17.97 μW cm−2 with 10 mmol L−1 glucose under air conditions. This confirms that A-Hesperidin can induce higher EBC performances than conventionally used mediators, which are often toxic and expensive. [Display omitted] [ABSTRACT FROM AUTHOR]

A new type of buckypaper of MWCNT with entrapped Nimodipine (NMD) drug was constructed. NMD features a nitroaromatic group that is electroreducible, and a dihydropyridine ring that can be electrooxidized. From the perspective of the nitroaromatic group's reductive capability, we have devised amperometric and voltammetric analytical strategies, including both differential pulse and linear voltammetric techniques. These methods are implemented using glassy carbon electrodes (GCE) modified with buckypaper (BP) disks composed of multiwalled carbon nanotubes (MWCNT), which are capable of adsorbing NMD. Furthermore, by capitalizing on the oxidative capacity of the dihydropyridine ring, we have designed strategies that involve amperometry using screen-printed electrodes (SPE) modified with BP-MWCNT mini discs within a Batch Injection Analysis Cell (BIAS) designed for SPE. The developed sensor was applied successfully to determine the drug in commercial tablets. The analytical parameters of this sensor were adequate, with a recovery value of 98.24 % and detection and quantification limits of 7.01 mgL−1 and 23.35 mgL−1, respectively using the DPV method. [Display omitted] • Nimodipine (NMD) was entrapped on a multi-walled carbon nanotubes (MWCNTs) buckypaper electrode. • Nimodipine has functional groups that can be both reducible and oxidizable. • Modified SPEs were utilized in a Batch Injection Analysis Cell (BIAS) for oxidation amperometry. • The reduction of NMD was quantified through amperometry and voltammetry on glassy carbon electrodes modified with BP-MWCNT. [ABSTRACT FROM AUTHOR]

Alessandro Paolini,1 Giulia Battafarano,1 Valentina D’Oria,1 Francesco Mura,2 Simona Sennato,3 Valentina Mussi,4 Roberta Risoluti,5 Stefano Materazzi,5 Andrea Del Fattore,1 Andrea Masotti1 1Bambino Gesù Children’s Hospital, IRCCS, Research Laboratories, Rome 00146, Italy; 2Center for Nanotechnology for Engineering (CNIS), Sapienza University of Rome, Rome 00185, Italy; 3CNR-ISC UOS Sapienza and Physics Department, Sapienza University of Rome, Rome 00185, Italy; 4National Research Council, Institute for Microelectronics and Microsystems IMM-CNR, Roma 00133, Italy; 5Department of Chemistry, Sapienza University of Rome, Rome 00185, ItalyCorrespondence: Andrea MasottiBambino Gesù Children’s Hospital, IRCCS, Research Laboratories, Gene Expression-Microarrays Laboratory, Viale di San Paolo 15, Rome 00146, ItalyTel +39-06-68592650Fax +39-0668592904Email andrea.masotti@opbg.netBackground: The advent of 3D printing technology allowed the realization of custom devices that can be used not only in the everyday life but also in the nanotechnology and biomedical fields. In nanotechnology, the use of bi-dimensional nanostructures based on carbon nanotubes, generally referred as buckypapers, have received considerable attention for their versatility and potential application in many biomedical fields. Unfortunately, buckypapers are extremely hydrophobic and cannot be used in aqueous media to culture cells.Methods: A polymeric device able to accommodate buckypapers and facilitate cell growth was fabricated by using 3D printing technology. We imparted hydrophilicity to buckypapers by coating them with polyamidoamine (PAMAM) dendrimers.Results: We found that by using novel techniques such as polymer coating the buckypaper hydrophilicity increased, whereas the use of 3D printing technology allowed us to obtain custom devices that have been used to culture cells on buckypapers for many days. We characterized in details the morphology of these structures and studied for the first time the kinetic of cell proliferation. We found that these scaffolds, if properly functionalized, are suitable materials to grow cells for long time and potentially employable in the biomedical field.Conclusion: Although these materials are cytotoxic under certain circumstances, we have found a suitable coating and specific experimental conditions that encourage using buckypapers as novel scaffolds for cell growth and for potential applications in tissue repair and regeneration.Keywords: 3D printing, buckypaper, PAMAM dendrimer, cell proliferation, tissue regeneration, transfection

