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1. A method to estimate surface mass-balance in glacier accumulation areas based on digital elevation models and submergence velocities

Author

Bruno Jourdain, Christian Vincent, Marion Réveillet, Antoine Rabatel, Fanny Brun, Delphine Six, Olivier Laarman, Luc Piard, Patrick Ginot, Olivier Sanchez, and Etienne Berthier

Subjects
Accumulation, glacier mass-balance, ground-penetrating radar, mountain glaciers, Environmental sciences, GE1-350, Meteorology. Climatology, QC851-999
Abstract

Measuring surface mass-balance in the accumulation areas of glaciers is challenging because of the high spatial variability of snow accumulation and the difficulty of conducting annual field glaciological measurements. Here, we propose a method that can solve both these problems for many locations. Ground-penetrating radar measurements and firn cores extracted from a site in the French Alps were first used to reconstruct the topography of a buried end-of-summer snow horizon from a past year. Using these data and surface elevation observations from LiDAR and Global Navigation Satellite System instruments, we calculated the submergence velocities over the period between the buried horizon and more recent surface elevation observations. The differences between the changes in surface elevation and the submergence velocities were then used to calculate the annual surface mass-balances with an accuracy of ±0.34 m w.e. Assuming that the submergence velocities remain stable over several years, the surface mass-balance can be reconstructed for subsequent years from the differences in surface elevation alone. As opposed to the glaciological method that requires substantial fieldwork year after year to provide only point observations, this method, once submergence velocities have been calculated, requires only remote-sensing data to provide spatially distributed annual mass-balances in accumulation areas.

Published
2023
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2. Retrieval of Snow Properties from the Sentinel-3 Ocean and Land Colour Instrument

Author

Alexander Kokhanovsky, Maxim Lamare, Olaf Danne, Carsten Brockmann, Marie Dumont, Ghislain Picard, Laurent Arnaud, Vincent Favier, Bruno Jourdain, Emmanuel Le Meur, Biagio Di Mauro, Teruo Aoki, Masashi Niwano, Vladimir Rozanov, Sergey Korkin, Sepp Kipfstuhl, Johannes Freitag, Maria Hoerhold, Alexandra Zuhr, Diana Vladimirova, Anne-Katrine Faber, Hans Christian Steen-Larsen, Sonja Wahl, Jonas K. Andersen, Baptiste Vandecrux, Dirk van As, Kenneth D. Mankoff, Michael Kern, Eleonora Zege, and Jason E. Box

Subjects
snow characteristics, optical remote sensing, sow grain size, specific surface area, albedo, sentinel 3, olci, Science
Abstract

The Sentinel Application Platform (SNAP) architecture facilitates Earth Observation data processing. In this work, we present results from a new Snow Processor for SNAP. We also describe physical principles behind the developed snow property retrieval technique based on the analysis of Ocean and Land Colour Instrument (OLCI) onboard Sentinel-3A/B measurements over clean and polluted snow fields. Using OLCI spectral reflectance measurements in the range 400−1020 nm, we derived important snow properties such as spectral and broadband albedo, snow specific surface area, snow extent and grain size on a spatial grid of 300 m. The algorithm also incorporated cloud screening and atmospheric correction procedures over snow surfaces. We present validation results using ground measurements from Antarctica, the Greenland ice sheet and the French Alps. We find the spectral albedo retrieved with accuracy of better than 3% on average, making our retrievals sufficient for a variety of applications. Broadband albedo is retrieved with the average accuracy of about 5% over snow. Therefore, the uncertainties of satellite retrievals are close to experimental errors of ground measurements. The retrieved surface grain size shows good agreement with ground observations. Snow specific surface area observations are also consistent with our OLCI retrievals. We present snow albedo and grain size mapping over the inland ice sheet of Greenland for areas including dry snow, melted/melting snow and impurity rich bare ice. The algorithm can be applied to OLCI Sentinel-3 measurements providing an opportunity for creation of long-term snow property records essential for climate monitoring and data assimilation studies—especially in the Arctic region, where we face rapid environmental changes including reduction of snow/ice extent and, therefore, planetary albedo.

Published
2019
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3. Spatial variability of Saharan dust deposition revealed through a citizen science campaign

Author

Marie Dumont, Simon Gascoin, Marion Réveillet, Didier Voisin, François Tuzet, Laurent Arnaud, Mylène Bonnefoy, Montse Bacardit Peñarroya, Carlo Carmagnola, Alexandre Deguine, Aurélie Diacre, Lukas Dürr, Olivier Evrard, Firmin Fontaine, Amaury Frankl, Mathieu Fructus, Laure Gandois, Isabelle Gouttevin, Abdelfateh Gherab, Pascal Hagenmuller, Sophia Hansson, Hervé Herbin, Béatrice Josse, Bruno Jourdain, Irene Lefevre, Gaël Le Roux, Quentin Libois, Lucie Liger, Samuel Morin, Denis Petitprez, Alvaro Robledano, Martin Schneebeli, Pascal Salze, Delphine Six, Emmanuel Thibert, Jürg Trachsel, Matthieu Vernay, Léo Viallon-Galinier, and Céline Voiron

Abstract

Saharan dust outbreaks have profound effects on ecosystems, climate, human health, and the cryosphere in Europe. However, the spatial deposition pattern of Saharan dust is poorly known due to a sparse network of ground measurements. Following the extreme dust deposition event of February 2021 across Europe, a citizen science campaign was launched to sample dust on snow over the Pyrenees and the European Alps. This somewhat improvised campaign triggered wide interest since 152 samples were collected from the snow in the Pyrenees, the French Alps, and the Swiss Alps in less than 4 weeks. Among the 152 samples, 113 in total could be analysed, corresponding to 70 different locations. The analysis of the samples showed a large variability in the dust properties and amount. We found a decrease in the deposited mass and particle sizes with distance from the source along the transport path. This spatial trend was also evident in the elemental composition of the dust as the iron mass fraction decreased from 11 % in the Pyrenees to 2 % in the Swiss Alps. At the local scale, we found a higher dust mass on south-facing slopes, in agreement with estimates from high-resolution remote sensing data. This unique dataset, which resulted from the collaboration of several research laboratories and citizens, is provided as an open dataset to benefit a large community and to enable further scientific investigations. Data presented in this study are available at https://doi.org/10.5281/zenodo.7969515 (Dumont et al., 2022a).

Published
2023

4. Supplementary material to 'Spatial variability of Saharan dust deposition revealed through a citizen science campaign'

Author

Marie Dumont, Simon Gascoin, Marion Réveillet, Didier Voisin, François Tuzet, Laurent Arnaud, Mylène Bonnefoy, Montse Bacardit Peñarroya, Carlo Carmagnola, Alexandre Deguine, Aurélie Diacre, Lukas Dürr, Olivier Evrard, Firmin Fontaine, Amaury Frankl, Mathieu Fructus, Laure Gandois, Isabelle Gouttevin, Abdelfateh Gherab, Pascal Hagenmuller, Sophia Hansson, Hervé Herbin, Béatrice Josse, Bruno Jourdain, Irene Lefevre, Gaël Le Roux, Quentin Libois, Lucie Liger, Samuel Morin, Denis Petitprez, Alvaro Robledano, Martin Schneebeli, Pascal Salze, Delphine Six, Emmanuel Thibert, Jürg Trachsel, Matthieu Vernay, Léo Viallon-Galinier, and Céline Voiron

Published
2023

5. Geodetic point surface mass balances: a new approach to determine point surface mass balances on glaciers from remote sensing measurements

Author

Vincent Peyaud, Bruno Jourdain, Emmanuel Thibert, Florent Gimbert, Laurent Arnaud, Andrea Walpersdorf, Fanny Brun, Christian Vincent, Luc Piard, Diego Cusicanqui, Adrien Gilbert, Delphine Six, Antoine Rabatel, Olivier Laarman, Ugo Nanni, Olivier Gagliardini, Institut des Géosciences de l’Environnement (IGE), Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA), Institut des Sciences de la Terre (ISTerre), Institut national des sciences de l'Univers (INSU - CNRS)-Institut de recherche pour le développement [IRD] : UR219-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Gustave Eiffel-Université Grenoble Alpes (UGA), Erosion torrentielle neige et avalanches (UR ETGR (ETNA)), Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), French National Research Agency (ANR) European Commission, French National Research Agency (ANR) 18 CE1 0015 01, Environnements, Dynamiques et Territoires de Montagne (EDYTEM), Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS), ANR-18-CE01-0015,SAUSSURE,Glissement des glaciers et pression hydrologique sous glaciaire en relat(2018), and Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Institut de Recherche pour le Développement (IRD)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )

Subjects
010504 meteorology & atmospheric sciences, Ice stream, Climate change, 010502 geochemistry & geophysics, 01 natural sciences, [SPI]Engineering Sciences [physics], Glacier mass balance, Point (geometry), [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, lcsh:Environmental sciences, 0105 earth and related environmental sciences, Earth-Surface Processes, Water Science and Technology, Remote sensing, lcsh:GE1-350, geography, geography.geographical_feature_category, Bedrock, lcsh:QE1-996.5, Geodetic datum, Glacier, 15. Life on land, lcsh:Geology, 13. Climate action, [SDE]Environmental Sciences, Satellite, Geology
Abstract

Mass balance observations are very useful to assess climate change in different regions of the world. As opposed to glacier-wide mass balances, which are influenced by the dynamic response of each glacier, point mass-balances provide a direct climatic signal that depends on surface accumulation and ablation only. Unfortunately, major efforts are required to conduct in situ measurements on glaciers. Here, we propose a new approach that determines point surface mass balances from remote sensing observations. We call this balance the geodetic point surface mass balance. From observations and modelling performed on Argentière and Mer de Glace glaciers over the last decade, we show that the vertical ice flow velocity changes are small in areas of low bedrock slope. Therefore, assuming constant vertical velocities in time for such areas and provided that the vertical velocities have been measured for at least one year in the past, our method can be used to reconstruct annual point surface mass balances from surface elevations and horizontal velocities alone. We demonstrate that the annual point surface mass balances can be reconstructed with an accuracy of about 0.3 m w.e. a-1 using the vertical velocities observed over the previous years and data from Unmanned Aerial Vehicle images. Given the recent improvements of satellite sensors, it should be possible to apply this method to high spatial resolution satellite images as well.

Published
2021

6. Regional Characteristics of Atmospheric Sulfate Formation in East Antarctica Imprinted on 17 O‐Excess Signature

Author

S. Preunkert, Michel Legrand, Joel Savarino, Sakiko Ishino, A. Yamada, Bruno Jourdain, Naohiro Yoshida, Jingyuan Shao, Lyatt Jaeglé, Shohei Hattori, Qianjie Chen, Jiayue Huang, Becky Alexander, Tokyo Institute of Technology [Tokyo] (TITECH), Institut des Géosciences de l’Environnement (IGE), Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA), University of Washington [Seattle], and ANR-16-CE01-0011,EAIIST,Projet International d'exploration de la calotte polaire de l'Antarctique de l'Est(2016)

Subjects
[SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, Atmospheric Science, 010504 meteorology & atmospheric sciences, methanesulfonate, Geochemistry, East antarctica, sulfate, 010501 environmental sciences, 01 natural sciences, chemistry.chemical_compound, Geophysics, chemistry, 13. Climate action, Space and Planetary Science, [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry, Earth and Planetary Sciences (miscellaneous), Environmental science, Antarctica, [SDU.STU.GL]Sciences of the Universe [physics]/Earth Sciences/Glaciology, Sulfate, Signature (topology), isotope, aerosols, 0105 earth and related environmental sciences
Abstract

International audience; 17O-excess (Δ17O = δ17O − 0.52 × δ18O) of sulfate trapped in Antarctic ice cores has been proposed as a potential tool for assessing past oxidant chemistry, while insufficient understanding of atmospheric sulfate formation around Antarctica hampers its interpretation. To probe influences of regional specific chemistry, we compared year-round observations of Δ17O of non-sea-salt sulfate in aerosols (Δ17O(SO42−)nss) at Dome C and Dumont d'Urville, inland and coastal sites in East Antarctica, throughout the year 2011. Although Δ17O(SO42−)nss at both sites showed consistent seasonality with summer minima (∼1.0‰) and winter maxima (∼2.5‰) owing to sunlight-driven changes in the relative importance of O3 oxidation to OH and H2O2 oxidation, significant intersite differences were observed in austral spring–summer and autumn. The cooccurrence of higher Δ17O(SO42−)nss at inland (2.0‰ ± 0.1‰) than the coastal site (1.2‰ ± 0.1‰) and chemical destruction of methanesulfonate (MS–) in aerosols at inland during spring–summer (October–December), combined with the first estimated Δ17O(MS–) of ∼16‰, implies that MS– destruction produces sulfate with high Δ17O(SO42−)nss of ∼12‰. If contributing to the known postdepositional decrease of MS– in snow, this process should also cause a significant postdepositional increase in Δ17O(SO42−)nss over 1‰, that can reconcile the discrepancy between Δ17O(SO42−)nss in the atmosphere and ice. The higher Δ17O(SO42−)nss at the coastal site than inland during autumn (March–May) may be associated with oxidation process involving reactive bromine and/or sea-salt particles around the coastal region.

