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This work aims to utilize the increased sensitivity and resolution of the JWST to quantify the HDO/H$_{2}$O ratio in ices toward young stellar objects (YSOs) and to determine if the HDO/H$_{2}$O ratios measured in the gas phase toward massive YSOs (MYSOs) are representative of the ratios in their ice envelopes. Two protostars observed in the Investigating Protostellar Accretion (IPA) program using JWST NIRSpec were analyzed: HOPS 370, an intermediate-mass YSO (IMYSO), and IRAS 20126+4104, a MYSO. The HDO ice toward these sources was detected above the 3$\sigma$ level and quantified via its 4.1 $\mu$m band. The contributions from the CH$_{3}$OH combination modes to the observed optical depth in this spectral region were constrained via the CH$_{3}$OH 3.53 $\mu$m band to ensure that the integrated optical depth of the HDO feature was not overestimated. H$_{2}$O ice was quantified via its 3 $\mu$m band. From these fits, ice HDO/H$_{2}$O abundance ratios of 4.6$\pm$1.8$\times$10$^{-3}$ and 2.6$\pm$1.2$\times$10$^{-3}$ are obtained for HOPS 370 and IRAS 20126+4104, respectively. The simultaneous detections of both crystalline HDO and crystalline H$_{2}$O corroborate the assignment of the observed feature at 4.1 $\mu$m to HDO ice. The ice HDO/H$_{2}$O ratios are similar to the highest reported gas HDO/H$_{2}$O ratios measured toward MYSOs as well as the hot inner regions of isolated low-mass protostars, suggesting that at least some of the gas HDO/H$_{2}$O ratios measured toward massive hot cores are representative of the HDO/H$_{2}$O ratios in ices. The need for an H$_{2}$O-rich CH$_{3}$OH component in the CH$_{3}$OH ice analysis supports recent experimental and observational results that indicate that some CH$_{3}$OH ice may form prior to the CO freeze-out stage in H$_{2}$O-rich ice layers., Comment: Accepted for publication in A&A. 23 pages, 17 figures, 10 tables

Accretion and ejection sets the outcome of the star and planet formation process. The mid-infrared wavelength range offers key tracers of those processes that were difficult to detect and spatially resolve in protostars until now. We aim to characterize the interplay between accretion and ejection in the low-mass Class I protobinary system TMC1, comprising two young stellar objects: TMC1-W and TMC1-E with 85 au separation. With the {\it James Webb} Space Telescope (JWST) - Mid-Infrared Instrument (MIRI) observations in 5 - 28 $\mu$m range, we measure intensities of emission lines of H$_2$, atoms and ions, e.g., [Fe II] and [Ne II], and HI recombination lines. We detect H$_2$ outflow coming from TMC1-E, with no significant H$_2$ emission from TMC1-W. The H$_2$ emission from TMC1-E outflow appears narrow and extends to wider opening angles with decreasing E$_{up}$ from S(8) to S(1) rotational transitions, indicating a disk wind origin. The outflow from TMC1-E protostar shows spatially extended emission lines of [Ne II], [Ne III], [Ar II], and [Ar III], with their line ratios consistent with UV radiation as a source of ionization. With ALMA, we detect accretion streamer infalling from $>$ 1000 au scales onto the TMC1-E component. TMC1-W protostar powers a collimated jet, detected with [Fe II] and [Ni II] consistent with energetic flow. A much weaker ionized jet is observed from TMC1-E. TMC1-W is associated with strong emission from hydrogen recombination lines, tracing the accretion onto the young star. Observations of a binary Class I protostellar system show that the two processes are clearly intertwined, with accretion from the envelope onto the disk influencing a wide-angle wind ejected on disk scales, while accretion from the protostellar disk onto the protostar is associated with the source launching a collimated high-velocity jet within the innermost regions of the disk., Comment: 18 pages, 13 figures, accepted for publication in Astronomy and Astrophysics