A new concept of hollow electrode based on the assembly of two buckypapers creating a microcavity which contains a biocatalyst is described. To illustrate this innovative concept, hollow bioelectrodes containing 0.16–4 mg bilirubin oxidase in a microcavity were fabricated and applied to electroenzymatic reduction of O2 in aqueous solution. For hemin-modified buckypaper, the bioelectrode shows a direct electron transfer between multi-walled carbon nanotubes and bilirubin oxidase with an onset potential of 0.77 V vs. RHE. The hollow bioelectrodes showed good storage stability in solution with an electroenzymatic activity of 30 and 11% of its initial activity after 3 and 6 months, respectively. The co-entrapment of bilirubin oxidase and 2,2-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) in the microcavity leads to a bioelectrode exhibiting mediated electron transfer. After 23 h of intermittent operation, 5.66 × 10−4 mol of O2 were electroreduced (turnover number of 19,245), the loss of catalytic current being only 54% after 7 days.

Water decontamination is an important challenge resulting from the incorrect disposal of heavy metal waste into the environment. Among the different available techniques (e.g., filtration, coagulation, precipitation, and ion-exchange), adsorption is considered the cheapest and most effective procedure for the removal of water pollutants. In the last years, several materials have been tested for the removal of heavy metals from water, including metal-organic frameworks (MOFs), single-walled carbon nanotubes (SWCNTs), and graphene oxide (GO). Nevertheless, their powder consistency, which makes the recovery and reuse after adsorption difficult, is the main drawback for these materials. More recently, SWCNT buckypapers (SWCNT BPs) have been proposed as self-standing porous membranes for filtration and adsorption processes. In this paper, the adsorption capacity and selectivity of Pb2+ (both from neat solutions and in the presence of other interferents) by SWCNT BPs were evaluated as a function of the increasing amount of GO used in their preparation (GO-SWCNT buckypapers). The highest adsorption capacity, 479 ± 25 mg g−1, achieved for GO-SWCNT buckypapers with 75 wt.% of graphene oxide confirmed the effective application of such materials for cheap and fast water decontamination from lead.

Glass fiber/epoxy resin composites (GF/EP) were prepared using one and three multiwalled carbon nanotube buckypapers (BPs) as a resistive element. Compared to the conventional hot compression molding process that demanded 4200 W to fabricate the GF/EP laminate, the proposed curing process consumed only 63 W, representing a saving power of 98.5%. The thermal distribution of the BP and their composites were recorded using an infrared thermometer. Differential scanning calorimetry (DSC) curves have not shown a residual cure, suggesting the curing process using the BP as a resistive element was effective. The cross section views of the laminates were analyzed by scanning electron microscopy (SEM), and the mechanical characterizations were performed by impulse excitation technique (IET), compression shear test (CST), and interlaminar shear strength (ILSS). The results demonstrated that the BP composites showed a good consolidation between the prepregs layers, and presented no significant variations in the mechanical tests compared to the traditional hot compression molding process. Nevertheless, dynamic mechanical analyses (DMA) showed a slight decrease in the BP composites' storage moduli compared to GF/EP laminate. [ABSTRACT FROM AUTHOR]