Published
2021

7. A Multi-Physics Experiment with a Temporary Dense Seismic Array on the Argentière Glacier, French Alps: The RESOLVE Project

Author

C. Vincent, Amandine Sergeant, Fabian Lindner, Bruno Jourdain, Florent Gimbert, Mickael Langlais, A. Walpersdorf, Ugo Nanni, Albanne Lecointre, Olivier Laarman, Agnès Helmstetter, Fabian Walter, Philippe Roux, and Stéphane Garambois

Subjects
geography, Geophysics, geography.geographical_feature_category, 010504 meteorology & atmospheric sciences, Seismic array, Glacier, 010502 geochemistry & geophysics, 01 natural sciences, Seismology, 0105 earth and related environmental sciences
Abstract

Recent work in the field of cryo-seismology demonstrates that high-frequency (>1 Hz) seismic waves provide key constraints on a wide range of glacier processes, such as basal friction, surface crevassing, or subglacial water flow. Establishing quantitative links between the seismic signal and the processes of interest, however, requires detailed characterization of the wavefield, which, at high frequencies, necessitates the deployment of large and dense seismic arrays. Although dense seismic array monitoring has recently become increasingly common in geophysics, its application to glaciated environments remains limited. Here, we present a dense seismic array experiment made of 98 three-component seismic stations continuously recording during 35 days in early spring 2018 on the Argentière Glacier, French Alps. The seismic dataset is supplemented with a wide range of complementary observations obtained from ground-penetrating radar, drone imagery, Global Navigation Satellite Systems positioning, and in situ measurements of basal glacier sliding velocities and subglacial water discharge. We present first results through conducting spectral analysis, template matching, matched-field processing, and eikonal-wave tomography. We report enhanced spatial resolution on basal stick slip and englacial fracturing sources as well as novel constraints on the heterogeneous nature of the noise field generated by subglacial water flow and on the link between crevasse properties and englacial seismic velocities. We outline in which ways further work using this dataset could help tackle key remaining questions in the field.

Published
2021

8. Englacial temperatures increase of Taconnaz glacier (Mont Blanc area) and consequences on glacier instability in the future

Author

Christian Vincent, Adrien Gilbert, Luc Piard, Olivier Gagliardini, Bruno Jourdain, Florent Gimbert, and Poul Christoffersen

Abstract

High elevation cold glaciers are experiencing important warming in response to on-going climate change. It could affect the ice/rock interface temperature and lead to avalanching glacier instabilities on steep slopes. Few of these glaciers are located in densely populated areas and could threaten inhabited areas in the future, when the ice/rock interface will become temperate. It is the case of Taconnaz hanging glacier (Mont Blanc area) with a large cold ice area located on a steep slope in the accumulation zone. This glacier is located above the valley of Chamonix. Modeling and measuring the progressive warming of this cold hanging glacier is critical to assess the evolution of its stability.The thermal regime of this glacier have been monitored over the last decades from deep boreholes observations. We found clear englacial temperatures increase. For instance, measurements performed in deep boreholes between 1994 and 2021 reveal strong changes in englacial temperature reaching 2 °C increase at a depth of 50 m close to the summit of this glacier (4300 m a.s.l.). We also found that the current englacial warming is now reaching the glacier base at most location. Our numerical simulations, using a thermo-mechanical model, are able to capture the observed warming and show that a large volume of ice could become unstable within the 21th century and could lead to a large ice avalanche. Such break-off could have catastrophic consequences for life and property in the valley.

Published
2022

9. Strong changes in englacial temperatures despite insignificant changes in ice thickness at Dôme du Goûter glacier (Mont Blanc area)

Author

C. Vincent, Patrick Ginot, Luc Piard, Philippe Possenti, Emmanuel Le Meur, Olivier Laarman, Vladimir Mikhalenko, Bruno Jourdain, Adrien Gilbert, Delphine Six, Institut des Géosciences de l’Environnement (IGE), Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), and Université Grenoble Alpes (UGA)

Subjects
lcsh:GE1-350, geography, geography.geographical_feature_category, Ice stream, Lead (sea ice), lcsh:QE1-996.5, Flux, Climate change, Glacier, Snow, Atmospheric sciences, lcsh:Geology, Glacier mass balance, [SDU]Sciences of the Universe [physics], Precipitation, sense organs, skin and connective tissue diseases, Geology, lcsh:Environmental sciences, Earth-Surface Processes, Water Science and Technology
Abstract

The response of very-high-elevation glaciated areas on Mont Blanc to climate change has been analysed using observations and numerical modelling over the last 2 decades. Unlike the changes at low elevations, we observe very low glacier thickness changes, of about −2.6 m on average since 1993. The slight changes in horizontal ice flow velocities and submergence velocities suggest a decrease of about 10 % in ice flux and surface mass balance. This is due to less snow accumulation and is consistent with the precipitation decrease observed in meteorological data. Conversely, measurements performed in deep boreholes since 1994 reveal strong changes in englacial temperature reaching a 1.5 ∘C increase at a depth of 50 m. We conclude that at such very high elevations, current changes in climate do not lead to visible changes in glacier thickness but cause invisible changes within the glacier in terms of englacial temperatures. Our analysis from numerical modelling shows that glacier near-surface temperature warming is enhanced by increasing melt frequency at high elevations although the impact on surface mass balance is low. This results in a non-linear response of englacial temperature to currently rising air temperatures. In addition, borehole temperature inversion including a new dataset confirms previous findings of similar air temperature changes at high and low elevations in the Alps.

Published
2020

10. Evidence of Seasonal Uplift in the Argentière Glacier (Mont Blanc Area, France)

Author

Christian Vincent, Adrien Gilbert, Andrea Walpersdorf, Florent Gimbert, Olivier Gagliardini, Bruno Jourdain, Juan Pedro Roldan Blasco, Olivier Laarman, Luc Piard, Delphine Six, Luc Moreau, Diego Cusicanqui, Emmanuel Thibert, Institut des Géosciences de l’Environnement (IGE), Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA), Institut des Sciences de la Terre (ISTerre), Institut national des sciences de l'Univers (INSU - CNRS)-Institut de recherche pour le développement [IRD] : UR219-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Gustave Eiffel-Université Grenoble Alpes (UGA), Chamonix Glaciol Association, and ANR-18-CE01-0015,SAUSSURE,Glissement des glaciers et pression hydrologique sous glaciaire en relat(2018)

Subjects
ice flow velocities, Geophysics, subglacial water storage, uplift, basal sliding and sub glacial runoff, [SDU.STU.GL]Sciences of the Universe [physics]/Earth Sciences/Glaciology, Earth-Surface Processes
Abstract

International audience; The hydromechanical processes by which basal water controls sliding at the glacier bed are poorly known, despite glacier basal motion being responsible for a large part of ice flux in temperate alpine glaciers. Previous studies suggest that sliding strongly relates to the quantity of water being stored at the ice-bedrock interface. However, this water storage is difficult to quantify accurately on the basis of surface-motion observations, given that uplift can also be affected by changes in vertical-strain rates and sliding velocity change. Here, we use a comprehensive data set of in situ measurements performed over 2 years on the Argentière Glacier in the French Alps to investigate the relationships between horizontal and vertical velocities, basal sliding, subglacial runoff and bed separation. We observe strikingly large uplifts varying spatially between 0.20 and 0.90 m over the winter/spring seasons between January and June and with a consistent spatial pattern from 1 year to another. We show, based on observations and three dimensional ice-flow modeling, that these large uplifts cannot be explained solely by changes in strain rates or in sliding up an inclined bed. Our results reveal that more than 80% of the observed uplift is related to enhanced bed separation through cavitation, allowing us to estimate the volume occupied by water-filled subglacial cavities. Our interpretation of uplift being mainly caused by increased cavitation is also consistent with an associated increase in the observed surface horizontal velocity. These findings provide important observational constraints for testing subglacial hydrological models

Published
2022

11. Ammonium in Antarctic Aerosol: Marine Biological Activity Versus Long‐Range Transport of Biomass Burning

Author

S. Preunkert, Michel Legrand, Bruno Jourdain, and Rolf Weller

Subjects
010504 meteorology & atmospheric sciences, Range (biology), Potassium, chemistry.chemical_element, 010501 environmental sciences, 01 natural sciences, Oxalate, Aerosol, chemistry.chemical_compound, Geophysics, chemistry, Environmental chemistry, General Earth and Planetary Sciences, Environmental science, Ammonium, Biomass burning, 0105 earth and related environmental sciences
Published
2021

12. Regional characteristics of atmospheric sulfate formation in East Antarctica imprinted on 17O-excess signature

Author

Bruno Jourdain, A. Yamada, Naohiro Yoshida, Jiayue Huang, Jingyuan Shao, Shohei Hattori, Qianjie Chen, Susanne Preunkert, Savarino Joel, Michel Legrand, Lyatt Jaeglé, Becky Alexander, and Sakiko Ishino

Subjects
chemistry.chemical_compound, chemistry, Geochemistry, East antarctica, Sulfate, Signature (topology), Geology
Abstract

17O-excess (Δ17O = δ17O − 0.52 × δ18O) of sulfate trapped in Antarctic ice cores has been proposed as a potential tool for assessing past oxidant chemistry, while insufficient understanding of atmospheric sulfate formation around Antarctica hampers its interpretation. To probe influences of regional specific chemistry, we compared year-round observations of Δ17O of non-sea-salt sulfate in aerosols (Δ17O(SO42−)nss) at Dome C and Dumont d’Urville, inland and coastal sites in East Antarctica, throughout the year 2011. Although Δ17O(SO42–)nss at both sites showed consistent seasonality with summer minima (~1.0 ‰) and winter maxima (~2.5 ‰) owing to sunlight-driven changes in the relative importance of O3-oxidation to OH- and H2O2-oxidation, significant inter-site differences were observed in austral spring–summer and autumn. The co-occurrence of higher Δ17O(SO42–)nss at inland (2.0 ± 0.1 ‰) than the coastal site (1.2 ± 0.1 ‰) and chemical destruction of methanesulfonate (MS–) in aerosols at inland during spring–summer (October to December), combined with the first estimated Δ17O(MS–) of ~16 ‰, implies that MS– destruction produces sulfate with high Δ17O(SO42–)nss of ~12 ‰. If contributing to the known post-depositional decrease of MS– in snow, this process should also cause a significant post-depositional increase in Δ17O(SO42–)nss over 1 ‰, that can reconcile the discrepancy between Δ17O(SO42–)nss in the atmosphere and ice.

Published
2021

13. Geodetic point surface mass balances: A new approach to determine point surface mass balances from remote sensing measurements

Author

Christian Vincent, Diego Cusicanqui, Bruno Jourdain, Olivier Laarman, Delphine Six, Adrien Gilbert, Andrea Walpersdorf, Antoine Rabatel, Luc Piard, Florent Gimbert, Olivier Gagliardini, Vincent Peyaud, Laurent Arnaud, Emmanuel Thibert, Fanny Brun, and Ugo Nanni

Abstract

Mass balance observations are very useful to assess climate change in different regions of the world. As opposed to glacier-wide mass balances, which are influenced by the dynamic response of each glacier, point mass-balances provide a direct climatic signal that depends on surface accumulation and ablation only. Unfortunately, major efforts are required to conduct in situ measurements on glaciers. Here, we propose a new approach that determines point surface mass balances from remote sensing observations. We call this balance the geodetic point surface mass balance. From observations and modelling performed on Argentière and Mer de Glace glaciers over the last decade, we show that the vertical ice flow velocity changes are small in areas of low bedrock slope. Therefore, assuming constant vertical velocities in time for such areas and provided that the vertical velocities have been measured for at least one year in the past, our method can be used to reconstruct annual point surface mass balances from surface elevations and horizontal velocities alone. We demonstrate that the annual point surface mass balances can be reconstructed with an accuracy of about 0.3 m w.e. a−1 using the vertical velocities observed over the previous years and data from Unmanned Aerial Vehicle images. Given the recent improvements of satellite sensors, it should be possible to apply this method to high spatial resolution satellite images as well.