The structure and composition of simple ices can be modified during stellar evolution by protostellar heating. Key to understanding the involved processes are thermal and chemical tracers that can diagnose the history and environment of the ice. The 15.2 $\mu$m bending mode of $^{12}$CO$_2$ has proven to be a valuable tracer of ice heating events but suffers from grain shape and size effects. A viable alternative tracer is the weaker $^{13}$CO$_2$ isotopologue band at 4.39 $\mu$m which has now become accessible at high S/N with the $\textit{James Webb}$ Space Telescope (JWST). We present JWST NIRSpec observations of $^{13}$CO$_2$ ice in five deeply embedded Class 0 sources spanning a wide range in luminosities (0.2 - 10$^4$ L$_{\odot}$ ) taken as part of the Investigating Protostellar Accretion Across the Mass Spectrum (IPA) program. The band profiles vary significantly, with the most luminous sources showing a distinct narrow peak at 4.38 $\mu$m. We first apply a phenomenological approach and show that a minimum of 3-4 Gaussian profiles are needed to fit the $^{13}$CO$_2$ absorption feature. We then combine these findings with laboratory data and show that a 15.2 $\mu$m $^{12}$CO$_2$ band inspired five-component decomposition can be applied for the isotopologue band where each component is representative of CO$_2$ ice in a specific molecular environment. The final solution consists of cold mixtures of CO$_2$ with CH$_3$OH, H$_2$O and CO as well as segregated heated pure CO$_2$ ice. Our results are in agreement with previous studies of the $^{12}$CO$_2$ ice band, further confirming that $^{13}$CO$_{2}$ is a useful alternative tracer of protostellar heating events. We also propose an alternative solution consisting only of heated CO$_2$:CH$_3$OH and CO$_2$:H$_2$O ices and warm pure CO$_2$ ice for decomposing the ice profiles of the two most luminous sources in our sample.

We investigate the bright CO fundamental emission in the central regions of five protostars in their primary mass assembly phase using new observations from JWST's Near-Infrared Spectrograph (NIRSpec) and Mid-Infrared Instrument (MIRI). CO line emission images and fluxes are extracted for a forest of $\sim$150 ro-vibrational transitions from two vibrational bands, $v=1-0$ and $v=2-1$. However, ${}^{13}$CO is undetected, indicating that ${}^{12}$CO emission is optically thin. We use H$_2$ emission lines to correct fluxes for extinction and then construct rotation diagrams for the CO lines with the highest spectral resolution and sensitivity to estimate rotational temperatures and numbers of CO molecules. Two distinct rotational temperature components are required for $v=1$ ($\sim600$ to 1000 K and 2000 to $\sim 10^4$ K), while one hotter component is required for $v=2$ ($\gtrsim 3500$ K). ${}^{13}$CO is depleted compared to the abundances found in the ISM, indicating selective UV photodissociation of ${}^{13}$CO; therefore, UV radiative pumping may explain the higher rotational temperatures in $v=2$. The average vibrational temperature is $\sim 1000$ K for our sources and is similar to the lowest rotational temperature components. Using the measured rotational and vibrational temperatures to infer a total number of CO molecules, we find that the total gas masses range from lower limits of $\sim10^{22}$ g for the lowest mass protostars to $\sim 10^{26}$ g for the highest mass protostars. Our gas mass lower limits are compatible with those in more evolved systems, which suggest the lowest rotational temperature component comes from the inner disk, scattered into our line of sight, but we also cannot exclude the contribution to the CO emission from disk winds for higher mass targets., Comment: 31 pages, 7 figures, 4 tables, received to ApJ December 10 2023, accepted to ApJ August 4 2024

The complex organic molecules (COMs) detected in star-forming regions are the precursors of the prebiotic molecules that can lead to the emergence of life. By studying COMs in more evolved protoplanetary disks we can gain a better understanding of how they are incorporated into planets. This paper presents ALMA band 7 observations of the dust and ice trap in the protoplanetary disk around Oph IRS 48. We report the first detection of dimethyl ether (CH3OCH3) in a planet-forming disk and a tentative detection of methyl formate (CH3OCHO). We determined column densities for the detected molecules and upper limits on non-detected species using the CASSIS spectral analysis tool. The inferred column densities of CH3OCH3 and CH3OCHO with respect to methanol (CH3OH) are of order unity, indicating unusually high abundances of these species compared to other environments. Alternatively, the 12CH3OH emission is optically thick and beam diluted, implying a higher CH3OH column density and a smaller emitting area than originally thought. The presence of these complex molecules can be explained by thermal ice sublimation, where the dust cavity edge is heated by irradiation and the full volatile ice content is observable in the gas phase. This work confirms the presence of oxygen-bearing molecules more complex than CH3OH in protoplanetary disks for the first time. It also shows that it is indeed possible to trace the full interstellar journey of COMs across the different evolutionary stages of star, disk, and planet formation., Comment: Accepted to A&A - 20th Jan 2022