Filtration based processing of nanotube and polymer-nanotube dispersions is used to create polymer and nano-filler hybrid materials. The composite morphology consists of two layers: (1) a region where polymer chains have direct matrix interaction with the nano-fillers and (2) a nano-filler rich region excluded from matrix interactions. The experimental work here demonstrates the processing of this hybrid material using polyacrylonitrile (PAN) and single-wall carbon nanotubes (SWNT) at various PAN/SWNT weight concentrations. Mechanical analyses were performed to evaluate effective contributions from the SWNT in each of the defined layers. The region of high matrix-filler interactions exhibits blending behavior with material properties following suit. As a result, mechanical performance is consistent and begins to exceed theoretical predictions derived from Halpin–Tsai calculations. Tensile strength and modulus reached values as high as 60 MPa and 7.7 GPa, respectively, surpassing the performance of neat nano-filler (36 MPa, 3.9 GPa) and neat polymer matrix (44 MPa, 2.0 GPa) films. Additionally, the measurement of electrical properties shows that the blended polymer-SWNT region exhibits conductivity comparable to the filler. The results of this work suggest that blending polymers and nano-fillers is possible and may facilitate the production of materials with comparatively high mechanical performance and electrical conductivities.

Polymer composites have been explored for electromagnetic interference (EMI) shielding materials instead of metals due to their low density and flexibility. However, the insufficient EMI shielding effectiveness (EMI SE) caused by the loss of the conducting pathways within the filler-to-filler contacts inside the polymer matrix limits the use of polymers. Herein, we demonstrate a facile and scalable approach for preparing ultrathin and lightweight multiwalled carbon nanotube (MWCNT) buckypaper/electrospun polyacrylonitrile (PAN) nanofiber (BP/NF) composite membranes via electrospinning, thermal-rolling, and vacuum filtration. The smooth surface, higher surface energy, and high mechanical strength of 19 MPa were dependent on the enhanced interfacial network between the BP and NF substrates, thermal-rolled at 130 °C. Furthermore, a superior specific shielding efficiency of 13 734 dB cm2 g–1 was achieved for the 100 μm thick BP/NF composite membrane, which is superior to most of the previously reported MWCNT/polymer composite membranes. This study demonstrates a critical breakthrough for the application of the polymer composites for applications in portable, wearable electronics and military equipment. [ABSTRACT FROM AUTHOR]

Highlights: Ultrathin, lightweight, and flexible carbon nanotube buckypaper enhanced using MXenes (Ti3C2Tx) for high-performance electromagnetic interference shielding is synthesized through facile electrophoretic deposition. The obtained Ti3C2Tx@CNT hybrid buckypaper demonstrates outstanding EMI shielding effectiveness of 60.5 dB in the X-band at 100 μm and a specific SE value of 5.7 × 104 dB cm2 g−1 at 5 μm.Lightweight, flexibility, and low thickness are urgent requirements for next-generation high-performance electromagnetic interference (EMI) shielding materials for catering to the demand for smart and wearable electronic devices. Although several efforts have focused on constructing porous and flexible conductive films or aerogels, few studies have achieved a balance in terms of density, thickness, flexibility, and EMI shielding effectiveness (SE). Herein, an ultrathin, lightweight, and flexible carbon nanotube (CNT) buckypaper enhanced using MXenes (Ti3C2Tx) for high-performance EMI shielding is synthesized through a facile electrophoretic deposition process. The obtained Ti3C2Tx@CNT hybrid buckypaper exhibits an outstanding EMI SE of 60.5 dB in the X-band at 100 μm. The hybrid buckypaper with an MXene content of 49.4 wt% exhibits an EMI SE of 50.4 dB in the X-band with a thickness of only 15 μm, which is 105% higher than that of pristine CNT buckypaper. Furthermore, an average specific SE value of 5.7 × 104 dB cm2 g−1 is exhibited in the 5-μm hybrid buckypaper. Thus, this assembly process proves promising for the construction of ultrathin, flexible, and high-performance EMI shielding films for application in electronic devices and wireless communications. [ABSTRACT FROM AUTHOR]

The present work aimed to prepare and characterize carbon nanotube (CNT) buckypapers (BPs) and to provide a perspective on possible applications in the optical device industry and power generation through triboelectric nanogenerators. The CNTs were dispersed in aqueous solution with the aid of a dispersing agent and then vacuum filtered. The prepared buckypaper has low average optical reflectance and shows an improvement in electrical conductivity and power generation when silver nanowires were added. This material includes new horizons and future applications for carbon nanotube buckypapers,including aerospace applications.