Published
2020

14. Evidence of uplift at Argentière glacier (Mont Blanc area, France)

Author

Diego Cusicanqui, Fabien Gillet-Chaulet, Christian Vincent, Delphine Six, Luc Moreau, Adrien Gilbert, Bruno Jourdain, Andrea Walpersdorf, Olivier Laarman, Florent Gimbert, Olivier Gagliardini, and Luc Piard

Subjects
geography, geography.geographical_feature_category, Glacier, Physical geography, Mont blanc, Geology
Abstract

Understanding basal processes is a prerequisite for predicting the overall motion of glaciers and its response to climate change. Although a number of studies have shown that subglacial hydrology affects glacier’s basal sliding motion, the involved mechanisms remain poorly known. Several studies suggested that glacier velocity increases with englacial and subglacial water storage, but observational quantification of subglacial water storage and associated velocity changes are challenging to make due to uncertainties on velocity measurements and on vertical straining.Here we tackle this observational challenge through analyzing numerous field measurements from the surface and from the subglacial observatory on the Argentière Glacier (French Alps). We analyze specifically the relationships between daily sliding velocities (measured continuously at the glacier base), surface horizontal and vertical velocities from DGPS observations and ice thickness changes over years 2018 and 2019. We find strong upward surface movements of about 0.5 m during the winter until the beginning of May that cannot be explained by longitudinal strain rate changes. We support that it is caused by water volume increase in subglacial cavities.Further analyzing the relationships between cavity growth, sliding and surface velocities, we find that unlike in previous studies bed separation variations are not synchronous with sliding speed variations. Surface uplift starts in winter, which is long before the spring sliding acceleration, and surface drop occurs mid-summer, which is long before the end of summer sliding deceleration. These findings support that the link between subglacial water storage and sliding speed may not be as direct as previously thought.

Published
2020

15. Seasonal variations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica

Author

Kota Kuribayashi, Bruno Jourdain, Susanne Preunkert, Naohiro Yoshida, Joel Savarino, Sakiko Ishino, Albane Barbero, Shohei Hattori, Nicolas Caillon, and Michel Legrand

Subjects
Atmospheric Science, Ozone, 010504 meteorology & atmospheric sciences, 01 natural sciences, Atmosphere, lcsh:Chemistry, chemistry.chemical_compound, Nitrate, TheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITY, medicine, Mixing ratio, Sulfate, NOx, 0105 earth and related environmental sciences, 010401 analytical chemistry, Seasonality, medicine.disease, lcsh:QC1-999, 0104 chemical sciences, chemistry, lcsh:QD1-999, Environmental chemistry, Climatology, Atmospheric chemistry, Environmental science, lcsh:Physics
Abstract

Triple oxygen isotopic compositions (Δ17O = δ17O − 0.52 × δ18O) of atmospheric sulfate (SO42−) and nitrate (NO3−) in the atmosphere reflect the relative contribution of oxidation pathways involved in their formation processes, which potentially provides information to reveal missing reactions in atmospheric chemistry models. However, there remain many theoretical assumptions for the controlling factors of Δ17O(SO42−) and Δ17O(NO3−) values in those model estimations. To test one of those assumption that Δ17O values of ozone (O3) have a flat value and do not influence the seasonality of Δ17O(SO42−) and Δ17O(NO3−) values, we performed the first simultaneous measurement of Δ17O values of atmospheric sulfate, nitrate, and ozone collected at Dumont d'Urville (DDU) Station (66°40′ S, 140°01′ E) throughout 2011. Δ17O values of sulfate and nitrate exhibited seasonal variation characterized by minima in the austral summer and maxima in winter, within the ranges of 0.9–3.4 and 23.0–41.9 ‰, respectively. In contrast, Δ17O values of ozone showed no significant seasonal variation, with values of 26 ± 1 ‰ throughout the year. These contrasting seasonal trends suggest that seasonality in Δ17O(SO42−) and Δ17O(NO3−) values is not the result of changes in Δ17O(O3), but of the changes in oxidation chemistry. The trends with summer minima and winter maxima for Δ17O(SO42−) and Δ17O(NO3−) values are caused by sunlight-driven changes in the relative contribution of O3 oxidation to the oxidation by HOx, ROx, and H2O2. In addition to that general trend, by comparing Δ17O(SO42−) and Δ17O(NO3−) values to ozone mixing ratios, we found that Δ17O(SO42−) values observed in spring (September to November) were lower than in fall (March to May), while there was no significant spring and fall difference in Δ17O(NO3−) values. The relatively lower sensitivity of Δ17O(SO42−) values to the ozone mixing ratio in spring compared to fall is possibly explained by (i) the increased contribution of SO2 oxidations by OH and H2O2 caused by NOx emission from snowpack and/or (ii) SO2 oxidation by hypohalous acids (HOX = HOCl + HOBr) in the aqueous phase.

Published
2017

16. A 60-year ice-core record of regional climate from Adélie Land, coastal Antarctica

Author

Olivier Magand, Martin Werner, Vincent Favier, Hubert Gallée, Michel Fily, Bruno Jourdain, Sentia Goursaud, Michel Legrand, Bénédicte Minster, Susanne Preunkert, Valérie Masson-Delmotte, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Glaces et Continents, Climats et Isotopes Stables (GLACCIOS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG ), Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), Institut des Géosciences de l’Environnement (IGE), Institut de Recherche pour le Développement (IRD)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), Alfred Wegener Institute for Polar and Marine Research (AWI), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), and Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)

Subjects
[SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, lcsh:GE1-350, geography, geography.geographical_feature_category, 010504 meteorology & atmospheric sciences, Atmospheric models, δ18O, Firn, lcsh:QE1-996.5, Antarctic ice sheet, Atmospheric model, 010502 geochemistry & geophysics, 01 natural sciences, lcsh:Geology, Ice core, 13. Climate action, Climatology, Sea ice, Environmental science, Precipitation, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, lcsh:Environmental sciences, 0105 earth and related environmental sciences, Earth-Surface Processes, Water Science and Technology
Abstract

A 22.4 m-long shallow firn core was extracted during the 2006/2007 field season from coastal Adélie Land. Annual layer counting based on subannual analyses of δ18O and major chemical components was combined with 5 reference years associated with nuclear tests and non-retreat of summer sea ice to build the initial ice-core chronology (1946–2006), stressing uncertain counting for 8 years. We focus here on the resulting δ18O and accumulation records. With an average value of 21.8 ± 6.9 cm w.e. yr−1, local accumulation shows multi-decadal variations peaking in the 1980s, but no long-term trend. Similar results are obtained for δ18O, also characterised by a remarkably low and variable amplitude of the seasonal cycle. The ice-core records are compared with regional records of temperature, stake area accumulation measurements and variations in sea-ice extent, and outputs from two models nudged to ERA (European Reanalysis) atmospheric reanalyses: the high-resolution atmospheric general circulation model (AGCM), including stable water isotopes ECHAM5-wiso (European Centre Hamburg model), and the regional atmospheric model Modèle Atmosphérique Régional (AR). A significant linear correlation is identified between decadal variations in δ18O and regional temperature. No significant relationship appears with regional sea-ice extent. A weak and significant correlation appears with Dumont d'Urville wind speed, increasing after 1979. The model-data comparison highlights the inadequacy of ECHAM5-wiso simulations prior to 1979, possibly due to the lack of data assimilation to constrain atmospheric reanalyses. Systematic biases are identified in the ECHAM5-wiso simulation, such as an overestimation of the mean accumulation rate and its interannual variability, a strong cold bias and an underestimation of the mean δ18O value and its interannual variability. As a result, relationships between simulated δ18O and temperature are weaker than observed. Such systematic precipitation and temperature biases are not displayed by MAR, suggesting that the model resolution plays a key role along the Antarctic ice sheet coastal topography. Interannual variations in ECHAM5-wiso temperature and precipitation accurately capture signals from meteorological data and stake observations and are used to refine the initial ice-core chronology within 2 years. After this adjustment, remarkable positive (negative) δ18O anomalies are identified in the ice-core record and the ECHAM5-wiso simulation in 1986 and 2002 (1998–1999), respectively. Despite uncertainties associated with post-deposition processes and signal-to-noise issues, in one single coastal ice-core record, we conclude that the S1C1 core can correctly capture major annual anomalies in δ18O as well as multi-decadal variations. These findings highlight the importance of improving the network of coastal high-resolution ice-core records, and stress the skills and limitations of atmospheric models for accumulation and δ18O in coastal Antarctic areas. This is particularly important for the overall East Antarctic ice sheet mass balance.

Published
2017

17. Retrieval of Snow Properties from the Sentinel-3 Ocean and Land Colour Instrument

Author

Emmanuel Le Meur, Sergey Korkin, Dirk van As, Anne-Katrine Faber, Diana Vladimirova, Maria Hoerhold, Alexander A. Kokhanovsky, Marie Dumont, Kenneth D. Mankoff, Vladimir Rozanov, Laurent Arnaud, Alexandra Zuhr, Olaf Danne, Johannes Freitag, Michael Kern, Maxim Lamare, Teruo Aoki, Masashi Niwano, Eleonora P. Zege, Jason E. Box, Carsten Brockmann, Jonas Kvist Andersen, Hans Christian Steen-Larsen, Baptiste Vandecrux, Ghislain Picard, Sonja Wahl, Sepp Kipfstuhl, Biagio Di Mauro, Vincent Favier, Bruno Jourdain, Centre d'Etudes de la Neige (CEN), Centre national de recherches météorologiques (CNRM), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG ), Institut national des sciences de l'Univers (INSU - CNRS)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Université Grenoble Alpes (UGA)-Météo-France -Institut national des sciences de l'Univers (INSU - CNRS)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Université Grenoble Alpes (UGA), Institut des Géosciences de l’Environnement (IGE), Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA), and ANR-16-CE01-0006,EBONI,Dépot, devenir et impact des impuretés absorbantes dans le manteau neigeux(2016)

Subjects
010504 meteorology & atmospheric sciences, 0211 other engineering and technologies, snow characteristics, optical remote sensing, sow grain size, specific surface area, albedo, Sentinel 3, OLCI, Greenland ice sheet, [SDU.STU]Sciences of the Universe [physics]/Earth Sciences, olci, 02 engineering and technology, Snow field, 010502 geochemistry & geophysics, 01 natural sciences, Data assimilation, ddc:550, lcsh:Science, 021101 geological & geomatics engineering, Remote sensing, 0105 earth and related environmental sciences, geography, snow grain size, geography.geographical_feature_category, Atmospheric correction, 15. Life on land, Albedo, Snow, atmospheric_science, 13. Climate action, Snowmelt, Climatology, sentinel 3, General Earth and Planetary Sciences, Environmental science, lcsh:Q, Institut für Geowissenschaften, Ice sheet
Abstract

The Sentinel Application Platform (SNAP) architecture facilitates Earth Observation data processing (http://step.esa.int/main/toolboxes/snap/). In this work we present results from a new Snow Processor for SNAP. We also describe physical principles behind the developed snow property retrieval technique based on the analysis of Ocean and Land Colour Instrument (OLCI) onboard Sentinel-3A/B measurements over clean and polluted snow fields. Using OLCI spectral reflectance measurements in the range 400-1020nm, we derive important snow properties such as spectral and broadband albedo, snow specific surface area, snow extent and grain size on the spatial grid of 300m. The algorithm also incorporates cloud screening and atmospheric correction procedures over snow surfaces. We present validation results using ground measurements from Antarctica, the Greenland ice sheet and the French Alps. We find the spectral albedo retrieved with accuracy of better than 3% on average, making our retrievals sufficient for a variety of applications. Broadband albedo is retrieved with the average accuracy of about 5% over snow. Therefore, the uncertainties of satellite retrievals are close to experimental errors of ground measurements. The retrieved surface grain size shows good agreement with ground observations. Snow specific surface area observations are also consistent with our OLCI retrievals. We present snow albedo and grain size mapping over the inland ice sheet of Greenland for areas including dry snow, melted/melting snow and impurity rich bare ice. The algorithm can be applied to OLCI Sentinel-3 measurements providing an opportunity for creation of long – term snow property records essential for climate monitoring and data assimilation studies - especially in the Arctic region, where we face rapid environmental changes including reduction of snow/ice extent and, therefore, planetary albedo.

Published
2019

18. Strong changes in englacial temperatures despite insignificantchanges in ice thickness at Dôme du Goûter glacier (Mont-Blanc area)

Author

Christian Vincent, Adrien Gilbert, Bruno Jourdain, Luc Piard, Patrick Ginot, Vladimir Mikhalenko, Philippe Possenti, Emmanuel Le Meur, Olivier Laarman, and Delphine Six

Subjects
sense organs, skin and connective tissue diseases
Abstract

The response of very high elevation glaciated areas on Mont Blanc to climate change has been analyzed using observations and numerical modeling. Unlike the changes at low elevations, we observe very low glacier thickness changes, of about −2.6 m on the average since 1993. The slight changes in horizontal ice flow velocities and submergence velocities suggest a decrease of about 10 % in ice flux and surface mass balance. This is due to snow accumulation changes and is consistent with the precipitation decrease observed in meteorological data. Conversely, measurements performed in deep boreholes since 1994 reveal strong changes in englacial temperature reaching 1.5 °C at a depth of 50 m. We conclude that at such very high elevations, current changes in climate do not lead to visible changes in glacier thickness but cause invisible changes within the glacier in terms of englacial temperatures. Our analysis from numerical modeling shows that glacier near-surface temperature warming is enhanced by increasing melt-frequency at high elevations although the impact on surface mass balance is low. This results in a non-linear response of englacial temperature to currently rising air temperatures. In addition, borehole temperature inversion including a new dataset confirms previous findings of similar air temperature changes at high and low elevations in the Alps.

Published
2019

20. Homogeneous sulfur isotope signature in East Antarctica and implication for sulfur source shifts through the last glacial-interglacial cycle

Author

Francis Albarède, Joel Savarino, Emmanuelle Albalat, Michel Legrand, Sakiko Ishino, Shohei Hattori, Susanne Preunkert, Bruno Jourdain, Naohiro Yoshida, School of Materials and Chemical Technology, Tokyo Institute of Technology, 226‐8502 Yokohama, Japan, Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), Laboratoire d’Optique Atmosphérique - UMR 8518 (LOA), Institut national des sciences de l'Univers (INSU - CNRS)-Université de Lille-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement (LGL-TPE), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Université Jean Monnet - Saint-Étienne (UJM)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Sciences de la Terre (LST), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Institut des Géosciences de l’Environnement (IGE), Institut de Recherche pour le Développement (IRD)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), ANR-16-CE01-0011,EAIIST,Projet International d'exploration de la calotte polaire de l'Antarctique de l'Est(2016), Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement [Lyon] (LGL-TPE), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École normale supérieure - Lyon (ENS Lyon), Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut de Recherche pour le Développement (IRD)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), Université Grenoble Alpes (UGA), Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Observatoire des Sciences de l'Univers de Grenoble (OSUG), and Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS)

Subjects
Cryospheric science, 0301 basic medicine, Atmospheric chemistry, lcsh:Medicine, Flux, Palaeoclimate, Article, Atmosphere, 03 medical and health sciences, chemistry.chemical_compound, 0302 clinical medicine, Ice core, Element cycles, Sulfate aerosol, 14. Life underwater, Glacial period, lcsh:Science, ComputingMilieux_MISCELLANEOUS, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, Multidisciplinary, lcsh:R, Sediment, 030104 developmental biology, Oceanography, chemistry, Productivity (ecology), 13. Climate action, Interglacial, Environmental science, lcsh:Q, 030217 neurology & neurosurgery
Abstract

Sulfate aerosol (SO42−) preserved in Antarctic ice cores is discussed in the light of interactions between marine biological activity and climate since it is mainly sourced from biogenic emissions from the surface ocean and scatters solar radiation during traveling in the atmosphere. However, there has been a paradox between the ice core record and the marine sediment record; the former shows constant non-sea-salt (nss-) SO42− flux throughout the glacial-interglacial changes, and the latter shows a decrease in biogenic productivity during glacial periods compared to interglacial periods. Here, by ensuring the homogeneity of sulfur isotopic compositions of atmospheric nss-SO42− (δ34Snss) over East Antarctica, we established the applicability of the signature as a robust tool for distinguishing marine biogenic and nonmarine biogenic SO42−. Our findings, in conjunction with existing records of nss-SO42− flux and δ34Snss in Antarctic ice cores, provide an estimate of the relative importance of marine biogenic SO42− during the last glacial period to be 48 ± 10% of nss-SO42−, slightly lower than 59 ± 11% during the interglacial periods. Thus, our results tend to reconcile the ice core and sediment records, with both suggesting the decrease in marine productivity around Southern Ocean under the cold climate.

Published
2019

21. Seasonality in sulfur isotopic compositions of atmospheric sulfate in East Antarctica

Author

Sakiko, Ishino, Shohei, Hattori, Joel, Savarino, Michel, Legrand, Emmanuelle, Albalat, Francis, Albarede, Susanne, Preunkert, Bruno, Jourdain, and Naohiro, Yoshida

Abstract

The Ninth Symposium on Polar Science/Special session: [S] Antarctic ice-ocean interaction ～observation, reconstruction, and modeling～, Tue. 4 Dec. / Entrance Hall (1st floor) at National Institute of Polar Research

Published
2018

22. Déclin des deux plus grands glaciers des Alpes françaises au cours du XXIe siècle : Argentière et Mer de Glace

Author

Christian Vincent, Antoine Rabatel, Vincent Peyaud, Adrien Gilbert, Olivier Laarman, Etienne Berthier, Deborah Verfaillie, Jordi Bolibar, Delphine Six, Samuel Morin, Fabien Gillet-Chaulet, and Bruno Jourdain

Abstract

Des modelisations ont ete realisees sur les deux plus grands glaciers des Alpes francaises afin d'estimer leur evolution au cours du XXI e siecle. Pour un scenario climatique intermediaire avec reduction des emissions de gaz a effet de serre avant la fin du XXI e siecle (RCP 4.5), les simulations indiquent que le glacier d'Argentiere devrait disparaitre vers la fin du XXI e siecle et que la surface de la Mer de Glace pourrait diminuer de 80 %. Dans l'hypothese la plus pessimiste d'une croissance ininterrompue des emissions de gaz a effet de serre (RCP 8.5), la Mer de Glace pourrait disparaitre avant 2100 et le glacier d'Argentiere une vingtaine d'annees plus tot.

Published
2019

24. Antarctic winter mercury and ozone depletion events over sea ice

Author

Anna Granfors, Katarina Abrahamsson, G. Méjean, Hans-Werner Jacobi, Aurélien Dommergue, Martin Ahnoff, Bruno Jourdain, M. G. Nerentorp Mastromonaco, Katarina Gårdfeldt, Department of Chemistry, University of Gothenburg (GU), Department of Analytical and Marine Chemistry ( Gothenburg, Sweden), Göteborgs Universitet (SWEDEN), CHANG, Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS), LIPhy-LAME, Laboratoire Interdisciplinaire de Physique [Saint Martin d’Hères] (LIPhy), Université Joseph Fourier - Grenoble 1 (UJF)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Université Joseph Fourier - Grenoble 1 (UJF)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA), Observatoire des Sciences de l'Univers de Grenoble (OSUG ), Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Spectrométrie Physique (LSP), Université Joseph Fourier - Grenoble 1 (UJF)-Centre National de la Recherche Scientifique (CNRS), Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG ), Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), and Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Université Joseph Fourier - Grenoble 1 (UJF)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Université Joseph Fourier - Grenoble 1 (UJF)

Subjects
Atmospheric Science, geography, [PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics], Ozone, geography.geographical_feature_category, 010504 meteorology & atmospheric sciences, chemistry.chemical_element, Antarctic sea ice, 010501 environmental sciences, Snow, Atmospheric sciences, 01 natural sciences, Ozone depletion, Mercury (element), Troposphere, chemistry.chemical_compound, chemistry, 13. Climate action, [SDE]Environmental Sciences, Sea ice, Environmental science, Terrestrial ecosystem, ComputingMilieux_MISCELLANEOUS, 0105 earth and related environmental sciences, General Environmental Science
Abstract

International audience; During atmospheric mercury and ozone depletion events in the springtime in polar regions gaseous elemental mercury and ozone undergo rapid declines. Mercury is quickly transformed into oxidation products, which are subsequently removed by deposition. Here we show that such events also occur during Antarctic winter over sea ice areas, leading to additional deposition of mercury. Over four months in the Weddell Sea we measured gaseous elemental, oxidized, and particulate-bound mercury, as well as ozone in the troposphere and total and elemental mercury concentrations in snow, demonstrating a series of depletion and deposition events between July and September.The winter depletions in July were characterized by stronger correlations between mercury and ozone and larger formation of particulate-bound mercury in air compared to later spring events. It appears that light at large solar zenith angles is sufficient to initiate the photolytic formation of halogen radicals. We also propose a dark mechanism that could explain observed events in air masses coming from dark regions. Br2 that could be the main actor in dark conditions was possibly formed in high concentrations in the marine boundary layer in the dark. These high concentrations may also have caused the formation of high concentrations of CHBr3 and CH2I2 in the top layers of the Antarctic sea ice observed during winter.These new findings show that the extent of depletion events is larger than previously believed and that winter depletions result in additional deposition of mercury that could be transferred to marine and terrestrial ecosystems.

Published
2016

25. Oxygen isotope mass balance of atmospheric nitrate at Dome C, East Antarctica, during the OPALE campaign

Author

Jaime Gil Roca, Alexandre Kukui, Joel Savarino, Nicolas Caillon, S. Preunkert, William Vicars, Bruno Jourdain, Michel Legrand, Markus M. Frey, Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG ), Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), Colorado Department of Public Health and Environment, University of Colorado [Denver], Institute of Arctic and Alpine Research (INSTAAR), University of Colorado [Boulder], British Antarctic Survey (BAS), Natural Environment Research Council (NERC), Laboratoire de Physique et Chimie de l'Environnement et de l'Espace (LPC2E), Observatoire des Sciences de l'Univers en région Centre (OSUC), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Centre National d’Études Spatiales [Paris] (CNES), TROPO - LATMOS, Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), European Community's Seventh Framework Programme (FP7/2007-2013), INSU (LEFE Programme), Agence Nationale de la Recherche (ANR), IPEV (programme SUNITEDC n° 1011), ANR-05-PGCU-0004,OPALE,Risque d'inondation en ville et évaluation de scénarios(2005), ANR-10-LABX-0056,OSUG@2020,Innovative strategies for observing and modelling natural systems(2010), European Project: 237890,EC:FP7:PEOPLE,FP7-PEOPLE-ITN-2008,INTRAMIF(2009), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS), CNRS-INSU : LEFE programThe Institute Polaire Paul-Emile Victor (IPEV)the program SUNITEDC No. 1011, Université Grenoble Alpes (UGA), Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Observatoire de Paris, PSL Research University (PSL)-PSL Research University (PSL)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Observatoire de Paris, PSL Research University (PSL)-PSL Research University (PSL)-Centre National d’Études Spatiales [Paris] (CNES), ANR: OPALE,NT09-451281, ANR-10-LABX-0056/10-LABX-0056,OSUG@2020,Innovative strategies for observing and modelling natural systems(2010), ANR10 LABX56,ANR10 LABX56, and Institute of Arctic Alpine Research [University of Colorado Boulder] (INSTAAR)

Subjects
Hydrology, [PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph], Atmospheric Science, Ozone, 010504 meteorology & atmospheric sciences, δ18O, 010401 analytical chemistry, 010501 environmental sciences, Atmospheric sciences, 01 natural sciences, Isotopes of oxygen, lcsh:QC1-999, 0104 chemical sciences, lcsh:Chemistry, chemistry.chemical_compound, Isotopic signature, chemistry, Nitrate, Ice core, lcsh:QD1-999, 13. Climate action, NOx, lcsh:Physics, Isotope analysis, 0105 earth and related environmental sciences
Abstract

Variations in the stable oxygen isotope composition of atmospheric nitrate act as novel tools for studying oxidative processes taking place in the troposphere. They provide both qualitative and quantitative constraints on the pathways determining the fate of atmospheric nitrogen oxides (NO + NO2 = NOx). The unique and distinctive 17O excess (Δ17O = δ17O − 0.52 × δ18O) of ozone, which is transferred to NOx via oxidation, is a particularly useful isotopic fingerprint in studies of NOx transformations. Constraining the propagation of 17O excess within the NOx cycle is critical in polar areas, where there exists the possibility of extending atmospheric investigations to the glacial–interglacial timescale using deep ice core records of nitrate. Here we present measurements of the comprehensive isotopic composition of atmospheric nitrate collected at Dome C (East Antarctic Plateau) during the austral summer of 2011/2012. Nitrate isotope analysis has been here combined for the first time with key precursors involved in nitrate production (NOx, O3, OH, HO2, RO2, etc.) and direct observations of the transferrable Δ17O of surface ozone, which was measured at Dome C throughout 2012 using our recently developed analytical approach. Assuming that nitrate is mainly produced in Antarctica in summer through the OH + NO2 pathway and using concurrent measurements of OH and NO2, we calculated a Δ17O signature for nitrate on the order of (21–22 ± 3) ‰. These values are lower than the measured values that ranged between 27 and 31 ‰. This discrepancy between expected and observed Δ17O(NO3−) values suggests the existence of an unknown process that contributes significantly to the atmospheric nitrate budget over this East Antarctic region. However, systematic errors or false isotopic balance transfer functions are not totally excluded.

Published
2016

26. Characterization of the boundary layer at Dome C (East Antarctica) during the OPALE summer campaign

Author

Hélène Barral, Etienne Vignon, Susanne Preunkert, Ilaria Pietroni, Markus M. Frey, Stefania Argentini, Christophe Genthon, Giampietro Casasanta, Michel Legrand, Bruno Jourdain, Hubert Gallée, Charles Amory, Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS), Istituto di Scienze dell'Atmosfera e del Clima (ISAC), Consiglio Nazionale delle Ricerche [Roma] (CNR), British Antarctic Survey (BAS), Natural Environment Research Council (NERC), Université Grenoble Alpes (UGA), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS), and Université Grenoble Alpes [2016-2019] (UGA [2016-2019])

Subjects
Atmospheric Science, 010504 meteorology & atmospheric sciences, SODAR, Albedo, Atmospheric sciences, Snow, 01 natural sciences, lcsh:QC1-999, 010305 fluids & plasmas, Physics::Geophysics, Troposphere, lcsh:Chemistry, Boundary layer, Dome (geology), lcsh:QD1-999, 13. Climate action, Climatology, 0103 physical sciences, [SDE]Environmental Sciences, Climate model, Geology, Sea level, Physics::Atmospheric and Oceanic Physics, lcsh:Physics, 0105 earth and related environmental sciences
Abstract

Regional climate model MAR (Modèle Atmosphérique Régional) was run for the region of Dome C located on the East Antarctic plateau, during Antarctic summer 2011–2012, in order to refine our understanding of meteorological conditions during the OPALE tropospheric chemistry campaign. A very high vertical resolution is set up in the lower troposphere, with a grid spacing of roughly 2 m. Model output is compared with temperatures and winds observed near the surface and from a 45 m high tower as well as sodar and radiation data. MAR is generally in very good agreement with the observations, but sometimes underestimates cloud formation, leading to an underestimation of the simulated downward long-wave radiation. Absorbed short-wave radiation may also be slightly overestimated due to an underestimation of the snow albedo, and this influences the surface energy budget and atmospheric turbulence. Nevertheless, the model provides sufficiently reliable information about surface turbulent fluxes, vertical profiles of vertical diffusion coefficients and boundary layer height when discussing the representativeness of chemical measurements made nearby the ground surface during field campaigns conducted at Concordia station located at Dome C (3233 m above sea level).

Published
2015

27. Field Comparison of Particulate PAH Measurements Using a Low-Flow Denuder Device and Conventional Sampling Systems

Author

Henri Wortham, Bruno Jourdain, Brice Temime, M. Goriaux, Nicolas Marchand, Alexandre Albinet, Eva Leoz-Garziandia, Jean-Luc Besombes, Université de Provence - Aix-Marseille 1, Ecole Supérieure d'Ingénieurs de Chambéry (ESIGEC), Polytech Annecy-Chambéry (EPU [Ecole Polytechnique Universitaire de l'Université de Savoie]), Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry]), and Institut National de l'Environnement Industriel et des Risques (INERIS)

Subjects
010504 meteorology & atmospheric sciences, BENZO[A]PYRENE, Air pollution, 010501 environmental sciences, Combustion, medicine.disease_cause, 01 natural sciences, Troposphere, Atmosphere, DENUDER TUBE, medicine, Environmental Chemistry, Polycyclic Aromatic Hydrocarbons, 0105 earth and related environmental sciences, chemistry.chemical_classification, Air Pollutants, Persistent organic pollutant, SAMPLING, Environmental engineering, Reproducibility of Results, Sampling (statistics), PAH, General Chemistry, Particulates, REACTIVITY, Hydrocarbon, chemistry, 13. Climate action, Environmental chemistry, [SDE]Environmental Sciences, ARTEFACT, Environmental science, ATMOSPHERIC POLLUTION, Environmental Monitoring
Abstract

International audience; Polyaromatic hydrocarbons (PAHs) are complex carbonaceous compounds emitted to the atmosphere by various combustion processes. Because the toxicity of many of them is now well recognized and documented, the determination of their atmospheric concentrations is of great interest to better understand and develop future atmospheric pollution control strategies. Hence, a common sampling protocol has to be defined to homogenize the results. With this goal in mind, field studies were carried out under different environmental conditions (74 samples) by simultaneously operating both a conventional sampler and a sampler equipped with a denuder tube upstream from the filter. The experimental results presented in this work show that the atmospheric particulate PAH concentrations are underestimated at least by a factor of 2 using a conventional sampler. The discrepancy between the two kinds of samplers used varied a lot from one compound to another and from one field campaign to another. This discrepancy may be explained by a simple degradation of particulate PAH in the natural atmosphere and on the filter. This is particularly worrisome because, based on the results presented in this work, the atmospheric PAH concentrations measured using conventional samplers not equipped with an ozone trap can underestimate the PAH concentration by more than 200%. This is especially true when the samples are collected in the vicinity of the point source of particulate PAHs and for highly reactive compounds such as benzo[a] pyrene.

Published
2006

29. Measurements of OH and RO2 radicals at Dome C, East Antarctica

Author

S. Preunkert, Alexandre Kukui, Rodrigue Loisil, J. Gil Roca, Michel Legrand, Bruno Jourdain, Gérard Ancellet, Markus M. Frey, and Martin D. King

Subjects
Atmospheric Science, 010504 meteorology & atmospheric sciences, Chemistry, Stereochemistry, Radical, Photodissociation, East antarctica, 010501 environmental sciences, Photochemistry, 01 natural sciences, Dome (geology), 13. Climate action, Molecule, Oxidative capacity, 0105 earth and related environmental sciences, Antarctic plateau
Abstract

Concentrations of OH radicals and the sum of peroxy radicals, RO2, were measured in the boundary layer for the first time on the East Antarctic Plateau at the Concordia Station (Dome C, 75.10° S, 123.31° E) during the austral summer 2011/2012. The median concentrations of OH and RO2 radicals were 3.1 × 106 molecule cm−3 and 9.9 × 106 molecule cm−3, respectively. These values are comparable to those observed at the South Pole, confirming that the elevated oxidative capacity of the Antarctic atmospheric boundary layer found at the South Pole is not restricted to the South Pole but common over the high Antarctic plateau. At Concordia, the concentration of radicals showed distinct diurnal profiles with the median maximum of 5.2 × 106 molecule cm−3 at 11:00 and the median minimum of 1.1 × 106 molecule cm−3 at 01:00 for OH radicals and 1.7 × 108 molecule cm−3 and 2.5 × 107 molecule cm−3 for RO2 radicals at 13:00 and 23:00, respectively (all times are local times). Concurrent measurements of O3, HONO, NO, NO2, HCHO and H2O2 demonstrated that the major primary source of OH and RO2 radicals at Dome C was the photolysis of HONO, HCHO and H2O2, with the photolysis of HONO contributing ~75% of total primary radical production. However, photochemical modelling with accounting for all these radical sources overestimates the concentrations of OH and RO2 radicals by a factor of 2 compared to field observations. Neglecting the net OH production from HONO in the photochemical modelling results in an underestimation of the concentrations of OH and RO2 radicals by a factor of 2. To explain the observations of radicals in this case an additional source of OH equivalent to about (25–35)% of measured photolysis of HONO is required. Even with a factor of 5 reduction in the concentrations of HONO, the photolysis of HONO represents the major primary radical source at Dome C. To account for a possibility of an overestimation of NO2 observed at Dome C the calculations were also performed with NO2 concentrations estimated by assuming steady-state NO2 / NO ratios. In this case the net radical production from the photolysis of HONO should be reduced by a factor of 5 or completely removed based on the photochemical budget of OH or 0-D modelling, respectively. Another major factor leading to the large concentration of OH radicals measured at Dome C was large concentrations of NO molecules and fast recycling of peroxy radicals to OH radicals.

Published
2014

30. Large mixing ratios of atmospheric nitrous acid (HONO) at Concordia (East Antarctic Plateau) in summer: a strong source from surface snow?

Author

Bruno Jourdain, Joel Savarino, Alexandre Kukui, S. Preunkert, Michel Kerbrat, Th Bartels-Rausch, Michel Legrand, Martin D. King, Markus M. Frey, Université Joseph Fourier - Grenoble 1 (UJF), Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS), British Antarctic Survey (BAS), Natural Environment Research Council (NERC), Laboratory of Radio- and Environmental Chemistry [Villigen], Paul Scherrer Institute (PSI), Laboratoire de Physique et Chimie de l'Environnement et de l'Espace (LPC2E), Observatoire des Sciences de l'Univers en région Centre (OSUC), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Centre National d’Études Spatiales [Paris] (CNES), School of Earth Sciences [Bristol], University of Bristol [Bristol], NERC NE/F0004796/1 and NE/F010788, and NERC FSF grants 555.0608 and 584.0609, Institut Polaire Français-Paul Emile Victor (IPEV), Italian colleagues from Meteo- Climatological Observatory of PNRA for the meteorological data collected at Concordia., ANR-09-BLAN-0226,OPALE(2009), ANR-11-JS56-0005,MONISNOW,Suivi temporel de la neige dans un climat changeant(2011), Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS), Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Observatoire de Paris, PSL Research University (PSL)-PSL Research University (PSL)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Observatoire de Paris, PSL Research University (PSL)-PSL Research University (PSL)-Centre National d’Études Spatiales [Paris] (CNES), ANR-09-BLAN-0226,OPALE, and ANR-11- JS56-005-01,MONISNOW

Subjects
Atmospheric Science, Nitrous acid, 010504 meteorology & atmospheric sciences, 010501 environmental sciences, Atmospheric sciences, Snow, 01 natural sciences, lcsh:QC1-999, Atmosphere, lcsh:Chemistry, chemistry.chemical_compound, chemistry, lcsh:QD1-999, 13. Climate action, [SDU]Sciences of the Universe [physics], Mixing ratio, Absorption (electromagnetic radiation), [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, NOx, Mixing (physics), lcsh:Physics, Antarctic plateau, 0105 earth and related environmental sciences
Abstract

During the austral summer 2011/2012 atmospheric nitrous acid (HONO) was investigated for the second time at the Concordia site (75°06' S, 123°33' E), located on the East Antarctic Plateau, by deploying a long-path absorption photometer (LOPAP). Hourly mixing ratios of HONO measured in December 2011/January 2012 (35 ± 5.0 pptv) were similar to those measured in December 2010/January 2011 (30.4 ± 3.5 pptv). The large value of the HONO mixing ratio at the remote Concordia site suggests a local source of HONO in addition to weak production from oxidation of NO by the OH radical. Laboratory experiments demonstrate that surface snow removed from Concordia can produce gas-phase HONO at mixing ratios half that of the NOx mixing ratio produced in the same experiment at typical temperatures encountered at Concordia in summer. Using these lab data and the emission flux of NOx from snow estimated from the vertical gradient of atmospheric concentrations measured during the campaign, a mean diurnal HONO snow emission ranging between 0.5 and 0.8 × 109 molecules cm−2 s−1 is calculated. Model calculations indicate that, in addition to around 1.2 pptv of HONO produced by the NO oxidation, these HONO snow emissions can only explain 6.5 to 10.5 pptv of HONO in the atmosphere at Concordia. To explain the difference between observed and simulated HONO mixing ratios, tests were done both in the field and at lab to explore the possibility that the presence of HNO4 had biased the measurements of HONO.

Published
2014

31. Formaldehyde (HCHO) in air, snow and interstitial air at Concordia (East Antarctic plateau) in summer

Author

Alexandre Kukui, Detlev Helmig, Hubert Gallée, Markus M. Frey, Joel Savarino, Martin D. King, Bruno Jourdain, William Vicars, Susanne Preunkert, Michel Legrand, Université Joseph Fourier - Grenoble 1 (UJF), Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS), British Antarctic Survey (BAS), Natural Environment Research Council (NERC), TROPO - LATMOS, Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Laboratoire de Physique et Chimie de l'Environnement et de l'Espace (LPC2E), Observatoire des Sciences de l'Univers en région Centre (OSUC), Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Observatoire de Paris, PSL Research University (PSL)-PSL Research University (PSL)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Observatoire de Paris, PSL Research University (PSL)-PSL Research University (PSL)-Centre National d’Études Spatiales [Paris] (CNES), Department of Physics [Egham], Royal Holloway [University of London] (RHUL), Institute of Arctic and Alpine Research (INSTAAR), University of Colorado [Boulder], ANR-10-LABX-100-01/10-LABX-0100,VOLTAIRE,Geofluids and Volatil elements – Earth, Atmosphere, Interfaces – Resources and Environment(2010), Birmingham City University (BCU), Agence Nationale de la Recherche (ANR), Institut Polaire Français- Paul Emile Victor (IPEV), ANR-09-BLAN-0226,OPALE,Oxidant Production over Antarctica Land and its Export(2009), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Centre National d’Études Spatiales [Paris] (CNES), ANR-09-BLAN-0226,OPALE(2009), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Institute of Arctic Alpine Research [University of Colorado Boulder] (INSTAAR), and ANR-10-LABX-0100,VOLTAIRE,Geofluids and Volatil elements – Earth, Atmosphere, Interfaces – Resources and Environment(2010)

Subjects
[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph], Atmospheric Science, 010504 meteorology & atmospheric sciences, Formaldehyde, 010501 environmental sciences, Snowpack, Noon, Snow, Atmospheric sciences, 01 natural sciences, lcsh:QC1-999, lcsh:Chemistry, chemistry.chemical_compound, Flux (metallurgy), lcsh:QD1-999, chemistry, 13. Climate action, Diurnal cycle, [SDU]Sciences of the Universe [physics], Climatology, Anaerobic oxidation of methane, [SDE]Environmental Sciences, Mixing ratio, lcsh:Physics, 0105 earth and related environmental sciences
Abstract

International audience; During the 2011/12 and 2012/13 austral summers , HCHO was investigated for the first time in ambient air, snow, and interstitial air at the Concordia site, located near Dome C on the East Antarctic Plateau, by deploying an Aerolaser AL-4021 analyzer. Snow emission fluxes were estimated from vertical gradients of mixing ratios observed at 1 cm and 1 m above the snow surface as well as in interstitial air a few centimeters below the surface and in air just above the snowpack. Typical flux values range between 1 and 2 × 1012 molecules m-2 s-1 at night and 3 and 5 × 1012 molecules m-2 s-1 at noon. Shading experiments suggest that the photochemical HCHO production in the snowpack at Concordia remains negligible compared to temperature-driven air–snow exchanges. At 1 m above the snow surface, the observed mean mixing ratio of 130 pptv and its diurnal cycle characterized by a slight decrease around noon are quite well reproduced by 1-D simulations that include snow emissions and gas-phase methane oxidation chemistry. Simulations indicate that the gas-phase production from CH4 oxidation largely contributes (66 %) to the observed HCHO mixing ratios. In addition, HCHO snow emissions account for ∼ 30 % at night and ∼ 10 % at noon to the observed HCHO levels.

Published
2014

32. Seasonal variations of atmospheric dimethylsulfide, dimethylsulfoxide, sulfur dioxide, methanesulfonate, and non-sea-salt sulfate aerosols at Dumont d'Urville (coastal Antarctica) (December 1998 to July 1999)

Author

Bruno Jourdain and Michel Legrand

Subjects
Atmospheric Science, Katabatic wind, food.ingredient, Soil Science, Aquatic Science, Oceanography, Methanesulfonic acid, Troposphere, chemistry.chemical_compound, food, Geochemistry and Petrology, Earth and Planetary Sciences (miscellaneous), Sea ice, Sulfate, Earth-Surface Processes, Water Science and Technology, geography, geography.geographical_feature_category, Ecology, Sea salt, fungi, Paleontology, Forestry, Aerosol, Geophysics, chemistry, Space and Planetary Science, Environmental chemistry, Dimethyl sulfide
Abstract

A study of oxidation products of dimethylsulfide (DMS) was conducted at Dumont d'Urville (DDU), coastal Antarctica, from summer 1998/1999 to midwinter 1999. The study involved multiple daily measurements of DMS and dimethylsulfoxide (DMSO) using a gas chromatograph at the site. Methanesulfonate (MSA), and non-sea-salt sulfate (nssSO42−) aerosols were studied on a daily basis. A few studies of size-segregated aerosol chemistry indicate that both MSA and nssSO42− are present in a dominant submicronic mode at 0.3 μm. MSA and nssSO42− levels exhibit a well-marked seasonal cycle characterized by summer maxima (0.6±0.3 and 3.8±1.4 nmol m−3 of MSA and nssSO42− in January 1999, respectively) and winter minima (0.01±0.004 and 0.21±0.22 nmol m−3 of MSA and nssSO42− in July, respectively). In contrast, weak seasonal cycles of DMS (from 13.1±6.1 nmol m−3 in January to 3.9±1.3 nmol m−3 in July) and DMSO (from 0.15±0.1 nmol m−3 in January to 0.06±0.01 nmol m−3 in July) are observed there. A few SO2 samplings indicate a seasonal cycle with 2.8±0.9 nmol m−3 in January and levels close to the detection limit (0.25 nmol m−3) in winter. The major finding of this study is the presence of large amounts of DMS and DMSO in winter, whereas MSA levels are strongly decreased. These winter DMS levels may be due to small DMS emissions from open water present in sea ice located offshore DDU and/or advection from further north in conjunction with a long lifetime of DMS. The hypothesis of a heterogeneous uptake of DMSO onto aerosols followed by a rapid oxidation into MSA could explain the seasonal DMSO and MSA changes. With respect to the summer situation, in winter, DMSO levels of a tenths of nmol m−3 would result from transport of air masses located further north associated with a lifetime of DMSO of 2 days (instead of a few hours in summer) and a local production of DMSO from DMS oxidation. Such a winter DMSO production in spite of decreased DMS/OH addition pathway (50 times slower than in summer) results from decreased heterogeneous uptake (30 times slower) partly driven by reduction of available aerosol surface by a factor of 15. Finally, when katabatic regime took place bringing air from inland Antarctica, it is shown that the free troposphere above the Antarctic plateau in summer is enriched in DMSO and MSA with respect to DMS and nssSO42−, respectively. That supports the assumption of a different chemistry of DMS taking place in the free troposphere over Antarctica due to dry air conditions and absence of high aerosol levels.

Published
2001

33. Oxidant Production over Antarctic Land and its Export (OPALE) project: An overview of the 2010-2011 summer campaign

Author

Gérard Ancellet, Valérie Gros, Michel Legrand, Alexandre Kukui, Bruno Jourdain, Michael Kerbrat, Susanne Preunkert, and Roland Sarda-Esteve

Subjects
Atmospheric Science, Marine boundary layer, 010504 meteorology & atmospheric sciences, Planetary boundary layer, Soil Science, 010501 environmental sciences, Aquatic Science, Oceanography, Atmospheric sciences, High ozone, 01 natural sciences, Geochemistry and Petrology, Earth and Planetary Sciences (miscellaneous), 14. Life underwater, Air mass, 0105 earth and related environmental sciences, Earth-Surface Processes, Water Science and Technology, Ecology, Chemical measurement, Paleontology, Forestry, East antarctica, Geophysics, 13. Climate action, Space and Planetary Science
Abstract

[1] This paper summarizes the objectives and setting of the OPALE (Oxidant Production over Antarctic Land and its Export) project during summer 2010/2011 at Dumont d'Urville. The primary goal of the campaign is to characterize the oxidizing environment of the atmospheric boundary layer along the coast of East Antarctica. A summary of the relevant field chemical measurements is presented including the carbon monoxide and ammonia records that are used here to identify local influences due to station activities and penguin emissions. An overview of the basic meteorological conditions experienced by the site is presented including the results from the trajectory/dispersion model FLEXPART to highlight which types of air mass were sampled (marine boundary layer versus continental Antarctic air). The results of the FLEXPART analysis demonstrate that high ozone levels and related changes in the OH concentrations are associated with the transport of continental air to DDU. Finally, three companion papers are introduced. A first paper is dedicated to the impact of local penguin emissions on the atmospheric budget of several oxygenated volatile organic compounds. The second paper reports on HONO levels that were measured for the first time in Antarctica by using the long path absorption photometer (LOPAP) technique. Finally, in a third paper, major findings on the HOx levels are detailed, leading to the overall conclusion that the photochemistry at coastal East Antarctica is strongly driven by an efficient HOx chemistry compared to the situation at other coastal Antarctic regions.

Published
2012

34. Snow accumulation variability in Adelie Land (East Antarctica) derived from radar and firn core data. A 600 km transect from Dome C

Author

Michel Fily, Olivier Magand, E. Le Meur, Vincent Favier, Deborah Verfaillie, Laurent Arnaud, and Bruno Jourdain

Subjects
Dome (geology), Oceanography, law, Firn, East antarctica, Radar, Snow, Transect, Geology, law.invention
Abstract

Polar ice sheets mass balance is a timely topic intensively studied in the context of global change and sea-level rise. However, obtaining mass balance estimates in Antarctica in particular, remains difficult due to various logistical problems. In the framework of the TASTE-IDEA program, labeled as an International Polar Year project, continuous Ground Penetrating Radar (GPR) measurements were carried out during a traverse realised in Adelie Land (East Antarctica) during the 2008–2009 austral summer between the Italo-French Dome C (DC) polar plateau site and French Dumont D'Urville (DdU) coastal station. The aim of this study was to process and interpret GPR data in terms of snow accumulation, to analyse its spatial and temporal variability along the DC-DdU traverse and compare it with historical data and modeling. The emphasis has been put on the last 300 yr, from the pre-industrial to recent time period. Beta-radioactivity counting and gamma spectrometry were studied in cores at LGGE laboratory, providing a depth-age calibration for radar measurements. Over the 600 km of usable GPR data, depth and snow accumulation were determined with the help of three distinct layers visible on the radargrams (≈1730, 1799 and 1941 AD). Preliminary results reveal a gradual accumulation increase towards the coast and the occurrence of previously undocumented undulating structures between 300 and 600 km from DC. Results agree fairly well with data from previous studies and modeling. Concluding on temporal variations is difficult because of the margin of error introduced by density estimation. This study should have various applications such as for model validation.

Published
2012

35. A reassessment of the budget of formic and acetic acids in the boundary layer at Dumont d'Urville (coastal Antarctica): The role of penguin emissions on the budget of several oxygenated volatile organic compounds

Author

Susanne Preunkert, Guillaume Pépy, Roland Sarda-Esteve, Bruno Jourdain, Michel Legrand, Anne-Mathilde Thierry, and Valérie Gros

Subjects
Atmospheric Science, 010504 meteorology & atmospheric sciences, Formic acid, Soil Science, 010501 environmental sciences, Aquatic Science, Oceanography, 01 natural sciences, Oxalate, Acetic acid, chemistry.chemical_compound, Ammonia, Geochemistry and Petrology, Earth and Planetary Sciences (miscellaneous), Acetone, 14. Life underwater, 0105 earth and related environmental sciences, Earth-Surface Processes, Water Science and Technology, Ecology, Acetaldehyde, Paleontology, Forestry, Decomposition, Geophysics, chemistry, 13. Climate action, Space and Planetary Science, Climatology, Environmental chemistry, Guano, Environmental science
Abstract

[1] Initiated in 1997, the year-round study of formic and acetic acids was maintained until 2011 at the coastal Antarctic site of Dumont d'Urville. The records show that formic and acetic acids are rather abundant in summer with typical mixing ratios of 200 pptv and 700 pptv, respectively. With the aim to constrain their budget, investigations of their potential marine precursors like short-chain alkenes and acetaldehyde were initiated in 2011. Acetic acid levels in December 2010 were four times higher than those observed over summers back to 1997. These unusually high levels were accompanied by unusually high levels of ammonia, and by an enrichment of oxalate in aerosols. These observations suggest that the guano decomposition in the large penguin colonies present at the site was particularly strong under weather conditions encountered in spring 2010 (important snow storms followed by sunny days with mild temperatures). Although being dependent on environmental conditions, this process greatly impacts the local atmospheric budget of acetic acid, acetaldehyde, and acetone during the entire summer season. Present at levels as high as 500 pptv, acetaldehyde may represent the major precursor of acetic acid, alkene-ozone reactions remaining insignificant sources. Far less influenced by penguin emissions, the budget of formic acid remains not fully understood even if alkene-ozone reactions contribute significantly.

Published
2012

36. Assessing the suitability of Scarisoara cave ice for glaciochemical research: a coupled chemical and water isotopic approach

Author

Daniel VERES, Joël SAVARINO, Bruno JOURDAIN, Bogdan P. ONAC, Ferenc FORRAY, Mihaly MOLNAR, Robert BEGY, and Patrick GINOT

Subjects
Q1-390, Science (General), Science
Abstract

Lacustrine sediments are excellent sources of palaeoenvironmental and palaeoclimatic information because they usually provide continuous and high-resolution records. In centraleastern Europe however lacustrine records that extend beyond the Holocene are rather sparse.Palaeomagnetic records from this region are also insufficiently explored, and usually associated with terrestrial deposits such as loess. In this context, the lacustrine record of Lake Sf. Ana, a volcanic crater lake in the East Carpathians, Romania, provides an important archive for reconstructing past paleomagnetic secular variation in the region from early Holocene to late Marine Isotope Stage (MIS) 3.

Published
2014

37. The atmospheric HCHO budget at Dumont d'Urville (East Antarctica): Contribution of photochemical gas-phase production versus snow emissions

Author

Susanne Preunkert, Hubert Gallée, Guillaume Pépy, Bruno Jourdain, Anna E. Jones, and Michel Legrand

Subjects
Atmospheric Science, geography, geography.geographical_feature_category, Planetary boundary layer, East antarctica, Photochemistry, Snow, Methane, Sink (geography), Gas phase, chemistry.chemical_compound, Geophysics, chemistry, Space and Planetary Science, Climatology, Anaerobic oxidation of methane, Earth and Planetary Sciences (miscellaneous), Dimethyl sulfide
Abstract

[1] HCHO was monitored throughout the year 2009 at the coastal East Antarctic site of Dumont d'Urville (DDU) using Aerolaser AL-4021 analyzers. The accurate determination of less than 100 pptv required optimization of the analyzers, in particular, to minimize effects of changing ambient temperatures. The impact of station activities and of the presence of large penguin colonies at the site in summer was scrutinized. The obtained contamination-free record indicates monthly means close to 50 pptv from May to September and a maximum of 200 pptv in January. Zero-dimensional and 2-D calculations suggest that in summer, the largest HCHO source is the gas-phase photochemistry (80%) mainly driven by methane oxidation, which is considerably greater than from snow emissions (20%). The influence of light alkenes, dimethyl sulfide, and halogens remains weak. In winter, snow emissions represent the main HCHO source (70%). These findings are compared to previous studies conducted at the West Antarctic coast. It is shown that in summer the HCHO production from methane chemistry is 3 times more efficient at DDU than at the west coast due to more frequent arrival of oxidant-rich air masses from inland Antarctica. Halogen chemistry is found to represent a weak HCHO sink at both West and East Antarctica. Compared to DDU, the shallower atmospheric boundary layer and the less efficient gas-phase production at the west coast make the snow pack the dominant HCHO source (85%) compared to gas-phase photochemistry (15%) there in summer.

Published
2013

38. Year-round record of size-segregated aerosol composition in central Antarctica (Concordia station): Implications for the degree of fractionation of sea-salt particles

Author

Susanne Preunkert, Hélène Castebrunet, Roberto Udisti, Bruno Jourdain, Michel Legrand, O. Cerri, Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS), Department of Chemistry, Università degli Studi di Firenze = University of Florence [Firenze] (UNIFI), Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS), University of Florence (UNIFI), and Department of Chemistry 'Ugo Schiff'

Subjects
Atmospheric Science, food.ingredient, 010504 meteorology & atmospheric sciences, [SDE.MCG]Environmental Sciences/Global Changes, Soil Science, 010501 environmental sciences, Aquatic Science, Oceanography, 01 natural sciences, Central Antarctica, chemistry.chemical_compound, food, Ice core, Geochemistry and Petrology, Earth and Planetary Sciences (miscellaneous), Sea ice, [SDU.STU.GL]Sciences of the Universe [physics]/Earth Sciences/Glaciology, 14. Life underwater, Sulfate, sea-salt fractionation, 0105 earth and related environmental sciences, Earth-Surface Processes, Water Science and Technology, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, geography, geography.geographical_feature_category, Plateau, Ecology, Sea salt, Paleontology, Forestry, Snow, size segregated aerosol, Aerosol, Geophysics, chemistry, [SDU]Sciences of the Universe [physics], 13. Climate action, Space and Planetary Science, [SDE]Environmental Sciences, Seawater, Geology
Abstract

International audience; The origin of sea-salt aerosol that reaches the high Antarctic plateau and is trapped in snow and ice cores remains still unclear. In particular, the respective role of emissions from the open ocean versus those from the sea-ice surface is not yet quantified. To progress on this question, the composition of bulk and size-segregated aerosol was studied in 2006 at the Concordia station (75°S, 123°E) located on the high Antarctic plateau. A depletion of sulfate relative to sodium with respect to the seawater composition is observed on sea-salt aerosol reaching Concordia from April to September. That suggests that in winter, when the sea-salt atmospheric load reaches a maximum, emissions from the sea-ice surface significantly contribute to the sea-salt budget of inland Antarctica. Citation: Jourdain, B., S. Preunkert, O. Cerri, H. Castebrunet, R. Udisti, and M. Legrand (2008), Year-round record of size-segregated aerosol composition in central Antarctica (Concordia station): Implications for the degree of fractionation of sea-salt particles

Published
2008

39. Seasonality of sulfur species (dimethyl sulfide, sulfate, and methanesulfonate) in Antarctica: Inland versus coastal regions

Author

Michel Legrand, Silvia Becagli, Bruno Jourdain, Roberto Udisti, O. Cerri, Susanne Preunkert, Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS), Department of Chemistry, Università degli Studi di Firenze = University of Florence [Firenze] (UNIFI), Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS), and University of Florence (UNIFI)

Subjects
Atmospheric Science, 010504 meteorology & atmospheric sciences, Soil Science, chemistry.chemical_element, 010501 environmental sciences, Aquatic Science, Oceanography, 01 natural sciences, chemistry.chemical_compound, Ice core, Geochemistry and Petrology, sulfur cycle, Earth and Planetary Sciences (miscellaneous), medicine, Mixing ratio, [SDU.STU.GL]Sciences of the Universe [physics]/Earth Sciences/Glaciology, Sulfate, 0105 earth and related environmental sciences, Earth-Surface Processes, Water Science and Technology, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, Ecology, DMS, fungi, Paleontology, Sulfur cycle, Forestry, Seasonality, medicine.disease, Sulfur, Aerosol, Geophysics, chemistry, 13. Climate action, Space and Planetary Science, Dimethyl sulfide, Geology
Abstract

International audience; To gain a better understanding of sulfate and methanesulfonate (MS−) signals recorded in central Antarctic ice cores in terms of past atmospheric changes, an atmospheric year-round study of these aerosols was performed in 2006 at the Concordia station (75°S, 123°E) located on the high Antarctic plateau. In addition, a year-round study of dimethyl sulfide (DMS), the gaseous precursor of sulfur aerosol, was conducted in 2007. The DMS mixing ratio remains below 1 pptv from October to January and exhibits a maximum of 10 pptv during the first half of winter (from April to July). Surprisingly, the well-marked maximum of sulfur aerosol recorded in January at coastal Antarctic sites is observed at Concordia for sulfate but not for MS− which peaks before and after sulfate in November and March, respectively. This first study of DMS and of its by-oxidation aerosol species conducted at inland Antarctica points out the complex coupling between transport and photochemistry of sulfur species over Antarctica. The findings highlight the complexity of the link between MS− ice core records extracted at high Antarctic plateau sites and DMS emissions from the Southern ocean.

Published
2008

40. Biogas (CO2, O2, dimethylsulfide) dynamics in spring Antarctic fast ice

Author

Daniel Delille, Bruno Delille, Alberto Borges, Jean-Louis Tison, and Bruno Jourdain

Subjects
0106 biological sciences, geography, Chlorophyll a, geography.geographical_feature_category, 010504 meteorology & atmospheric sciences, Ice crystals, 010604 marine biology & hydrobiology, Brine rejection, Aquatic Science, Oceanography, 01 natural sciences, Sink (geography), chemistry.chemical_compound, chemistry, Fast ice, 13. Climate action, Environmental chemistry, Carbon dioxide, Sea ice, Carbonate, Environmental science, 14. Life underwater, 0105 earth and related environmental sciences
Abstract

We studied the temporal variations of CO2, O2, and dimethylsulfide (DMS) concentrations within three environments (sea-ice brine, platelet ice-like layer, and underlying water) in the coastal area of Adelie Land, Antarctica, during spring 1999 before ice breakup. Temporal changes were different among the three environments, while similar temporal trends were observed within each environment at all stations. The underlying water was always undersaturated in O2 (around 85%) and oversaturated in CO2 at the deepest stations. O2 concentrations increased in sea-ice brine as it melted, reaching oversaturation up to 160% due to the primary production by the sea-ice algae community (chlorophyll a in the bottom ice reached concentrations up to 160 µg L-1 of bulk ice). In parallel, DMS concentrations increased up to 60 nmol L-1 within sea- ice brine and the platelet ice- like layer. High biological activity consumed CO2 and promoted the decrease of partial pressure of CO2 (pCO2). In addition, melting of pure ice crystals and calcium carbonate (CaCO3) dissolution promoted the shift from a state of CO2 oversaturation to a state of marked CO2 undersaturation (pCO2 < 30 dPa). On the whole, our results suggest that late spring land fast sea ice can potentially act as a sink of CO2 and a source of DMS for the neighbouring environments, i.e., the underlying water or/ and the atmosphere.

Published
2007

41. Interannual variability of dimethylsulfide in air and seawater and its atmospheric oxidation by-products (methanesulfonate and sulfate) at Dumont d'Urville, coastal Antarctica (1999–2003)

Author

Toru Hirawake, Michel Legrand, Mitsuo Fukuchi, Sauveur Belviso, Susanne Preunkert, Bruno Jourdain, Cyril Moulin, Nobue Kasamatsu, Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), ICOS-RAMCES (ICOS-RAMCES), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), National Institute of Polar Research [Tokyo] (NiPR), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS), and Université Paris-Saclay-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS)

Subjects
Atmospheric Science, Chlorophyll a, food.ingredient, 010504 meteorology & atmospheric sciences, Soil Science, 010501 environmental sciences, Aquatic Science, Oceanography, 01 natural sciences, Methanesulfonic acid, chemistry.chemical_compound, food, Geochemistry and Petrology, sulfur cycle, Earth and Planetary Sciences (miscellaneous), [SDU.STU.GL]Sciences of the Universe [physics]/Earth Sciences/Glaciology, Sulfate, 0105 earth and related environmental sciences, Earth-Surface Processes, Water Science and Technology, Ecology, Sea salt, Paleontology, Sulfur cycle, Forestry, Geophysics, SeaWiFS, chemistry, 13. Climate action, Space and Planetary Science, Environmental science, Antarctica, Dimethyl sulfide, Seawater, dimethylsulfure
Abstract

International audience; A multiple year-round study of atmospheric dimethyl sulfide (DMS) (from December 1998 to April 2003) as well as sulfur-derived aerosols (methanesulfonic acid (MSA) and non-sea-salt sulfate) (from March 1991 to February 2003) was conducted at Dumont d'Urville, coastal Antarctica. The three sulfur-derived species exhibit a seasonal cycle characterized by maxima in midsummer (January). Whereas the interannual variability of winter levels remains low, a strong interannual variability is shown in summer, particularly for DMS and MSA, and to a lesser extent for non-sea-salt sulfate. Over the 1998–2003 time period, January 2002 stands out with high values for all sulfur species. These interannual variabilities of atmospheric summer levels are examined in the light of seawater chlorophyll a content derived from Sea-viewing Wide Field-of-view Sensor (SeaWiFS) data (themselves compared to field measurements made south of 60°S), oceanic DMS levels estimated from chlorophyll a SeaWiFS data, and various sea-ice indices.

Published
2007

42. Seasonal variations of triple oxygen isotopic compositions of tmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica.

Author

Sakiko Ishino, Shohei Hattori, Joel Savarino, Bruno Jourdain, Susanne Preunkert, Legrand, Michel, Caillon, Nicolas, Barbero, Albane, Kota Kuribayashi, and Naohiro Yoshida

Subjects
OXYGEN compounds, OZONE generators, SULFATES & the environment, ATMOSPHERIC chemistry, OXIDATION
Abstract

Triple oxygen isotopic compositions (Δ17O = δ17O - 0.52 x δ18O) of atmospheric sulfate (SO2-4) and nitrate (NO-3) in the atmosphere reflect the relative contribution of oxidation pathways involved in their formation processes, which potentially provides information to reveal missing reactions in atmospheric chemistry models. However, there remain many theoretical assumptions for the controlling factors of Δ17O(SO2-4) and Δ17O(NO-3) values in those model estimations. To test one of those assumption that Δ17O values of ozone (O3) have a flat value and do not influence the seasonality of Δ17O(SO2-4) and Δ17O(NO-3) values, we performed the first simultaneous measurement of Δ17O values of atmospheric sulfate, nitrate, and ozone collected at Dumont d'Urville (DDU) Station (66δ400´ S, 140δ01´ E) throughout 2011. Δ17O values of sulfate and nitrate exhibited seasonal variation characterized by minima in the austral summer and maxima in winter, within the ranges of 0.9-3.4 and 23.0-41.9%, respectively. In contrast, Δ17O values of ozone showed no significant seasonal variation, with values of 26±1% throughout the year. These contrasting seasonal trends suggest that seasonality in Δ17O(SO2-4) and Δ17O(NO-3) values is not the result of changes in Δ17O(O3), but of the changes in oxidation chemistry. The trends with summer minima and winter maxima for Δ17O(SO2-4) and Δ17O(NO-3) values are caused by sunlight-driven changes in the relative contribution of O3 oxidation to the oxidation by HOx, ROx, and H2O2. In addition to that general trend, by comparing Δ17O(SO2-4) and Δ17O(NO-3) values to ozone mixing ratios, we found that Δ17O(SO2-4) values observed in spring (September to November) were lower than in fall (March to May), while there was no significant spring and fall difference in Δ17O(NO-3) values. The relatively lower sensitivity of Δ17O(SO2-4) values to the ozone mixing ratio in spring compared to fall is possibly explained by (i) the increased contribution of SO2 oxidations by OH and H2O2 caused by NOx emission from snowpack and/or (ii) SO2 oxidation by hypohalous acids (HOX = HOC1 + HOBr) in the aqueous phase. [ABSTRACT FROM AUTHOR]

Published
2017
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43. Year-round records of gas and particulate formic and acetic acids in the boundary layer at Dumont d'Urville, coastal Antarctica

Author

Susanne Preunkert, Bruno Jourdain, Bernard Aumont, and Michel Legrand

Subjects
Atmospheric Science, Ozone, Ecology, Formic acid, Paleontology, Soil Science, Forestry, Aquatic Science, Particulates, Oceanography, Aerosol, chemistry.chemical_compound, Acetic acid, Geophysics, chemistry, Space and Planetary Science, Geochemistry and Petrology, Environmental chemistry, Climatology, Dissolved organic carbon, Earth and Planetary Sciences (miscellaneous), Mixing ratio, Formate, Earth-Surface Processes, Water Science and Technology
Abstract

[1] Multiple year-round levels of acetate and formate in gas and aerosol phases were investigated at Dumont d'Urville (DDU, a coastal Antarctic site) by using mist chamber and aerosol filter sampling. Formate and acetate aerosol levels range from

Published
2004

44. Year-round records of bulk and size-segregated aerosol composition and HCl and HNO3levels in the Dumont d'Urville (coastal Antarctica) atmosphere: Implications for sea-salt aerosol fractionation in the winter and summer

Author

Michel Legrand and Bruno Jourdain

Subjects
Atmospheric Science, food.ingredient, Mirabilite, Soil Science, Aquatic Science, Oceanography, Chloride, chemistry.chemical_compound, food, Geochemistry and Petrology, Earth and Planetary Sciences (miscellaneous), medicine, Sulfate, Sea salt aerosol, Earth-Surface Processes, Water Science and Technology, Ecology, Sea salt, Paleontology, Forestry, Aerosol, Geophysics, chemistry, Space and Planetary Science, Environmental chemistry, Environmental science, Dimethyl sulfide, Seawater, medicine.drug
Abstract

[1] Year-round composition of bulk and size-segregated aerosol was examined at a coastal Antarctic site (Dumont d'Urville). Sea-salt particles display a summer depletion of chloride relative to sodium, which reaches ∼10%. The mass chloride loss is maximum on 1- to 3-μm-diameter particles, nitrate being often the anion causing the chloride loss. The summer SO42−/Na+ ratio exceeds the seawater value on submicron particles due to biogenic sulfate and on coarse particles due to ornithogenic (guano-enriched soils) sulfate and to heterogeneous uptake of SO2 (or H2SO4). HCl levels range from 47 ± 28 ng m−3 in the winter to 130 ± 110 ng m−3 in the summer, being close to the mass chloride loss of sea-salt aerosols. In the winter, sea-salt particles exhibit Cl−/Na+ and SO42−/Na+ mass ratios of 1.9 ± 0.1 and 0.13 ± 0.04, respectively. Resulting from precipitation of mirabilite during freezing of seawater, this sulfate-depletion-relative sodium takes place from May to October. From March to April, warmer temperatures and/or smaller sea ice extent offshore the site limit the phenomenon. A range of 14–50 ng m−3 of submicron sulfate is found, confirming the existence of nssSO42− in the winter at a coastal Antarctic site, highest values being found in the winters of 1992–1994 due to the Pinatubo volcanic input. Apart from these three winters, nssSO42− levels range between 15 and 30 ng m−3, but its origin is still unclear (quasi-continuous SO2 emissions from the Mount Erebus volcano or local wintertime dimethyl sulfide [DMS] oxidation, in addition to long-range transported by-product of DMS oxidation).

Published
2002

45. Subdaily variations of atmospheric dimethylsulfide, dimethylsulfoxide, methanesulfonate, and non-sea-salt sulfate aerosols in the atmospheric boundary layer at Dumont d'Urville (coastal Antarctica) during summer

Author

Jean Sciare, Bruno Jourdain, Michel Legrand, Christophe Genthon, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Chimie Atmosphérique Expérimentale (CAE), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), and Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)

Subjects
Atmospheric Science, food.ingredient, 010504 meteorology & atmospheric sciences, Soil Science, 010501 environmental sciences, Aquatic Science, Oceanography, 01 natural sciences, Methanesulfonic acid, Troposphere, chemistry.chemical_compound, food, Geochemistry and Petrology, Earth and Planetary Sciences (miscellaneous), Mixing ratio, Sulfate, [SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment, 0105 earth and related environmental sciences, Earth-Surface Processes, Water Science and Technology, [SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere, Ecology, Sea salt, Paleontology, Forestry, Particulates, Aerosol, Geophysics, chemistry, 13. Climate action, Space and Planetary Science, Climatology, Environmental chemistry, Dimethyl sulfide
Abstract

A study of atmospheric dimethylsulfide (DMS) and dimethylsulfoxide (DMSO) was conducted on a subdaily basis during austral summer months (450 samples from mid-December 1998 to late-February 1999) at Dumont d'Urville, a coastal Antarctic site (66° 40′S, 140° 01′E). In addition, subdaily aerosol samplings were analyzed for particulate methanesulfonate (MSA) and non-sea-salt sulfate (nssSO42−). During these summer months, DMS and DMSO levels fluctuated from 34 to 2923 pptv (mean of 290±305 pptv) and from 0.4 to 57 pptv (mean of 3.4±4.4 pptv), respectively. Mean MSA and non-sea-salt sulfate (nssSO42−) mixing ratios were close to 12.5±8.2 pptv and 68.1±35.0 pptv, respectively. In two occasions characterized by stable wind conditions and intense insolation, it was possible to examine the local photochemistry of DMS. During these events, DMSO levels tracked quite closely the solar flux and particulate MSA levels were enhanced during the afternoons. Photochemical calculations reproduce quite well observed diurnal variations of DMSO when we assume an 0.8 yield of DMSO from the DMS/OH addition channel and an heterogeneous loss rate of DMSO proportional to the OH radical concentration: 0.5×10−10 [OH] + 5.5x10−5 (in s−1). If correct, on a 24 hour average the heterogeneous loss of DMSO is estimated to be 2 times faster than the DMSO/OH gas phase oxidation in these regions. Very low levels of DMSO were found in the aerosol phase (less than 0.01 pptv), suggesting that an efficient oxidation of DMSO subsequently takes place onto the aerosol surface. The observed increase of MSA levels which takes place quasi-immediately after the noon DMSO maximum suggests that an heterogeneous oxidation of DMSO onto aerosols represents a more efficient pathway producing MSA compared to the gas phase DMSO/OH pathway. Since only a third of the total amount of DMSO lost can be explained by the observed enhancement of MSA levels, further studies investigating other species including methanesulfinic acid and dimethylsulfone (DMSO2) formed during the oxidation of DMS are here needed. When katabatic winds took place, bringing continental Antarctic air at the site, enrichments of DMSO relative to DMS and MSA relative to non-sea-salt sulfate levels were observed. That is in agreement with the hypothesis of an accumulation of DMSO and probably of gaseous MSA in the free Antarctic troposphere in relation to a less efficient heterogeneous loss rate of DMSO.

Published
2001

46. OH and RO2 radicals at Dome C (East Antarctica): first observations and assessment of photochemical budget

Author

Alexandre Kukui, Rodrigue Loisil, Michael Kerbrat, Markus Frey, Jaime Gil, Bruno Jourdain, Gérard Ancellet, Slimane Bekki, Michel Legrand, Susanne Preunkert, Laboratoire de Physique et Chimie de l'Environnement et de l'Espace (LPC2E), Observatoire des Sciences de l'Univers en région Centre (OSUC), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Université d'Orléans (UO)-Centre National de la Recherche Scientifique (CNRS)-Centre National d’Études Spatiales [Paris] (CNES), Division technique INSU/SDU (DTI), Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Institut de chimie et procédés pour l'énergie, l'environnement et la santé (ICPEES), Université de Strasbourg (UNISTRA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Matériaux et Nanosciences Grand-Est (MNGE), Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS), Centre Alpin de Recherche sur les Réseaux Trophiques et Ecosystèmes Limniques (CARRTEL), Institut National de la Recherche Agronomique (INRA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry]), Centre d'Enseignement et de Recherche en Mathématiques et Calcul Scientifique (CERMICS), École des Ponts ParisTech (ENPC), TROPO - LATMOS, Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), STRATO - LATMOS, Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université d'Orléans (UO)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National d’Études Spatiales [Paris] (CNES), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS), Université de Strasbourg (UNISTRA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Matériaux et nanosciences d'Alsace (FMNGE), and Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)

Subjects
[SDU]Sciences of the Universe [physics]
Abstract

International audience; Measurements of OH and total peroxy RO 2 (HO 2 + organic peroxy) radicals were performed in December 2011/January 2012 at the Dome C Concordia station (East Antarctica, 75.1˚S / 123.3˚E) in the frame of the Oxi-dant Production over Antarctic Land and its Export (OPALE) project. The goal of these first on the East Antarctica plateau radical measurements was to estimate the oxidative capacity and assess the role of snow emissions on the radical budget in this part of Antarctica. The OH concentration levels were found to be in general similar to those observed at South Pole. However, based on the analysis of the OH sources and sinks derived from the available measurements of NO x , HONO, HCHO, H 2 O 2 and others, it has been concluded that, in contrast to South Pole, the photolysis of HONO is the major OH source at Dome C site. The role of HONO as the major source of OH is also supported by an excellent correlation of OH with the production rate of OH from the HONO photolysis. The observed diurnal profiles of OH and RO 2 are discussed in relation with boundary dynamics and the variability of photolysis and snow emissions rates.

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